23 results on '"SOIL-PHOSPHORUS"'
Search Results
2. Soil phosphorus sorption properties in different fertilization systems
- Author
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Ewa Szara, Tomasz Sosulski, and Magdalena Szymańska
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macronutrient ,secale cereale l. ,vertical variability of phosphorus ,static experiment ,soil-phosphorus ,Plant culture ,SB1-1110 - Abstract
The study aimed at the evaluation of the accumulation and vertical distribution of different forms of phosphorus (P) in reference to phosphorus sorption properties subject to mineral (NPK), mineral-organic (NPK + M), and organic (M) fertilisation. It was carried out in a long-term experimental field in Skierniewice (Central Poland) conducted since 1923 under rye monoculture. Total P content in the M and NPK soil profile was similar and lower than in the NPK + M soil. The content of organic P in Ap and Eet horizons of both manured soils was similar and higher than in the NPK soil. The Langmuir P sorption maximum (Smax) in the studied soils ranged from 39.7 to 90 mg P/kg, while the Freundlich P sorption coefficient aF ranged from 6.9 to 41.9 mg P/kg. Higher variability of parameters related to the binding energy from the Lanqmuir (k) and Freundlich (aF) equations was determined between soil horizons than between the fertilisation systems. Nonetheless, in M and NPK + M soils, sorption parameters aF and Smax and binding energy (k, bF) were considerably lower than in the NPK soil. The content of water extracted P in manured soils was higher than in the NPK soil.
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- 2019
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3. Soil phosphorus sorption properties in different fertilization systems.
- Author
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SZARA, EWA, SOSULSKI, TOMASZ, and SZYMAŃSKA, MAGDALENA
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PHOSPHORUS ,SORPTION ,MINERALS ,MONOCULTURE agriculture ,SOILS - Abstract
The study aimed at the evaluation of the accumulation and vertical distribution of different forms of phosphorus (P) in reference to phosphorus sorption properties subject to mineral (NPK), mineral-organic (NPK + M), and organic (M) fertilisation. It was carried out in a long-term experimental field in Skierniewice (Central Poland) conducted since 1923 under rye monoculture. Total P content in the M and NPK soil profile was similar and lower than in the NPK + M soil. The content of organic P in A
p and Eet horizons of both manured soils was similar and higher than in the NPK soil. The Langmuir P sorption maximum (Smax ) in the studied soils ranged from 39.7 to 90 mg P/kg, while the Freundlich P sorption coefficient aF ranged from 6.9 to 41.9 mg P/kg. Higher variability of parameters related to the binding energy from the Lanqmuir (k) and Freundlich (aF ) equations was determined between soil horizons than between the fertilisation systems. Nonetheless, in M and NPK + M soils, sorption parameters aF and Smax and binding energy (k, bF ) were considerably lower than in the NPK soil. The content of water extracted P in manured soils was higher than in the NPK soil. [ABSTRACT FROM AUTHOR]- Published
- 2019
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4. Plant diversity in hedgerows and road verges across Europe
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Jaan Liira, Guillaume Decocq, Kenny Helsen, Monika Wulf, Sigrid Lindmo, Camille Meeussen, Anna Orczewska, Pieter Vangansbeke, Martin Diekmann, Kathrin Litza, Willem de Kesel, Sanne Van Den Berge, Thomas Vanneste, Jörg Brunet, Sara A. O. Cousins, Pieter De Frenne, Tobias Naaf, Jan Plue, Rozália Erzsebet Kapás, Sanne Govaert, Bente J. Graae, Thilo Heinken, Per-Ola Hedwall, Kris Verheyen, Jonathan Lenoir, Ecologie et Dynamique des Systèmes Anthropisés - UMR CNRS 7058 (EDYSAN), and Université de Picardie Jules Verne (UPJV)-Centre National de la Recherche Scientifique (CNRS)
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0106 biological sciences ,Biodiversity & Conservation ,Plant colonization dynamics ,linear landscape elements ,Biodiversity ,plant colonization dynamics ,landscape connectivity ,Generalist and specialist species ,01 natural sciences ,Road verges ,CONNECTIVITY ,road verges ,HABITAT ,macro-environmental gradient ,[SDV.EE]Life Sciences [q-bio]/Ecology, environment ,2. Zero hunger ,Habitat fragmentation ,Ecology ,SPECIES RICHNESS ,Macro-environmental gradient ,Vegetation ,FOREST ,Geography ,EUTROPHICATION ,Biodiversity Conservation ,Nestedness ,SOIL-PHOSPHORUS ,Life Sciences & Biomedicine ,Landscape connectivity ,[SDE.MCG]Environmental Sciences/Global Changes ,CONSERVATION ,Environmental Sciences & Ecology ,[SDV.BID]Life Sciences [q-bio]/Biodiversity ,010603 evolutionary biology ,QUALITY ,hedgerows ,Science & Technology ,010604 marine biology & hydrobiology ,multiscale analysis ,CORRIDORS ,Microclimate ,15. Life on land ,Linear landscape elements ,13. Climate action ,Earth and Environmental Sciences ,Hedgerows ,BIODIVERSITY ,Species richness ,Road verge ,[SDE.BE]Environmental Sciences/Biodiversity and Ecology ,microclimate ,Multiscale analysis - Abstract
Linear landscape elements such as hedgerows and road verges have the potential to mitigate the adverse effects of habitat fragmentation and climate change on species, for instance, by serving as a refuge habitat or by improving functional connectivity across the landscape. However, so far this hypothesis has not been evaluated at large spatial scales, preventing us from making generalized conclusions about their efficacy and implementation in conservation policies. Here, we assessed plant diversity patterns in 336 vegetation plots distributed along hedgerows and road verges, spanning a macro‐environmental gradient across temperate Europe. We compared herb‐layer species richness and composition in these linear elements with the respective seed‐source (core) habitats, that is, semi‐natural forests and grasslands. Next, we assessed how these differences related to several environmental drivers acting either locally, at the landscape level or along the studied macro‐ecological gradient. Across all regions, about 55% of the plant species were shared between forests and hedgerows, and 52% between grasslands and road verges. Habitat‐specialist richness was 11% lower in the linear habitats than in the core habitats, while generalist richness was 14% higher. The difference in floristic composition between both habitat types was mainly due to species turnover, and not nestedness. Most notably, forest‐specialist richness in hedgerows responded positively to tree cover, tree height and the proportion of forests in the surrounding landscape, while generalist richness was negatively affected by tree height and buffering effect of trees on subcanopy temperatures. Grassland and road verge diversity was mainly influenced by soil properties, with positive effects of basic cation levels on the number of specialists and those of bioavailable soil phosphorus on generalist diversity. Synthesis and applications. We demonstrate that linear landscape elements provide a potential habitat for plant species across Europe, including slow‐colonizing specialists. Additionally, our results stress the possibility for land managers to modify local habitat features (e.g. canopy structure, subcanopy microclimate, soil properties, mowing regime) through management practices to enhance the colonization success of specialists in these linear habitats. These findings underpin the management needed to better conserving the biodiversity of agricultural landscapes across broad geographical scales. ispartof: Journal Of Applied Ecology vol:57 issue:7 pages:1244-1257 status: Published online
- Published
- 2020
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5. Clustering and Smoothing Pipeline for Management Zone Delineation Using Proximal and Remote Sensing
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S. Hamed Javadi, Abdul Mouazen, and Angela P. Guerrero C.
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Agriculture and Food Sciences ,ACCURACY ,TP1-1185 ,management zone delineation ,Biochemistry ,Article ,Analytical Chemistry ,Soil ,FUSION ,feature selection ,Cluster Analysis ,Electrical and Electronic Engineering ,FIELD ,Instrumentation ,Spatial Analysis ,precision agriculture ,Chemical technology ,Atomic and Molecular Physics, and Optics ,VARIABILITY ,YIELD ,ATTRIBUTES ,clustering ,Remote Sensing Technology ,SOIL-PHOSPHORUS ,Algorithms - Abstract
In precision agriculture (PA) practices, the accurate delineation of management zones (MZs), with each zone having similar characteristics, is essential for map-based variable rate application of farming inputs. However, there is no consensus on an optimal clustering algorithm and the input data format. In this paper, we evaluated the performances of five clustering algorithms includingk-means, fuzzy C-means (FCM), hierarchical, mean shift, and density-based spatial clustering of applications with noise (DBSCAN) in different scenarios and assessed the impacts of input data format and feature selection on MZ delineation quality. We used key soil fertility attributes (moisture content (MC), organic carbon (OC), calcium (Ca), cation exchange capacity (CEC), exchangeable potassium (K), magnesium (Mg), sodium (Na), exchangeable phosphorous (P), and pH) collected with an online visible and near-infrared (vis-NIR) spectrometer along with Sentinel2 and yield data of five commercial fields in Belgium. We demonstrated thatk-means is the optimal clustering method for MZ delineation, and the input data should be normalized (range normalization). Feature selection was also shown to be positively effective. Furthermore, we proposed an algorithm based on DBSCAN for smoothing the MZs maps to allow smooth actuating during variable rate application by agricultural machinery. Finally, the whole process of MZ delineation was integrated in a clustering and smoothing pipeline (CaSP), which automatically performs the following steps sequentially: (1) range normalization, (2) feature selection based on cross-correlation analysis, (3)k-means clustering, and (4) smoothing. It is recommended to adopt the developed platform for automatic MZ delineation for variable rate applications of farming inputs.
- Published
- 2021
6. Speciation of P in Solid Organic Fertilisers from Digestate and Biowaste
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Erik Meers, Filip Tack, I.C. Regelink, and Caleb Elijah Egene
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EXTRACTION ,compost ,ADSORPTION ,BIOAVAILABILITY ,media_common.quotation_subject ,chemistry.chemical_element ,Fraction (chemistry) ,010501 environmental sciences ,Raw material ,engineering.material ,SORPTION ,01 natural sciences ,iron salts ,WASTE-WATER ,CHEMISTRY ,PHOSPHATE ,Duurzaam Bodemgebruik ,phosphorus ,PIG SLURRY ,0105 earth and related environmental sciences ,media_common ,Sustainable Soil Use ,Compost ,Chemistry ,AVAILABILITY ,Phosphorus ,solid fraction of digestate ,Agriculture ,04 agricultural and veterinary sciences ,Manure ,Speciation ,Earth and Environmental Sciences ,manure ,Environmental chemistry ,Digestate ,040103 agronomy & agriculture ,engineering ,0401 agriculture, forestry, and fisheries ,Composition (visual arts) ,SOIL-PHOSPHORUS ,Agronomy and Crop Science - Abstract
Phosphorus (P) is a finite resource and its reuse in organic fertilisers made from biowaste and manure should therefore be encouraged. The composition of solid organic fertilisers (SOFs) depends on the type of feedstock and processing conditions, and this may affect P speciation and hence P availability. Phosphorus speciation was assessed in eighteen different SOFs produced from biowaste and digestate. Available P was determined in 10 mM CaCl2 extracts at a fixed pH of 5.5 and at a fixed total P concentration in the suspension. P was dominantly present as inorganic P (>, 80% of total P). There was a strong variation in the Fe content of the SOFs and hence in the fraction of P bound to reactive Fe/Al-oxides (PFe). The fraction of total P soluble at pH 5.5 correlated negatively with PFe pointing to fixation of P by metal salts added during processing, or by soil mineral particles in case garden waste was processed. Therefore, the use of iron salts in processing plants should be avoided. In addition, the presence of P in poorly soluble precipitates lowered the fraction of easily available P. Overall, this study shows that Pt alone is not a good indicator for the agronomic efficiency of SOFs due to large differences in P speciation among SOFs.
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- 2021
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7. Crop response to P fertilizer omission under a changing climate - Experimental and modeling results over 115 years of a long-term fertilizer experiment
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Maximilian Koch, Gabriel Schaaf, Hubert Hüging, Thomas Gaiser, Stefan Siebert, Sabine J. Seidel, Martina Gocke, Sara L. Bauke, Frank Ewert, H.E. Ahrends, Kathlin Schweitzer, Department of Agricultural Sciences, and Agrotechnology
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DYNAMICS ,0106 biological sciences ,EFFICIENCY ,Field experiment ,Soil Science ,engineering.material ,PLANT PHOSPHORUS ,01 natural sciences ,4111 Agronomy ,CARBON ,Crop ,Nutrient ,Climate change ,FIELD EXPERIMENTS ,TEMPERATURE ,1172 Environmental sciences ,2. Zero hunger ,Topsoil ,biology ,AVAILABILITY ,Long-term field experiment ,04 agricultural and veterinary sciences ,15. Life on land ,Crop rotation ,biology.organism_classification ,Manure ,N DEPOSITION ,YIELD ,Agronomy ,13. Climate action ,040103 agronomy & agriculture ,engineering ,Nutrient availability ,Crop modeling ,0401 agriculture, forestry, and fisheries ,Environmental science ,ddc:640 ,Sugar beet ,Fertilizer ,Soil phosphorus simulation ,SOIL-PHOSPHORUS ,Agronomy and Crop Science ,010606 plant biology & botany - Abstract
Phosphorus (P) is an essential plant nutrient. However, our understanding of the complex interactions between soil P availability, environment, management and crop growth is still limited. We used unique historic and recent soil and crop data spanning more than a century combined with a process-based crop model to analyze the impact of P fertilizer omission and P fertilization on the biomass production of five crops. The long-term field experiment at Dikopshof, Germany, was established in 1904 with a 5-year crop rotation of sugar beet, winter wheat, winter rye, clover and oat/potato (potato replaced oat in 1953) on a fertile Luvisol. Averaged over the period from 1906 to 2018, the yield loss due to P omission was low for winter wheat and winter rye (7-8 %). In contrast, yield losses for sugar beet, clover and potato were relatively high (15-24 %). The yield loss from P fertilizer omission in comparison to the reference treatment (rotation mean excluding oat/potato) increased until the middle of the last century from 7% to 18 %, but subsequently decreased to 13 %. Trend and correlation analyses suggest that this decrease was related to an increase in air temperatures in especial during spring and a lower yield loss under P omission. Crop model simulations showed decreasing topsoil organic carbon concentrations after the 1930ies as manure was discontinued in 1942 but also due to increasing air temperatures. The increase in plant-available topsoil P concentrations during the last decades was one of the main factors offsetting yield losses despite P fertilizer omission. Our study suggests that climate change and, in particular, a marked increase in temperature since the middle of the last century most likely influenced soil P dynamics with a significant impact on crop production.
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- 2021
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8. Reducing agricultural nutrient surpluses in a large catchment - Links to livestock density
- Author
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Svanbäck, Annika, McCrackin, Michelle L., Swaney, Dennis P., Linefur, Helena, Gustafsson, Bo G., Howarth, Robert W., Humborg, Christoph, Marine Ecosystems Research Group, and Tvärminne Zoological Station
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FLUXES ,Baltic Sea ,Livestock density ,FERTILIZER PRODUCTION ,Agriculture ,MANURE APPLICATIONS ,Eutrophication ,Manure ,LIFE-CYCLE ASSESSMENT ,REGIONAL-VARIATION ,MANAGEMENT STRATEGIES ,USE EFFICIENCY ,NET ANTHROPOGENIC NITROGEN ,SOIL-PHOSPHORUS ,FARM-LEVEL ,Nutrient surplus ,1172 Environmental sciences - Abstract
The separation between crop- and livestock production is an important driver of agricultural nutrient surpluses in many parts of the world. Nutrient surpluses can be symptomatic of poor resource use efficiency and contribute to environmental problems. Thus, it is important not only to identify where surpluses can be reduced, but also the potential policy tools that could facilitate reductions. Here, we explored linkages between livestock production and nutrient flows for the Baltic Sea catchment and discuss management practices and policies that influence the magnitude of nutrient surpluses. We found that the majority of nutrients cycled through the livestock sector and that large nitrogen and phosphorus surpluses often occurred in regions with high livestock density. Imports of mineral fertilizers and feed to the catchment increased overall surpluses, which in turn increased the risk of nutrient losses from agriculture to the aquatic environment. Many things can be done to reduce agricultural nutrient surpluses; an important example is using manure nutrients more efficiently in crop production, thereby reducing the need to import mineral fertilizers. Also, existing soil P reserves could be used to a greater extent, which further emphasizes the need to improve nutrient management practices. The countries around the Baltic Sea used different approaches to manage agricultural nutrient surpluses, and because eight of the coastal countries are members in the European Union (EU), common EU policies play an important role in management. We observed reductions in surpluses between 2000 and 2010 in some countries, which suggested the influence of different approaches to management and policy and that there are opportunities for further improvement. However, the separation between crop and livestock production in agriculture appears to be an underlying cause of nutrient surpluses; thus, further research is needed to understand how policy can address these structural issues and increase sustainability in food production. (C) 2018 The Authors. Published by Elsevier B.V.
- Published
- 2019
9. Facilitated Iron Reduction as a Possible Means of Rejuvenating Phosphorus Removal Performance of Filtration Substrates
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C. L. Levy, David H. Vaughan, Matthew J. Eick, Shawn E. Rosenquist, W. C. Hession, S. T. Sell, Biological Systems Engineering, and School of Plant and Environmental Sciences
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Stormwater ,Biomedical Engineering ,Soil Science ,chemistry.chemical_element ,Phosphate ,law.invention ,chemistry.chemical_compound ,Adsorption ,law ,Nutrient removal ,Vertical flow ,Filtration ,Constructed wetlands ,Chemistry ,Phosphorus ,Environmental engineering ,Agriculture ,Forestry ,Sorption ,Eutrophication ,Management-practices ,Soil-phosphorus ,Bioretention ,Water quality ,Environmental chemistry ,Nutrient pollution ,Constructed wetland ,Waste-water ,Desorption ,Sediment ,Best management practices ,Agronomy and Crop Science ,Food Science - Abstract
In order to mitigate nutrient pollution in surface runoff more sustainably, the finite capacity for phosphorus (P) sequestration in best management practices (BMP) that rely heavily on sorption processes must be addressed. These BMP include sand filters, bioretention cells, and several types of constructed wetland. This study investigated facilitated microbial reduction of iron-based filtration substrates to promote controlled release of P previously sequestered by the BMP, P harvest for recycling, and rejuvenation of the substrate sorption capacity. Total dissolved P was well correlated with total dissolved iron during the reduction process, indicating that microbial iron reduction was capable of releasing previously sequestered P from substrates. Furthermore, results indicated that a sufficient carbon source was necessary but addition of a microbial culture was not necessary to facilitate iron reduction. While a large percentage of the previously sequestered P was removed, the process was much slower than initial sequestration of P by adsorption, and further research is needed to promote a more rapid release of P in order to optimize the rejuvenation process for field application. NSF 0649079
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- 2011
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10. Impacts of agricultural phosphorus use in catchments on shallow lake water quality: about buffers, time delays and equilibria
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Peter Schippers, Marten Scheffer, Jeroen J. M. de Klein, Hendrika van de Weerd, and Barend de Jong
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Conservation of Natural Resources ,Aquatic Ecology and Water Quality Management ,Time Factors ,Environmental Engineering ,Rain ,sediment phosphorus ,Fresh Water ,runoff ,thame catchment ,Buffers ,nitrogen ,surface waters ,Water Supply ,Water Movements ,Environmental Chemistry ,Water pollution ,Waste Management and Disposal ,Hydrology ,WIMEK ,soil-phosphorus ,Intensive farming ,nutrient ,Water Pollution ,Environmental engineering ,Lake ecosystem ,Agriculture ,Phosphorus ,Models, Theoretical ,Aquatische Ecologie en Waterkwaliteitsbeheer ,Pollution ,land ,eutrophication ,Soil water ,Environmental science ,Water quality ,Eutrophication ,Surface runoff ,Surface water ,Water Pollutants, Chemical ,management - Abstract
Phosphorus (P) losses caused by intensive agriculture are known to have potentially large negative effects on the water quality of lakes. However, due to the buffering capacity of soils and lake ecosystems, such effects may appear long after intensive agriculture started. Here we present the study of a coupled shallow lake catchment model, which allows a glimpse of the magnitude of these buffer-related time delays. Results show that the buffering capacity of the lake water was negligible whereas buffering in the lake sediment postponed the final lake equilibrium for several decades. The surface soil layer in contact with runoff water was accountable for a delay of 550 years. The most important buffer, however, was the percolation soil layer that may cause a delay of 150-1700 years depending on agricultural P surplus levels. Although the buffers could postpone final lake equilibria for a considerable time, current and target agricultural surplus levels eventually led to very turbid conditions with total P concentrations of 2.0 and 0.6 mg L-1 respectively. To secure permanent clear water states the current agricultural P surplus of 15 kg P ha(-1) yr(-1) should drop to 0.7 kg P ha(-1) yr(-1). We present several simple equations that can be used to estimate the sustainable P surplus levels, buffer related time delays and equilibrium P concentrations in other catchment-lake systems. (c) 2006 Elsevier B.V. All rights reserved.
- Published
- 2006
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11. Mapping hydrological pathways of phosphorus transfer in apparently homogeneous landscapes using a high - resolution DEM
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Jeroen M. Schoorl, M.P.W. Sonneveld, A. Veldkamp, Faculty of Geo-Information Science and Earth Observation, Department of Natural Resources, and UT-I-ITC-FORAGES
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management-practices ,Drainage basin ,Soil Science ,netherlands ,runoff ,nitrogen ,Leerstoelgroep Landdynamiek ,surface waters ,Hydrology (agriculture) ,Land Dynamics ,Drainage ,Digital elevation model ,Hydrology ,geography ,geography.geographical_feature_category ,soil-phosphorus ,ADLIB-ART-2536 ,PE&RC ,losses ,agricultural land ,quality ,ITC-ISI-JOURNAL-ARTICLE ,Environmental science ,Precision agriculture ,Water quality ,grassland ,Surface runoff ,Surface water - Abstract
Agriculture is a significant contributor to the diffuse loading of phophorus (P) in fresh water systems. At the landscape level, source areas and targeted surface waters are connected through different hydrological pathways. One of these pathways, P removal through surface runoff, may increase in relative importance when storm events occur and in wet seasons. With Digital Elevation Models (DEMs) it is possible to identify dominant surface pathways in the landscape although resolution of available DEMs is often not detailed enough for areas with low relief or for more detailed landscape-field studies. New high-resolution DEMs that do combine a high resolution with substantial spatial coverage provide the opportunity to develop site-specific management alternatives for sensitive or critical source areas at the landscape level. The objective of this paper is to map hydrological pathways of P for a relatively flat glacial till landscape in the Northern part of the Netherlands and to compare two strategies (A and B) in this landscape for minimizing P loading of surface waters following different scenarios. Strategy A assumes equal lowering of phosphate input rates for all fields and strategy B takes into account the relative sensitivity of fields for removal through overland flow. Available soil data, which did not allow to geo-reference individual fields, showed high soil P levels in about 5% of all fields. Data on field inputs of total phosphate (P2O5) were available for 29 farms and showed that fertilized fields received on average 124 kg ha− 1 in the year 2000. Transfer potential of each individual field was evaluated on the basis of two characteristics in a 5 × 5 m resolution DEM: 1) the degree of internal drainage through re-distribution and 2) the degree of external drainage, which indicates the overland flow potential. Almost every field was characterised by sinks (98%) and external drainage into along-field ditches (99%). In addition, almost half of the fields showed drainage directly into surface waters (47%). Applying a classification scheme to rank the sensitivity for losses through overland flow provided a framework to distribute catchment inputs of phosphate at field level (strategy B). Comparing the strategy of distributed phosphate inputs (B) with generic phosphate inputs (A) showed that catchment input-to-output ratios are higher for strategy B for three out of four of the applied scenarios.
- Published
- 2006
12. SELECTIVE EXTRACTION OF LABILE PHOSPHORUS USING DIALYSIS MEMBRANE TUBES FILLED WITH HYDROUS IRON HYDROXIDE
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Gerwin F. Koopmans, Jan Dolfing, M.E. van der Zeeuw, and Wim J. Chardon
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soil-phosphorus ,Soil test ,Chemistry ,Environmental remediation ,water ,Soil Science Centre ,Soil Science ,Lessivage ,Mineralogy ,netherlands ,runoff ,release ,losses ,Adsorption ,Environmental chemistry ,Desorption ,Soil water ,Leaching (pedology) ,Alterra - Centrum Bodem ,oxide ,Saturation (chemistry) ,phosphate - Abstract
Leaching of phosphorus (P) can be a serious problem in P-enriched sandy soils. Techniques that decrease the P content of such soils have been proposed as possible remediation methods. In this study, we determined the effect of P removal from two P-rich sandy soils on extractability of soil P in a laboratory experiment. We created soil samples in increasing stages of P depletion by using a sink method, which consists of a dialysis membrane tube filled with hydrous Fe-(hydr)oxide (DMT-HFO). Total amounts of P removed were relatively small compared with the high initial ammonium-oxalate extractable P contents. However, amounts of water and CaCl2 extractable P in the depleted soil samples decreased by 57 to 80%, on average, for both soils. On the other hand, the ammonium-oxalate-based P saturation index decreased by only 11%. Apparently, labile P forms were readily removed, which means that depletion by the DMT-HFO was selective. Our results suggest that remediation methods that remove a small but selective amount of P from soil may cause a significant decrease of the soil potential to release dissolved P. We also used our results to evaluate the suitability of the DMT-HFO to act as an infinite sink for P. For that, the desorption results were described with a simple kinetic Langmuir equation. Errors of kd (desorption constant) and Q0 (amount of P initially adsorbed) were calculated. Although the model fit was good for both soils (r2=0.98*** and 0.99***), errors in Q0 and kd were large. Therefore, the DMT-HFO method could not be used to determine the desorption constants of our soils. Values of kd and Q0 obtained by this method should not be used in modeling studies
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- 2001
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13. Key role of China and its agriculture in global sustainable phosphorus management
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Sattari, S.Z., van Ittersum, M.K., Giller, K.E., Zhang, F., Bouwman, A.F., Bio-, hydro-, and environmental geochemistry, Geochemistry, Bio-, hydro-, and environmental geochemistry, and Geochemistry
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China ,Resource (biology) ,perspective ,engineering.material ,Agricultural economics ,Earth System Science ,nitrogen ,balances ,crop ,General Environmental Science ,agriculture ,Food security ,industry ,soil-phosphorus ,Renewable Energy, Sustainability and the Environment ,business.industry ,Crop yield ,Public Health, Environmental and Occupational Health ,scarcity ,food security ,environmental impacts ,crop yield ,PE&RC ,fertilizer ,food-chain ,Plant Production Systems ,Agriculture ,Plantaardige Productiesystemen ,Sustainability ,phosphorus reserves ,engineering ,Environmental science ,Leerstoelgroep Aardsysteemkunde ,Fertilizer ,Arable land ,business - Abstract
Growing global demand for food leads to increased pressure on phosphorus (P), a finite and dwindling resource. China is the largest producer and consumer of P fertilizer in the world. A mass balance analysis of historical P use on China’s arable land shows that P input substantially exceeds crop P uptake leading to the accumulation of residual soil P. A Dynamic P Pool Simulator (DPPS) model is applied to estimate future P demand in China’s arable land. Our simulations show that more sustainable use of P accounting for the residual P can save ca. 20% of the P fertilizer needed until 2050 in China relative to the Rio+20 Trend scenario. This saving would be equivalent to half of the P required in Africa or sufficient for Western Europe to achieve target crop P uptake in 2050. S Online supplementary data available from stacks.iop.org/ERL/9/054003/mmedia
- Published
- 2014
14. Do earthworms affect phosphorus availability to grass? A pot experiment
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J.W. van Groenigen, Mart B.H. Ros, M.J. Vos, and Gerwin F. Koopmans
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Bodemscheikunde en Chemische Bodemkwaliteit ,Population ,Bulk soil ,Soil Science ,chemistry.chemical_element ,geophagous earthworm ,lumbricus-terrestris ,colloidal phosphorus ,Biology ,engineering.material ,Microbiology ,Lolium perenne ,phosphate adsorption ,education ,organic-matter ,Bodembiologie ,education.field_of_study ,soil-phosphorus ,casts ,Phosphorus ,Earthworm ,Soil Biology ,biology.organism_classification ,Lumbricus rubellus ,PE&RC ,plant-growth ,Agronomy ,chemistry ,engineering ,tropical soil ,Fertilizer ,pontoscolex-corethrurus glossoscolecidae ,Lumbricus terrestris ,Soil Chemistry and Chemical Soil Quality - Abstract
The largest part of phosphorus (P) in soil is bound by the soil solid phase; its release to the soil solution therefore often does not meet the demand of plants. Since global P fertilizer reserves are declining, it becomes increasingly important to better utilize soil P. We tested whether earthworm activity can increase P availability to grass ( Lolium perenne L.) in a 75-day greenhouse pot experiment in a soil with low P availability. The full factorial design included two factors: P fertilization (control without P; phytate; and inorganic P) and earthworm population (control without earthworms; Lumbricus rubellus Hoffmeister, Lr; Aporrectodea caliginosa Savigny, Ac; and Lumbricus terrestris L., Lt). At four times during the experiment, aboveground plant growth and P uptake were determined. In a separate incubation experiment, earthworm casts and bulk soil were analyzed for inorganic and organic P in water extracts. We observed higher levels of dissolved P pools ( p −1 for inorganic P ( p = 0.007) and from 0.18 to 1.30 mg L −1 for organic P ( p = 0.007). After three harvests, presence of Lt significantly increased P uptake by grass to 44.1 mg per pot compared to 41.8 mg per pot for the control ( p = 0.010). Plant growth increased from 15.68 to 16.85 g dry biomass per pot ( p
- Published
- 2014
15. Indicators of risk for phosphorus transfer, addressed at the scale of a European region
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Aurousseau, Pierre, Vinatier, T., Gascuel-Odoux, C., Sol Agro et hydrosystème Spatialisation (SAS), Institut National de la Recherche Agronomique (INRA)-AGROCAMPUS OUEST, AGROCAMPUS OUEST, and Institut national d'enseignement supérieur pour l'agriculture, l'alimentation et l'environnement (Institut Agro)-Institut national d'enseignement supérieur pour l'agriculture, l'alimentation et l'environnement (Institut Agro)-Institut National de la Recherche Agronomique (INRA)
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index ,non ,soil-phosphorus ,[SDE.SDS]Environmental Sciences/domain_sde.sds ,indicator ,point source pollution ,pathways ,runoff ,sediment ,agricultural landscape ,transport ,phosphorus ,catchment ,transfer ,management ,drainage ,catchment scale ,overland-flow - Abstract
Indexes of the risk of phosphorus transfer are operational tools to help end users to manage and decrease the non-point-source pollution in agricultural catchments. They are based on the identification of source factors and transfer factors. These factors
- Published
- 2009
16. Diffuse Phosphorus Models in the United States and Europe: Their Usages, Scales, and Uncertainties
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Oscar Schoumans, Jim Freer, and David E. Radcliffe
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Pollution ,Geologic Sediments ,Environmental Engineering ,media_common.quotation_subject ,agricultural watersheds ,river ,surface-applied manures ,catchments ,Management, Monitoring, Policy and Law ,intensively farmed grasslands ,Alterra - Centre for Water and Climate ,Computer Simulation ,Wageningen Environmental Research ,Temporal scales ,Waste Management and Disposal ,Nonpoint source pollution ,Water Science and Technology ,media_common ,Pollutant ,Hydrology ,soil-phosphorus ,business.industry ,Environmental resource management ,Uncertainty ,Water ,risk-assessment ,Phosphorus ,Models, Theoretical ,United States ,Europe ,Manure ,Identification (information) ,dynamic topmodel ,Total maximum daily load ,stream water phosphorus ,Environmental science ,Spatial variability ,spatial variability ,Water quality ,business ,Environmental Monitoring ,Alterra - Centrum Water en Klimaat - Abstract
Today there are many well-established computer models that are being used at different spatial and temporal scales to describe water, sediment, and P transport from diffuse sources. In this review, we describe how diffuse P models are commonly being used in the United States and Europe, the challenge presented by different temporal and spatial scales, and the uncertainty in model predictions. In the United States, for water bodies that do not meet water quality standards, a total maximum daily load (TMDL) of the pollutant of concern must be set that will restore water quality and a plan implemented to reduce the pollutant load to meet the TMDL. Models are used to estimate the current maximum daily and annual average load, to estimate the contribution from different nonpoint sources, and to develop scenarios for achieving the TMDL target. In Europe, the EC-Water Framework Directive is the driving force to improve water quality and models are playing a similar role to that in the United States, but the models being used are not the same. European models are more likely to take into account leaching of P and the identification of critical source areas. Scaling up to the watershed scale has led to overparameterized models that cannot be used to test hypotheses regarding nonpoint sources of P or transport processes using the monitoring data that is typically available. There is a need for more parsimonious models and monitoring data that takes advantage of the technological improvements that allow nearly continuous sampling for P and sediment. Tools for measuring model uncertainty must become an integral part of models and be readily available for model users.
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- 2009
17. Speciation of phosphorus fractionation in river sediments by explanatory data analysis
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Katsaounos, C. Z., Giokas, D. L., Leonardos, I. D., and Karayannis, M. I.
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soil-phosphorus ,temporal variations ,phosphate fractions ,release ,water-quality ,speciation ,bed-sediments ,forms ,fractionation ,phosphorus ,lake ,explanatory data analysis ,multivariate chemometrics ,river sediments ,discrimination - Abstract
This article investigates the controls on sediment phosphorus (P) speciation dynamics as a function of its fractionation into chemically defined operational pools along a river continuum. A total of 27 variables were analyzed in bed sediment samples collected for one year from six sampling points, along a 75 km river continuum (Louros River, NW Greece). Multivariate explanatory analysis of the complex experimental data matrix was performed in order to unravel the spatial pattern of P speciation. Non-parametric examinations were also applied in order to elucidate the temporal variations encountered in the speciation of P. The results suggest that inorganic P species control P bioavailability in space and time. Organic P was found to be very reactive among the various fractions thus changing its bioavailability but exhibited no temporal variation. The utility of the proposed approach in the differentiation of natural and anthropogenic P inputs and their classification to point and non-point sources is demonstrated presenting a significant improvement compared to mere fractionation analysis. (c) 2006 Elsevier Ltd. All rights reserved. Water Res
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- 2007
18. Facilitated iron reduction as a possible means of rejuvenating phosphorus removal performance of filtration substrates
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Rosenquist, Shawn E., Levy, C. L., Sell, S. T., Hession, W. Cully, Eick, Matthew J., Vaughan, David H., Rosenquist, Shawn E., Levy, C. L., Sell, S. T., Hession, W. Cully, Eick, Matthew J., and Vaughan, David H.
- Abstract
In order to mitigate nutrient pollution in surface runoff more sustainably, the finite capacity for phosphorus (P) sequestration in best management practices (BMP) that rely heavily on sorption processes must be addressed. These BMP include sand filters, bioretention cells, and several types of constructed wetland. This study investigated facilitated microbial reduction of iron-based filtration substrates to promote controlled release of P previously sequestered by the BMP, P harvest for recycling, and rejuvenation of the substrate sorption capacity. Total dissolved P was well correlated with total dissolved iron during the reduction process, indicating that microbial iron reduction was capable of releasing previously sequestered P from substrates. Furthermore, results indicated that a sufficient carbon source was necessary but addition of a microbial culture was not necessary to facilitate iron reduction. While a large percentage of the previously sequestered P was removed, the process was much slower than initial sequestration of P by adsorption, and further research is needed to promote a more rapid release of P in order to optimize the rejuvenation process for field application.
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- 2011
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19. Facilitated iron reduction as a possible means of rejuvenating phosphorus removal performance of filtration substrates
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Biological Systems Engineering, School of Plant and Environmental Sciences, Rosenquist, Shawn E., Levy, C. L., Sell, S. T., Hession, W. Cully, Eick, Matthew J., Vaughan, David H., Biological Systems Engineering, School of Plant and Environmental Sciences, Rosenquist, Shawn E., Levy, C. L., Sell, S. T., Hession, W. Cully, Eick, Matthew J., and Vaughan, David H.
- Abstract
In order to mitigate nutrient pollution in surface runoff more sustainably, the finite capacity for phosphorus (P) sequestration in best management practices (BMP) that rely heavily on sorption processes must be addressed. These BMP include sand filters, bioretention cells, and several types of constructed wetland. This study investigated facilitated microbial reduction of iron-based filtration substrates to promote controlled release of P previously sequestered by the BMP, P harvest for recycling, and rejuvenation of the substrate sorption capacity. Total dissolved P was well correlated with total dissolved iron during the reduction process, indicating that microbial iron reduction was capable of releasing previously sequestered P from substrates. Furthermore, results indicated that a sufficient carbon source was necessary but addition of a microbial culture was not necessary to facilitate iron reduction. While a large percentage of the previously sequestered P was removed, the process was much slower than initial sequestration of P by adsorption, and further research is needed to promote a more rapid release of P in order to optimize the rejuvenation process for field application.
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- 2011
20. Multiple regime shifts in a subtropical peatland: community-specific thresholds to eutrophication
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Statistics, Hagerthey, Scot E., Newman, Susan, Rutchey, Ken, Smith, Eric P., Godin, Jason, Statistics, Hagerthey, Scot E., Newman, Susan, Rutchey, Ken, Smith, Eric P., and Godin, Jason
- Abstract
Ecosystems have a natural resilience to perturbations, where resilience is the magnitude of a disturbance that an ecosystem can resist before changes in structure, function, and services result in a regime shift. The Everglades region of Florida, USA, has been detrimentally impacted by phosphorus (P) enrichment and a regime shift from Cladium (sawgrass) to Typha (cattail) marsh has been described. We examine another facet of the low-nutrient Everglades stability regime, open-water sloughs, to determine if eutrophication leads to similar regime shifts. We analyzed surface water P and soil P as controlling variables that, once a critical threshold is surpassed, alter ecosystem state variables. Nonlinear relationships between P and vegetation were observed along a northern Everglades eutrophication gradient. In addition to the Cladium-Typha regime shift, a second independent regime shift, slough-Typha, was identified. Synoptic surveys of 49 sloughs within the boundary between the slough and Typha regime revealed that surface water total phosphorus (TP) and the benthic algal floc layer (BAFL) were the controlling variables, with critical thresholds of 11 mu g/L and 412 mg/kg, respectively. The slough regime below these thresholds was characterized by calcareous periphyton (BAFL TP 298 mg P/kg; BAFL calcium 149 g Ca/kg). Above the TP thresholds, vegetation composition shifted to open-marsh species with significantly higher BAFL TP (700 mg P/kg) and total organic carbon (TOC) ( 350 g C/kg). A second BAFL TP threshold occurred at 712 mg P/kg, above which Nymphaea dominated and BAFL TP ( 1034 mg P/kg) and TOC (417 g C/kg) significantly increased. Nymphaea sloughs transitioned to the Typha regime. The boundary reflects the loss of ecosystem resilience due to eutrophication. Both low-nutrient stability regimes (slough and Cladium) lie precariously close to the P critical threshold but differ in how eutrophication is absorbed and resisted. The slough regime transitions rapidly
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- 2008
21. Risk assessment methodologies for predicting phosphorus losses
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Schoumans, O.F., Chardon, W.J., Schoumans, O.F., and Chardon, W.J.
- Abstract
Risk assessment parameters are needed to assess the contribution of phosphorus (P) losses from soil to surface water, and the effectiveness of nutrient and land management strategies for the reduction of P loss. These parameters need to take into account the large temporal and spatial variation in P transfer from individual fields arising from (a) changing but predictable factors such as land use, soil P status, P application rates, forms and ways of fertilization and spreading, (b) predictable but inherent factors such as soil type, soil dispersivity, slope and hydrological routing, and (c) unpredictable weather factors such as rainfall amount and intensity. In most situations, water transport is the driving force of P loss from agricultural land to surface water. Therefore, the hydrological pathways determine to a large extent the relevance of these different factors. Over the last decade several soil P tests have been proposed as a first step to link field conditions to risk of P loss. The major reason is that these soil P tests are also meaningful in discussions with farmers. Recently, more complex P loss risk parameters have been derived based on different approaches. However, the scope and purposes of these P loss risk parameters vary remarkably. Finally, there is a need to evaluate the usefulness of new P tests that can be used as an indicator of P loss risk, e.g. in relation to monitoring purposes. The implementation of the EU Water Framework Directive will increase this need. In this paper, the practicable applicability of P parameters for risk assessment is discussed in relation to purpose, scale (from field, farm to catchment), effectiveness, sensibility etc. Furthermore, a conceptual framework for P indicators is presented and evaluated, based on the outcome of the presentations and the discussions in Zurich.
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- 2003
22. Selective extraction of labile phosphorus using dialysis membrane tubes filled with hydrous iron hydroxide
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Koopmans, G.F., van der Zeeuw, M.E., Chardon, W.J., Dolfing, J., Koopmans, G.F., van der Zeeuw, M.E., Chardon, W.J., and Dolfing, J.
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Leaching of phosphorus (P) can be a serious problem in P-enriched sandy soils. Techniques that decrease the P content of such soils have been proposed as possible remediation methods. In this study, we determined the effect of P removal from two P-rich sandy soils on extractability of soil P in a laboratory experiment. We created soil samples in increasing stages of P depletion by using a sink method, which consists of a dialysis membrane tube filled with hydrous Fe-(hydr)oxide (DMT-HFO). Total amounts of P removed were relatively small compared with the high initial ammonium-oxalate extractable P contents. However, amounts of water and CaCl2 extractable P in the depleted soil samples decreased by 57 to 80%, on average, for both soils. On the other hand, the ammonium-oxalate-based P saturation index decreased by only 11%. Apparently, labile P forms were readily removed, which means that depletion by the DMT-HFO was selective. Our results suggest that remediation methods that remove a small but selective amount of P from soil may cause a significant decrease of the soil potential to release dissolved P. We also used our results to evaluate the suitability of the DMT-HFO to act as an infinite sink for P. For that, the desorption results were described with a simple kinetic Langmuir equation. Errors of kd (desorption constant) and Q0 (amount of P initially adsorbed) were calculated. Although the model fit was good for both soils (r2=0.98*** and 0.99***), errors in Q0 and kd were large. Therefore, the DMT-HFO method could not be used to determine the desorption constants of our soils. Values of kd and Q0 obtained by this method should not be used in modeling studies
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- 2001
23. Variable response to phosphorus mitigation measures across the nutrient transfer continuum in a dairy grassland catchment
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Philip Jordan, Paul N. C. Murphy, Mairead Shore, G. Shortle, Cathal Buckley, S. Mechan, Per-Erik Mellander, O. Shine, M. Treacy, Alice R. Melland, David P. Wall, and Department of Agriculture, Food and Marine
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ecological status ,chemistry.chemical_element ,nitrogen ,water-quality ,Interflow ,Nutrient ,Animal science ,Nutrient transfer continuum ,Mitigation measures ,Comparative economics ,Dairy farming ,soil-phosphorus ,Ecology ,Nutrient management ,Intensive farming ,Phosphorus ,agricultural catchments ,dynamics ,fertilizer ,rivers ,land ,Water quality ,chemistry ,Agricultural catchment ,Soil water ,Environmental science ,Animal Science and Zoology ,Agronomy and Crop Science ,management ,Phosphorus loss - Abstract
peer-reviewed Phosphorus (P) loss from soils to water can be a major pressure on freshwater quality and dairy farming, with higher animal stocking rates, may lead to potentially greater nutrient source pressures. In many countries with intensive agriculture, regulation of P management aims to minimise these losses. This study examined the P transfer continuum, from source to impact, in a dairy-dominated, highly stocked, grassland catchment with free-draining soils over three years. The aim was to measure the effects of P source management and regulation on P transfer across the nutrient transfer continuum and subsequent water quality and agro-economic impacts. Reduced P source pressure was indicated by: (a) lower average farm-gate P balances (2.4 kg ha−1 yr−1), higher P use efficiencies (89%) and lower inorganic fertilizer P use (5.2 kg ha−1 yr−1) relative to previous studies; (b) almost no recorded P application during the winter closed period, when applications were prohibited, to avoid incidental transfers; and (c) decreased proportions of soils with excessive P concentrations (32–24%). Concurrently, production and profitability remained comparable with the top 10% of dairy farmers nationally with milk outputs of 14,585 l ha−1, and gross margins of € 3130 ha−1. Whilst there was some indication of a response in P delivery in surface water with declines in quick flow and interflow pathway P concentrations during the winter closed period for P application, delayed baseflows in the wetter third year resulted in elevated P concentrations for long durations and there were no clear trends of improving stream biological quality. This suggests a variable response to policy measures between P source pressure and delivery/impact where the strength of any observable trend is greater closer to the source end of the nutrient transfer continuum and a time lag occurs at the other end. Policy monitoring and assessment efforts will need to be cognisant of this.
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