1. Influence of Dimensionality of Carbon-based Additives on Thermoelectric Transport Parameters in Polymer Electrolytes
- Author
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Frank, Maximilian, Schilling, Julian-Steven, Zorn, Theresa, Kessler, Philipp, Bachmann, Stephanie, Pöppler, Ann-Christin, and Pflaum, Jens
- Subjects
Physics - Applied Physics ,Condensed Matter - Materials Science - Abstract
This paper investigates the thermoelectric properties of solid polymer electrolytes (SPE) containing lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) and sodium bis(trifluoromethanesulfonyl)imide (NaTFSI) salts, along with carbon-based additives of various dimensionalities. Increasing salt concentration leads to higher Seebeck coefficients as a result of the increasing number of free charge carriers and additional, superimposed effects by ion-ion and ion-polymer interactions. NaTFSI-based electrolytes exhibit negative Seebeck coefficients (up to $S = -1.5\,\mathrm{mV\,K^{-1}}$), indicating dominant mobility of $\mathrm{TFSI^-}$ ions. Quasi-one-dimensional carbon nanotubes (CNTs) increase the Seebeck coefficient by a factor of 3. Planar, two-dimensional graphite flakes (GF) moderately enhance it, affecting $\mathrm{Na^+}$ and $\mathrm{TFSI^-}$ ion mobilities and electronic conductivity. Bulky, three-dimensional carbon black (CB) additives induce a unique behavior where the sign of the Seebeck coefficient changes with temperature, presumably due to interaction with $\mathrm{TFSI^-}$ ions within the CB structure. Changes in activation energy and Vogel temperature with salt concentration suggest structural and mechanical modifications in the polymer matrix. The choice of carbon-based additives and salt concentration significantly influences the thermoelectric properties of SPEs thermoelectric properties, providing insights into their potential for thermoelectric applications. Sodium-based electrolytes emerge as promising, sustainable alternatives to lithium-based systems, aligning with sustainable energy research demands.
- Published
- 2024