Search

We present the results of a molecular survey of long period comets C/2021 A1 (Leonard) and C/2022 E3 (ZTF). Comet C/2021 A1 was observed with the IRAM 30-m radio telescope in November-December 2021 before perihelion when it was closest to the Earth. We observed C/2022 E3 in January-February 2023 with the Odin 1-m space telescope and IRAM 30-m, shortly after its perihelion, and when it was closest to the Earth. Snapshots were obtained during 12-16 November 2021 period for comet C/2021 A1. Spectral surveys were undertaken over the 8-13 December 2021 period for comet C/2021 A1 (8, 16, and 61 GHz bandwidth in the 3 mm, 2 mm, and 1 mm window) and over the 3-7 February 2023 period for comet C/2022 E3 (25 and 61 GHz at 2 and 1mm). We report detections of 14 molecular species (HCN, HNC, CH3CN, HNCO, NH2CHO, CH3OH, H2CO, HCOOH, CH3CHO, H2S, CS, OCS, C2H5OH and aGg-(CH2OH)2 ) in both comets plus HC3N and CH2OHCHO marginally detected in C/2021 A1 and CO and H2O (with Odin detected in C/2022 E3. The spatial distribution of several species is investigated. Significant upper limits on the abundances of other molecules and isotopic ratios are also presented. The activity of comet C/2021 A1 did not vary significantly between 13 November and 13 December 2021. Short-term variability in the outgassing of comet C/2022 E3 on the order of +-20% is present and possibly linked to its 8h rotation period. Both comets exhibit rather low abundances relative to water for volatiles species such as CO (< 2%) and H2S (0.15%). Methanol is also rather depleted in comet C/2021 A1 (0.9%). Following their revised photo-destruction rates, HNCO and HCOOH abundances in comets have been reevaluated. Both molecules are relatively enriched in these two comets (0.2% relative to water). We cannot exclude that these species could be produced by the dissociation of ammonium salts., Comment: To be published in Astronomy & Astrophysics

The Odin satellite is now into its twentieth year of operation, much surpassing its design life of two years. One of its major pursuits was the search for and study of H2O in the Solar System and the Milky Way galaxy. Herschel has observed the central region of NGC 1365 in two positions, and both its SPIRE and PACS observations are available in the Herschel Science Archive. Herschel PACS images have been produced of the 70 and 160 micron infrared emission from the whole galaxy, and also of the cold dust distribution as obtained from the ratio of the 160 to 70 micron images. The Herschel SPIRE observations have been used to produce maps of the 557 GHz o-H2O, 752 GHz p-H2O, 691 GHz CO(6-5), 1037 GHz CO(9-8), 537 GHz CH, 835 GHz CH+, and the 1461 GHz NII lines; however, these observations have no effective velocity resolution. Odin has recently observed the 557 GHz o-H2O ground state line in the central region with high (5 km/s) spectral resolution. The emission and absorption of H2O at 557 GHz, with a velocity resolution of 5 km/s, has been marginally detected in NGC 1365 with Odin. The H2O is predominantly located in a shocked 15" (1.3 kpc) region near some central compact radio sources and hot-spot HII regions, close to the northeast component of the molecular torus surrounding the nucleus. An analysis of the H2O line intensities and velocities indicates that a shock-region is located here. This is corroborated by a statistical image deconvolution of our SEST CO(3-2) observations, yielding 5" resolution, and a study of our VLA HI absorption observations. Additionally, an enticing 20" HI ridge is found to extend south-southeast from the nucleus, coinciding in position with the southern edge of an OIII outflow cone, emanating from the nucleus. The molecular chemistry of the shocked central region is analyzed with special emphasis on the CO, H2O and CH, CH+ results., Comment: 25 pages, 11 figures

Comet Shoemaker-Levy 9 impacted Jupiter in July 1994, leaving its stratosphere with several new species, among them water vapor (H2O). With the aid of a photochemical model H2O can be used as a dynamical tracer in the jovian stratosphere. In this paper, we aim at constraining vertical eddy diffusion (Kzz) at the levels where H2O resides. We monitored the H2O disk-averaged emission at 556.936 GHz with the Odin space telescope between 2002 and 2019, covering nearly two decades. We analyzed the data with a combination of 1D photochemical and radiative transfer models to constrain vertical eddy diffusion in the stratosphere of Jupiter. The Odin observations show us that the emission of H2O has an almost linear decrease of about 40% between 2002 and 2019.We can only reproduce our time series if we increase the magnitude of Kzz in the pressure range where H2O diffuses downward from 2002 to 2019, i.e. from ~0.2 mbar to ~5 mbar. However, this modified Kzz is incompatible with hydrocarbon observations. We find that, even if allowance is made for the initially large abundances of H2O and CO at the impact latitudes, the photochemical conversion of H2O to CO2 is not sufficient to explain the progressive decline of the H2O line emission, suggestive of additional loss mechanisms. The Kzz we derived from the Odin observations of H2O can only be viewed as an upper limit in the ~0.2 mbar to ~5 mbar pressure range. The incompatibility between the interpretations made from H2O and hydrocarbon observations probably results from 1D modeling limitations. Meridional variability of H2O, most probably at auroral latitudes, would need to be assessed and compared with that of hydrocarbons to quantify the role of auroral chemistry in the temporal evolution of the H2O abundance since the SL9 impacts. Modeling the temporal evolution of SL9 species with a 2D model would be the next natural step., Comment: 9 pages, 8 figures, accepted in Astronomy and Astrophysics

Context. The Odin satellite is now into its sixteenth year of operation, much surpassing its design life of two years. One of the sources which Odin has observed in great detail is the Sgr A Complex in the centre of the Milky Way. Aims. To study the presence of NH3 in the Galactic Centre and spiral arms. Methods. Recently, Odin has made complementary observations of the 572 GHz NH3 line towards the Sgr A +50 km/s Cloud and Circumnuclear Disk (CND). Results. Significant NH3 emission has been observed in both the +50 km/s Cloud and the CND. Clear NH3 absorption has also been detected in many of the spiral arm features along the line of sight from the Sun to the core of our Galaxy. Conclusions. The very large velocity width (80 km/s) of the NH3 emission associated with the shock region in the southwestern part of the CND may suggest a formation/desorption scenario similar to that of gas-phase H2O in shocks/outflows., Comment: 5 pages, 3 figures, 3 tables

The apparition of bright comets C/2012 F6 (Lemmon) and C/2014 Q2 (Lovejoy) in March-April 2013 and January 2015, combined with the improved observational capabilities of submillimeter facilities, offered an opportunity to carry out sensitive compositional and isotopic studies of the volatiles in their coma. We observed comet Lovejoy with the IRAM 30m telescope between 13 and 26 January 2015, and with the Odin submillimeter space observatory on 29 January - 3 February 2015. We detected 22 molecules and several isotopologues. The H$_2^{16}$O and H$_2^{18}$O production rates measured with Odin follow a periodic pattern with a period of 0.94 days and an amplitude of ~25%. The inferred isotope ratios in comet Lovejoy are $^{16}$O/$^{18}$O = 499 $\pm$ 24 and D/H = 1.4 $\pm$ 0.4 $\times 10^{-4}$ in water, $^{32}$S/$^{34}$S = 24.7 $\pm$ 3.5 in CS, all compatible with terrestrial values. The ratio $^{12}$C/$^{13}$C = 109 $\pm$ 14 in HCN is marginally higher than terrestrial and $^{14}$N/$^{15}$N = 145 $\pm$ 12 in HCN is half the Earth ratio. Several upper limits for D/H or 12C/13C in other molecules are reported. From our observation of HDO in comet C/2014 Q2 (Lovejoy), we report the first D/H ratio in an Oort Cloud comet that is not larger than the terrestrial value. On the other hand, the observation of the same HDO line in the other Oort-cloud comet, C/2012 F6 (Lemmon), suggests a D/H value four times higher. Given the previous measurements of D/H in cometary water, this illustrates that a diversity in the D/H ratio and in the chemical composition, is present even within the same dynamical group of comets, suggesting that current dynamical groups contain comets formed at very different places or times in the early solar system., Comment: Accepted for publication in Astronomy and Astrophysics

To date O2 has definitely been detected in only two sources, namely rho Oph A and Orion, reflecting the extremely low abundance of O2 in the interstellar medium. One of the sources in the HOP program is the +50 km/s Cloud in the Sgr A Complex in the centre of the Milky Way. The Herschel HIFI is used to search for the 487 and 774 GHz emission lines of O2. No O2 emission is detected towards the Sgr A +50 km/s Cloud, but a number of strong emission lines of methanol (CH3OH) and absorption lines of chloronium (H2Cl+) are observed. A 3 sigma upper limit for the fractional abundance ratio of (O2)/(H2) in the Sgr A +50 km/s Cloud is found to be X(O2) less than 5 x 10(-8). However, since we can find no other realistic molecular candidate than O2 itself, we very tentatively suggest that two weak absorption lines at 487.261 and 487.302 GHz may be caused by the 487 GHz line of O2 in two foreground spiral arm clouds. By considering that the absorption may only be apparent, the estimated upper limit to the O2 abundance of less than (10-20) x 10(-6) in these foreground clouds is very high. This abundance limit was determined also using Odin non-detection limits. If the absorption is due to a differential Herschel OFF-ON emission, the O2 fractional abundance may be of the order of (5-10) x 10(-6). With the assumption of pure absorption by foreground clouds, the unreasonably high abundance of (1.4-2.8) x 10(-4) was obtained. The rotation temperatures for CH3OH-A and CH3OH-E lines in the +50 km/s Cloud are found to be 64 and 79 K, respectively, and the fractional abundance of CH3OH is approximately 5 x 10(-7)., Comment: Accepted by Astronomy & Astrophysics, 11 pages, 12 figures

Models of pure gas-phase chemistry in well-shielded regions of molecular clouds predict relatively high levels of molecular oxygen, O2, and water, H2O. Contrary to expectation, the space missions SWAS and Odin found only very small amounts of water vapour and essentially no O2 in the dense star-forming interstellar medium. Only toward rho Oph A did Odin detect a weak line of O2 at 119 GHz in a beam size of 10 arcmin. A larger telescope aperture such as that of the Herschel Space Observatory is required to resolve the O2 emission and to pinpoint its origin. We use the Heterodyne Instrument for the Far Infrared aboard Herschel to obtain high resolution O2 spectra toward selected positions in rho Oph A. These data are analysed using standard techniques for O2 excitation and compared to recent PDR-like chemical cloud models. The 487.2GHz line was clearly detected toward all three observed positions in rho Oph A. In addition, an oversampled map of the 773.8GHz transition revealed the detection of the line in only half of the observed area. Based on their ratios, the temperature of the O2 emitting gas appears to vary quite substantially, with warm gas (> 50 K) adjacent to a much colder region, where temperatures are below 30 K. The exploited models predict O2 column densities to be sensitive to the prevailing dust temperatures, but rather insensitive to the temperatures of the gas. In agreement with these model, the observationally determined O2 column densities seem not to depend strongly on the derived gas temperatures, but fall into the range N(O2) = (3 to >6)e15/cm^2. Beam averaged O2 abundances are about 5e-8 relative to H2. Combining the HIFI data with earlier Odin observations yields a source size at 119 GHz of about 4 - 5 arcmin, encompassing the entire rho Oph A core., Comment: 10 pages, 8 figures intended for publication in A&A

We have used the Odin submillimetre-wave satellite telescope to observe the ground state transitions of ortho-ammonia and ortho-water, including their 15N, 18O, and 17O isotopologues, towards Sgr B2. The extensive simultaneous velocity coverage of the observations, >500 km/s, ensures that we can probe the conditions of both the warm, dense gas of the molecular cloud Sgr B2 near the Galactic centre, and the more diffuse gas in the Galactic disk clouds along the line-of-sight. We present ground-state NH3 absorption in seven distinct velocity features along the line-of-sight towards Sgr B2. We find a nearly linear correlation between the column densities of NH3 and CS, and a square-root relation to N2H+. The ammonia abundance in these diffuse Galactic disk clouds is estimated to be about (0.5-1)e-8, similar to that observed for diffuse clouds in the outer Galaxy. On the basis of the detection of H218O absorption in the 3 kpc arm, and the absence of such a feature in the H217O spectrum, we conclude that the water abundance is around 1e-7, compared to ~1e-8 for NH3. The Sgr B2 molecular cloud itself is seen in absorption in NH3, 15NH3, H2O, H218O, and H217O, with emission superimposed on the absorption in the main isotopologues. The non-LTE excitation of NH3 in the environment of Sgr B2 can be explained without invoking an unusually hot (500 K) molecular layer. A hot layer is similarly not required to explain the line profiles of the 1_{1,0}-1_{0,1} transition from H2O and its isotopologues. The relatively weak 15NH3 absorption in the Sgr B2 molecular cloud indicates a high [14N/15N] isotopic ratio >600. The abundance ratio of H218O and H217O is found to be relatively low, 2.5--3. These results together indicate that the dominant nucleosynthesis process in the Galactic centre is CNO hydrogen burning., Comment: 10 pages, 5 figures

Our aim is to observationally investigate the cosmic Dark Ages in order to constrain star and structure formation models, as well as the chemical evolution in the early Universe. Spectral lines from atoms and molecules in primordial perturbations at high redshifts can give information about the conditions in the early universe before and during the formation of the first stars in addition to the epoch of reionisation. The lines may arise from moving primordial perturbations before the formation of the first stars (resonant scattering lines), or could be thermal absorption or emission lines at lower redshifts. The difficulties in these searches are that the source redshift and evolutionary state, as well as molecular species and transition are unknown, which implies that an observed line can fall within a wide range of frequencies. The lines are also expected to be very weak. Observations from space have the advantages of stability and the lack of atmospheric features which is important in such observations. We have therefore, as a first step in our searches, used the Odin satellite to perform two sets of spectral line surveys towards several positions. The first survey covered the band 547-578 GHz towards two positions, and the second one covered the bands 542.0-547.5 GHz and 486.5-492.0 GHz towards six positions selected to test different sizes of the primordial clouds. Two deep searches centred at 543.250 and 543.100 GHz with 1 GHz bandwidth were also performed towards one position. The two lowest rotational transitions of H2 will be redshifted to these frequencies from z~20-30, which is the predicted epoch of the first star formation. No lines are detected at an rms level of 14-90 and 5-35 mK for the two surveys, respectively, and 2-7 mK in the deep searches with a channel spacing of 1-16 MHz. The broad bandwidth covered allows a wide range of redshifts to be explored for a number of atomic and molecular species and transitions. From the theoretical side, our sensitivity analysis show that the largest possible amplitudes of the resonant lines are about 1 mK at frequencies <200 GHz, and a few micro K around 500-600 GHz, assuming optically thick lines and no beam-dilution. However, if existing, thermal absorption lines have the potential to be orders of magnitude stronger than the resonant lines. We make a simple estimation of the sizes and masses of the primordial perturbations at their turn-around epochs, which previously has been identified as the most favourable epoch for a detection. This work may be considered as an important pilot study for our forthcoming observations with the Herschel Space Observatory., Comment: 15 pages, 9 figures, 3 on-line pages. Accepted for publication in Astronomy & Astrophysics 8 March 2010.

We investigate the physical and chemical conditions in a typical star forming region, including an unbiased search for new molecules in a spectral region previously unobserved. Due to its proximity, the Orion KL region offers a unique laboratory of molecular astrophysics in a chemically rich, massive star forming region. Several ground-based spectral line surveys have been made, but due to the absorption by water and oxygen, the terrestrial atmosphere is completely opaque at frequencies around 487 and 557 GHz. To cover these frequencies we used the Odin satellite to perform a spectral line survey in the frequency ranges 486-492 GHz and 541-577 GHz, filling the gaps between previous spectral scans. Odin's high main beam efficiency and observations performed outside the atmosphere make our intensity scale very well determined. We observed 280 spectral lines from 38 molecules including isotopologues, and, in addition, 64 unidentified lines. The beam-averaged emission is dominated by CO, H2O, SO2, SO, 13CO and CH3OH. Species with the largest number of lines are CH3OH, (CH33)2O, SO2, 13CH3OH, CH3CN and NO. Six water lines are detected including the ground state rotational transition o-H2O, its isotopologues o-H218O and o-H217O, the Hot Core tracing p-H2O transition 6(2,4)-7(1,7), and the 2(0, 2)-1(1,1) transition of HDO. Other lines of special interest are the 1_0-0_0 transition of NH3 and its isotopologue 15NH3. Isotopologue abundance ratios of D/H, 12C/13C, 32S/34S, 34S/33S, and 18O/17O are estimated. The temperatures, column densities and abundances in the various subregions are estimated, and we find very high gas-phase abundances of H2O, NH3, SO2, SO, NO, and CH3OH. A comparison with the ice inventory of ISO sheds new light on the origin of the abundant gas-phase molecules., Comment: 51 pages, 47 figures, 35 tables, accepted for publication in Astronomy and Astrophysics 17 September 2007

Spectral line surveys are useful since they allow identification of new molecules and new lines in uniformly calibrated data sets. Nonetheless, large portions of the sub-millimetre spectral regime remain unexplored due to severe absorptions by H2O and O2 in the terrestrial atmosphere. The purpose of the measurements presented here is to cover wavelength regions at and around 0.55 mm -- regions largely unobservable from the ground. Using the Odin astronomy/aeronomy satellite, we performed the first spectral survey of the Orion KL molecular cloud core in the bands 486--492 and 541--576 GHz with rather uniform sensitivity (22--25 mK baseline noise). Odin's 1.1 m size telescope, equipped with four cryo-cooled tuneable mixers connected to broad band spectrometers, was used in a satellite position-switching mode. Two mixers simultaneously observed different 1.1 GHz bands using frequency steps of 0.5 GHz (25 hours each). An on-source integration time of 20 hours was achieved for most bands. The entire campaign consumed ~1100 orbits, each containing one hour of serviceable astro-observation. We identified 280 spectral lines from 38 known interstellar molecules (including isotopologues) having intensities in the range 80 to 0.05 K. An additional 64 weak lines remain unidentified. Apart from the ground state rotational 1(1,0)--1(0,1) transitions of ortho-H2O, H218O and H217O, the high energy 6(2,4)--7(1,7) line of para-H2O and the HDO(2,0,2--1,1,1) line have been observed, as well as the 1,0--0,1 lines from NH3 and its rare isotopologue 15NH3. We suggest assignments for some unidentified features, notably the new interstellar molecules ND and SH-. Severe blends have been detected in the line wings of the H218O, H217O and 13CO lines changing the true linewidths of the outflow emission., Comment: 21 pages, 10 figures, 7 tables, accepeted for publication in Astronomy and Astrophysics 30 August 2007

We have used the Odin satellite to obtain strip maps of the ground-state rotational transitions of ortho-water and ortho-ammonia, as well as CO(5-4) and 13CO(5-4) across the PDR, and H218O in the central position. A physi-chemical inhomogeneous PDR model was used to compute the temperature and abundance distributions for water, ammonia and CO. A multi-zone escape probability method then calculated the level populations and intensity distributions. These results are compared to a homogeneous model computed with an enhanced version of the RADEX code. H2O, NH3 and 13CO show emission from an extended PDR with a narrow line width of ~3 kms. Like CO, the water line profile is dominated by outflow emission, however, mainly in the red wing. The PDR model suggests that the water emission mainly arises from the surfaces of optically thick, high density clumps with n(H2)>10^6 cm^-3 and a clump water abundance, with respect to H2, of 5x10^-8. The mean water abundance in the PDR is 5x10^-9, and between ~2x10^-8 -- 2x10^-7 in the outflow derived from a simple two-level approximation. Ammonia is also observed in the extended clumpy PDR, likely from the same high density and warm clumps as water. The average ammonia abundance is about the same as for water: 4x10^-9 and 8x10^-9 given by the PDR model and RADEX, respectively. The similarity of water and ammonia PDR emission is also seen in the almost identical line profiles observed close to the bright rim. Around the central position, ammonia also shows some outflow emission although weaker than water in the red wing. Predictions of the H2O(110-101) and (111-000) antenna temperatures across the PDR are estimated with our PDR model for the forthcoming observations with the Herschel Space Observatory., Comment: 13 pages, 14 figures, 10 tables. Accepted for publication in Astronomy & Astrophysics 14 November 2008

Aims. We investigate the ortho-water abundance in outflows and shocks in order to improve our knowledge of shock chemistry and of the physics behind molecular outflows. Methods. We have used the Odin space observatory to observe the H2O(110-101) line. We obtain strip maps and single pointings of 13 outflows and two supernova remnants where we report detections for eight sources. We have used RADEX to compute the beam averaged abundances of o-H2O relative to H2. In the case of non-detection, we derive upper limits on the abundance. Results. Observations of CO emission from the literature show that the volume density of H2 can vary to a large extent, a parameter that puts severe uncertainties on the derived abundances. Our analysis shows a wide range of abundances reflecting the degree to which shock chemistry is affecting the formation and destruction of water. We also compare our results with recent results from the SWAS team. Conclusions. Elevated abundances of ortho-water are found in several sources. The abundance reaches values as high as what would be expected from a theoretical C-type shock where all oxygen, not in the form of CO, is converted to water. However, the high abundances we derive could also be due to the low densities (derived from CO observations) that we assume. The water emission may in reality stem from high density regions much smaller than the Odin beam. We do not find any relationship between the abundance and the mass loss rate. On the other hand, there is a relation between the derived water abundance and the observed maximum outflow velocity., Comment: 19 pages, 20 figures, 4 tables

Aims: Spectrally resolved circumstellar H2O(1_10 - 1_01) lines have been obtained towards three M-type AGB stars using the Odin satellite. This provides additional strong constrains on the properties of circumstellar H2O and the circumstellar envelope. Methods: ISO and Odin satellite H2O line data are used as constraints for radiative transfer models. Special consideration is taken to the spectrally resolved Odin line profiles, and the effect of excitation to the first excited vibrational states of the stretching modes (nu1=1 and nu3=1) on the derived abundances is estimated. A non-local, radiative transfer code based on the ALI formalism is used. Results: The H2O abundance estimates are in agreement with previous estimates. The inclusion of the Odin data sets stronger constraints on the size of the H2O envelope. The H2O(1_10 - 1_01) line profiles require a significant reduction in expansion velocity compared to the terminal gas expansion velocity determined in models of CO radio line emission, indicating that the H2O emission lines probe a region where the wind is still being accelerated. Including the nu3=1 state significantly lowers the estimated abundances for the low-mass-loss-rate objects. This shows the importance of detailed modelling, in particular the details of the infrared spectrum in the range 3 to 6 micron, to estimate accurate circumstellar H2O abundances. Conclusions: Spectrally resolved circumstellar H2O emission lines are important probes of the physics and chemistry in the inner regions of circumstellar envelopes around asymptotic giant branch stars. Predictions for H2O emission lines in the spectral range of the upcoming Herschel/HIFI mission indicate that these observations will be very important in this context., Comment: accepted in A&A, 10 pages, 8 figures

The Odin satellite has been used to search for the 118.75-GHz line of molecular oxygen (O2)in the Galactic centre. Odin observations were performed towards the Sgr A* circumnuclear disk (CND), and the Sgr A +20 km/s and +50 km/s molecular clouds using the position-switching mode. Supplementary ground-based observations were carried out in the 2-mm band using the ARO Kitt Peak 12-m telescope to examine suspected SiC features. A strong emission line was found at 118.27 GHz, attributable to the J=13-12 HC3N line. Upper limits are presented for the 118.75-GHz O2 (1,1-1,0) ground transition line and for the 118.11-GHz 3Pi2, J=3-2 ground state SiC line at the Galactic centre. Upper limits are also presented for the 487-GHz O2 line in the Sgr A +50 km/s cloud and for the 157-GHz, J=4-3, SiC line in the Sgr A +20 and +50 km/s clouds, as well as the CND. The CH3OH line complex at 157.2 - 157.3 GHz has been detected in the +20 and +50 km/s clouds but not towards Sgr A*/CND. A 3-sigma upper limit for the fractional abundance ratio of [O2]/[H2] is found to be X(O2) < 1.2 x 10exp(-7) towards the Sgr A molecular belt region., Comment: Accepted for publication in A&A. 6 journal pages, 5 figures

We have searched for emission from the 557 GHz ortho-water line in the interstellar medium of six nearby starburst galaxies. We used the Odin satellite to observe the 1_10-1_01 transition of o-H2O in the galaxies NGC253, IC342, M82, NGC4258, CenA, and M51. None of the galaxies in our sample was detected. We derive three sigma upper limits to the H2O abundance relative to H2 ranging from 2e-9 to 1e-8. The best of these upper limits are comparable to the measured abundance of H$_2$O in the Galactic star forming region W3. However, if only 10% of the molecular gas is in very dense cores, then the water abundance limits in the cores themselves would be larger by a factor of 10 i.e. 2e-8 to 1e-7. These observations suggest that detections of H2O emission in galaxies with the upcoming Herschel Space Observatory are likely to require on-source integration times of an hour or more except in the very brightest extragalactic targets such as M82 and NGC253., Comment: Now accepted to A&A. Major change to Herschel time estimates in section 4. New estimates done with HSPOT and should be accurate; old estimates were done based on a HIFI memo that seems to have a factor of 5 error in the rms in W/m^2. 5 pages, 6 figures

Molecular oxygen, O2 has been expected historically to be an abundant component of the chemical species in molecular clouds and, as such, an important coolant of the dense interstellar medium. However, a number of attempts from both ground and from space have failed to detect O2 emission. The work described here uses heterodyne spectroscopy from space to search for molecular oxygen in the interstellar medium. The Odin satellite carries a 1.1 m sub-millimeter dish and a dedicated 119 GHz receiver for the ground state line of O2. Starting in 2002, the star forming molecular cloud core rho Oph A was observed with Odin for 34 days during several observing runs. We detect a spectral line at v(LSR) = 3.5 km/s with dv(FWHM) = 1.5 km/s, parameters which are also common to other species associated with rho Ohp A. This feature is identified as the O2 (N_J = 1_1 - 1_0) transition at 118 750.343 MHz. The abundance of molecular oxygen, relative to H2,, is 5E-8 averaged over the Odin beam. This abundance is consistently lower than previously reported upper limits., Comment: 10 pages, 11 figures, accepted for publication in A&A

The Odin satellite, launched in Feb. 2001, is equipped with a 1.1-m submillimetre telescope. Odin was used to observe the 557 GHz line of water with high spectral resolution in 12 comets between 2001 and 2005. Line shapes and spatial mapping provide information on the anisotropy of the outgassing and constraints on water excitation, enabling accurate measurements of the water production rate. Five comets were regularly observed over periods of more than one month to monitor the variation of their water outgassing rate with heliocentric distance. Observing campaigns have been generally coordinated with ground-based observations of molecular lines at Nan\c{c}ay, CSO or IRAM 30-m telescopes to obtain molecular abundances relative to water. Thanks to Odin's frequency coverage, it was also possible to detect the H_2^18O 548GHz line, first in comet 153P/Ikeya-Zhang in April 2002 (Lecacheux et al., 2003) and then in comets C/2002 T7 (LINEAR), C/2001 Q4 (NEAT) and C/2004 Q2 (Machholz). The ^16O/^18O isotopic ratio (\approx450) is consistent with the terrestrial value. Ammonia has been searched for in three comets through its J_K = 1_0-0_0 line at 572 GHz and was tentatively detected in C/2001 Q4 and C/2002 T7. The derived abundances of NH_3 relative to water are 0.5 % and 0.3 %, respectively, similar to values obtained in other comets with different techniques., Comment: accepted for publication in Planetary and Space Science

Comet 9P/Tempel 1 was the target of a multi-wavelength worldwide investigation in 2005. The NASA Deep Impact mission reached the comet on 4.24 July 2005, delivering a 370 kg impactor which hit the comet at 10.3 km/s. Following this impact, a cloud of gas and dust was excavated from the comet nucleus. The comet was observed in 2005 prior to and after the impact, at 18-cm wavelength with the Nan\c{c}ay radio telescope, in the millimetre range with the IRAM and CSO radio telescopes, and at 557 GHz with the Odin satellite. Post-impact observations at IRAM and CSO did not reveal a significant change of the outgassing rates and relative abundances, with the exception of CH_3OH which may have been more abundant by up to one order of magnitude in the ejecta. Most other variations are linked to the intrinsic variability of the comet. The Odin satellite monitored nearly continuously the H_2O line at 557 GHz during the 38 hours following the impact on the 4th of July, in addition to weekly monitoring. Once the periodic variations related to the nucleus rotation are removed, a small increase of outgassing related to the impact is present, which corresponds to the release of \approx 5000+/-2000 tons of water. Two other bursts of activity, also observed at other wavelengths, were seen on 23 June and 7 July; they correspond to even larger releases of gas., Comment: accepted for publication in Icarus

We present Odin observations of the AGB star W Hya in the ground-state transition of ortho-H2O, 1(10)-1(01), at 557GHz. The line is clearly of circumstellar origin. Radiative transfer modelling of the water lines observed by Odin and ISO results in a mass-loss rate of (2.5 +/- 0.5)E-7 Msol/yr, and a circumstellar H2O abundance of (2.0 +/- 1.0)E-3. The inferred mass-loss rate is consistent with that obtained from modelling the circumstellar CO radio line emission, and also with that obtained from the dust emission modelling combined with a dynamical model for the outflow. The very high water abundance, higher than the cosmic oxygen abundance, can be explained by invoking an injection of excess water from evaporating icy bodies in the system. The required extra mass of water is quite small, on the order of ~ 0.1 earth mass., Comment: 7 pages, 6 figures Accepted for publication in Astronomy and Astrophysics

We present a 39 h integration with the Odin satellite on the ground-state 118.75 GHz line of O2 towards the region of strongest molecular emission in the Small Magellanic Cloud. Our 3sigma upper limit to the O2 integrated intensity of <0.049 K km/s in a 9'(160 pc) diameter beam corresponds to an upper limit on the O2/H2 abundance ratio of <1.3E-6. Although a factor of 20 above the best limit on the O2 abundance obtained for a Galactic source, our result has interesting implications for understanding oxygen chemistry at sub-solar metal abundances. We compare our abundance limit to a variety of astrochemical models and find that, at low metallicities, the low O2 abundance is most likely produced by the effects of photo-dissociation on molecular cloud structure. Freeze-out of molecules onto dust grains may also be consistent with the observed abundance limit, although such models have not yet been run at sub-solar initial metallicities., Comment: 4 pages, accepted to A&A Letters

There is a widespread impression that the scientific journal "Astronomy & Astrophysics" (A&A) has a smaller impact, as measured by citations to articles, than some of the other major astronomy journals. This impression was apparently supported - and probably created - by the Journal Citation Report (JCR), which is prepared annually by the Institute of Scientific Information (ISI) Web of Knowledge. The published poor impact factor of A&A was in fact wrong and was due to a serious flaw in the method used by ISI Web of Knowledge to determine it. The resulting damage inflicted upon A&A by the JCR is incalculable., Comment: 4 pages, to be published in A. Heck (ed.) "Organizations and Strategies in Astronomy, Vol. 5" (Kluwer, 2004)

The Odin satellite has been used to detect emission and absorption in the 557-GHz H2O line in the Galactic Centre towards the Sgr A* Circumnuclear Disk (CND), and the Sgr A +20 km/s and +50 km/s molecular clouds. Strong broad H2O emission lines have been detected in all three objects. Narrow H2O absorption lines are present at all three positions and originate along the lines of sight in the 3-kpc Spiral Arm, the -30 km/s Spiral Arm and the Local Sgr Spiral Arm. Broad H2O absorption lines near -130 km/s are also observed, originating in the Expanding Molecular Ring. A new molecular feature (the ``High Positive Velocity Gas'' - HPVG) has been identified in the positive velocity range of ~ +120 to +220 km/s, seen definitely in absorption against the stronger dust continuum emission from the +20 km/s and +50 km/s clouds and possibly in emission towards the position of Sgr A* CND. The 548-GHz H2_18O isotope line towards the CND is not detected at the 0.02 K (rms) level., Comment: 5 pages, 3 figures, accepted by A&A, special Odin Letters issue

Odin has successfully observed the molecular core rho Oph A in the 572.5 GHz rotational ground state line of ammonia, NH3 (J,K = 1,0 - 0,0). The interpretation of this result makes use of complementary molecular line data obtained from the ground (C17O and CH3OH) as part of the Odin preparatory work. Comparison of these observations with theoretical model calculations of line excitation and transfer yields a quite ordinary abundance of methanol, X(CH3OH) = 3e-9. Unless NH3 is not entirely segregated from C17O and CH3OH, ammonia is found to be significantly underabundant with respect to typical dense core values, viz. X(NH3) = 8e-10., Comment: 4 pages, 2 figures, 2 tables, to appear in Astron. Astrophys. Letters

We have mapped the submillimeter emission from the 1(10)-1(01) transition of ortho-water in the W3 star-forming region. A 5'x5' map of the W3 IRS4 and W3 IRS5 region reveals strong water lines at half the positions in the map. The relative strength of the Odin lines compared to previous observations by SWAS suggests that we are seeing water emission from an extended region. Across much of the map the lines are double-peaked, with an absorption feature at -39 km/s; however, some positions in the map show a single strong line at -43 km/s. We interpret the double-peaked lines as arising from optically thick, self-absorbed water emission near the W3 IRS5, while the narrower blue-shifted lines originate in emission near W3 IRS4. In this model, the unusual appearance of the spectral lines across the map results from a coincidental agreement in velocity between the emission near W3 IRS4 and the blue peak of the more complex lines near W3 IRS5. The strength of the water lines near W3 IRS4 suggests we may be seeing water emission enhanced in a photon-dominated region., Comment: Accepted to A&A Letters as part of the special Odin issue; 4 pages

Odin has successfully observed three regions in the Orion A cloud, i.e. Ori KL, Ori S and the Orion Bar, in the 572.5 GHz rotational ground state line of ammonia, ortho-NH3 (J,K) = (1,0) -> (0,0), and the result for the Orion Bar represents the first detection in an ammonia line. Several velocity components are present in the data. Specifically, the observed line profile from the Orion Bar can be decomposed into two components, which are in agreement with observations in high-J CO lines by Wilson et al. 2001. Using the source model for the Orion Bar by these authors, our Odin observation implies a total ammonia abundance of NH3/H2 = 5E-9., Comment: 4 pages with 2 figures, accepted for publication in A&A