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The wavelength and rate of the $5p-5s$ transition of W XIV - W XVI ions have been calculated by the relativistic configuration interaction (RCI) method with the implementation of Flexible Atomic code (FAC). A reasonable collisional-radiative model (CRM) has been constructed to simulate the $5p - 5s$ transition spectrum of W XIV - W XVI ions which had been observed in electron beam ion trap (EBIT) device. The results are in reasonable agreement with the available experimental and theoretical data, and might be applied to identify the controversial spectra. The confusion on the assignment of the ionization stage are solved in the present work.

We present extreme ultraviolet spectra of Ag-like W$^{27+}$ observed with an electron beam ion trap. In the spectra, the $4f_{7/2, 5/2}$ -- $5s$ transitions are identified as the first observation of spontaneous electric octupole emission. Our theoretical investigation shows that the emission line intensity is strongly and specifically enhanced at the atomic number 74 by an anomalous behavior of cascading contribution to $5s$ via $5p\leftarrow5d$.

A detailed-level collisional-radiative model for the M1 transition spectrum of the Ca-like W$^{54+}$ ion as observed in an electron beam ion trap (EBIT) was constructed based on atomic data calculated by the relativistic configuration interaction method and distorted wave theory. The present calculated transition energy, rate and intensity of W$^{54+}$ M1 transitions are compared with previous theoretical and experimental values. The results are in reasonable agreement with the available experimental and theoretical data. The synthetic spectrum explained the EBIT spectrum in the 12-20 nm region, while a new possibly strong transition has been predicted to be observable with an appropriate electron beam energy. The present work provides accurate atomic data that may be used in plasma diagnostics applications.

We present laboratory spectra of the $3p$--$3d$ transitions in Fe$^{14+}$ and Fe$^{15+}$ excited with a mono-energetic electron beam. In the energy dependent spectra obtained by sweeping the electron energy, resonant excitation is confirmed as an intensity enhancement at specific electron energies. The experimental results are compared with theoretical cross sections calculated based on fully relativistic wave functions and the distorted-wave approximation. Comparisons between the experimental and theoretical results show good agreement for the resonance strength. A significant discrepancy is, however, found for the non-resonant cross section in Fe$^{14+}$. %, which can be considered as a fundamental cause of the line intensity ratio problem that has often been found in both observatory and laboratory measurements. This discrepancy is considered to be the fundamental cause of the previously reported inconsistency of the model with the observed intensity ratio between the $^3\!P_2$ -- $^3\!D_3$ and $^1\!P_1$ -- $^1\!D_2$ transitions.

Ejected material from neutron star mergers give rise to electromagnetic emission powered by radioactive decays of r-process nuclei, which is so called kilonova or macronova. While properties of the emission are largely affected by opacities in the ejected material, available atomic data for r-process elements are still limited. We perform atomic structure calculations for r-process elements: Se (Z=34), Ru (Z=44), Te (Z=52), Ba (Z=56), Nd (Z=60), and Er (Z=68). We confirm that the opacities from bound-bound transitions of open f-shell, Lanthanide elements (Nd and Er) are higher than those of the other elements over a wide wavelength range. The opacities of open s-shell (Ba), p-shell (Se and Te), and d-shell (Ru) elements are lower than those of open f-shell elements and their transitions are concentrated in the ultraviolet wavelengths. We show that the optical brightness can be different by >2 mag depending on the element abundances in the ejecta such that post-merger, Lanthanide-free ejecta produce brighter and bluer optical emission. Such blue emission from post-merger ejecta can be observed from the polar directions if the mass of the preceding dynamical ejecta in these regions is small. For the ejecta mass of 0.01 Msun, observed magnitudes of the blue emission will reach 21.0 mag (100 Mpc) and 22.5 mag (200 Mpc) in g and r bands within a few days after the merger, which are detectable with 1m or 2m-class telescopes., Comment: 11 pages, 9 figures, submitted to ApJ

A detailed level collisional-radiative model of the E1 transition spectrum of Ca-like W$^{54+}$ ion has been constructed. All the necessary atomic data has been calculated by relativistic configuration interaction (RCI) method with the implementation of Flexible Atomic Code (FAC). The results are in reasonable agreement with the available experimental and previous theoretical data. The synthetic spectrum has explained the EBIT spectrum in 29.5-32.5 \AA ,, while several new strong transitions has been proposed to be observed in 18.5-19.6 \AA , for the future EBIT experiment with electron density $n_e$ = $10^{12}$ cm$^{-3}$ and electron beam energy $E_e$ = 18.2 keV.

The electron correlation effects and Breit interaction as well as Quantum Electro-Dynamics (QED) effects were expected to have important contribution to the energy level and transition properties of heavy highly charged ions. The ground states [Ne]$3s^{2}3p^{6}3d^{2}$ and first excited states [Ne]3s$^{2}3p^{5}3d^{3}$ of W$^{54+}$ ion have been studied by using Multi-Configuration Dirac-Fock method with the implementation of Grasp2K package. A restricted active space was employed to investigate the correlation contribution from different models. The Breit interaction and QED effects were taken into account in the relativistic configuration interaction calculation with the converged wavefunction. It is found that the correlation contribution from 3s and 3p orbital have important contribution to the energy level, transition wavelength and probability of the ground and the first excited state of W$^{54+}$ ion.

We present direct observation of the M1 transition between the fine structure splitting in the 4f13 5s2 5p6 2F ground state of W VIII. The spectroscopic data of few-times ionized tungsten ions are important for the future ITER diagnostics, but there is a serious lack of data. The present study is part of an ongoing effort to solve this lack. Emission from the tungsten ions produced and trapped in a compact electron beam ion trap is observed with a Czerny-Turner visible spectrometer. Spectra in the EUV range are also observed at the same time to help the identification of the previously-unreported visible lines. The observed wavelength 574.47 pm 0.03 nm (air), which corresponds to the fine structure splitting of 17402.5 pm 0.9 cm-1, shows reasonable agreement with the previously reported value 17410 pm 5 cm-1 obtained indirectly through the analysis of EUV spectra [Ryabtsev et al., Atoms 3 (2015) 273].

A comprehensive theoretical study of the E1, M1, E2 transitions of Ca-like tungsten ions is presented. Using multi-configuration Dirac-Fock (MCDF) method with a restricted active space treatment, the wavelengths and probabilities of the M1 and E2 transitions between the multiplets of the ground state configuration ([Ne]3s$^{2}$3p$^{6}$3d$^{2}$) and of the E1 transitions between [Ne]3s$^{2}$3p$^{5}$3d$^{3}$ and [Ne]3s$^{2}$3p$^{6}$3d$^{2}$ have been calculated. The results are in reasonable agreement with available experimental data. The present E1 and M1 calculations are compared with previous theoretical values. For E2 transitions, the importance of electron correlation from 3s and 3p orbitals is pointed out. Several strong E1 transitions are predicted, which have potential advantage for plasma diagnostics.

Plasma diagnostics in magnetic confinement fusion plasmas by using visible spectrum strongly depends on the knowledge of fundamental atomic properties. A detailed collisional-radiative model of W$^{26+}$ ions has been constructed by considering radiative and electron excitation processes, in which the necessary atomic data had been calculated by relativistic configuration interaction method with the implementation of Flexible Atomic Code. The visible spectrum observed at an electron beam ion trap (EBIT) in Shanghai in the range of 332 nm to 392 nm was reproduced by present calculations. Some transition pairs of which the intensity ratio are sensitive to the electron density were selected as potential candidate of plasma diagnostics. Their electron density dependence are theoretically evaluated for the cases of EBIT plasmas and magnetic confinement fusion plasmas.

We present extreme ultraviolet and visible spectra of promethiumlike tungsten and gold obtained with an electron beam ion trap (EBIT). Although the contributions from a few charge states are involved in the spectra, the charge state of the ion assigned to the observed lines is definitely identified by the time-of-flight analysis of the ions performed at the same time with the spectroscopic measurements. Experimental results are compared with collisional-radiative model calculations as well as previous experimental and theoretical studies.