Search

Particulate matter (PM) emitted from compression ignition (CI) engines (diesel engines) has a detrimental effect on human health and the environment. The physical and chemical characteristics of PM emitted from CI-engines are influenced by engine operating conditions and fuel properties. The morphology, nanostructure, and chemical composition of PM affect its toxicity and interaction with the environment. From automotive industry perspective, these parameters influence the design of diesel particulate filters. This study presents a review of the physical and chemical characteristics of particulate emissions from the CI-engine. The present study commences with a brief description about the composition of PM emitted from CI-engine and the PM formation mechanism in CI-engine. Later on, the detailed review of PM's physical and chemical characteristics and the effect of engine operating parameters and alternative fuels on the particle number concentration, morphology, nano-structure, and oxidative reactivity of PM is presented. Online and offline methods of diesel particulate characterization and emerging chemical characterization techniques such as X-ray photoelectron spectroscopy and X-ray absorption fine structure (EXAFS) are also discussed briefly. Correlation between physical and chemical properties, and oxidative reactivity of PM is also discussed. It was found that engine operating parameters affect the physical and chemical properties of PM. Use of alternative fuels changes the diesel particulate morphology, nanostructure, and chemical composition which enhances the oxidative reactivity of PM.

This study presents the influence of low-temperature heat release (LTHR) and high-temperature heat release (HTHR) on the combustion and particle number characteristics of the RCCI engine. The study investigates the relationship between the amount of LTHR, HTHR, and particle number emission characteristics. In this study, gasoline and methanol are used as low reactivity fuel (LRF), and diesel is used as a high reactivity fuel (HRF). The LRF is injected into the intake manifold using a port-fuel injection (PFI) strategy, and HRF is directly injected into the cylinder using a direct injection strategy. A particle sizer is used to measure particle emission in size ranging from 5 to 1000 nm. First, the LTHR and HTHR are analyzed for different diesel injection timing (SOI) for RCCI operation. Later, the variation of particle emissions with LTHR and HTHR is characterized. Additionally, empirical correlations are developed to understand the relation between the LTHR and HTHR with particle emission. Two-staged auto-ignition of charge has been observed in RCCI combustion. Results depict that LTHR varies with diesel injection timing and the phasing of HTHR depends on the amount and location of LTHR. Results also showed that HTHR and LTHR significantly influence the formation of particle number concentration in RCCI combustion. The developed empirical correlation depicts a good correlation between diesel SOI and the ratio of HTHR to LTHR to estimate total particle number concentration.

In 2018, over 30,000 L of fluorine-free firefighting foam was used to extinguish an industrial warehouse fire of uncharacterized chemical and industrial waste. Contaminated firewater and runoff were discharged to an adjacent freshwater creek in Melbourne, Australia. In this study, we applied nontarget analysis using liquid chromatography quadrupole time-of-flight mass spectrometry (LC-QToF-MS) to 15 surface water samples to investigate the presence of legacy, novel and emerging per-and polyfluoroalkyl substances (PFAS). We identified six novel and emerging fluorotelomer-based fluorosurfactants in the Australian environment for the first time, including: fluorotelomer sulfonamido betaines (FTABs or FTSA-PrB), fluorotelomer thioether amido sulfonic acids (FTSASs), and fluorotelomer sulfonyl amido sulfonic acids (FTSAS-So). Legacy PFAS including C