1. Reducing Surface Roughness to Achieve Li2CO3‐Existent Lithiophilic Interface in Garnet‐Type Solid‐State Batteries.
- Author
-
Zhang, Jiaxu, Wang, Changhong, Fu, Jiamin, Ye, Minghao, Zhai, Huiyu, Li, Jun, Tan, Gangjian, Tang, Xinfeng, and Sun, Xueliang
- Subjects
- *
SURFACES (Physics) , *SURFACE roughness , *CRITICAL currents , *GARNET , *METALS - Abstract
The presence of Li2CO3 has been identified as the cause of poor lithophilicity in garnet‐type Li7La3Zr2O12 (LLZO) solid‐state batteries. A Li2CO3‐free garnet is expected to enhance the Li/LLZO interface contact. However, permanently eradicating regenerative Li2CO3 from the LLZO surface is extremely challenging and the influence of regenerated Li2CO3 is often ignored. Herein, it is found that glossy Li2CO3 pellets can also be perfectly wetted by molten Li, contradicting the common belief that Li2CO3 is lithiophobic. Therefore, reducing the surface roughness of LLZO allows it to be directly wetted by lithium metal, regardless of the presence of Li2CO3. Additionally, smooth LLZO exhibits better air stability due to its reduced active area. The symmetric cell with a smooth LLZO pellet shows a low interfacial impedance of 2 Ω cm2 and a high critical current density of 1.4 mA cm−2 at 25 °C. This work highlights the surface physics of garnet which significantly influences its interface properties, apart from surface chemistry. [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
- View/download PDF