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Abstract Wide-bandgap (WBG) perovskite solar cells (PSCs) are employed as top cells of tandem cells to break through the theoretical limits of single-junction photovoltaic devices. However, WBG PSCs exhibit severe open-circuit voltage (V oc) loss with increasing bromine content. Herein, inhomogeneous halogen-phase distribution is pointed out to be the reason, which hinders efficient extraction of carriers. We thus propose to form homogeneous halogen-phase distribution to address the issue. With the help of density functional theory, we construct a double-layer structure (D-2P) based on 2-(9H-Carbazol-9-yl)ethyl]phosphonic acid molecules to provide nucleation sites for perovskite crystallization. Homogeneous perovskite phase is achieved through bottom-up templated crystallization of halogen component. The efficient carrier extraction reduces the Shockley-Read-Hall recombination, resulting in a high V oc of 1.32 V. As a result, D-2P-treated device (1.75 eV) achieves a record power conversion efficiency of 20.80% (certified 20.70%), which is the highest value reported for WBG (more than 1.74 eV) PSCs.

This study investigated the potential use of biochar produced from Iraqi date kernels (Khestawi) as an adsorbent for methylene blue (MB) removal from polluted water. A full factorial design methodology was employed to examine the effects of heating rate, pyrolysis temperature and holding time on the performance of the produced biochar. The results showed that pyrolysis temperature and time had a strong effect on the biochar performance, while the heating rate had a weaker effect. The biochar produced at pyrolysis temperatures of 350°C and 550°C exhibited MB removal percentages (% R) of 48.9% and 30.9%, respectively. Similarly, biochar production through pyrolysis durations of 30 and 90 minutes resulted in MB removal rates of 47.5% and 30.3%, respectively. The adsorption experimental data was well-fitted by the Freundlich isotherm model, with a high value of the Freundlich constant (KF = 1.64), indicating a high adsorption capacity of the biochar. The activation of biochar using bio-oil (organic-1) led to a substantial enhancement in the adsorption capacity, with the activated biochar (ABC-1) exhibiting a higher adsorption capability and a higher value of the Freundlich constant (KF = 7.12). Overall, the results suggest that biochar produced from date kernels has the potential as an effective and sustainable adsorbent for MB removal from polluted water, with the potential for further enhancement through biochar activation.

Desert environments harbor unique microbial communities. This study focuses on Cellulosimicrobium funkei isolate RVMD1, isolated from rock varnish in the Ma’an Desert. Initial identification was achieved using 16S rRNA gene sequencing, followed by whole-genome sequencing (WGS) for comprehensive characterization. The genome comprises 4,264,015 base pairs (857 contigs) with a high G + C content of 74.59%. A total of 4,449 proteins were predicted. Comparative analysis utilizing OrthoANI, ANI, AAI, and dDDH metrics suggests that RVMD1 belongs to the C. cellulans group, with the highest similarity to C. funkei (97.71% ANI). Phylogenomic analysis of 43 Cellulosimicrobium genomes revealed significant heterogeneity within the genus. Our results challenge current systematics, with C. cellulans potentially representing up to 9 distinct genomospecies. Isolate RVMD1 shows genetic adaptations to its desert environment, including genes for denitrification, oxygen and sulfur cycling, and diverse hydrogen metabolism. Pangenomic analysis uncovered a considerable number of unique genes within RVMD1, highlighting its genetic distinctiveness. Gene family expansions suggest evolution in response to stressors like UV radiation and nutrient limitation. This study represents the first whole-genome analysis of a bacterium isolated from Jordanian rock varnish, emphasizing the value of WGS in understanding microbial diversity and adaptation in extreme environments.

IntroductionGroundwater demand has been considerably heightened due to rapid urban growth, specifically in arid areas that rely primarily on groundwater. This study aims to utilize remote sensing and aeromagnetic data, combined with the Analytic Hierarchy Process (AHP) based GIS, to evaluate potential groundwater zones in the Sohag area, Egypt.MethodsNine thematic layers, including soil moisture, rainfall, lithology, normalized difference vegetation index (NDVI), drainage density, lineament density, slope, and land use/land cover, were developed using various remote sensing datasets. Besides the remote sensing-derived thematic layers, a geophysics-derived thematic layer represented by the RTP aeromagnetic map was included. The aeromagnetic data were analyzed and interpreted to outline the subsurface structure affecting groundwater storage and flow. Also, the aeromagnetic data analysis helps estimate the basement depth that constitutes the Nubian Aquifer’s base and identifies regions with considerable thick sedimentary deposits and significant water reserves.Results and discussionThe groundwater potentiality map was consistent with production wells in the area, and sites for drilling new wells were predicted, especially in the Nile Valley around the Tahta, El-Hamimia, and west Sohag cities. The most promising sites are clustered along the Nile Valley, and the study area’s northwestern and northeastern parts. The results indicate that the predominant magnetic structural trends are NW-SE, NE-SW, N-S, and E-W, which contribute to the formation of a series of subsurface horsts (H) and grabens (G). Three main basins (A, B, and C) were identified as the most profound areas. These basins represent the most promising areas for groundwater accumulation, making them attractive for future hydrogeological exploration. This integrated approach strongly offers a powerful and effective tool to assist in developing an appropriate plan to manage groundwater in arid regions.

Background: Globally, resistance to antimicrobial drugs is a major hazard to public health. Infections that were once easily treatable with antibiotics are becoming harder to control, leading to prolonged illnesses, increased mortality rates, and higher healthcare costs. Aim: This study intended to assess the antimicrobial, specifically the anti- Methicillin-resistant Staphylococcus aureus (MRSA) , and anticancer properties of different extracts obtained from A. herba-alba (AHA). Methods: The antibacterial tests of AHA were performed on two Gram-negative bacterial strains (Escherichia coli and Klebsiella pneumonia), two Gram-positive bacterial strains (Methicillin-resistant Staphylococcus aureus (MRSA) and Staphylococcus aureus). Initial screening for antibacterial activities was conducted using the agar-disc diffusion technique. Subsequently, the minimum inhibitory concentration (MIC) and minimum bactericidal concentration (MBC) were determined through the broth-dilution assay. The anticancer test was carried out in vitro on a human colorectal carcinoma cell line (HCT-116) using 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide, a tetrazole) )MTT( method. Results: Among all extracts, n-hexane extract of AHA was the most effective against S. aureus with the highest inhibition zone (24.67 mm) comparing to standard antibiotic (erythromycin, 24.00 mm) followed by the methanolic extract against MRSA (24.00 mm). The methanol extract of AHA showed the highest antibacterial activity against MRSA. The results of MIC and MBC of the AHA methanol extract against MRSA were 1.17±1.09 mg/mL and 9.375±0.0 mg/mL, respectively demonstrated therapeutically significant antibacterial activity. Ethyl acetate extract has no antibacterial activity against E. coli and K. pneumonia. The findings indicated that the methanol extract of AHA exhibited the highest efficacy against the colorectal carcinoma cell line (HCT-116), with an IC50 value of 126.61±13.35 µg/mL. Conclusion: These findings suggest that methanol extract of AHA could be considered as a potential agent to serve as a source of antibacterial and anticancer compounds. [Open Vet J 2024; 14(4.000): 990-1001]

The Sb3+ doping strategy has been proven to be an effective way to regulate the band gap and improve the photophysical properties of organic-inorganic hybrid metal halides (OIHMHs). However, the emission of Sb3+ ions in OIHMHs is primarily confined to the low energy region, resulting in yellow or red emissions. To date, there are few reports about green emission of Sb3+-doped OIHMHs. Here, we present a novel approach for regulating the luminescence of Sb3+ ions in 0D C10H22N6InCl7·H2O via hydrogen bond network, in which water molecules act as agents for hydrogen bonding. Sb3+-doped C10H22N6InCl7·H2O shows a broadband green emission peaking at 540 nm and a high photoluminescence quantum yield (PLQY) of 80%. It is found that the intense green emission stems from the radiative recombination of the self-trapped excitons (STEs). Upon removal of water molecules with heat, C10H22N6In1-xSbxCl7 generates yellow emission, attributed to the breaking of the hydrogen bond network and large structural distortions of excited state. Once water molecules are adsorbed by C10H22N6In1-xSbxCl7, it can subsequently emit green light. This water-induced reversible emission switching is successfully used for optical security and information encryption. Our findings expand the understanding of how the local coordination structure influences the photophysical mechanism in Sb3+-doped metal halides and provide a novel method to control the STEs emission.

In this paper, an attempt has been made to investigate the impacts of leaching on the geotechnical and microstructural properties of clayey gypseous soils at various percentages of gypsum; 20 %, 40 %, and 60 %, and their respective densities. In this respect, the work delves into the interaction of the properties based on the following experiments: oedometer permeability leaching and modified permeability leaching tests for investigating the effects of gypsum content, density, and leachate on significant soil properties such as compressibility, permeability, and Total dissolved solids (TDS). Scanning electron microscopy (SEM) and Energy dispersive spectroscopy (EDS) used for microstructural analysis reveal how the soil fabric and dissolution patterns change during leaching. The conclusions derived from the results of the study state that with an increase in the content of gypsum in soil, it increases the porosity and permeability of the soil and at the same time decreases the plasticity. The soils which were denser showed lesser leaching strain due to reduced permeability. It can be ascertained that the modified leaching test is a more realistic and accurate method in comparison to the oedometer test. Results from microstructural observations hence bring out important changes in the soil fabric after leaching: increases in voids and cavities responsible for the change of soil stability and engineering properties. This research allows a good contribution to understanding and the management of gypseous soil behavior in geotechnical engineering projects and provides new lines of future investigation for the long-term performance and stabilization technique of effectiveness.

Image semantic segmentation using deep learning algorithms plays a vital role in identifying different rock-forming minerals. In this paper, we employ the U-net model for its architecture that guarantees precise localization and efficient data utilization. We implement this deep learning model across two distinct datasets: (1) the first dataset from the ALEX Streckeisen website, and (2) the second dataset from the Gabal Nikeiba area, South Eastern Desert of Egypt. Our model exhibits excellent performance in both datasets, with an average accuracy of precision at 0.89 and 0.83, recall at 0.80 and 0.78, and F1 score at 0.82 and 0.79, respectively, helping in identifying and detecting rock-forming minerals in thin-section images. The model’s most exceptional performance is clearly in eleven different basement rock-forming minerals with precision up to 0.89, recall at 0.80, and F1 score at 0.82 on average. This study is significant as it represents the key to identifying and detecting minerals in the thin sections of rock samples in Egypt and the Arabian–Nubian Shield as a whole. By significantly reducing analysis time and improving accuracy compared to manual methods, it revolutionizes geological research and resource exploration in the region.

The Igla Ahmr region in the Central Eastern Desert (CED) of Egypt comprises mainly syenogranites and alkali feldspar granites, with a few tonalite xenoliths. The mineral potential maps were presented in order to convert the concentrations of total rare earth elements (REEs) and associated elements such as Zr, Nb, Ga, Y, Sc, Ta, Mo, U, and Th into mappable exploration criteria based on the line density, five alteration indices, random forest (RF) machine learning, and the weighted sum model (WSM). According to petrography and geochemical analysis, random forest (RF) gives the best result and represents new locations for rare metal mineralization compared with the WSM. The studied tonalites resemble I-type granites and were crystallized from mantle-derived magmas that were contaminated by crustal materials via assimilation, while the alkali feldspar granites and syenogranites are peraluminous A-type granites. The tonalites are the old phase and are considered a transitional stage from I-type to A-type, whereas the A-type granites have evolved from the I-type ones. Their calculated zircon saturation temperature TZr ranges from 717 °C to 820 °C at pressure < 4 kbar and depth < 14 km in relatively oxidized conditions. The A-type granites have high SiO2 (71.46–77.22 wt.%), high total alkali (up to 9 wt.%), Zr (up to 482 ppm), FeOt/(FeOt + MgO) ratios > 0.86, A/CNK ratios > 1, Al2O3 + CaO < 15 wt.%, and high ΣREEs (230 ppm), but low CaO and MgO and negative Eu anomalies (Eu/Eu* = 0.24–0.43). These chemical features resemble those of post-collisional rare metal A-type granites in the Arabian-Nubian Shield (ANS). The parent magma of these A-type granites was possibly derived from the partial melting of the I-type tonalitic protolith during lithospheric delamination, followed by severe fractional crystallization in the upper crust in the post-collisional setting. Their rare metal-bearing minerals, including zircon, apatite, titanite, and rutile, are of magmatic origin, while allanite, xenotime, parisite, and betafite are hydrothermal in origin. The rare metal mineralization in the Igla Ahmr granites is possibly attributed to: (1) essential components of both parental peraluminous melts and magmatic-emanated fluids that have caused metasomatism, leading to rare metal enrichment in the Igla Ahmr granites during the interaction between rocks and fluids, and (2) structural control of rare metals by the major NW–SE structures (Najd trend) and conjugate N–S and NE–SW faults, which all are channels for hydrothermal fluids that in turn have led to hydrothermal alteration. This explains why rare metal mineralization in granites is affected by hydrothermal alteration, including silicification, phyllic alteration, sericitization, kaolinitization, and chloritization.

Drinking water defluoridation has attracted significant attention in the scientific community, from which membrane technology, by exploring thin film nanocomposite (TFN) membranes, has demonstrated a great potential for treating fluoride-contaminated water. This study investigates the development of a TFN membrane by integrating titanium oxide nanosheets (TiO2 NSs) into the polyamide (PA) layer using interfacial polymerization. The characterization results suggest that successfully incorporating TiO2 NSs into the PA layer of the TFN membrane led to a surface with a high negative charge, hydrophilic properties, and a smooth surface at the nanoscale. The TFN membrane, containing 80 ppm of TiO2 NSs, demonstrated a notably high fluoride rejection rate of 98%. The Donnan-steric-pore-model-dielectric-exclusion model was employed to analyze the effect of embedding TiO2 NSs into the PA layer of TFN on membrane properties, including charge density (Xd), the pore radius (rp), and pore dielectric constant (εp). The results indicated that embedding TiO2 NSs increased Xd and decreased the εp by less than the TFC membrane without significantly affecting the rp. The resulting TFN membrane demonstrates promising potential for application in water treatment systems, providing an effective and sustainable solution for fluoride remediation in drinking water.

The emergence of drug-resistant microorganisms presents a substantial global public health threat. The increase in pathogens resistant to commonly prescribed antibiotics underscores the urgent requirement to explore alternative treatment strategies. This study adopts a novel approach by harnessing natural resources, specifically essential oils (EO), to combat bacterial pathogenicity. The primary aim of this research was to analyze the chemical composition of the aerial part of the Matricaria aurea (M. aureas) EO and evaluate its potential for inhibiting quorum sensing (QS) and disrupting biofilm formation in Pseudomonas aeruginosa (P. aeruginosa). The gas chromatography-mass spectrometry (GCMS) analysis unveiled that α-bisabolol oxide A constituted the predominant portion, comprising 64.8% of the total, with β-bisabolene at 6.3% and α-farnesene at 4.8% following closely behind. The antibiofilm efficacy was observed at concentrations of 0.3, 0.15, and 0.08 mg/mL, demonstrating negligible effects on cell viability. Furthermore, the EO from M. aurea effectively inhibited the formation of P. aeruginosa biofilms by diminishing aggregation, hydrophobicity, and swarming motility. Significantly, the EO treatment resulted in a conspicuous decrease in the production of pyocyanin, rhamnolipid, and extracellular polymeric substances (EPS), along with a reduction in the enzymatic activity of protease and chitinase. The EO effectively hindered QS by disrupting QS mechanisms, resulting in a marked decline in the secretion of N-Acyl homoserine lactone (AHL) molecules and the expression of phazA1 and aprA genes. This investigation offers compelling evidence supporting the potential of M. aurea EO as a promising therapeutic candidate for addressing infectious diseases induced by biofilm formation.

Additionally, it has been demonstrated that osseointegrated implantation offers superior proprioception and control over the prosthesis, enabling more natural movement and improved functional results. Additionally, it lowers the chance of falling and increases energy transfer efficiency, making it simpler for amputees to engage in physical activity. Furthermore, as compared to conventional socket prosthesis attachment, osseointegrated implantation has been linked to higher patient satisfaction and quality of life. It is crucial to remember that osseointegration is a surgical operation with risks including infection and implant failure. Additionally, for effective implantation, it needs a specific amount and quality of bone, which may restrict its usage in some individuals. Furthermore, osseointegrated implantation could be more expensive than conventional socket prosthetics. Understanding the efficacy and safety of this method requires research on complication rates and outcome metrics in patients having osseointegrated prosthesis implantation. You may acquire information on things like infection rates, implant failure, patient satisfaction, and functional results by studying original research papers. Clinical decision-making can then be improved with the use of this information. In transfemoral amputees, osseointegration has showed promise as a powerful substitute for socket prostheses. A growing corpus of research has shown that osseointegrated implantation provides advantages in terms of increasing mobility, decreasing discomfort, and improving general quality of life. The efficiency of osseointegration for transtibial and upper extremity implants has received little attention. Minor soft tissue infections are the most frequent consequences, although they are manageable with the right treatment and monitoring. To further reduce the risk of problems and improve the overall success of osseointegrated implantation, research and development are ongoingly focused on enhancing surgical methods and implant design. Although osseointegration has a lot of potential, not all amputees may be good candidates for it. Considerations for osseointegrated implantation must take into consideration elements including the degree and nature of the amputation, the quality and density of the bone, and the desires of the patient.

ويهدف البحث إلى دراسة أثر بعض المتغيرات الاقتصادية والمتمثلة في (الناتج المحلي الإجمالي، سعر الصرف، الرقم القياسي لأسعار المستهلك، النفقات العامة، عرض النقد M1)، في سوق العراق للأوراق المالية المعبر عنه بالمؤشر العام للسوق، وفي دراستنا هذه تم اعتماد منهجية الانحدار الذاتي ذات فترات الإبطاء الموزعة (ARDL) التي أثبتت تماشيها مع قياس أثر هذه المتغيرات في مؤشر السوق المالي، وكذلك طبيعة السلاسل الزمنية من حيث درجة الاستقرارية، أثبتت نتائج النموذج القياسي (ARDL)، وجود علاقة تكامل مشترك بين المتغيرات المستعملة في النموذج القياسي، أي أن هناك علاقة توازنية طويلة الأجل بين متغيرات البحث في سوق العراق للأوراق المالية، فيما أوصى الباحث مواصلة البحث بالدراسات المتعمقة لمحددات الاستثمار في الأسواق المالية الأخرى، والأكثر تفسيراً للتغيرات التي تحصل في المؤشر العام للسوق المالي، والتنبؤ بالأزمات المستقبلة في هذه الأسواق.

Abstract Objective Ectopic fat deposition within and around organs is a stronger predictor of cardiometabolic disease status than body mass index (BMI). Fat deposition within the lymphatic system is poorly understood. This study examined the association between the prevalence of cardiometabolic disease and ectopic fat deposition within axillary lymph nodes (LNs) visualized on screening mammograms. Methods A cross‐sectional study was conducted on 834 women presenting for full‐field digital screening mammography. The status of fat‐infiltrated LNs was assessed based on the size and morphology of axillary LNs from screening mammograms. The prevalence of cardiometabolic disease was retrieved from the electronic medical records, including type 2 diabetes mellitus (T2DM), hypertension, dyslipidemia, high blood glucose, cardiovascular disease, stroke, and non‐alcoholic fatty liver disease. Results Fat‐infiltrated axillary LNs were associated with a high prevalence of T2DM among all women (adjusted odds ratio: 3.92, 95% CI: [2.40, 6.60], p‐value < 0.001) and in subgroups of women with and without obesity. Utilizing the status of fatty LNs improved the classification of T2DM status in addition to age and BMI (1.4% improvement in the area under the receiver operating characteristic curve). Conclusion Fat‐infiltrated axillary LNs visualized on screening mammograms were associated with the prevalence of T2DM. If further validated, fat‐infiltrated axillary LNs may represent a novel imaging biomarker of T2DM in women undergoing screening mammography.

Microbial antibiotic resistance is rapidly increasing as a result of overuse or misuse of antibiotics, as well as a lack of new, effective antibiotics. Alternative antimicrobial treatments, such as nanoparticles, and their potential for stronger synergetic effect when paired with other active chemicals, could be a viable option. This study is prepared to estimate the antibacterial activity of silver nanoparticles (AgNPs) that have been synthesized using the biomass-free filtrate of Aspergillus flavus. The formation of AgNPs was reported by color changed to a dark brownish-black after 72 hours of incubation. The AgNPs surface plasmon resonance peak was indicated in the UV–Vis spectrum at 427 nm. The synthesis of AgNPs with a nanoparticle size of 10 to 35 nm was validated using transmission electron microscopy. The increase in folding area was calculated to detect the synergistic potential of the combined AgNPs with a broad range of conventional antibiotics. AgNPs have broad-spectrum activity against all strains tested. The most sensitive strain was Escherichia coli (11 mm), whereas the most resistant strain was Pseudomonas aeruginosa, as indicated by the lowest inhibition zone (7 mm). The lowest Minimum Inhibitory Concentration indicated was against K. pneumonia and Enterobacter cloacae (0.025 mg/mL, each), followed by Staphylococcus epidermidis (0.05 mg/mL), E. coli and Shigella sp. (0.075 mg/mL, each), and then S. aureus (0.1 mg/mL). Notable synergy was reported between AgNPs and either ampicillin, erythromycin, ceftriaxone, vancomycin, azlocillin, or amoxicillin against S. aureus in the range between 29.3-fold to 8-fold. In addition, synergy was seen between AgNPs and either vancomycin, clindamycin, or erythromycin against P. aeruginosa (31.1-8.0-fold). Also, a maximum increase in IFA when erythromycin and vancomycin were synergized with AgNPs against E. cloacae was reported (IFA of 10.0 and 9.0, respectively). Similarly, AgNPs with either aztreonam or azlocillin against E. coli and amoxicillin, ciprofloxacin, or ceftriaxone against Shigella sp. caused an increase in the fold area of inhibition of between 5.3-3.7-fold. This result may have an advantage in encouraging the use of combined AgNPS with conventional antibiotics in treating infectious diseases caused by antibiotic-resistant bacteria.

This work explored the activities of bergamot oil nano-emulsion (NBG) in modulating blood biochemical parameters, redox status, immunity indices, inflammation markers, semen quality, testicular changes and the expression of HSPs genes in stressed rabbit bucks. Twenty-four mature rabbit bucks (5 months) were randomly divided into three groups; control group (NBG0) received 1 ml of distilled water, while the other two groups received NBG orally at doses of 50 and 100 mg/kg (bw) twice a week. The present study's findings revealed that treated groups had lower values of total and direct bilirubin, triglyceride, lactate dehydrogenase, and creatinine compared with NBG0 group (p

The tRNA adaptation index (tAI) is a translation efficiency metric that considers weighted values (Sij values) for codon–tRNA wobble interaction efficiencies. The initial implementation of the tAI had significant flaws. For instance, generated Sij weights were optimized based on gene expression in Saccharomyces cerevisiae, which is expected to vary among different species. Consequently, a species-specific approach (stAI) was developed to overcome those limitations. However, the stAI method employed a hill climbing algorithm to optimize the Sij weights, which is not ideal for obtaining the best set of Sij weights because it could struggle to find the global maximum given a complex search space, even after using different starting positions. In addition, it did not perform well in computing the tAI of fungal genomes in comparison with the original implementation. We developed a novel approach named genetic tAI (gtAI) implemented as a Python package (https://github.com/AliYoussef96/gtAI), which employs a genetic algorithm to obtain the best set of Sij weights and follows a new codon usage-based workflow that better computes the tAI of genomes from the three domains of life. The gtAI has significantly improved the correlation with the codon adaptation index (CAI) and the prediction of protein abundance (empirical data) compared to the stAI.

Background: Obesity is a complex metabolic disorder that is associated with several diseases. Recently, precision nutrition (PN) has emerged as a tailored approach to provide individualised dietary recommendations. Aim: This review discusses the major intrinsic and extrinsic components considered when applying PN during the management of obesity and common associated chronic conditions. Results: The review identified three main PN components: gene–nutrient interactions, intestinal microbiota, and lifestyle factors. Genetic makeup significantly contributes to inter-individual variations in dietary behaviours, with advanced genome sequencing and population genetics aiding in detecting gene variants associated with obesity. Additionally, PN-based host-microbiota evaluation emerges as an advanced therapeutic tool, impacting disease control and prevention. The gut microbiome’s composition regulates diverse responses to nutritional recommendations. Several studies highlight PN’s effectiveness in improving diet quality and enhancing adherence to physical activity among obese patients. PN is a key strategy for addressing obesity-related risk factors, encompassing dietary patterns, body weight, fat, blood lipids, glucose levels, and insulin resistance. Conclusion: PN stands out as a feasible tool for effectively managing obesity, considering its ability to integrate genetic and lifestyle factors. The application of PN-based approaches not only improves current obesity conditions but also holds promise for preventing obesity and its associated complications in the long term.

Solar cells can be designed for indoor applications to provide a feasible solution for harnessing photon energy from indoor lighting. In this paper, we analyze the suitability of a selenium-based solar cell for gathering photon energy emitted by indoor light-emitting diodes (LEDs). The absorption band of selenium (Se) is found to be aligned with the LED spectrum, making it a promising contender for efficient indoor applications. In order to simulate the Se-based photovoltaic (PV) device, we started by calibrating the simulation model against a fabricated Se cell that was tested under AM1.5G. After the verification of the physical models and the technological key factors of the different layers incorporated in cell design, a systematic approach was performed to assess the operation of the Se solar cell under an LED light environment. We show an optimized power conversion efficiency (PCE) of 26.93% for the Se-based cell under LED illumination (311 μW/cm2). This is achieved by providing an effective design that incorporates a double-ETL structure, which can significantly improve the band alignment between the different layers of the cell device. The simulation results presented in this work serve to judge the potential of Se solar cells as indoor PVs and offer an approach for providing indoor use specifically designed for internet-of-things (IoT) devices.

The study aimed to identify the similarities between the activities of athletics in sport injuries according to the body parts for males and females players in clubs and institutions of federal Iraq championship which is established in Baghdad (4-7 / 11 / 2020). The researcher depended on descriptive method where the research sample consists of 139 male and female players. 100 male players and 39 female players where participated in the study from most of Iraq provinces and the research depends on the questionnaire form which is prepared accurately by the researcher which was presented to many experts and coaches of the track and field games where the questionnaire included specifying the locations, types and the most important causes of its occurrence for sport injuries, the data processed statically by using the percentage and the grade correlation coefficient between injuries according to parts of the body for athletics activities. The results of the research shown that the percentage of common sport injuries for the advanced participants in the track and field games championship according to the type of the game and the location of the injury, also the study shown the similarities between the activities of running for short, medium and long distances concerning the male players while for the female players the results shown the similarities in running for short and medium distances, also there is similarities between the injuries of running for medium distances, throwing, jumping and heptathion, where a number of recommended and suggestions are presented.

In this study, we investigated the optoelectronic properties of cubic (Pm3m) and orthorhombic (Pnma) CsPbX3 (X = I, Br, and Cl). We utilized the full potential linear augmented plane wave method, which is implemented in the WIEN2k code, to facilitate the investigation. Different exchange potentials were used to analyze the optoelectronic behavior using the available density functional theory methods. Our findings revealed that CsPbX3 perovskites display direct band gaps at the R and Г points for cubic (Pm3m) and orthorhombic (Pnma) structures, respectively. Among the exchange potentials, the mBJ-GGA method provided the most accurate results. These outcomes concurred with the experimental results. In both Pm3m and Pnma structures, interesting changes were observed when iodide (I) was replaced with bromine (Br) and then chlorine (Cl). The direct band gap at the R and Г points shifted to higher energy levels. Similarly, when I was replaced with Br and Cl, there was a noticeable decrease in the absorption coefficient, dielectric constants, refractive index, and reflectivity, in addition to a band gap shift to higher energy levels.

High percentage of the Iraqi population profoundly rely on folk medicine to meet their health needs which makes their safety questionable. This study aims to evaluate Iraqi herbalists' knowledge and practice to ensure the public's safety. This study was conducted in a cross-sectional design between October 2021 and March 2022, using a pretested questionnaire administered to Iraqi herbalists practicing in Middle Euphrates Area. Through face-to-face meetings, participants completed a multicomponent questionnaire comprising 15 items in four sections. The data obtained were analyzed using a statistical package for social sciences; Chi-square was used to correlate some variables, and P-values of

Attacking a transferred data over a network is frequently happened millions time a day. To address this problem, a secure scheme is proposed which is securing a transferred data over a network. The proposed scheme uses two techniques to guarantee a secure transferring for a message. The message is encrypted as a first step, and then it is hided in a video cover. The proposed encrypting technique is RC4 stream cipher algorithm in order to increase the message's confidentiality, as well as improving the least significant bit embedding algorithm (LSB) by adding an additional layer of security. The improvement of the LSB method comes by replacing the adopted sequential selection by a random selection manner of the frames and the pixels with two secret random keys. Therefore, the hidden message remains protected even if the stego-object is hacked because the attacker is unable to know the correct frames and pixels that hold each bit of the secret message in addition to difficulty to successfully rebuild the message. The results refer to that the proposed scheme provides a good performance for evaluation metric that is used in this purpose when compared to a large number of related previous methods.

Perovskite-type lead halides exhibit promising performances in optoelectronic applications, for which lasers are one of the most promising applications. Although the bulk structure has some advantages, perovskite has additional advantages at the nanoscale owing to its high crystallinity given by a lower trap density. Although the nanoscale can produce efficient light emission, its comparatively poor chemical and colloidal stability limits further development of devices based on this material. Nevertheless, bulk perovskites are promising as optical amplifiers. There has been some developmental progress in the study of optical response and amplified spontaneous emission (ASE) as a benchmark for perovskite bulk phase laser applications. Therefore, to achieve high photoluminescence quantum yields (PLQYs) and large optical gains, material development is essential. One of the aspects in which these goals can be achieved is the incorporation of a bulk structure of high-quality crystallization films based on inorganic perovskite, such as cesium lead halide (CsPb(Br/Cl)3), in polymethyl methacrylate (PMMA) polymer and encapsulation with the optimal thickness of the polymer to achieve complete surface coverage, prevent degradation, surface states, and surface defects, and suppress emission at depth. Sequential evaporation of the perovskite precursors using a single-source thermal evaporation technique (TET) effectively deposited two layers. The PL and ASEs of the bare and modified films with a thickness of 400 nm PMMA were demonstrated. The encapsulation layer maintained the quantum yield of the perovskite layer in the air for more than two years while providing added optical gain compared to the bare film. Under a picosecond pulse laser, the PL wavelength of single excitons and ASE wavelength associated with the stimulated decay of bi-excitons were achieved. The two ASE bands were highly correlated and competed with each other; they were classified as exciton and bi-exciton recombination, respectively. According to the ASE results, bi-exciton emission could be observed in an ultrastable CsPb(Br/Cl)3 film modified by PMMA with a very low excitation energy density of 110 µJ/cm2. Compared with the bare film, the ASE threshold was lowered by approximately 5%. A bi-exciton has a binding energy (26.78 meV) smaller than the binding energy of the exciton (70.20 meV).

The growth of nanocrystals (NCs) from metal oxide-based substrates with exposed high-energy facets is of particular importance for many important applications, such as solar cells as photoanodes due to the high reactivity of these facets. The hydrothermal method remains a current trend for the synthesis of metal oxide nanostructures in general and titanium dioxide (TiO2) in particular since the calcination of the resulting powder after the completion of the hydrothermal method no longer requires a high temperature. This work aims to use a rapid hydrothermal method to synthesize numerous TiO2-NCs, namely, TiO2 nanosheets (TiO2-NSs), TiO2 nanorods (TiO2-NRs), and nanoparticles (TiO2-NPs). In these ideas, a simple non-aqueous one-pot solvothermal method was employed to prepare TiO2-NSs using tetrabutyl titanate Ti(OBu)4 as a precursor and hydrofluoric acid (HF) as a morphology control agent. Ti(OBu)4 alone was subjected to alcoholysis in ethanol, yielding only pure nanoparticles (TiO2-NPs). Subsequently, in this work, the hazardous chemical HF was replaced by sodium fluoride (NaF) as a means of controlling morphology to produce TiO2-NRs. The latter method was required for the growth of high purity brookite TiO2 NRs structure, the most difficult TiO2 polymorph to synthesize. The fabricated components are then morphologically evaluated using equipment, such as transmission electron microscopy (TEM), high resolution transmission electron microscopy (HRTEM), electron diffraction (SAED), and X-ray diffraction (XRD). In the results, the TEM image of the developed NCs shows the presence of TiO2-NSs with an average side length of about 20–30 nm and a thickness of 5–7 nm. In addition, the image TEM shows TiO2-NRs with diameters between 10 and 20 nm and lengths between 80 and 100 nm, together with crystals of smaller size. The phase of the crystals is good, confirmed by XRD. The anatase structure, typical of TiO2-NS and TiO2-NPs, and the high-purity brookite-TiO2-NRs structure, were evident in the produced nanocrystals, according to XRD. SAED patterns confirm that the synthesis of high quality single crystalline TiO2-NSs and TiO2-NRs with the exposed {001} facets are the exposed facets, which have the upper and lower dominant facets, high reactivity, high surface energy, and high surface area. TiO2-NSs and TiO2-NRs could be grown, corresponding to about 80% and 85% of the {001} outer surface area in the nanocrystal, respectively.

The importance and pervasiveness of emotions in our lives makes affective computing a tremendously important and vibrant line of work. Systems for automatic emotion recognition (AER) and sentiment analysis can be facilitators of enormous progress (e.g., in improving public health and commerce) but also enablers of great harm (e.g., for suppressing dissidents and manipulating voters). Thus, it is imperative that the affective computing community actively engage with the ethical ramifications of their creations. In this article, I have synthesized and organized information from AI Ethics and Emotion Recognition literature to present fifty ethical considerations relevant to AER. Notably, this ethics sheet fleshes out assumptions hidden in how AER is commonly framed, and in the choices often made regarding the data, method, and evaluation. Special attention is paid to the implications of AER on privacy and social groups. Along the way, key recommendations are made for responsible AER. The objective of the ethics sheet is to facilitate and encourage more thoughtfulness on why to automate, how to automate, and how to judge success well before the building of AER systems. Additionally, the ethics sheet acts as a useful introductory document on emotion recognition (complementing survey articles).

The relevance of the research is caused by the need to obtain objective information about the patterns of territorial and temporal variability of vegetation state and the factors that determine it for the most effective use of lands in extreme natural and socio-economic conditions in the Republic of Iraq. The aim of the research is to analyze the dynamics of vegetation of territories of the four provinces in Central Iraq using the normalized difference vegetation index NDVI in the period from 2014 to 2017. The objects of the research are territories of Central Iraq: Babil, Baghdad, Wasit and Diyala. The subject of the study is temporal-territorial variability of vegetation state. Methods: remote sensing, thematic mapping, image processing, spatial data analysis, statistical analysis. Results. Patterns of temporarily-territorial dynamics of vegetation state in Central Iraq were revealed using vegetation index NDVI calculated with remote sensing data obtained by Landsat-8. Regional features of the vegetation structure and the rate of its state change were established. The maximum areas of non-vegetated territories were found in Baghdad and Wasit; covered by vegetation of most classes – also in Wasit; covered by dense vegetation – in Diyala, marked as well by minimum of barren areas. Babil is characterized by minimum area covered by vegetation. Baghdad in the studied indicators is intermediate. These patterns are poorly consistent with the absolute values of the province areas. They are caused by the prevailing economic conditions and are manifested in the qualitative and quantitative heterogeneity of the distribution of vegetation in the provinces. During the active stage of vegetation, from February to March, the variations in areas of non-vegetated territories, occupied by moderate and dense vegetation, are stable. At the same time, the variability of areas of territories with very dense vegetation is growing, with weak vegetation and vegetation of maximum density decreases. A correlation analysis between NDVI values and weather conditions did not reveal any significant relationships.

Perovskite halide has many advantages that attracted the attention of researchers in the last years, but many challenges prevent the use of halide perovskites in different applications. One of these challenges is the low thermal stability resulting in phase transitions with temperatures. Here, the photoluminescence (PL) characteristics and related phase transitions of different CH3NH3Pb(BrxI1−x)3 (MA(BrxI1−x)3)3 perovskites structures have been investigated under a wide temperature range. The work that has been conducted demonstrates that under temperature, the exciton behavior of the halide anions, I and Br, has a considerable impact on structural phases and the fluorescence process. The obtained results for the temperature dependence of PL for MAPb(BrxI1−x)3 showed a wide range of emission wavelengths, between 500–800 nm with a decrease in PL intensity with increasing temperature. In addition, the ratio of both bromine and iodine in MAPb(BrxI1−x)3 affects the range of phase transition temperatures, where at x = 0.00, 0.25, and 0.50 the first transition occurs below room temperature (orthorhombic to tetragonal) phase and the other occurs above room temperature (tetragonal to cubic) phase. Furthermore, increasing the proportion of bromine causes all the transitions to occur below room temperature. The presented findings suggest a suitable halide component under a temperature-controlled phase transformation to benefit these materials in photonics devices.

The strengthening and rehabilitation of reinforced concrete structures is an important issue all over the world. Fiber-reinforced composites (FRC) are mainly used for the strength and rehabilitation of concrete members. However, its use is limited due to its high price and environmental effects and its adoption of epoxy as an adhesive, where epoxy is considered inefficient at high temperatures and loses most of its properties. The solution to this problem leads to the use of low-cost locally available geopolymer adhesive paste, with the possibility of adding fibers to improve the mechanical properties. This paper presents the experimental results of the circular RC columns confined by carbon fiber reinforced geopolymer adhesive (CFRGA) with fibers at geopolymer adhesive (GPA). Variables included; Geopolymer adhesive with or without fibers and type of fiber added to GPA (micro steel fibers, carbon fibers, and polypropylene fibers) with the volumetric ratio of (2%, 0.4%, 0.2%), respectively. The results where it was found that confinement by carbon fiber reinforced fibrous geopolymer adhesive improved the columns compressive strength estimated by (215%) and the axial strain improved by (268%). When adding (micro steel fibers, carbon fibers, and polypropylene fibers) to the adhesive led to an improvement in the strength of about (16.1%, 8.4%, and 7.96%) respectively, compared with the confined RC column without fibers at (GPA). Finally, confinements by carbon fiber reinforced geopolymer adhesive are more suitable for use in strengthening and rehabilitation of RC columns in areas with a hot climate.

The improvement of optical and optoelectronic properties of the individual poly [2-methoxy-5- (2-ethylhexyloxy)-1,4-phenylenevinylene] (MEH-PPV), poly[2-methoxy-5-(3,7-dimethyl-octyloxy)-1,4-phenylenevinylene]–End capped with Dimethyl phenyl (OC1C10–PPV–DMP), and poly (9,9′-di- n -octylfluorenyl-2,7-diyl) (F8) was revealed by blending them in ternary hybrid with optimal ratio (F8/2 wt.% MEH-PPV/2 wt.% OC1C10–PPV–DMP). All individual and optimal ternary solutions were prepared via the solution-blending method followed by depositing them onto glass and ITO substrates using spin-coating technique. The semi-crystalline phase of the ternary hybrid and the strong mixing between the conjugated polymers were evidenced by observing the X-ray diffraction patterns that related to F8 into the hybrid diffractogram. The optical and optoelectronic properties of all prepared thin films were investigated in terms of absorption and emission spectra, Commission International d′Eclairage (CIE) coordinates, and current–voltage (I-V) characterizations. Emission peaks at the entire range of visible spectrum can be revealed from the ternary hybrid of the three individual conjugated polymers, producing white emission as evidenced from the emission spectrum and CIE coordinates of the hybrid. Among all fabricated organic light-emitting diodes (OLEDs) devices, the ternary hybrid-based-OLED revealed the best performance in terms of current and turn-on voltage.

Image is an important digital information that used in many internet of things (IoT) applications such as transport, healthcare, agriculture, military, vehicles and wildlife. etc. Also, any image has very important characteristic such as large size, strong correlation and huge redundancy, therefore, encrypting it by using single key Advanced Encryption Standard (AES) through IoT communication technologies makes it vulnerable to many threats, thus, the pixels that have the same values will be encrypted to another pixels that have same values when they use the same key. The contribution of this work is to increase the security of transferred image. This paper proposed multiple key AES algorithm (MECCAES) to improve the security of the transmitted image through IoT. This approach is evaluated via applying it on RGB bmp images and analyzing the results using standard metrics such as entropy, histogram, correlation, Peak Signal-to-Noise Ratio (PSNR) and Mean Square Error (MES) metrics. Also, the time for encryption and decryption for the proposed MECCAES is the same time consumed by original single key AES is 12 second(the used image size is 12.1MB therefore time is long). The performance experiments show that this scheme achieves confidentiality also it encourages to use effectively in a wide IoTs fields to secure transmitted image.

The coexistence of cystic fibrosis (CF) and sarcoidosis is rare. We report a 22-year-old male cystic fibrosis patient who presented multiple times to the Sultan Qaboos University Hospital, Muscat, Oman, in 2013. He was diagnosed with non-parathyroid-related hypercalcaemia and anterior uveitis, while computed tomography revealed mediastinal and abdominal lymphadenopathy and mild hepatosplenomegaly. These findings, in addition to the presence of calciuria and a high angiotensin-converting enzyme (ACE) level, confirmed a clinical diagnosis of sarcoidosis. The patient responded well to treatment with oral prednisolone which, over the course of two years, resulted in the near-complete resolution of parenchymal nodular infiltrates, regression of hilar lymphadenopathy, resolution of hypercalcaemia and the normalisation of his ACE levels. Diagnosing pulmonary sarcoidosis in CF can be challenging as most adult patients already have extensive lung disease. Physicians should be aware that hypercalcaemia may be an early manifestation of sarcoidosis in such cases. Keywords: Sarcoidosis; Cystic Fibrosis; Hypercalcemia; Case Report; Oman.

When looking at installing a renewable energy generator, you need to be confident of the resource (solar, wind) at your particular location as this affects the energy generated at the selected site. With solar photovoltaic (PV) systems, this can be done by looking at historic data, generally from satellite readings, for the particular latitude. This will yield pretty accurate resource data. However, the wind resource is incredibly variable and depends upon the exact topology of the area. Houses, trees, and valleys all can affect the local wind resource. For this reason, wind speed data is collected at a potential wind turbine installation site. This gives real data which can be used to assess the wind speed. When installing a number of very expensive large wind turbines, one must be very confident about the wind speed data. The data must be robust and reliable and the developer will be willing to spend a lot of money on accurate industrial equipment to have lots of confidence in the data. This project intends to overcome this barrier by providing a low-cost, reusable, open-source wind speed recording unit, which can be left at high altitude in a remote location to record data and help improve the site’s wind speed assessment. We have proposed and developed a low-cost hardware module based on Arduino open source platform, which measures the meteorological data, including air, temperature, relative humidity, wind speed and solar radiation, with two options: The first is the wireless option at which it sends the measured information to Excel spreadsheet running on a PC through wireless link. The second is the data logger option at which it records the measured data to SD card as Excel file with date and time every 10 seconds.

Zinc oxide (ZnO) has attracted significant interest due to its exceptional material characteristics like its wide band gap (3.37 eV) and the high exciton binding energy. However, the application of ZnO is constrained by the difficulty in obtaining P-type samples. In this study, p- type ZnO thin films were fabricated using the co-doping technique with ZnO and AlN targets. Different RF powers were used for ZnO to deposite the films. However, the power on AlN target was fixed at 90 W. The structural, optical and electrical properties of the prepared films were inspected. The results of XRD showed that all the films exhibited ZnO (002) peak of wurzite structure. The UV emission peaks (3.24 eV–3.53 eV) identified in PL spectra is possibly due to the recombination of free excitons. The Raman peaks which shown at 576.22 cm−1 and 274 cm−1 denote ZnO:AlN and ZnO:N respectively. The Hall measurements of the films deposited at RF powers of 250 W and 200 W for ZnO target exhibited n-type conduction with corresponding mobilities of 2.75 cm2 V−1 s−1 and 1.58 cm2 V−1 s−1 respectively with electron concentrations of 2.35 × 1018cm−3 and 5.26 × 1018cm−3, respectively. However, the films deposited using RF powers of (150, 175) W and 225 W for ZnO target exhibited p-type conduction with hole concentrations of 2.14 × 1017 cm−3, 2.37 × 1019 cm−3 and 3.68 × 1021 cm−3 with corresponding mobilities of 9.21 cm2 V−1 s−1, 0.129 cm2 V−1 s−1 and 3.41 × 10−3 cm2 V−1 s−1 respectively. Therefore, RF power values of (150, 175) W and 225 W might be ideal for dopants activation to obtain p-type ZnO.