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Twenty-six samples from two major altered volcanic ash beds, Kinnekulle and BII Bentonite of the Kuressaare core section (K-3), Saaremaa Island, were explored to record the geochemical and mineralogical heterogeneity of beds. Signs of ash transport fractionation, redeposition of volcanic ash and diagenetic redistribution of material are described and interpreted. In authigenic mineralogy of the Kinnekulle Bentonite illite--smectite dominates with addition of K-feldspar at the margins. The BII Bentonite is composed of chlorite--smectite and illite--smectite. The stability of phenocryst compositions, including that of sanidine and biotite, indicates that both bentonites originate from a single eruption. The observed rather stable pyroclastic sanidine compositions in the cross section of bentonites confirm the reliability of sanidine-based fingerprinting of altered volcanic ash beds. Trace element distribution in bentonites and host rocks indicates that Zr, Ga, Rb, Nb, Ti and Th stayed largely immobile during volcanic ash alteration and reflect primary ash composition. However, some redistribution of Nb and Ti as well as Y has probably occurred near the contacts of bentonite with the host rock. More scattered grain size distribution and immobile element patterns of the Kinnekulle Bentonite support the idea that the primary ash bed had a heterogeneous composition and it was one of the biggest bentonites of the Phanerozoic and most likely records an extended volcanic event. Significant geochemical variations, including a high S content, near the upper and lower contacts of the Kinnekulle Bentonite and elevated Ca and P in host rocks of both bentonites suggest that the studied large ash-falls caused notable perturbations in shallow marine and early post-sedimentary environment. [ABSTRACT FROM AUTHOR]

The article deals with grain size distribution of the insoluble residue of Upper Ordovician carbonate rocks of the Baltoscandian Basin in the West Latvian Aizpute-41 core. Great fluctuations in mean grain size in the sections of the Pirgu (uppermost Katian) and Porkuni (Hirnantian) stages are considered as indications of eustatic sea level fluctuations, pointing to the glaciation in the Hirnantian and its prelude in Pirgu time. An alternative cause of grain size fluctuations might be the up-and-down tectonic movements. Nevertheless, the synchronicity of cessation of fluctuations with the end of the Hirnantian glaciation supports the glaciation-related reasons. [ABSTRACT FROM AUTHOR]

In three drill cores in Latvia and Lithuania a thin (1 cm thick) altered volcanic ash bed with high concentrations of phosphorus (up to 3%), cerium (1%), lanthanum (0.5%) and strontium (2.5%), has been found close to the Aeronian/Telychian boundary (Llandovery, Silurian, ca 438Ma). Small,millimetre-thick lenses within the ash bed contain up to 12%P and Sr, up to 6%Ce and 3%La. These elements occur as a solid solution of goyazite-florencitemineral. Additionally, authigenic K-feldspar and kaolinite occur in this ash bed. The high concentrations of REE elements, strontium and phosphorus suggest a carbonatite source magma, but the strontium isotope ratio contradicts that origin. Such a unique composition in a volcanic ash layer is a good basis for using it as a marker horizon for correlation of sections. [ABSTRACT FROM AUTHOR]

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Abstract: In the Fennoscandian Shield the fluctuations in arid–humid climate conditions are inferred from the Al2O3/TiO2 ratio of the clay fraction of Estonian carbonate rocks of the Baltoscandian sedimentary Basin. The Late Ordovician climate of the Fennoscandian Shield was mainly semi-humid with several humid pulses in the Sandbian, mid-Katian and Hirnantian. The post-Hirnantian climate was fluctuating between humid and arid until stable humid conditions were established in the Middle and early Late Llandovery. Starting from the latest Llandovery, the climate turned semi-arid and arid. The Ordovician–Silurian long-term trend toward aridity was caused by the equator-ward drift of the Baltica plate. Shorter-term fluctuations of Al2O3/TiO2 reflect climate changes of the global extent. [Copyright &y& Elsevier]