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Mid-infrared emission features probe the properties of ionized gas, and hot or warm molecular gas. The Orion Bar is a frequently studied photodissociation region (PDR) containing large amounts of gas under these conditions, and was observed with the MIRI IFU aboard JWST as part of the "PDRs4All" program. The resulting IR spectroscopic images of high angular resolution (0.2") reveal a rich observational inventory of mid-IR emission lines, and spatially resolve the substructure of the PDR, with a mosaic cutting perpendicularly across the ionization front and three dissociation fronts. We extracted five spectra that represent the ionized, atomic, and molecular gas layers, and measured the most prominent gas emission lines. An initial analysis summarizes the physical conditions of the gas and the potential of these data. We identified around 100 lines, report an additional 18 lines that remain unidentified, and measured the line intensities and central wavelengths. The H I recombination lines originating from the ionized gas layer bordering the PDR, have intensity ratios that are well matched by emissivity coefficients from H recombination theory, but deviate up to 10% due contamination by He I lines. We report the observed emission lines of various ionization stages of Ne, P, S, Cl, Ar, Fe, and Ni, and show how certain line ratios vary between the five regions. We observe the pure-rotational H$_2$ lines in the vibrational ground state from 0-0 S(1) to 0-0 S(8), and in the first vibrationally excited state from 1-1 S(5) to 1-1 S(9). We derive H$_2$ excitation diagrams, and approximate the excitation with one thermal (~700 K) component representative of an average gas temperature, and one non-thermal component (~2700 K) probing the effect of UV pumping. We compare these results to an existing model for the Orion Bar PDR and highlight the differences with the observations., Comment: 26 pages, 12 figures, 3 tables. Submitted to A&A, under review (1st revision)

Most low-mass stars form in stellar clusters that also contain massive stars, which are sources of far-ultraviolet (FUV) radiation. Theoretical models predict that this FUV radiation produces photo-dissociation regions (PDRs) on the surfaces of protoplanetary disks around low-mass stars, impacting planet formation within the disks. We report JWST and Atacama Large Millimetere Array observations of a FUV-irradiated protoplanetary disk in the Orion Nebula. Emission lines are detected from the PDR; modelling their kinematics and excitation allows us to constrain the physical conditions within the gas. We quantify the mass-loss rate induced by the FUV irradiation, finding it is sufficient to remove gas from the disk in less than a million years. This is rapid enough to affect giant planet formation in the disk.

(Abridged) We investigate the impact of radiative feedback from massive stars on their natal cloud and focus on the transition from the HII region to the atomic PDR (crossing the ionisation front (IF)), and the subsequent transition to the molecular PDR (crossing the dissociation front (DF)). We use high-resolution near-IR integral field spectroscopic data from NIRSpec on JWST to observe the Orion Bar PDR as part of the PDRs4All JWST Early Release Science Program. The NIRSpec data reveal a forest of lines including, but not limited to, HeI, HI, and CI recombination lines, ionic lines, OI and NI fluorescence lines, Aromatic Infrared Bands (AIBs including aromatic CH, aliphatic CH, and their CD counterparts), CO2 ice, pure rotational and ro-vibrational lines from H2, and ro-vibrational lines HD, CO, and CH+, most of them detected for the first time towards a PDR. Their spatial distribution resolves the H and He ionisation structure in the Huygens region, gives insight into the geometry of the Bar, and confirms the large-scale stratification of PDRs. We observe numerous smaller scale structures whose typical size decreases with distance from Ori C and IR lines from CI, if solely arising from radiative recombination and cascade, reveal very high gas temperatures consistent with the hot irradiated surface of small-scale dense clumps deep inside the PDR. The H2 lines reveal multiple, prominent filaments which exhibit different characteristics. This leaves the impression of a "terraced" transition from the predominantly atomic surface region to the CO-rich molecular zone deeper in. This study showcases the discovery space created by JWST to further our understanding of the impact radiation from young stars has on their natal molecular cloud and proto-planetary disk, which touches on star- and planet formation as well as galaxy evolution., Comment: 52 pages, 30 figures, submitted to A&A

We carried out a sensitive survey of C$_2$ and C$_3$ using the EDIBLES data set. We also expanded our searches to C$_4$, C$_5$, and $^{13}$C$^{12}$C isotopologue in the most molecule-rich sightlines. We fit synthetic spectra generated following a physical excitation model to the C$_2$ (2-0) Phillips band to obtain the C$_2$ column density ($N$) as well as the kinetic temperature ($T_\textrm{kin}$) and number density ($n$) of the host cloud. The C$_3$ molecule was measured through its $\tilde{A} - \tilde{X}$ (000-000) electronic origin band system. We simulated the excitation of this band with a double-temperature Boltzmann distribution. We present the largest combined survey of C$_2$ and C$_3$ to date in which the individual transitions can be resolved. In total we detected C$_2$ in 51 velocity components along 40 sightlines, and C$_3$ in 31 velocity components along 27 sightlines. The two molecules are detected in the same velocity components. We find a very good correlation between $N$(C$_2$) and $N$(C$_3$) with Pearson $r = 0.93$ and an average $N$(C$_2$)/$N$(C$_3$) ratio of 15.5$\pm$1.4. A comparison with the behaviour of the C$_2$ DIBs shows that there are no clear differences among sightlines with and without detection of C$_2$ and C$_3$. This is in direct contrast to the better-studied non-C$_2$ DIBs who have reduced strengths in molecule-rich environments. We also identify for the first time the $Q$(2), $Q$(3), and $Q$(4) transitions of the $^{13}$C$^{12}$C (2-0) Phillips band in a stacked average spectrum, and estimate the isotopic ratio of carbon $^{12}$C/$^{13}$C as 79$\pm$8. Our search for the C$_4$ and C$_5$ optical bands was unsuccessful., Comment: 31 pages, 23 figures. To appear in A&A

The JWST has captured the most detailed and sharpest infrared images ever taken of the inner region of the Orion Nebula, the nearest massive star formation region, and a prototypical highly irradiated dense photo-dissociation region (PDR). We investigate the fundamental interaction of far-ultraviolet photons with molecular clouds. The transitions across the ionization front (IF), dissociation front (DF), and the molecular cloud are studied at high-angular resolution. These transitions are relevant to understanding the effects of radiative feedback from massive stars and the dominant physical and chemical processes that lead to the IR emission that JWST will detect in many Galactic and extragalactic environments. Due to the proximity of the Orion Nebula and the unprecedented angular resolution of JWST, these data reveal that the molecular cloud borders are hyper structured at small angular scales of 0.1-1" (0.0002-0.002 pc or 40-400 au at 414 pc). A diverse set of features are observed such as ridges, waves, globules and photoevaporated protoplanetary disks. At the PDR atomic to molecular transition, several bright features are detected that are associated with the highly irradiated surroundings of the dense molecular condensations and embedded young star. Toward the Orion Bar PDR, a highly sculpted interface is detected with sharp edges and density increases near the IF and DF. This was predicted by previous modeling studies, but the fronts were unresolved in most tracers. A complex, structured, and folded DF surface was traced by the H2 lines. This dataset was used to revisit the commonly adopted 2D PDR structure of the Orion Bar. JWST provides us with a complete view of the PDR, all the way from the PDR edge to the substructured dense region, and this allowed us to determine, in detail, where the emission of the atomic and molecular lines, aromatic bands, and dust originate.

(Abridged) Mid-infrared observations of photodissociation regions (PDRs) are dominated by strong emission features called aromatic infrared bands (AIBs). The most prominent AIBs are found at 3.3, 6.2, 7.7, 8.6, and 11.2 $\mu$m. The most sensitive, highest-resolution infrared spectral imaging data ever taken of the prototypical PDR, the Orion Bar, have been captured by JWST. We provide an inventory of the AIBs found in the Orion Bar, along with mid-IR template spectra from five distinct regions in the Bar: the molecular PDR, the atomic PDR, and the HII region. We use JWST NIRSpec IFU and MIRI MRS observations of the Orion Bar from the JWST Early Release Science Program, PDRs4All (ID: 1288). We extract five template spectra to represent the morphology and environment of the Orion Bar PDR. The superb sensitivity and the spectral and spatial resolution of these JWST observations reveal many details of the AIB emission and enable an improved characterization of their detailed profile shapes and sub-components. While the spectra are dominated by the well-known AIBs at 3.3, 6.2, 7.7, 8.6, 11.2, and 12.7 $\mu$m, a wealth of weaker features and sub-components are present. We report trends in the widths and relative strengths of AIBs across the five template spectra. These trends yield valuable insight into the photochemical evolution of PAHs, such as the evolution responsible for the shift of 11.2 $\mu$m AIB emission from class B$_{11.2}$ in the molecular PDR to class A$_{11.2}$ in the PDR surface layers. This photochemical evolution is driven by the increased importance of FUV processing in the PDR surface layers, resulting in a "weeding out" of the weakest links of the PAH family in these layers. For now, these JWST observations are consistent with a model in which the underlying PAH family is composed of a few species: the so-called 'grandPAHs'., Comment: 25 pages, 10 figures, to appear in A&A

Massive stars disrupt their natal molecular cloud material through radiative and mechanical feedback processes. These processes have profound effects on the evolution of interstellar matter in our Galaxy and throughout the Universe, from the era of vigorous star formation at redshifts of 1-3 to the present day. The dominant feedback processes can be probed by observations of the Photo-Dissociation Regions (PDRs) where the far-ultraviolet photons of massive stars create warm regions of gas and dust in the neutral atomic and molecular gas. PDR emission provides a unique tool to study in detail the physical and chemical processes that are relevant for most of the mass in inter- and circumstellar media including diffuse clouds, proto-planetary disks and molecular cloud surfaces, globules, planetary nebulae, and star-forming regions. PDR emission dominates the infrared (IR) spectra of star-forming galaxies. Most of the Galactic and extragalactic observations obtained with the James Webb Space Telescope (JWST) will therefore arise in PDR emission. In this paper we present an Early Release Science program using the MIRI, NIRSpec, and NIRCam instruments dedicated to the observations of an emblematic and nearby PDR: the Orion Bar. These early JWST observations will provide template datasets designed to identify key PDR characteristics in JWST observations. These data will serve to benchmark PDR models and extend them into the JWST era. We also present the Science-Enabling products that we will provide to the community. These template datasets and Science-Enabling products will guide the preparation of future proposals on star-forming regions in our Galaxy and beyond and will facilitate data analysis and interpretation of forthcoming JWST observations., Comment: Submitted to PASP

More than 500 diffuse interstellar bands (DIBs) have been observed in astronomical spectra, and their signatures and correlations in different environments have been studied over the past decades to reveal clues about the nature of the carriers. We compare the equivalent widths of the DIBs, normalized to the amount of reddening, E_B-V, to search for anti-correlated DIB pairs using a data sample containing 54 DIBs measured in 25 sight lines. This data sample covers most of the strong and commonly detected DIBs in the optical region, and the sight lines probe a variety of ISM conditions. We find that 12.9% of the DIB pairs are anti-correlated, and the lowest Pearson correlation coefficient is r_norm ~ -0.7. We revisit correlation-based DIB families and are able to reproduce the assignments of such families for the well-studied DIBs by applying hierarchical agglomerative and k-means clustering algorithms. We visualize the dissimilarities between DIBs, represented by 1 - r_norm, using multi-dimensional scaling (MDS). With this representation, we find that the DIBs form a rather continuous sequence, which implies that some properties of the DIB carriers are changing gradually following this sequence. We also find at that least two factors are needed to properly explain the dissimilarities between DIBs. While the first factor may be interpreted as related to the ionization properties of the DIB carriers, a physical interpretation of the second factor is less clear and may be related to how DIB carriers interact with surrounding interstellar material., Comment: 16 pages after compiling, 9 figures

In Titan's nitrogen-methane atmosphere, photochemistry leads to the production of complex organic particles, forming Titan's thick haze layers. Laboratory-produced aerosol analogs, or "tholins", are produced in a number of laboratories; however, most previous studies have investigated analogs produced by only one laboratory rather than a systematic, comparative analysis. In this study, we performed a comparative study of an important material property, the surface energy, of seven tholin samples produced in three independent laboratories under a broad range of experimental conditions, and explored their commonalities and differences. All seven tholin samples are found to have high surface energies, and are therefore highly cohesive. Thus, if the surface sediments on Titan are similar to tholins, future missions such as Dragonfly will likely encounter sticky sediments. We also identified a commonality between all the tholin samples: a high dispersive (non-polar) surface energy component of at least 30 mJ/m2. This common property could be shared by the actual haze particles on Titan as well. Given that the most abundant species interacting with the haze on Titan (methane, ethane, and nitrogen) are non-polar in nature, the dispersive surface energy component of the haze particles could be a determinant factor in condensate-haze and haze-lake liquids interactions on Titan. With this common trait of tholin samples, we confirmed the findings of a previous study by Yu et al. (2020) that haze particles are likely good cloud condensation nuclei (CCN) for methane and ethane clouds and would likely be completely wetted by the hydrocarbon lakes on Titan., Comment: 20 pages, 5 figures, 6 tables

Laboratory studies for planetary science and astrobiology aimat advancing our understanding of the Solar System through the promotion of theoretical and experimental research into the underlying processes that shape it. Laboratory studies (experimental and theoretical) are crucial to interpret observations and mission data, and are key incubators for new mission concepts as well as instrument development and calibration. They also play a vital role in determining habitability of Solar System bodies, enhancing our understanding of the origin of life, and in the search for signs of life beyond Earth, all critical elements of astrobiology. Here we present an overview of the planetary science areas where laboratory studies are critically needed, in particular in the next decade. These areas include planetary & satellites atmospheres, surfaces, and interiors, primitive bodies such as asteroids, meteorites, comets, and trans-Neptunian objects, and signs of life. Generating targeted experimental and theoretical laboratory data that are relevant for a better understanding of the physical, chemical, and biological processes occurring in these environments is crucial. For each area we present i) a brief overview of the state-of-the-art laboratory work, ii) the challenges to analyze and interpret data sets from missions and ground-based observations and to support mission and concept development, and iii) recommendations for high priority laboratory studies., Comment: White paper submitted to the Planetary Science Decadal Survey 2013-2022

We outline a flagship-class mission concept focused on studying Titan as a global system, with particular emphasis on the polar regions. Investigating Titan from the unique standpoint of a polar orbit would enable comprehensive global maps to uncover the physics and chemistry of the atmosphere, and the topography and geophysical environment of the surface and subsurface. The mission includes two key elements: (1) an orbiter spacecraft, which also acts as a data relay, and (2) one or more small probes to directly investigate Titan's seas and make the first direct measurements of their liquid composition and physical environment. The orbiter would carry a sophisticated remote sensing payload, including a novel topographic lidar, a long-wavelength surface-penetrating radar, a sub-millimeter sounder for winds and for mesospheric/thermospheric composition, and a camera and near-infrared spectrometer. An instrument suite to analyze particles and fields would include a mass spectrometer to focus on the interactions between Titan's escaping upper atmosphere and the solar wind and Saturnian magnetosphere. The orbiter would enter a stable polar orbit around 1500 to 1800 km, from which vantage point it would make global maps of the atmosphere and surface. One or more probes, released from the orbiter, would investigate Titan's seas in situ, including possible differences in composition between higher and lower latitude seas, as well as the atmosphere during the parachute descent. The number of probes, as well as the instrument complement on the orbiter and probe, remain to be finalized during a mission study that we recommend to NASA as part of the NRC Decadal Survey for Planetary Science now underway, with the goal of an overall mission cost in the "small flagship" category of ~$2 bn. International partnerships, similar to Cassini-Huygens, may also be included for consideration., Comment: 13 pages, white paper submitted to the NRC Decadal Survey for Planetary Science and Astrobiology

We are now on a clear trajectory for improvements in exoplanet observations that will revolutionize our ability to characterize their atmospheric structure, composition, and circulation, from gas giants to rocky planets. However, exoplanet atmospheric models capable of interpreting the upcoming observations are often limited by insufficiencies in the laboratory and theoretical data that serve as critical inputs to atmospheric physical and chemical tools. Here we provide an up-to-date and condensed description of areas where laboratory and/or ab initio investigations could fill critical gaps in our ability to model exoplanet atmospheric opacities, clouds, and chemistry, building off a larger 2016 white paper, and endorsed by the NAS Exoplanet Science Strategy report. Now is the ideal time for progress in these areas, but this progress requires better access to, understanding of, and training in the production of spectroscopic data as well as a better insight into chemical reaction kinetics both thermal and radiation-induced at a broad range of temperatures. Given that most published efforts have emphasized relatively Earth-like conditions, we can expect significant and enlightening discoveries as emphasis moves to the exotic atmospheres of exoplanets., Comment: Submitted as an Astro2020 Science White Paper

About two generations ago, a large part of AMO science was dominated by experimental high energy collision studies and perturbative theoretical methods. Since then, AMO science has undergone a transition and is now dominated by quantum, ultracold, and ultrafast studies. But in the process, the field has passed over the complexity that lies between these two extremes. Most of the Universe resides in this intermediate region. We put forward that the next frontier for AMO science is to explore the AMO complexity that describes most of the Cosmos., Comment: White paper submission to the Decadal Assessment and Outlook Report on Atomic, Molecular, and Optical (AMO) Science (AMO 2020)

The carriers of the diffuse interstellar bands (DIBs) are largely unidentified molecules ubiquitously present in the interstellar medium (ISM). After decades of study, two strong and possibly three weak near-infrared DIBs have recently been attributed to the C60+ fullerene based on observational and laboratory measurements. There is great promise for the identification of the over 400 other known DIBs, as this result could provide chemical hints towards other possible carriers. In an effort to systematically study the properties of the DIB carriers, we have initiated a new large-scale observational survey: the ESO Diffuse Interstellar Bands Large Exploration Survey (EDIBLES). The main objective is to build on and extend existing DIB surveys to make a major step forward in characterising the physical and chemical conditions for a statistically significant sample of interstellar lines-of-sight, with the goal to reverse-engineer key molecular properties of the DIB carriers. EDIBLES is a filler Large Programme using the Ultraviolet and Visual Echelle Spectrograph at the Very Large Telescope at Paranal, Chile. It is designed to provide an observationally unbiased view of the presence and behaviour of the DIBs towards early-spectral-type stars whose lines-of-sight probe the diffuse-to-translucent ISM. Such a complete dataset will provide a deep census of the atomic and molecular content, physical conditions, chemical abundances and elemental depletion levels for each sightline. Achieving these goals requires a homogeneous set of high-quality data in terms of resolution (R ~ 70000 -- 100000), sensitivity (S/N up to 1000 per resolution element), and spectral coverage (305--1042 nm), as well as a large sample size (100+ sightlines). In this first paper the goals, objectives and methodology of the EDIBLES programme are described and an initial assessment of the data is provided., Comment: 29 pages (including 14 pages appendix), 15 figures, accepted by A&A

Commission 14 has been operating for almost a century. It was one of the 32 Standing IAU Commissions and established in 1919. The main purpose of Commission 14 is to foster interactions between the astronomical community and those conducting research on atoms, molecules, and solid state particles to provide data vital to reducing and analysing astronomical observations and performing theoretical investigations. Although Commission 14 terminated at the Honolulu General Assembly, the field Atomic and Molecular Data remains with the IAU. By call of the IAU, the Commission 14 OC initiated a proposal for a new Commission on Laboratory Astrophysics that was approved. Commission on Laboratory Astrophysics will be a natural evolution of Commission 14., Comment: TRIENNIAL REPORT 2012-2015, 4 pages, to be published in Transactions IAU, Volume 29A, Reports on Astronomy 2012-2015, Thierry Montmerle, ed

The WGLA of the AAS (http://www.aas.org/labastro/) promotes collaboration and exchange of knowledge between astronomy and planetary sciences and the laboratory sciences (physics, chemistry, and biology). Laboratory data needs of ongoing and next generation planetary science missions are carefully evaluated and recommended in this white paper submitted by the WGLA to Planetary Decadal Survey.

Laboratory astrophysics and complementary theoretical calculations are the foundations of astronomy and astrophysics and will remain so into the foreseeable future. The mission enabling impact of laboratory astrophysics ranges from the scientific conception stage for airborne and space-based observatories, all the way through to the scientific return of these missions. It is our understanding of the under-lying physical processes and the measurements of critical physical parameters that allows us to address fundamental questions in astronomy and astrophysics. In this regard, laboratory astrophysics is much like detector and instrument development at NASA. These efforts are necessary for the success of astronomical research being funded by NASA. Without concomitant efforts in all three directions (observational facilities, detector/instrument development, and laboratory astrophysics) the future progress of astronomy and astrophysics is imperiled. In addition, new developments in experimental technologies have allowed laboratory studies to take on a new role as some questions which previously could only be studied theoretically can now be addressed directly in the lab. With this in mind we, the members of the AAS Working Group on Laboratory Astrophysics (WGLA), have prepared this White Paper on the laboratory astrophysics infrastructure needed to maximize the scientific return from NASA's space and Earth sciences program., Comment: White Paper submitted by the AAS Working Group on Laboratory Astrophysics (WGLA) to the National Academy of Science, Space Sciences Board, Ad Hoc Committee studying "The Role and Scope of Mission-Enabling Activities in NASA's Space and Earth Science Missions"

Laboratory astrophysics and complementary theoretical calculations are the foundations of astronomy and astrophysics and will remain so into the foreseeable future. The impact of laboratory astrophysics ranges from the scientific conception stage for ground-based, airborne, and space-based observatories, all the way through to the scientific return of these projects and missions. It is our understanding of the under-lying physical processes and the measurements of critical physical parameters that allows us to address fundamental questions in astronomy and astrophysics. In this regard, laboratory astrophysics is much like detector and instrument development at NASA, NSF, and DOE. These efforts are necessary for the success of astronomical research being funded by the agencies. Without concomitant efforts in all three directions (observational facilities, detector/instrument development, and laboratory astrophysics) the future progress of astronomy and astrophysics is imperiled. In addition, new developments in experimental technologies have allowed laboratory studies to take on a new role as some questions which previously could only be studied theoretically can now be addressed directly in the lab. With this in mind we, the members of the AAS Working Group on Laboratory Astrophysics, have prepared this State of the Profession Position Paper on the laboratory astrophysics infrastructure needed to ensure the advancement of astronomy and astrophysics in the next decade., Comment: Position paper submitted by the AAS Working Group on Laboratory Astrophysics (WGLA) to the State of the Profession (Facilities, Funding and Programs Study Group) of the Astronomy and Astrophysics Decadal Survey (Astro2010)

As the panel on Planetary Systems and Star Formation (PSF) is fully aware, the next decade will see major advances in our understanding of these areas of research. To quote from their charge, these advances will occur in studies of solar system bodies (other than the Sun) and extrasolar planets, debris disks, exobiology, the formation of individual stars, protostellar and protoplanetary disks, molecular clouds and the cold ISM, dust, and astrochemistry. Central to the progress in these areas are the corresponding advances in laboratory astro- physics which are required for fully realizing the PSF scientific opportunities in the decade 2010-2020. Laboratory astrophysics comprises both theoretical and experimental studies of the underlying physics and chemistry which produce the observed spectra and describe the astrophysical processes. We discuss four areas of laboratory astrophysics relevant to the PSF panel: atomic, molecular, solid matter, and plasma physics. Section 2 describes some of the new opportunities and compelling themes which will be enabled by advances in laboratory astrophysics. Section 3 provides the scientific context for these opportunities. Section 4 discusses some experimental and theoretical advances in laboratory astrophysics required to realize the PSF scientific opportunities of the next decade. As requested in the Call for White Papers, we present in Section 5 four central questions and one area with unusual discovery potential. We give a short postlude in Section 6., Comment: White paper submitted by the AAS Working Group on Laboratory Astrophysics (WGLA) to the PSF SFP of the Astronomy and Astrophysics Decadal Survey (Astro2010)

As the Galactic Neighborhood (GAN) panel is fully aware, the next decade will see major advances in our understanding of this area of research. To quote from their charge, these advances will occur in studies of the galactic neighborhood, including the structure and properties of the Milky Way and nearby galaxies, and their stellar populations and evolution, as well as interstellar media and star clusters. Central to the progress in these areas are the corresponding advances in laboratory astrophysics that are required for fully realizing the GAN scientific opportunities within the decade 2010-2020. Laboratory astrophysics comprises both theoretical and experimental studies of the underlying physics and chemistry that produces the observed astrophysical processes. The 5 areas of laboratory astrophysics that we have identified as relevant to the GAN panel are atomic, molecular, solid matter, plasma, and nuclear physics. In this white paper, we describe in Section 2 some of the new scientific opportunities and compelling scientific themes that will be enabled by advances in laboratory astrophysics. In Section 3, we provide the scientific context for these opportunities. Section 4 briefly discusses some of the experimental and theoretical advances in laboratory astrophysics required to realize the GAN scientific opportunities of the next decade. As requested in the Call for White Papers, Section 5 presents four central questions and one area with unusual discovery potential. Lastly, we give a short postlude in Section 6., Comment: White paper submitted by the AAS Working Group on Laboratory Astrophysics (WGLA) to the GAN SFP of the Astronomy and Astrophysics Decadal Survey (Astro2010)

As the Stars and Stellar Evolution (SSE) panel is fully aware, the next decade will see major advances in our understanding of these areas of research. To quote from their charge, these advances will occur in studies of the Sun as a star, stellar astrophysics, the structure and evolution of single and multiple stars, compact objects, SNe, gamma-ray bursts, solar neutrinos, and extreme physics on stellar scales. Central to the progress in these areas are the corresponding advances in laboratory astrophysics, required to fully realize the SSE scientific opportunities within the decade 2010-2020. Laboratory astrophysics comprises both theoretical and experimental studies of the underlying physics that produces the observed astrophysical processes. The 6 areas of laboratory astrophysics, which we have identified as relevant to the CFP panel, are atomic, molecular, solid matter, plasma, nuclear physics, and particle physics. In this white paper, we describe in Section 2 the scientific context and some of the new scientific opportunities and compelling scientific themes which will be enabled by advances in laboratory astrophysics. In Section 3, we discuss some of the experimental and theoretical advances in laboratory astrophysics required to realize the SSE scientific opportunities of the next decade. As requested in the Call for White Papers, Section 4 presents four central questions and one area with unusual discovery potential. Lastly, we give a short postlude in Section 5., Comment: White paper submitted by the AAS Working Group on Laboratory Astrophysics (WGLA) to the SSE SFP of the Astronomy and Astrophysics Decadal Survey (Astro2010)

As the Cosmology and Fundamental Physics (CFP) panel is fully aware, the next decade will see major advances in our understanding of these areas of research. To quote from their charge, these advances will occur in studies of the early universe, the microwave background, the reionization and galaxy formation up to virialization of protogalaxies, large scale structure, the intergalactic medium, the determination of cosmological parameters, dark matter, dark energy, tests of gravity, astronomically determined physical constants, and high energy physics using astronomical messengers. Central to the progress in these areas are the corresponding advances in laboratory astrophysics which are required for fully realizing the CFP scientific opportunities within the decade 2010-2020. Laboratory astrophysics comprises both theoretical and experimental studies of the underlying physics which produce the observed astrophysical processes. The 5 areas of laboratory astrophysics which we have identified as relevant to the CFP panel are atomic, molecular, plasma, nuclear, and particle physics. Here, Section 2 describes some of the new scientific opportunities and compelling scientific themes which will be enabled by advances in laboratory astrophysics. In Section 3, we provide the scientific context for these opportunities. Section 4 briefly discusses some of the experimental and theoretical advances in laboratory astrophysics required to realize the CFP scientific opportunities of the next decade. As requested in the Call for White Papers, Section 5 presents four central questions and one area with unusual discovery potential. Lastly, we give a short postlude in Section 6., Comment: White paper submitted by the AAS Working Group on Laboratory Astrophysics (WGLA) to the CFP SFP of the Astronomy and Astrophysics Decadal Survey (Astro2010)

As the Galaxies across Cosmic Time (GCT) panel is fully aware, the next decade will see major advances in our understanding of these areas of research. To quote from their charge, these advances will occur in studies of the formation, evolution, and global properties of galaxies and galaxy clusters, as well as active galactic nuclei and QSOs, mergers, star formation rate, gas accretion, and supermassive black holes. Central to the progress in these areas are the corresponding advances in laboratory astrophysics that are required for fully realizing the GCT scientific opportunities within the decade 2010-2020. Laboratory astrophysics comprises both theoretical and experimental studies of the underlying physics that produce the observed astrophysical processes. The 5 areas of laboratory astrophysics that we have identified as relevant to the CFP panel are atomic, molecular, solid matter, plasma, nuclear, and particle physics. In this white paper, we describe in Section 2 some of the new scientific opportunities and compelling scientific themes that will be enabled by advances in laboratory astrophysics. In Section 3, we provide the scientific context for these opportunities. Section 4 briefly discusses some of the experimental and theoretical advances in laboratory astrophysics required to realize the GCT scientific opportunities of the next decade. As requested in the Call for White Papers, Section 5 presents four central questions and one area with unusual discovery potential. Lastly, we give a short postlude in Section 6., Comment: White paper submitted by the AAS Working Group on Laboratory Astrophysics (WGLA) to the GCT SFP of the Astronomy and Astrophysics Decadal Survey (Astro2010)

A new optical constant facility has been developed at NASA Ames that will allow the determination of optical constants in the infrared of various materials, analogs of (exo)planetary hazes and cloud particles. Our facility is composed of a Fourier Transform Infrared (FTIR) spectrometer continuously covering the Near-IR to Far-IR range (from 0.74 to 200 μm), coupled to variable angle transmittance and reflectance accessories that allow the characterization of the scattering properties of non-homogeneous samples (laboratory (exo)planetary aerosol analogs, films, slabs of material, crystals, powders, etc.) over a wide incidence and emittance angle range (0-90 degrees). This new experimental setup allows the characterization of angular light distribution in both transmission and reflection measurements, and enables the determination of the complex indices of refraction, n and k, over the full NIR-FIR range via modeling of the laboratory measurements. The resulting refractive indices are critical input parameters in radiative transfer models, microphysical models, cloud models, protoplanetary disk simulations and other models used for the interpretation of observational data from past, current and future (exo)planetary NASA missions. Here we present a description of the facility along with the first determination of optical constants for Titan aerosol analogs produced in the Titan Haze Simulation (THS) experiment on COSmIC, a unique experimental setup developed at NASA Ames that allows the simulation of Titan’s complex atmospheric chemistry at Titan-like temperature (200 K). We also introduce a new study of the optical properties of ammonium-bearing phosphates, potential cloud particles forming in temperate exoplanets and brown dwarfs.

Understanding the origin of organic matter in astrophysical environments ranging from circumstellar (CS) outflows to diffuse and dense interstellar (IS) clouds to protoplanetary disks and planetary bodies has become a central objective in astrophysics. Experimental facilities dedicated to the formation and characterization of laboratory analogs generated under conditions relevant to the targeted environments have been developed in the past recent years. Recent advances achieved in laboratory astrophysics using COSmIC’s laboratory data in synergy with observational data will be presented. These results include the use of laboratory spectra to search for IS organic molecules and ions in astronomical spectra, the formation of laboratory analogs of CS and IS dust grains and planetary atmospheres aerosols from molecular precursors.

Here we present optical constants covering a broad wavelength range, from the visible to the far infrared, for Titan aerosol analogs produced in the Titan Haze Simulation (THS) experiment at Ames COSmIC facility, as well as other exoplanet-relevant materials.

Microphysical modeling of cloud formation and growth relies on fundamental measurements of the properties of condensable gases which form cloud particles. NASA's Ames Chemistry Laboratory has the capability to measure vapor pressures and heterogeneous nucleation conditions for a variety of gases found in the atmospheres of solar system bodies. Highlights from work for Earth, Mars, and Titan demonstrate the range of conditions and atmospheres studied to date.

Here we present a new optical constant facility developed at NASA Ames that will allow the determination of optical constants in the infrared of various materials, analogs of hazes and cloud particles in (exo)planet atmospheres and brown dwarfs. Our facility is composed of a Fourier Transform Infrared (FTIR) spectrometer continuously covering the Near-IR, mid-IR and Far-IR range (from 0.74 to 200 µm), coupled to variable angle transmittance and reflectance accessories that allow the characterization of the scattering properties of nonhomogeneous samples (laboratory planetary aerosol analogs, films, slabs of material, crystals, powders...) over a wide incidence and emittance angle range (0-90 degrees). This permits the angular light distribution in both transmission and reflection measurements to be characterized, enabling the determination of the complex indices of refraction, n and k, over the full NIR-FIR range via modeling of the laboratory observations. The resulting refractive indices are critical input parameters in radiative transfer models, exoplanet and brown dwarf cloud models, protoplanetary disk simulations and other models used for the interpretation of observational data from past, current and future (exo)planetary NASA missions. We will present preliminary data obtained on Titan aerosol analogs produced in the Titan Haze Simulation (THS) experiment on COSmIC, a unique experimental platform developed at NASA Ames that allows the simulation of Titan's complex atmospheric chemistry at Titan-like temperature (200 K). We will also introduce a new study of the optical properties of ammonium-bearing phosphates, potential cloud particles forming in temperate exoplanets and brown dwarfs.

The Cosmic SImulation Chamber (COSmIC) facility was developed at NASA Ames to study, in the laboratory, neutral and ionized molecules and nanoparticles under the low temperature and high vacuum conditions representative of interstellar, circumstellar and planetary environments. COSmIC is composed of a Pulsed Discharge Nozzle expansion that generates a plasma in a free supersonic jet expansion coupled to highsensitivity, complementary in situ diagnostic tools, used for the detection and characterization of the species present in the expansion: a Cavity Ring Down Spectroscopy and fluorescence spectroscopy systems operating in the UV-Visible range, and a Reflectron Time-Of-Flight Mass Spectrometer (ReTOF-MS). We will present recent advances that were achieved in laboratory astrophysics using COSmIC. These include advances in the domain of the diffuse interstellar bands (DIBs) and in the formation of dust grains and aerosols from their gas-phase molecular precursors in environments as varied as circumstellar outflows and planetary atmospheres. An extension of the spectral response of the facility into the infrared (IR) range is in progress with the addition of a high-resolution near-IR to mid-IR CRDS system that will allow to further investigate cosmic molecules and grains with COSmIC. Acquisition of laser induced fluorescence spectra of cosmic molecule analogs and the laser induced incandescence spectra of cosmic grain analogs are also planned. Preliminary results in these fronts will presented and the implications of the on-going studies for astronomy will be addressed.

Recent progress in astrochemistry and in our understanding of the Molecular Universe has been driven by new detector technologies and advances in ground-, airborne- and space astronomy coupled to new, innovative approaches in molecular spectroscopy. The search for the complex carbon-based molecules (PAHs, Fullerenes, nanoparticles) thought to be responsible for the ubiquitous infrared emission bands (UIBs) and optical absorption bands (DIBs) that are observed in various regions of the interstellar medium of local- and extragalactic environments illustrates the progress in spectroscopy techniques that has been driven by astronomy. Recent progresses reached in this domain will be discussed together with the laboratory techniques that have been developed to measure the spectra of laboratory analogs of cosmic molecules in the UV Visible-NIR range under experimental conditions that attempt to reproduce the interstellar conditions.

The COSmIC facility was developed at NASA Ames to study interstellar, circumstellar and planetary analogs in the laboratory]. COSmIC stands for "Cosmic Simulation Chamber" and is dedicated to the study of neutral and ionized molecules and nanoparticles under the low temperature and high vacuum conditions that are required to simulate space environments. COSmIC integrates a variety of instruments that allow generating; processing and monitoring simulated space conditions in the laboratory. It is composed of a Pulsed Discharge Nozzle (PDN) expansion that generates a plasma in a free supersonic jet expansion coupled to high-sensitivity, complementary in situ diagnostic tools, used for the detection and characterization of the species present in the expansion: a Cavity Ring Down Spectroscopy (CRDS) and fluorescence spectroscopy systems for photonic detection, and a Reflectron Time-Of-Flight Mass Spectrometer (ReTOF-MS) for mass detection. Recent advances achieved in laboratory astrophysics using COSmIC will be presented, in particular in the domain of the diffuse interstellar bands (DIBs) and the monitoring, in the laboratory, of the formation of dust grains and aerosols from their gasphase molecular precursors in environments as varied as circumstellar outflows and planetary atmospheres. Plans for future laboratory experiments on cosmic molecules and grains in the growing field of laboratory astrophysics (NIR-MIR CRDS, Laser Induced Fluorescence spectra of cosmic molecule analogs and the laser induced incandescence spectra of cosmic grain analogs) will also be addressed as well as the implications of the on-going studies for astronomy.

The Diffuse Interstellar Bands (DIBs) are a set of apporoximately 500 absorption bands that are seen in the spectra of reddened stars (i.e., stars obscured by the presence of interstellar clouds in their line of sight). The first DIBs were detected in the visible over a century ago. Diffuse Interstellar Bands are now detected from the near ultraviolet to the near infrared in the spectra of reddened stars spanning a variety of interstellar environments in our local, and in other galaxies. Although DIB carriers are a significant part of the interstellar chemical inventory as they account for a noticeable fraction of the interstellar extinction, the nature of their carriers is still unknown over a century after the detection of the first bands. DIB carriers are stable and ubiquitous in a broad variety of interstellar environments and play a unique role in interstellar physics and chemistry. It has long been realized that the solving of the DIB problem requires a strong synergy between astronomical observations, laboratory astrophysics and astrochemistry, quantum chemistry calculations and astrophysical modeling of line-of-sights. In this review, we'll present and discuss the current state of this perplexing problem. We'll review the progress and the failures that have been encountered in the long quest for the identification of the carriers of these ubiquitous interstellar bands.

We describe the characteristics and the capabilities of the laboratory facility, COSmIC, that was developed at NASA Ames to generate, process and analyze interstellar, circumstellar and planetary analogs in the laboratory. COSmIC stands for "Cosmic Simulation Chamber" and is dedicated to the study of neutral and ionized molecules and nanoparticles under the low temperature and high vacuum conditions that are required to simulate various space environments such as diffuse interstellar clouds, circumstellar outflows and planetary atmospheres. COSmIC integrates a variety of state-of-the-art instruments that allow recreating simulated space conditions to generate, process and monitor cosmic analogs in the laboratory. The COSmIC experimental setup is composed of a Pulsed Discharge Nozzle (PDN) expansion, that generates a plasma in the stream of a free supersonic jet expansion, coupled to high-sensitivity, complementary in situ diagnostics: cavity ring down spectroscopy (CRDS) and laser induced fluorescence (LIF) systems for photonic detection, and Reflectron Time-Of-Flight Mass Spectrometer (ReTOF-MS) for mass detection. Recent results obtained using COSmIC will be highlighted. In particular, the progress that has been achieved in the domain of the diffuse interstellar bands (DIBs) and in monitoring, in the laboratory, the formation of circumstellar dust grains and planetary atmosphere aerosols from their gas-phase molecular precursors. Plans for future laboratory experiments on interstellar and planetary molecules and grains will also be addressed, as well as the implications of the studies underway for astronomical observations and past and future space mission data analysis.

Cosmic carbon dust analogs are produced, processed and analyzed in the laboratory using NASA's COSmIC (COSmIC Simulation Chamber) Facility. These experiments can be used to derive information on the most efficient molecular precursors in the chemical pathways that eventually lead to the formation of carbonaceous grains in the stellar envelopes of carbon stars.