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Among the small cation sized rare earth sesquioxides, the reported transition pressure of cubic Tm2O3 is ambiguous. Pressure induced structural phase transition in cubic Tm2O3 has been reinvestigated using the synchrotron X-ray diffraction, Raman spectroscopy, and ab initio density functional theory (DFT) calculations up to a pressure of 25 GPa. Both the X-ray diffraction and Raman spectroscopic measurements revealed an irreversible polymorphic structural phase transition from type-C cubic to type-B monoclinic at around 12 GPa, whereas the same is predicted to be 8 GPa from the density functional theory. The phase transition observed at 12 GPa is in contrast to the literature and the reasoning has been established by other studies, viz., Raman spectroscopy and DFT. A third order Birch-Murnaghan equation of state fit to the experimental compressibility curve yielded a zero pressure bulk modulus of 149(2) GPa with the pressure derivatives 4.8(5) for the parent cubic phase and 169(2) GPa with the pressure derivative 4 for the high pressure monoclinic phase, respectively. These values are in good agreement with the calculated bulk modulus of 146 and 151 GPa for the cubic and monoclinic phases, respectively. Raman modes for the monoclinic phase of Tm2O3 are measured and reported for the first time. The mode Grüneisen parameter of different Raman modes for both cubic and monoclinic phases of Tm2O3 has also been determined. The experimental results are correlated with changes in the density of states near the Fermi level, which are indicative of structural instabilities in the parent cubic structure. [ABSTRACT FROM AUTHOR]

High-pressure X-ray diffraction has been performed on UGa2 up to 20 GPa using a diamond anvil cell. UGa2 exhibits the AlB2-type structure with space group P6/mmm at room temperature and atmospheric pressure. At about 16 GPa a reversible structural transformation to a tetragonal phase was observed. The bulk modulus of the AlB2-type phase has been determined to be ∼100 GPa, which is comparable to rare earth digallides like TmGa2 and HoGa2. [ABSTRACT FROM AUTHOR]

High-pressure X-ray diffraction has been performed on UGa2 up to 20 GPa using a diamond anvil cell. UGa2 exhibits the AlB2-type structure with space group P6/mmm at room temperature and atmospheric pressure. At about 16 GPa a reversible structural transformation to a tetragonal phase was observed. The bulk modulus of the AlB2-type phase has been determined to be ∼100 GPa, which is comparable to rare earth digallides like TmGa2 and HoGa2. [ABSTRACT FROM AUTHOR]

We have investigated the structural stability of ThGa 2 under high pressures up to 62 GPa by performing X-ray powder diffraction studies in a diamond-anvil cell. ThGa 2 exhibits a tetragonal ThSi 2 -type structure at room temperature and pressure. At about 0.2 GPa the unit-cell volume drops significantly (4%) without any change in the structure. The tetragonal structure remains stable for pressures up to as high as 62 GPa. Possible reasons for the structural stability of ThGa 2 are discussed from the view point of the influence of the number of valence band electrons in stabilizing various crystal structures. [ABSTRACT FROM AUTHOR]