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CO2 flux measurements and soil gas samples were collected to determine the origin and distribution characteristics of soil gas discharged at Andeok area, Jeju, South Korea. Additionally, this study aims to discuss agricultural activities that may contribute to increased soil CO2 emissions. CO2 flux was measured at 127 points, while soil gas sampling for gas components and carbon-13 (δ13CCO2) analysis was performed at 56 points. The measured CO2 fluxes in the study area ranged from 0.8 to 83.8 g/m2/d (mean: 14.3 g/m2/d), which was lower than CO2 fluxes observed in areas with geogenic CO2 discharge (e.g., near active volcanoes, faults, and CO2-rich water sources). The soil gas analysis revealed that the CO2 concentration and δ13CCO2 ranged from 491 to 23,722 ppmv (mean: 3,205 ppmv) and from −25.2 to −10.7‰ (mean: −19.4‰), respectively. In the cumulative probability diagram, the threshold values for CO2 flux and soil CO2 concentration were 41.3 g/m2/d and 6,693 ppmv, respectively. Samples exceeding the CO2 flux threshold were affected by urea fertilizer application based on land use nearby, and did not overlay with samples exceeding the soil CO2 threshold, indicating different transport mechanisms. Results from a detailed survey near a soil gas sampling location close to high soil CO2 showed that soil CO2 concentrations increased with depth, especially during summer when atmospheric temperatures increased. Spatially, higher soil CO2 concentrations were observed in areas with accumulated plant debris from tangerine orchards. The δ13CCO2 and relationships among CO2-O2, N2-CO2, and N2/O2-CO2 indicated that all collected samples had a biogenic origin. Although geogenic soil gases were not observed in this study, our findings are useful for future research on Jeju Island, as they provide baseline values for distinguishing geogenic soil gas from those with natural and agricultural origins. Moreover, this result provides insights into agricultural activities such as urea fertilization and plowing and their contribution to soil CO2 increase, and inspires future research on negative soil CO2 flux. [ABSTRACT FROM AUTHOR]

Radon (Rn) and helium (He) gases from uranium decay form distinct anomalies related to buried uranium deposits. In order to trace the geochemical anomalous sources from the volcanic-related uranium deposits in deeply buried areas, systematical Rn contents and He isotope ratios were analyzed from the Daguanchang uranium deposit. The soil gas Rn concentrations above the deep uranium are ten times higher than those in barren areas, indicating that instantaneous Rn content measurements can be used to detect deeply buried uranium. The helium isotope ratios (3He/4He) of the unmineralized samples from the mineralized drill hole (ZK1) are relatively lower and uniform compared to those of the samples from no-mineral drill hole (ZK2). However, the Th and U contents of the drill core samples from ZK1 are slightly lower than those of the samples from ZK2, indicating that the lower 3He/4He ratios in ZK1 are most likely due to the addition of 4He from underlying uranium intervals. The differences in the instantaneous Rn contents are consistent with the variations in the He isotope ratios of the drill core samples. These results demonstrate that soil gas Rn and 3He/4He ratios are useful tracers and can indicate the existence of deeply buried volcanic-related hydrothermal uranium ores. [ABSTRACT FROM AUTHOR]

Effective management of surface emissions from abandoned gob methane (AGM) is crucial for mitigating greenhouse gas emissions and ensuring public safety. An important geochemical characteristic of near-surface AGM migration is the potential presence of abnormal component concentrations in near-surface soil gas over abandoned coal gobs. To investigate this phenomenon, a surface geochemical survey was conducted based on four survey lines in the Dongyi and Dongsan abandoned gob groups in the Xinghua Coal Mine, Jixi Basin, in China. The gas chromatography technique was used to analyze the concentrations of methane, carbon dioxide, ethane, propane, and butane in the collected 43 soil gas samples. The results revealed a significant anomaly of soil gas concentrations, particularly methane and carbon dioxide anomalies, in the near-surface soil over abandoned gobs. The background concentration for methane was determined to be 7.49 ppm, with an anomalous threshold set at 10 ppm based on a statistical analysis and an iterative method. This threshold could be confirmed by examining the coupling and decoupling relationship between methane, carbon dioxide, and C2–3 as well. A spatial correlation between regions exhibiting anomalous methane and carbon dioxide concentrations and the positions of gob areas, abandoned surface wells, and faults was observed. Abandoned and sealed coalbed methane surface wells and faults near gas-rich gob areas have the potential to act as conduits for AGM leakage to the surface. Furthermore, concentrations of methane, carbon dioxide, and C2–3 in soil gas over abandoned coal gobs were significantly higher compared to areas unaffected by mining activities. This suggests that elevated concentrations of methane, carbon dioxide, and C2–3 in soil gas may originate from underground AGM. [ABSTRACT FROM AUTHOR]

The objectives of the current study are to carry out soil gas radon (Rn) measurements, to evaluate the total inhalation effective dose, to determine risk levels over the lithological formations of the study area. The behavior investigation of Rn activity concentration distributions in dwellings and soils, and soil Rn mapping were also conducted. Soil gas Rn measurements were made at 102 sampling points by Markus 10 instrument. This data was combined with previously reported results from 140 indoor Rn RADTRAK dosimeters to determine the total inhalation effective dose and to conduct a statistical analysis. Overall, the Rn activity concentrations in soil and dwellings range from 4 to 66 kBq m−3 and from 15 to 140 Bq m−3, with averages of 31 ± 15 kBq m−3 and 41 ± 24 Bq m−3 respectively. The corresponding total inhalation effective dose ranges from 0.35 to 3.53 mSv y−1, with a mean value of 1.37 ± 0.58 mSv y−1. For soil gas Rn, the chlorite schist lithology showed the highest average concentration level. Which could be justified by the possible presence, within chlorite minerals, highly emitting zones of alpha particles, leading to the formation of radioactive halos. Normal and high‐risk level of Rn were found for about 82% and 11% of the total area surveyed respectively. These findings highlight the need for preventive measure against Rn exposure in homes within the investigated areas. This study contributes valuable insights into Rn distribution patterns and risk assessment, offering a basis for targeted interventions in the region. Plain Language Summary: Radon (222Rn (Rn or radon)) is the ubiquitous natural radioactive gas in the earth's crust. It is responsible for about 50% of the total dose received by the public from exposure to natural ionizing radiation. This gas have been recognized as the second leading cause of lung cancer in the world. The current work objectives are to measure the soil gas Rn activity concentrations, to assess the total inhalation dose received by the public and to determine risk levels of various lithological formations. In general, we found that the chlorite schist lithology had the highest average concentration level, due to the presence of minerals such as biotite and chlorite. Public exposure to Rn is greater indoors than outdoors with average inhalation dose relatively higher than the worldwide average. This is due to the numerous factors such as type of construction, building materials, low indoor air renewal rates, etc. The whole study area surveyed were classified as normal‐risk zones. These results reveal that preventive and protective measures against the public exposure to Rn are required from the construction of dwellings. Based on the activity concentrations distribution model and risk assessment, areas that could be targeted for potential intervention could be identified. Key Points: First in situ direct measurement of soil gas Rn activity concentration using Markus‐10 instrument in the various lithological formationsValuable insights into indoor and soil gas Rn distribution patterns and risk assessment, offering a basis for targeted interventionsProduction of a map of Rn distribution in the soil in this part of the country for the first time [ABSTRACT FROM AUTHOR]

A study on the dynamics of Radon and meteorological parameters was conducted in Bengaluru (12056′44'' N, 77030′25″ E, 840 m AMSL) during monsoon of 2014. All measured parameters exhibited a clear diurnal pattern, except for pressure, and are attributed to morning temperature inversion and afternoon enhanced vertical mixing. Concentration of Radon is higher during north eastern monsoon compared with south western monsoon and is due to the presence of continental air mass from north east of India. Monthly average Radon activity has exhibited a positive link with long wave radiation while displaying a negative correlation with ambient temperature, accumulated rainfall and soil temperature. During the study, ambient gamma dose rate of 190.8 nSv hour−1, shortwave radiation of 184.4 Wm−2, longwave radiation of −40.4 Wm−2, soil temperature (at 10 cm) of 26.3°C, humidity of 62.9%, pressure of 918.1 mbar and radon activity of 8.4 ± 0.5 Bq m−3 were recorded. [ABSTRACT FROM AUTHOR]

Indoor radon (222Rn), thoron (220Rn) and their progeny concentrations have been measured in different types of buildings at different locations in different dwellings in different seasons in Hassan city, Karnataka, using time-integrated passive radon dosemeters containing LR-115 Type II solid-state nuclear track detectors. The annual effective dose due to radon and thoron has been estimated. The activity concentrations were observed to be highest in winter and lowest in summer, and the data also shows that bathrooms and kitchens have significantly higher radon-thoron concentrations and annual effective doses. [ABSTRACT FROM AUTHOR]

The Fast Fourier Transform (FFT) analysis of the activity concentration of radon and selected meteorological parameters was carried out at Department of Physics, Bangalore University, Bengaluru (12056′44"N, 77030′25″E, 840 m above MSL). All of the measured parameters, with the exception of pressure, showed a clear diurnal trend, which can be explained by the presence of typical atmospheric processes such as temperature inversion in the morning and greater vertical mixing in the afternoon. Radon's time series has a latent memory of sub-diurnal cycles, as shown via FFT analysis. The monthly average radon has higher levels of activity during winter months compared with monsoon and summer months. Days during the monsoon season had the lowest radon activity, which may be ascribed to the fact that less radon was being exhaled from the soil as a result of the rain. Radon was recorded at 8.06 ± 0.56 Bq/m3, temperature at 28.9 °C, humidity at 55.2% and pressure at 918 mbar. [ABSTRACT FROM AUTHOR]

Agricultural intensification has increased the consumption of inputs, mainly fertilizers, which may increase emissions of greenhouse gases (GHG). The improvement of our knowledge on GHG dynamics in the soil is mandatory to optimize the use of fertilizers and reduce environmental impacts. We developed an electronic sensor prototype based on Arduino to monitor concentrations of carbon dioxide (CO2), ethylene (C2H4), ammonia (NH3), and nitrogen oxides (N2O/NOx) in the soil air in a greenhouse experiment with soybean (Glycine max L.) under two treatments: single inoculation (Bradyrhizobium spp.) or triple co-inoculation (Bradyrhizobium spp. Azospirillum brasilense and Pseudomonas fluorescens) in a completely randomized design. One-way analysis of variance, as well as correlation between plant traits at 35 days of emergence and the average daily concentration of gases in the soil air were performed. Although not affecting plant growth or yield-related traits, co-inoculation increased CO2, while decreased NOx concentrations compared with single inoculation, whereas C2H4 emission changed with the plant growth stage. Although co-inoculation increased respiration, decreased N losses by denitrification, mitigating the total emissions of GHG. The prototype showed to be efficient for monitoring GHG across the experiment at a low cost and easy use, contributing for monitoring GHG concentrations in the soil air. [ABSTRACT FROM AUTHOR]

Appropriate mechanized straw returning and tillage sowing techniques were effective means to optimize soil physical properties and enhance agricultural productivity, as well as important measures for the conservation and restoration of mollisols region in Northeast China. Under the condition of full-scale maize straw returning, four mechanized tillage and sowing modes were set, including plough tillage and sowing (PTS), combined tillage and sowing (CTS), no-tillage and sowing (NTS), and no-tillage and sowing with straw mulching (NTSM). In 2020 and 2021, the study investigated the effects of different mechanized tillage and sowing modes on soil physical properties, soybean yield and economic benefits. The results showed that during the pod-setting and pod-filling period of soybean, the NTS and NTSM treatments exhibited better effects on deep soil insulation and shallow soil moisture retention, the soil physical structure of PTS and CTS treatments were relatively ideal. Compared with PTS and CTS treatments, NTS and NTSM treatments significantly increased soil gravimetric water content (SWC) by 2.35% to 7.98% in the 5-15 cm soil layer and increased soil temperature (ST) by 3.94% to 10.42% in the 2535 cm soil layer (p<0.05), significantly increased soil bulk density (SBD) by 2.98% to 6.72% and significantly reduced soil total porosity (STP) by 3.88% to 6.53% in the 5-25 cm soil layer, and significantly reduced soil gas phase ratio by 8.26% to 6.27% at the 15-25 cm soil layers, which caused soil three-phase ratio (STPR) of PTS and CTS treatment in 15-25 cm soil layer were relatively ideal. The soybean yield of NTSM treatment in 2020 was not significantly different from PTS and CTS treatment (p>0.05), the soybean yield of NTSM treatment in 2021 significantly increased by 7.30% and 5.84% over PTS and CTS treatments, respectively. And the average annual profit per unit area of NTSM treatment increased by 12.84%, 12.41% and 8.57% compared with PTS, CTS and NTS treatments, respectively. Therefore, it was recommended to combine NTSM technique with PTS or CTS technique in a maize-soybean rotation system in mollisols region. The research results provided reference for the selection of appropriate mechanized tillage and sowing techniques in Northeast China's mollisols region and had important guiding significance and practical value for the construction of rational plow layers and the implementation of conservation tillage. [ABSTRACT FROM AUTHOR]

When studying the fault tectonics of the Vychegodskii trough, we detected an area of high concentrations of soil radon, confined to the zone of the Vychegda–Lokchim fault. To localize the radon anomaly, we carried measurements of the volumetric radon activity out over a network of observation points. Air sampling at each point was performed from the wellhead with a depth of 0.5 m and a diameter of 0.1 m. Based on the data obtained, an intense radon anomaly was contoured. At different times, the anomaly changed in the size, shape, and intensity, but its center always remained fixed. According to areal observations, in the central part of the 2 × 2-km anomaly, the radon concentration reached 3800–4800 Bq/m3. The results of continuous daily monitoring in the center of the anomaly showed that the of radon concentration is subject to daily dynamics, which directly depends on meteorological parameters, namely on temperature and humidity. At night, with a decrease in temperature and an increase in air humidity, the level of radon increased to 6000–8000 Bq/m3 on average, in rare cases up to 10 000–12 000 Bq/m3. In the daytime, with an increase in temperature, a decrease in the volumetric radon activity was noted. In addition to the daily dynamics, seasonal variability of the radon field was observed. In autumn, the radon concentration is lower than in summer, which is associated with short-term precipitation and, as a result, the filling of the pore space with water. The Archean–Early Proterozoic basement composed of gneisses, amphibolites, quartzites, and migmatites at a depth of 2 km is considered as the main source of radon. Due to the fact that the anomaly is located in the zone controlled by the Vychegda–Lokchim fault, the latter is considered the main pathway for fluid transport to the surface. [ABSTRACT FROM AUTHOR]

Soil gas radon (Rn) serves as an effective indicator for assessing fault activity in fault zones. Measurement of Rn degassing at the active faults was conducted twice in 2017 and 2018 to assess fault activity in the western margin of the Ordos block. The concentration and flux values of Rn ranged from 0.41 to 40.93 kBq m−3 and 5.17 to 140.33 mBq m−2 s−1, respectively. The compression of the Tibetan Plateau has led to higher Rn concentration and flux in the southern part compared with the northern part. The fault activity is evaluated by the index of IRn calculated from Rn concentrations. The Haiyuan arcuate tectonic region exhibited the most intensive fault activity, followed by the Yinchuan Basin and Jilantai‐Linhe Basin. These findings enhance our understanding of the relationship between fault activity and Rn emission and provide a significant geochemical reference for the fault activity. [ABSTRACT FROM AUTHOR]

The present study deals with the observation of Rn-222 emanation process in terms of its exhalation rate for 48 h from sub-surface soil at 3 h intervals, using a continuous Rn-222 monitoring system RAD7 at Sidho-Kanho-Birsha University campus in Purulia district, located in the easternmost part of the Chotanagpur Plateau, India based on local weather conditions, over five different seasons. For every season, the diurnal variations of the Rn-222 exhalation rate increase after sunset, reaching to its maximum at mid-night and thereafter starts decreasing until it falls to the minimum around noon time. Local meteorological parameters such as ambient temperature, relative humidity, atmospheric pressure were also recorded during the observation period to study the possible influences of these parameters on the soil gas Rn-222 emission rates using Pearson's correlation matrix. There exists a strong positive correlation between relative humidity and Rn-222 exhalation rate and a positive correlation between atmospheric pressure and Rn-222 exhalation rate for all the observation periods. On the other hand, negative correlations between the atmospheric temperature and the Rn-222 exhalation rate exist for all the seasons. [ABSTRACT FROM AUTHOR]

Long-term internal exposure to radon and its progenies may lead to lung cancer. An experimental setup was arranged to assess the impact of temperature and humidity on the distribution of radon concentration in a walk-in type stability test chamber. Different temperature and humidity conditions were established between 15–35 °C and 45–85%, respectively. Passive measurement of radon concentration was carried out using pinhole dosimeters on a monthly basis. The average radon concentration was found to increase with an increase in temperature and decreases with an increase in humidity. The distribution of radon concentration was found to be highly affected by ventilation and air circulation patterns inside the chamber. [ABSTRACT FROM AUTHOR]

Site owners, regulators, and consultants now have decades of experience with vapor intrusion (VI), but guidance for the evaluation of VI continues to vary significantly among states. For those with sites in different regulatory jurisdictions, one challenge is addressing how the requirements or expectations for VI investigation and mitigation differ from one jurisdiction to the next. The overall lack of consensus can make it difficult to manage sites in a consistent manner between jurisdictions. This paper takes into account VI guidance, petroleum hydrocarbon‐specific VI guidance, and/or media‐specific volatilization criteria found in broader regulatory programs. This is an update of the author's previous reviews published in 2007, 2012, and 2018. Since our most recent update, 30 states have revised their guidance, issued new guidance or updated criteria or other VI‐related information. For each State and the District of Columbia, the review includes tabulations of the available types of screening values (e.g., soil, groundwater, soil gas, and indoor air), the screening values for selected chemicals that commonly drive VI investigations (e.g., trichloroethylene [TCE], tetrachloroethylene [PCE], benzene, and other selected volatile organic compounds [VOCs]), and the basis of risk levels used for cancer and non‐cancer risk. Federal values are also included for comparison. In addition, we summarize available key policy criteria for each state including: trigger distances, default subsurface to indoor air attenuation factors, policies for evaluation of petroleum VI, strategies for preferential pathways, and policies for mitigation of VI. The details presented in this paper provide a useful technical reference and regulatory summary for practitioners and the regulated community nationwide. [ABSTRACT FROM AUTHOR]

Subslab soil gas (SSSG) samples were collected as part of an investigation to evaluate vapor intrusion (VI) into a building. The June 2015 Office of Solid Waste and Emergency Response (OSWER) VI Guide (U.S. Environmental Protection Agency [U.S. EPA] 2015) does not provide specific, detailed recommendations regarding how to collect SSSG samples. The data collected in this study will be used to provide input into future OSWER VI Guidance documents on SSSG sample collection. To this end, three different types of subslab sampling ports were constructed with various sampling techniques within a hexagon‐shaped grid in near proximity to each other. Conventional‐, Vapor Pin‐, and California‐style ports were established in duplicate for continual analysis by onsite gas chromatography‐electron capture detection (GC‐ECD). Triplicate ports were established to evaluate active and passive long‐term sampling methods to determine short range temporal differences. Active sampling methods included evacuated stainless‐steel canisters fitted with capillary flow controllers (Modified U.S. EPA Method TO‐15 [U.S. EPA 1999a]) and sorbent tubes collected using a syringe (Modified EPA TO‐17 [U.S. EPA 1999b]). The Passive sampling method used was sorbent tube samples collected following the EPA TO‐17 sampling method (Modified). This study did not identify any systematic differences in sample results between conventional, Vapor Pin, and CA‐style probes for used in SSSG sampling. The decisions for site management would probably be the same for data from any subslab port style, active or passive sampling techniques over durations less than 2 weeks. [ABSTRACT FROM AUTHOR]

This study investigates the temporal variations in methane concentration and flare activity in the Hola trough (offshore Norway) during May 2018 and June 2022. Between these time periods, methane seep activity exhibits 3.5 times increase, as evidenced by hydroacoustic measurements. As the seep area in the Hola trough is constantly within the hydrate stability zone, the observed increase cannot be attributed to migration of its shallow boundary due to temperature increase. However, a combination of low tide conditions resulting in a lower sediment pore pressure and a bottom water temperature increase resulting in a lower methane solubility is likely to explain the increase in the number of seeps observed in June 2022. The hypothesis of tide influence is supported by data collected from a piezometer deployed and recovered during the cruise showing that the tidal effect was observed 3 m below the seafloor. Despite the numerous methane seeps detected, methane concentration and gas flow rates near the seafloor were low (<19 nM and <70 mL min−1, respectively) compared to other areas with methane seep activity. This is likely due to strong currents rapidly dispersing methane in the water column. Sub‐seafloor investigations identified pathways for gas migration in methane seep areas, influenced by topography. This study provides valuable insights into the temporal dynamics of methane concentrations, flare activity, and gas distribution in the Hola trough, contributing to our understanding of offshore methane dynamics in the region. Plain Language Summary: The Hola Trough, offshore Norway's Lofoten‐Vesterålen (LoVe) area, has been of interest for many years due to its rich marine life and potential oil and gas resources. There, coral mounds thrive around methane seepage. The LoVe observatory network monitors this unique environment. Using this observatory platform, associated data set and research expeditions at sea, the project EMAN7 (Environmental impact of Methane seepage and sub‐seabed characterization at LoVe‐Node 7) aims to understand the environmental impact of methane seepage as well as its spatio‐temporal variability. The comparison of methane seep activity during two summers with different environmental conditions revealed 3.5 times more seeps when a combination of warmer bottom water and low tide changes the sediment pore properties. A sensor recording subseafloor pore pressure and bottom temperature supports these findings. Sub‐seafloor investigations identified routes for gas migration in methane seep areas, influenced by topography. Key Points: A combination of warmer bottom water and low tide increases methane seeps 3.5 times by altering sediment gas solubility and pore pressureIntermittent seeps and strong oceanic currents explain the limited microbial mats and the low methane concentration in the water columnWe found sub‐seafloor pathways for gas migration in methane seep areas, influenced by topography [ABSTRACT FROM AUTHOR]

Various anomalies occurring before earthquakes are currently being studied to predict seismic events, with one of them being the radioactive element radon (222Rn). Radon concentrations in the soil, water, and atmosphere fluctuate in response to crustal movement. Recent research has statistically detected anomalies by analyzing the fluctuations in radon concentrations before earthquakes and conducting quantitative evaluations of radon. However, the method used to determine the parameters in the analysis was problematic. Therefore, in this study, we compared observed atmospheric radon concentration data with predicted values based on typical annual patterns using Random Forest analysis. We conducted a more objective analysis by employing this method and statistically determining anomalies using thresholds. This analysis was conducted using atmospheric radon concentration observation data obtained at Kobe Pharmaceutical University (KPU) before the 1995 Kobe Earthquake, and ionization currents emitted when radon decays were obtained at Fukushima Medical University (FMU) before the 2011 Tohoku-oki Earthquake. Consequently, before the major earthquakes occurred at both locations, the difference between the predicted and observed values exceeded the standard deviation by a factor of three. These results indicate the potential of Random Forest analysis to identify anomalies in atmospheric radon concentrations before earthquakes occur. [ABSTRACT FROM AUTHOR]

From autumn 2021 through summer 2023, scientists from the National Oceanic and Atmospheric Administration (NOAA) and partners conducted the Study of Precipitation, the Lower Atmosphere, and Surface for Hydrometeorology (SPLASH) campaign in the East River Watershed of Colorado. One objective of SPLASH was to observe the transfer of energy between the atmosphere and the surface, which was done at several locations. Two remote sites were chosen that did not have access to power utilities. These were along the valley floor near the East River in the vicinity of the unincorporated town of Gothic, Colorado. Energy balance measurements were made at these locations using autonomous, single-level flux towers referred to as Atmospheric Surface Flux Stations (ASFS). The ASFS were deployed on 28 September 2021 at the "Kettle Ponds Annex" site and on 12 October 2021 at the "Avery Picnic" site and operated until 19 July and 21 June 2023, respectively. Measurements included basic meteorology; upward and downward longwave and shortwave radiative fluxes, and subsurface conductive flux, each at 1-minute resolution; 3-d winds from a sonic anemometer and H2O/CO2 from an open-path gas analyser, both at 20 Hz from which sensible, latent heat, and CO2 fluxes were derived; and profiles of soil properties in the upper 0.5 m (both sites) and temperature profiles through the snow (at Avery Picnic), each reported between 10 min and 6 hours. For most measurements, uptime was 96 % (Kettle Ponds) and 89 % (Avery Picnic), and collectively 1,184 days of data were obtained between the stations. The purpose of this manuscript is to document the ASFS deployment at SPLASH, the data acquisition and post-processing of measurements, and to serve as a guide for interested users of the data sets, which are archived under the Creative Commons 4.0 Public Domain licensing at Zenodo. [ABSTRACT FROM AUTHOR]

In this work, a full characterization of the new user-friendly version of the Atmospheric Radon MONitor (ARMON), used to measure very low activity concentrations of the radioactive radon gas in the outdoor atmosphere, is carried out. The ARMON is based on the electrostatic collection of 218 Po + particles on a semiconductor detector surface. A main advantage of this instrument is that it offers high-resolution alpha-energy spectra, which will allow us to separate radon progeny (210 Po, 218 Po, and 214 Po). The monitor feature may also allow measurements of thoron (220 Rn) by collection of 216 Po + , although the instrument is not calibrated for this gas. In the paper, the physical principle; the hardware configuration; and the software development of the automatic and remotely controlled ARMON, conceived and constructed within the MAR 2 EA and the traceRadon projects, are described. The monitor efficiency and its linearity over a wide span of radon concentration activities have been evaluated and tested here using theoretical and experimental approaches. Finally, a complete budget analysis of the total uncertainty of the monitor was also achieved. Results from the application of a simplified theoretical approach show a detection efficiency for 218 Po + of about 0.0075 (Bq m -3) -1 s -1. The experimental approach, consisting of exposing the ARMON at controlled radon concentrations between a few hundreds to a few thousands of becquerels per cubic metre (Bq m -3), gives a detection efficiency for 218 Po + of 0.0057 ± 0.0002 (Bq m -3) s -1. This last value and its independence from the radon levels were also confirmed thanks to a new calibration method which allows us, using low-emanation sources, to obtain controlled radon levels of a few tens of becquerels per cubic metre (Bq m -3). The total uncertainty of the ARMON detection efficiency obtained for hourly radon concentrations above 5 Bq m -3 was lower than 10 % (k= 1). The characteristic limits of the ARMON – being those dependent on the presence of thoron in the sampled air – were also calculated. A detection limit of 0.132 Bq m -3 was estimated in the absence of thoron. At a typical thoron concentration at atmospheric sites of 0.017 min -1 , the detection limit was calculated to be 0.3 Bq m -3 , but this can be reduced if using a delay volume, obtaining a decision threshold of 0.0045 Bq m -3. Current results may allow us to confirm that the ARMON is suitable to measure low-level radon activity concentrations (1–100 Bq m -3) and to be used as a transfer standard to calibrate secondary atmospheric radon monitors. [ABSTRACT FROM AUTHOR]

Afyonkarahisar and its surroundings are in the middle of the Akşehir-Simav Fault System. Before the earthquakes in the region, radon anomalies were observed in some well waters. Linear equations between radon minima and earthquake magnitudes (Mw) were obtained, and correlation coefficients (R2) were calculated. The correlation coefficient (R2) values of the wells from 1 to 6 were obtained as 0.93, 0.83, 0.82, 0.97, 0.87 and 0.85, respectively. Good correlations (high R2 values) were obtained between the radon minimum and the earthquake magnitude (Mw) in 6 wells. The precursory minimum observed at the radon concentration in groundwater decreased as the earthquake's magnitude increased. [ABSTRACT FROM AUTHOR]

Purpose: This study aims to assess the spatial distribution of carbon reserves in the surface of organic and mineral soil layers, in a carbon landfill. The studied areas are located within the broad-leaved forests of the Southern Urals. Methods: The analysis of the forest carbon cycle was conducted in early spring on trees, shrubs, and grass vegetation. Soil gas flux measurements were performed using a Smart Chamber connected to a LI-COR 7810 gas analyser. CO2 flux emission from the soil surface reached up to 493.2 Gf a day, under the tree canopy and did not exceed 471.8 Gf in uncovered areas (glades). Results: Thus, in early spring, the CO2 flux emissions from the soil surface in forest stands is higher in absolute terms, than in uncovered areas. It can presumably be explained by the difference in vegetation cover, along with the size, depth, and spatial distribution of roots from trees, shrubs and herbaceous plants. Conclusion: Forest litter and humus, mainly composed of potassium, nitrogen, and phosphorus, are critical for maintaining the carbon balance in forest areas. [ABSTRACT FROM AUTHOR]

Afyonkarahisar and its surroundings are in the middle of the Akşehir-Simav Fault System. Before the earthquakes in the region, radon anomalies were observed in some well waters. Linear equations between radon minima and earthquake magnitudes (Mw) were obtained, and correlation coefficients (R2) were calculated. The correlation coefficient (R2) values of the wells from 1 to 6 were obtained as 0.93, 0.83, 0.82, 0.97, 0.87 and 0.85, respectively. Good correlations (high R2 values) were obtained between the radon minimum and the earthquake magnitude (Mw) in 6 wells. The precursory minimum observed at the radon concentration in groundwater decreased as the earthquake's magnitude increased. [ABSTRACT FROM AUTHOR]

Gas hydrates deposits in the Andaman forearc basin are inferred from seismic data and confirmed by drilling/coring during the NGHP-01 expedition. We present new evidence of gas flares in the Andaman forearc basin, detected through water column image (WCI), subbottom profiling, and high-resolution seismic data acquired onboard RV Sindhu Sadhana (SSD-085) in November- December 2021. The gas flares are located over an elongated sedimentary ridge, featuring two prominent mounds (M1 and M2) with distinct geological features. Compressional tectonics induced by the Diligent fault (DLF) formed the ridge with varying slopes and elevations. Gas flares observed above the mound M1 in WCI and sub-bottom profiler data. Seafloor samples reveal carbonate rocks with visible pores, indicating gas/fluid migration or burrows. The regional seismic profile delineates three sedimentary sequences: folded and faulted strata, mass transport deposits, and horizontal-to-sub-horizontal sedimentary layers. Additionally, we observed a bottom simulating reflector (BSR), indicating potential subsurface gas hydrate deposits. Detailed high-resolution seismic data revealed complex fault systems near bathymetry mounds (M1 and M2), which may serve as pathways for vertical fluid/gas migration. [ABSTRACT FROM AUTHOR]

Hydrogen exploration in the municipality of Maricá (Rio de Janeiro State, Brazil) indicates that important hydrogen and helium gas fluxes are emitted through reactivated faults. The gas concentrations in the soils, and the modelled gas fluxes, are among the most intense measured so far in the world. This exploration has shown new surface expression of hydrogen micro-seeps, observed along reactivated large tectonic accidents instead of "fairy circles", most common proxy for hydrogen systems in cratonic formation. The geology of Maricá, consisting in Neoproterozoic metamorphic rocks without any already documented evidence of hydrogen-prone formations, appears as a very new field of investigation for natural hydrogen. Results indicate the presence of systematic hydrogen saturation of the usual detectors plugged at 80 cm depth, as well as a permanent recharge of hydrogen through time, without relaxation time. Moreover, positive helium anomalies are associated with this hydrogen soil gas, proving the existence of a gas flux coming from deep horizons of the subsurface. This reduces the risk of misinterpretation of surface hydrogen measurement, since the fear of drill bit metamorphism or superficial biological activity inducing hydrogen artefacts is always a possibility. These hydrogen and helium micro-seeps are associated with positive thorium concentration superficial anomalies, as it was already observed in other places associated with hydrogen exudations. We present a model of soil gas behavior, with a differential process of adsorption/desorption of each gas compound (N 2 , O 2 , Ne, H 2 and He), associated with a deep flux of hydrogen and helium. It is possible to assess a quantification of hydrogen flux of 0.32 m3 m−2.day−1. The surface flux ratio He/H 2 is much higher than any published value of generative flux. This may be explained by a subsurface accumulation, where hydrogen is severely altered whereas helium is preserved, increasing the relative proportion of helium versus hydrogen. [Display omitted] • The Marica municipality (Brazil) reveals important potential for natural hydrogen. • Reactivated faults are excellent proxies for natural hydrogen exploration. • Hydrogen seeping out of reactivated faults may be larger than in fairy circles. • Association of hydrogen and helium in soils indicates that no artefact concerns the hydrogen measurements in soils. • Metamorphic formations may be excellent candidates for hydrogen exploration. [ABSTRACT FROM AUTHOR]

Over the last decades and due to the current climate change situation, the study of the impacts of human activities on climate has reached great importance, being agriculture one of the main sources of soil greenhouse gas. There are different techniques to quantify the soil gas fluxes, such as micrometeorological techniques or chamber techniques, being the last one capable to assess different treatment at the same site. Manual chambers are the most common one. However, due to the low sampling frequency, this approach cannot resolve short-term emission events, like fertilization or rewetting. For this reason, automated chamber systems are an opportunity to improve soil gas flux determination, but their distribution is still scarce due to the cost and challenging technical implementation. The objective of this study was to develop an automated chamber system for agricultural systems under Mediterranean conditions and compare measured GHG flux rates to those derived using manual chambers. A comparison between manual and automated chamber systems was conducted to evaluate the soil gas fluxes obtained by the automated system. Moreover, over a period of one month the soil gas fluxes were determined by both systems to compare their capabilities to capture the temporal variability of soil gas emissions. The automated system reported higher soil GHG fluxes compared to the manual chamber system. Additionally, the higher sampling frequency of the automated chamber system allowed for the capture of daily flux variations, resulting in a more accurate estimation of cumulative soil gas emissions. The study emphasises the importance of chamber dimension and shape, as well as sampling frequency, in the development of chamber systems, especially when using the manual chamber system. [ABSTRACT FROM AUTHOR]

At many dormant volcanoes, magmatic gases are not channeled through preferential degassing routes as fumaroles and only percolate through the flanks of the volcano in a diffuse way. This type of volcanic gas emission provides valuable information, even though the soil matrix contains an important atmospheric component. This study aimed to demonstrate that chemical ratios such as He/CO2 in soil gases provide excellent information on the evolution of volcanic unrest episodes and help forecast the volcanic eruption onset. Before and during the occurrence of the October 2011–March 2012 submarine of El Hierro, Canary Islands, more than 8500 soil He analyses and diffuse CO2 emission measurements were performed. The results show that the soil He/CO2 emission ratio began increasing drastically one month before eruption onset, reaching the maximum value 10 days before. During the eruptive period, this ratio also showed a maximum value several days before the period with the highest magma emission rate. The He/CO2 ratio was also helpful in forecasting the eruption onset. We demonstrate that this tool can be applied in real-time during volcanic emergencies. Our results also encourage a reevaluation of the global He emission from the subaerial volcanism. [ABSTRACT FROM AUTHOR]

The geochemical monitoring of volcanic activity today relies largely on remote sensing, but the combination of this approach together with soil gas monitoring, using the appropriate parameters, is still not widely used. The main purpose of this study was to correlate data from crater gas emissions with flank emissions of soil gases at Mt. Etna volcano from June 2006 to December 2020. Crater SO2 fluxes were measured from fixed stations around the volcano using the DOAS technique and applying a modeled clear-sky spectrum. The SO2/HCl ratio in the crater plume was measured with the OP-FTIR technique from a transportable instrument, using the sun as an IR source. Soil CO2 efflux coupled with the 220Rn/222Rn activity ratio in soil gases (named SGDI) were measured at a fixed monitoring site on the east flank of Etna. All signals acquired were subject both to spectral analysis and to filtering of the periodic signals discovered. All filtered signals revealed changes that were nicely correlated both with other geophysical signals and with volcanic eruptions during the study period. Time lags between parameters were explained in terms of different modes of magma migration and storage inside the volcano before eruptions. A comprehensive dynamic degassing model is presented that allows for a better understanding of magma dynamics in an open-conduit volcano. [ABSTRACT FROM AUTHOR]

Indoor radon surveying and remediation were implemented in a single-family home affected by high levels of indoor radon in the Celleno municipality (central Italy) with the aim of identifying the contribution of radon sources, evaluating the factors affecting radon entry into the building, and reducing radon risk. Average radon levels were relatively low at the ground floor (286 ± 202 Bq m−3) and first floor (167 ± 84 Bq m−3) in autumn when the temperature was still warm and the windows were open, but increased up to 2776 ± 1768 Bq m−3 and 970 ± 202 Bq m−3 in the first half of December, when the heating system was on and the windows were closed. The inner walls of the pilot room at the ground floor, semi buried on one side, were then treated with a waterproof product (a silane terminated polymer) and the average radon was halved (1475 ± 1092 Bq m−3) in the following month, which was still characterised by winter conditions. Radon entry in the room was identified and sealed with the same product, and a radon accumulation space behind a NE-SW oriented wall was naturally ventilated, reducing radon below the reference level in April with northerly winds conditions. [ABSTRACT FROM AUTHOR]

The severe health risk associated with elevated levels of indoor radon gas is well known and widely reported. Measuring residential indoor radon-in-air levels is expensive, labour- and time-intensive. Two of the most important estimators of high levels of indoor radon gas are the underlying geology of an area and the climatic conditions, especially temperature and wind. While varying geology leads to different exhalation rates of radon gas, the climate can mitigate or enhance indoor radon gas levels. The research in this study developed and tested a novel approach to rapidly identify the most probable areas of high indoor radon levels, potential targets for indoor radon measurements. The study utilizes GIS tools to superimpose overlays of geology, climate, and wind to identify possible radon hotspots. South Africa was selected as a study site due to its varying climatic conditions and unique geology which have large areas of underlaying uranium-bearing rock units. Several of the identified hotspots were compared to actual indoor radon measurements, and a good similarity between actual and estimated indoor radon levels was found. This method can easily be applied to other sites or regions, giving it both practical and theoretical values. [ABSTRACT FROM AUTHOR]

When optimizing irrigation methods, much consideration is given to crop growth indicators while less attention has been paid to soil's gaseous carbon (C) and nitrogen (N) emission indicators. Therefore, adopting an irrigation practice that can reduce emissions while maintaining crop yield and quality is of great interest. Thus, open-field experiments were conducted from September 2020 to January 2022 using a single-factor randomized block design with three replications. The lettuce plants ("Feiqiao Lettuce No.1") were grown using four different irrigation methods established by setting the lower limit of drip irrigation to 75%, 65%, and 55% of soil water content at field capacity corresponding to DR1, DR2, and DR3, respectively. Furrow irrigation (FI) was used as a control. Crop growth indicators and soil gas emissions were observed. Results showed that the mean lettuce yield under DR1 (64,500 kg/ha) was the highest, and it was lower under DR3 and FI. The lettuces under DR3 showed greater concentrations of crude fiber, vitamin C, and soluble sugar, and a greater nitrate concentration. Compared with FI, the DR treatments were more conducive to improving the comprehensive quality of lettuce, including the measured appearance and nutritional quality. Among all the irrigation methods, FI had the maximum cracking rate of lettuce, reaching 25.3%, 24.6%, and 22.7%, respectively, for the three continuous seasons. The stem cracking rates under DR2 were the lowest—only 10.1%, 14.4%, and 8.2%, respectively, which were decreased to nearly half compared with FI. The entropy model detected that the weight coefficient evaluation value of DR2 was the greatest, reaching 0.93, indicating that the DR2 method has the optimal benefits under comprehensive consideration of water saving, yield increase, quality improvement, and emission reduction. [ABSTRACT FROM AUTHOR]

Indoor radon source potential from unground soil was monitored using prototype devices approaching a dwelling with a cellar basement at 1 depth from the soil-atmosphere interface. Therefore, the radon concentrations in soil gas were monitored at 1 m depth. Integrated radon measurements were performed, and the results correlated with meteorological parameters. The influence of the difference in outdoor and device-soil temperature was considered, and the infiltration rate was calculated. The effect of the soil temperature gradient on the soil radon entry rate was evaluated. The indoor radon entry rate due to the soil gas was 7.0 ± 2.7 Bq m−3 h−1. The radon entry rate was 5.0 ± 0.8 Bq m−3 h−1 due to diffusion. In contrast, the advection-drive flow of soil gas is ranged up to ± 4.0 Bq m−3 h−1. So, the infiltration rate of the model dwelling was 0.7 (± 0.5) × 10−1 h−1 if only the stack effect occurred. The radon levels in tap water were measured, and the radon entry rate was estimated at 1.3 ± 0.7 Bq m−3 h−1. If the ventilation rate is low or seismic faulting appears, the soil radon entry is increased by one order of magnitude. The soil radon appeared like the building materials, having 1/3 of the total indoor radon entry, while outdoor air was slightly lower (28%), with tap water at 5%. The resident's mortality risk occurred at < 2.5% for typical dwellings in temperate climate areas founded on sand-gravel underground. The risk rises to 34% with an extremely low ventilation rate between indoors and outdoors or high radon entry from the soil due to seismic faulting. [ABSTRACT FROM AUTHOR]

222Rn activity was measured in Asansol city and the adjacent mining area, West Bengal, India. 222Rn concentrations were found to vary in the range 6.4–145, 1080–91002, and 2070–180000 Bqm−3 in indoor air, soil gas, and groundwater, respectively. Total effective doses (TEDs) due to 222Rn exposure were also estimated. In some sampling locations, TEDs appear to exceed the maximum permissible limit (100 µSvy−1). 222Rn concentration variation contour mapping was prepared. Carcinogenic health risk factors (HRF) due to 222Rn activity were also estimated. In some places, HRFs are found to be very high (> permissible limit ~ 1.0). [ABSTRACT FROM AUTHOR]

Agricultural landscape management and climate seasonality can influence soil structure, hydraulic conductivity, and air permeability within the context of soil water and soil gas mobility. To investigate this, in situ and laboratory-based data were collected from three agricultural landscape positions within a watershed in eastern Ontario, Canada during a growing season. Macropore classification, water infiltration tests, and air permeability measurements were conducted in situ and standard soil characterizations were carried out on soil samples. Hydraulic conductivity of the soil matrix, based on grain size data, indicated that the highest values were consistently measured in the B horizon at each landscape setting. Macropores were found to be more abundant within uncultivated drainage ditch bank soils, compared to the adjacent cropped fields. Macropores in the ditch bank soils were exclusively consisted of circular biopores, while both circular and linear macropores were observed in the cultivated field soils. Air permeability, vertical hydraulic conductivity, and horizontal hydraulic conductivity were also greater in the uncultivated soils, relative to the cultivated soils. Field saturated hydraulic conductivity measurements offered evidence of anisotropy, likely due to the vertical nature of the macropore features. Macropore disposition and extent varied over the growing season, especially in the cultivated field soils where tillage and field trafficking are physically disruptive. Seasonality of macropore development will influence temporal changes in advection-based mass exchange of gas and water in the vadose zone. Modeling of mass exchange in agricultural soils should consider time variability in macroporosity to more realistically characterize infiltration and soil gas emissions. [ABSTRACT FROM AUTHOR]

The aim. To study the behaviour of enisamium iodide, thiloron dihydrochloride, morpholinium thiazotate, and the suitability of the previously developed GC-FID methodology in soil. Materials and methods. The determination of the Enisamium iodide, Tilorone dihydrochloride, and Morpholinium thiazotate in soil gas chromatography with a flame ionization detector using the Rxi-5 ms (30 m long, 0.25 mm outer diameter and 0.25 μm liquid stationary phase thickness). Results. A study was conducted on the behaviour of enisamium iodide, thiloron dihydrochloride, and morpholinium thiazotate in soil, along with the assessment of the suitability of the developed GC-FID methodology for determination in soil. The half-life in soil was investigated, which amounted to 45 days for enisamium iodide, 30 days for thilorone dihydrochloride, and 7 days for morpholinium thiazotate, with corresponding decay rate constants of 0.001 mg/mL, 0.001 mg/mL, and 0.0005 mg/mL, respectively. Conclusions. The previously developed GC-FID methodology is suitable for the determination of enisamium iodide, thilorone dihydrochloride, and morpholinium thiazotate in soil, with necessary analysis conditions established. Under aerobic conditions, the selected pharmaceutical preparations' dispersion rate followed the following decreasing order: enisamium iodide>thilorone dihydrochloride > morpholinium thiazotate in soil [ABSTRACT FROM AUTHOR]

Methane spikes observed in the Martian atmosphere require the abrupt release of large amounts of methane from the Martian subsurface. The mechanism for such release has not been identified. We tested whether gas traps can form under Mars‐like conditions in the shallow Martian regolith due to salt migration in the icy soil. Experiments were performed on various soil samples in a Mars Simulation Chamber comprising different perchlorate salts and water concentrations mixed with JSC Mars‐1A. Inside the chamber, the samples were exposed to a range of temperatures from −20°C to 10°C and maintained CO2 gaseous pressure between 8 and 10 mbars. As a methane analog, Neon was injected periodically underneath the soil sample. It was found that over a wide range of Mars‐like soil parameters, a gas impermeable soil seal can form over a relatively short period (3–13 days) but requires 5%–10% of perchlorate salt content in the soil. It was determined that such a seal could sustain several mbars of neon above the Martian atmospheric pressure in the soil. Based on our experiments, substantial amounts of gaseous methane may accumulate under the soil seal and get released abruptly into the atmosphere upon seal cracking. An abrupt release of methane from the shallow subsurface may help explain methane variability at the Martian surface, as the Mars Science Laboratory detected. Plain Language Summary: Spikes of atmospheric methane on Mars, recently observed by the Mars Science Laboratory mission, are puzzling. To explain rapid variations in methane abundance in the Martian atmosphere, methane has to be released abruptly. Our experiments in the Mars simulation chamber demonstrated that perchlorate salts can be transported toward the surface regolith via water migration and subsequent sublimation. We showed that under Mars‐like conditions, the soil with migrated salts can become cemented and form a solid gas impermeable seal. Methane and other volatiles can accumulate under the soil seal. Methane seasonal variability and occasional methane spikes in the Gale crater on Mars can be due to a sudden release of methane from the soil gas pockets when the Curiosity rover breaks soil seals by moving or drilling. Key Points: Gas impermeable seals can form in Mars‐like conditions in the soil with 5%–10% perchlorate salts by mass and a shallow permafrost layerMethane could accumulate under the seal in the shallow subsurface and be released abruptly into the atmosphere when the seal breaks [ABSTRACT FROM AUTHOR]

This study looks at the annual variations in landfill gas concentrations within the surface layer of the dump as well as the effect of climatic factors on these variations under the tropical climate. The experiment was carried out at part of the Karadiyana landfill, Sri Lanka, containing old mixed municipal solid waste covered by vegetation. The gas concentrations of the landfill surface layer were measured from three gas wells established on the dump surface layer, which contains 2.5 m depth, throughout the year with the measuring of climatic factors. The results show the annual fluctuation of temperature, cumulative rainfall, relative humidity, and atmospheric pressure were 27–42°C, 66.7–357.7 mm, 24.7%–78.2%, and 999.5–1014 mbar around the studied landfill area, and the average concentration value of the CH4, NH3, H2S, and VOCs gases were 18.94 ± 11.49%, 15.48 ± 15.17 mg m−3, 15.06 ± 19.02 mg m−3, and 0.83 ± 0.99 mg m−3, respectively. The rainfall and atmospheric temperature were significant metrological factors influencing the surface layer gas concentrations and showed a significant positive correlation with cumulative rainfall and a negative correlation with atmospheric temperature. The relative humidity shows a moderate positive correlation, and there was no evidence of a considerable impact of atmospheric pressure on the surface layer concentrations. Annual fluctuation is a critical factor for landfill gas emission quantification, and surface layer concentration variation can be used to study the emission fluctuation by considering their relationship. [ABSTRACT FROM AUTHOR]

This study uses CR-39 radon detectors to examine radon distributions, seasonal indoor radon variations, correction factors, and the influence of building materials and characteristics on indoor radon concentration in 120 dwellings. The study also determines the spatial distribution of radon levels using the ArcGIS geostatistical method. Radon detectors were exposed in bedrooms from April to July (RS), August to November (DS); December to March (HS), and January-December (YS) from 2021 to 2022. The result for the radon levels during the weather seasons were; 32.3 to 190.1 Bqm-3 (80.9 ± 3.2 Bq/m3) for (RS), 30.8 to 151.4 Bqm-3 (68.5 ± 2.7 Bqm-3) for HS and 24.8 to 112.9 Bqm-3(61.7 ± 2.1 Bqm-3) for DS, and 25.2 to 145.2 Bq/m3 (69.4 ± 2.7 Bqm-3). The arithmetic mean for April to July season was greater than August to November. The correction factors associated with this study ranged from 0.9 to 1.2. The annual effective dose (AE) associated with radon data was varied from 0.6 to 4.04 mSv/y (1.8 ± 0.1 mSv/y). The April to July period which was characterized by rains recorded the highest correlation coefficient and indoor radon concentration. Distribution and radon mapping revealed radon that the exposure to the occupant is non-uniformly spread across the studied dwellings. 15.4% of the studied data exceeded WHO reference values of 100 Bq/m3. The seasonal variation, dwelling age, and building materials were observed to have a substantial impact on the levels of radon concentration within the buildings. [ABSTRACT FROM AUTHOR]

The article presents the results of the development of a universal radiometric device for measuring the activities of alpha, beta, and gamma radiation and the volumetric activity of radon in soil, air, and water. The structure of a multichannel radiometric device with software, a diagram of a microcontroller unit with a signal conditioner, and the operation of electronic units are presented. The data of monitoring the volumetric activity of radon alpha particles and the activities of beta and gamma radiation in the soil air are given. The monitoring results showed that activities vary depending on temperature, humidity, and time of day. The device is compact, mobile, and universal and can be used both stationary and in the field. The developed RMI V1.7 program allows for long-term, real-time monitoring, and all measurements are displayed on a computer monitor. [ABSTRACT FROM AUTHOR]

This study investigated the spatiotemporal variations in the occurrence of polychlorinated biphenyl (PCB) congeners both in soil and ambient air. Soil and air samples were taken simultaneously for three seasons (spring, summer, and autumn) from industrial, urban, and semi-rural areas in Bursa, Turkey. Light and medium PCB homologous groups were dominant in all samples.Total PCB (∑25 PCBs) concentrations in the air were 0.12 ± 0.13, 0.06 ± 0.07, and 0.08 ± 0.11 ng/m3 and in soil were 4.01.±2.38, 5.44 ± 3.14, and 3.66 ± 1.56 ng/g DM for summer, spring, and winter, respectively. Moreover, the samples were taken from different sites to determine the spatial fluctuations. The average ∑25 PCBs in the air were 0.22 ± 0.06, 0.03 ± 0.01, and 0.03 ± 0.02 ng/m3 and in soil were 7.08 ± 1.84, 2.98 ± 0.52, and 3.06 ± 0.70 ng/g DM for industrial, urban and semi-rural sites, respectively. Maximum air and soil PCB concentrations were determined in the industrial region. The spatiotemporal changes in the fugacity fractions and net fluxes were also examined. The direction of the PCB movement was assessed and the results indicated that soil was a diffusive source for PCBs. The calculated fugacity fractions (ff) were above 0.7 while average flux values were calculated as 0.65 ± 0.33 ng/m2-d, 0.21 ± 0.19 ng/m2-d, and 0.26 ± 0.27 ng/m2-day for industrial, urban and semi-rural regions, respectively. [ABSTRACT FROM AUTHOR]

The Jiangmen Underground Neutrino Observatory is constructing the world's largest liquid scintillator detector, with a 20 kt target mass and approximately 700 m of overburden. The total underground space of civil construction is around 300,000 m 3 , with the main hall comprising about 120,000 m 3 , making it the largest experimental hall in the world. Maintaining a low radon concentration in the underground air is crucial for both human health and the accuracy of experiments involving rare decay detection, such as neutrino and dark matter experiments. To ensure human health and the integrity of neutrino physics experiments, the nominal radon concentration in the main hall must be kept below 200 Bq/m 3 with a maximum value below 400 Bq/m 3 . Introduction of fresh air from above ground can significantly lower radon concentration. A benchmark experiment conducted in the refuge room near the main hall revealed that the radon emanating from underground water is a significant source of radon in the underground air. The total underground ventilation rate is approximately 160,000 m 3 /h of fresh air with about 30 Bq/m 3 222 Rn from the bottom of the vertical tunnel after the installation of powerful fans. Of this, 55,000 m 3 /h is used for ventilation in the main hall. As a result of these measures, the radon concentration inside the main hall has decreased from 1600 Bq/m 3 to below 200 Bq/m 3 under stable working conditions, with exceptions during rare adverse weather events or fan failures. The employed strategies to control radon concentration in the underground air are described in this paper. [ABSTRACT FROM AUTHOR]

Against the background of climate change, the global carbon and water cycle has undergone significant changes, and it is of great significance to explore the interrelationships of the carbon and water cycles in different regions to cope with future climate change. In this study, based on gross primary productivity (GPP) and precipitation (PRE) data, the precipitation use efficiency (PUE) of the Loess Plateau (LP) was calculated, and the Sen trend analysis and Mann‐Kendall test were used to analyse the temporal and spatial variation characteristics of PUE, as well as the first‐order difference method was used to derive the relative contributions to quantify the impact of vegetation growth and meteorological factors on PUE. The results show that (1) from 2001 to 2018, the spatial distribution pattern of vegetation PUE exhibited an increasing trend from northwest to southeast. On the time scale, the multi‐year average value of PUE was 1.17 gC m−2 mm−1, showing an overall upward trend. Among the different land cover types, paddy fields had the highest PUE level, and sparse grassland had the lowest; (2) LAI had the highest relative contribution to vegetation PUE, followed by temperature (Temp), net radiation of the ground surface (RN), specific humidity (Shum), and wind speed (WS). LAI contributes positively to 88.9% of the area. RN positively influences high‐altitude areas, while Shum had a larger area with a negative contribution. The contribution of Temp increases from northwest to southeast, and WS has balanced positive and negative contributions; (3) LAI is the dominant factor for the spatial and temporal variation of PUE in the LP, and the size of the areas where different meteorological factors dominate the changes of PUE are as follows: WS > Shum>RN > Temp. At high altitudes, the dominant meteorological driver is WS, while at low altitudes, the dominant climate driver is Shum. This study is of guiding significance for the ecological restoration and management of the LP, and it can also provide a scientific basis for the improvement of ecosystems and the sustainable management of water resources in the context of global climate change. [ABSTRACT FROM AUTHOR]

Boreal forests nowadays act as a sink for atmospheric carbon dioxide; however, their sequestration capacity is highly sensitive to weather conditions and, specifically to ongoing climate warming. Extreme weather events such as heavy rainfalls or, conversely, heat waves during the growing season might perturb the ecosystem carbon balance and convert them to an additional CO2 source. Thus, there is an urgent need to revise ecosystem carbon fluxes in vast Siberian taiga ecosystems as influenced by extreme weather events. In this study, we focused on the soil CO2 pulses appearing after the rainfall events and quantification of their input to the seasonal cumulative CO2 efflux in the boreal forests in Central Siberia. Seasonal measurements of soil CO2 fluxes (both soil respiration and net soil exchange) were conducted during three consecutive frost-free seasons using the dynamic chamber method. Seasonal dynamics of net soil exchange fluxes demonstrated positive values, reflecting that soil respiration rates exceeded CO2 uptake in the forest floor vegetation layer. Moreover, the heavy rains caused a rapid pulse of soil emissions and, as a consequence, the release of additional amounts of CO2 from the soil into the atmosphere. A single rain event may cause a 5–11-fold increase of the NSE flux compared to the pre-rainfall values. The input of CO2 pulses to the seasonal cumulative efflux varied from near zero to 39% depending on precipitation patterns of a particular season. These findings emphasize the critical need for more frequent measurements of soil CO2 fluxes throughout the growing season which capture the CO2 pulses induced by rain events. This approach has inevitable importance for the accurate assessment of seasonal CO2 soil emissions and adequate predictions of response of boreal pine forests to climatic changes. [ABSTRACT FROM AUTHOR]

How convective boundary‐layer (CBL) processes modify fluxes of sensible (SH) and latent (LH) heat and CO2 (Fc) in the atmospheric surface layer (ASL) remains a recalcitrant problem. Here, large eddy simulations for the CBL show that while SH in the ASL decreases linearly with height regardless of soil moisture conditions, LH and Fc decrease linearly with height over wet soils but increase with height over dry soils. This varying flux divergence/convergence is regulated by changes in asymmetric flux transport between top‐down and bottom‐up processes. Such flux divergence and convergence indicate that turbulent fluxes measured in the ASL underestimate and overestimate the "true" surface interfacial fluxes, respectively. While the non‐closure of the surface energy balance persists across all soil moisture states, it improves over drier soils due to overestimated LH. The non‐closure does not imply that Fc is always underestimated; Fc can be overestimated over dry soils despite the non‐closure issue. Plain Language Summary: Large swirling motions, called large turbulent eddies, efficiently transport water vapor, carbon dioxide, and heat up and down throughout the convective boundary layer (CBL). To what extent scalar fluxes in the atmospheric surface layer (ASL) are modulated by large turbulent eddies from the top of the CBL (i.e., top‐down eddies) remains a recalcitrant problem in many fields spanning atmospheric sciences, hydrology, ecology, and climate change. Here, high‐resolution computational simulations of the CBL show that scalar fluxes in the ASL linearly change with height across soil wetness conditions largely due to changes in the interactions of top‐down processes and bottom‐up surface exchange. Such linear height‐dependence of the fluxes indicates that reported fluxes from direct turbulent measurements in the ASL are not identical to their sought surface values. As a result, the non‐closure of the surface energy balance occurs across all soil moisture conditions but improves as soil becomes dry. CO2 measured fluxes are underestimated over wet soils and overestimated over dry soils, which has its implication when interpreting CO2 exchanges from global flux measuring networks utilizing turbulence theories. Height dependence of fluxes, which confirms that the constant flux layer assumption is not routinely satisfied, is a fundamental reason for the non‐closure. Key Points: Asymmetric flux transport by bottom‐up and top‐down processes leads to varying flux divergence/convergence (FDC) in the surface layerLatent heat and CO2 fluxes are underestimated when soil is wet and overestimated when dry, but sensible heat flux is always underestimatedNon‐closure of the surface energy balance is regulated by varying FDC and improves for dry soils due to overestimated latent heat flux [ABSTRACT FROM AUTHOR]

Natural hydrogen has generated great interest as a potential clean and renewable energy source. To understand the occurrence of natural hydrogen, 103 1-m deep soil gas samples were acquired near the San Andreas Fault at Jasper Ridge and Portola Valley, California, USA. The gas samples were analyzed for hydrogen, helium, carbon dioxide, light hydrocarbons, and fixed gas concentrations. Statistical data analysis was carried out to group samples, reveal their spatial distribution, and understand possible sources of the gases. High concentrations of hydrogen up to 20.3 ppmv and 17.3 ppmv occur in Jasper Ridge and Portola Valley, respectively, ∼30–35 times greater than the atmospheric concentration. Most samples with high hydrogen concentrations fall on or near faults, suggesting an origin by serpentinization or geomechanical activation of catalytic sites in minerals, although a deep-seated primordial origin cannot be excluded. Elevated concentrations of carbon dioxide resulted from aerobic microbial degradation of organic matter and elevated concentrations of light hydrocarbons likely resulted from thermal cracking of organic matter. • High concentrations of hydrogen discovered to occur in Jasper Ridge and Portola Valley near faults. • Hierarchical cluster and principal component analyses reveal spatial clustering of gas samples. • Alternating least squares regression reveals pure components and sources of gases. • Geochemical soil sampling and data analysis is a tool for natural H 2 exploration. [ABSTRACT FROM AUTHOR]

Atmospheric radon measurements assist in many aspects of climate and meteorological research, notably as an airmass tracer and for modelling boundary layer development, mixing heights and stability. Daughter products from radon decay are sometimes incorporated into the particle pollution measurements of commercially available beta-attenuation monitors (BAM). BAMs incorporating radon measurements are used in air quality monitoring networks and can supplement traditional radon measurements. Here we compare in-situ radon measurements from Thermo Fisher Scientific (Franklin, MA, USA) BAM instruments (Thermo Scientific 5014i, Thermo Scientific 5030 SHARP, Thermo Anderson FH62C14) at two air quality monitoring stations in New South Wales, Australia. Between systems we find strong correlations for hourly measurements (r = 0.97–0.99); daily means (r = 0.97–0.99); hour of the day (r = 0.84–0.98); and month (r = 0.82–0.98). The regression analysis for radon measurements between systems showed strong linear responses, although there are some variations in the slopes of the regressions. This implies that with correction BAM measurements can be comparable to standard measurement techniques, for example, from the Australian Nuclear Science and Technology Organisation (ANSTO) dual flow loop monitors. Our findings imply that BAM derived radon measurements are precise, although their accuracy varies. BAM radon measurements can support studies on boundary layer development or where radon is used as an atmospheric transport tracer. [ABSTRACT FROM AUTHOR]

The Arctic landscape has experienced many dramatic forms of change due to anthropogenic warming. Large crater‐like forms surrounded by fragmented blocks scattered outward to great distances with precursor mounds appeared in the continuous permafrost zone of the Yamal and Gydan peninsulas of Western Siberia. The morphologies of these craters, in addition to the abundant evidence of active and intense gas emissions across the region, indicate that they formed due the subsurface accumulation, pressurization, and explosive release of gasses trapped within the permafrost. Therefore, these craters were termed "gas emission craters" (GEC). However, some have suggested that in addition to gas accumulation, these features form in a manner similar to ice‐cored pingos and require pressurization due to the freezing of subsurface ice. This is despite the fact that not all GECs form in areas conducive to pingo‐like ice accumulation. Here, we test whether the pressurization and explosive release of methane gas alone can reproduce the observed morphology of the first‐discovered and most intensely studied GEC, Yamal crater. We use the available field and satellite data to constrain the initial dimension parameters of a model of the explosion process and consider several plausible configurations for the unknown interior cavity shape, the overlying permafrost cap thickness, and gas chamber volume. The explosion process is modeled in phases: gas migrates upward and accumulates in the subsurface until the gas pressure fractures the overlying cap, the expanding gas and cap blocks are initially accelerated outward together, and then the blocks are launched as projectiles. The sizes and locations of the ejected blocks found at Yamal crater are used to determine the initial gas pressures required to launch those projectiles to the observed locations. Finally, we estimate the amount of gas released in each of the multiple model runs testing different plausible internal cavity geometries. For the range of plausible block sizes and densities, and a subset of gas chamber volumes considered, we find that the gas pressure (0.6–2.6 MPa) required to launch the Yamal crater blocks to their observed distances was within the range of the sum of the ice/permafrost tensile strength and the lithostatic pressure (0.22–2.87 MPa). Thus, the observed blocks could have been launched by the energy required to fracture and displace the overlying permafrost cap. We show that the mechanism of formation of this GEC does not require pressure from the freezing of ice in the subsurface to crack and explode the overlying permafrost—gas pressure alone can produce these GECs. We expect that as our planet warms, the Siberian permafrost will continue to warm, weaken, and release gasses such as the greenhouse gas methane, and contribute to a permafrost carbon‐positive feedback cycle that would lead to the formation of even more explosive GECs. [ABSTRACT FROM AUTHOR]

Radon and its progenies found in water indicate the existence of seismically active faults in the region. However, exposure to high levels of radon can also result in radiation-related health risks. This study focuses on radon-based active tectonic studies along the Muzaffarabad Fault in the core of the Hazara-Kashmir Syntaxis (HKS), NW Himalayas, Pakistan. In this study, spring water samples were collected along roadside of Jhelum Valley and in close proximity to the Muzaffarabad Fault in Pakistan using Radon Thoron Monitor (RTM1688-2). The results of the study showed that the radon concentrations in the water samples ranged from 1.895 to 17.097 Bq/l. The study found that the highest radon concentration was observed in the samples collected closest to the fault, while the lowest concentration was observed in the samples collected further away. The statistical analysis between the radon concentration and the distance from the fault showed a strong inverse relationship (R2=0.73). The study also found that 68% of the sampling sites had radon concentrations that exceeded the maximum contamination level (MCL) set by the US Environmental Protection Agency (EPA). The higher radon concentrations in the springs water suggest the probability of earthquake, which in turn poses potential health risks for the local population. The findings suggest that the measurement of radon concentration in water can be used as a tool for identifying seismically active faults in the region. [ABSTRACT FROM AUTHOR]

In the frame of a collaboration between the Italian National Research Council (CNR) and Mares s.r.l., a study, about the possibility of determining radon vertical distribution at different soil depths in order to trace light non-aqueous phase liquid (LNAPL) contaminations, was developed. The radon deficit technique, based on the preferential solubility of soil gas radon into non-polar fluids, such as refined hydrocarbons, has been investigated by various theoretical and applied research so far. According to international scientific literature, radon deficit can be used both for geochemical prospection of the spatial irregular NAPL dispersion and for monitoring of remediation activities. Even though it is well known that this type of pollutants can be distributed along the vertical soil profile—firstly due to their density in comparison to water density, and secondly due to fluctuations of shallow aquifers, soil pore size, aging of contamination, and so on—the vertical localization of the plume still represents a scientific challenge. In this article, a method to determine the radon vertical profile is tested and applied to assess the potential use of the radon deficit technique in the vertical detection of pollutant presence for the first time in a fuelling station. Two LNAPL-contaminated sites were selected for a pilot test. Experimental findings seem to support the use of vertical radon geochemical prospection to delimit the depth range of a LNAPL pollution directly. Systematic data collection and modeling may lead to a 3D reconstruction of the dispersion of contaminant in different soil levels. [ABSTRACT FROM AUTHOR]

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