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High-resolution chronologies with the best time control are key for comparing palaeoenvironmental studies with independent high-precision historical, archaeological or climatic data. Precise chronologies are also essential for inter-site comparisons of palaeo records at decadal to centennial time scales. We present an updated sediment chronology from Burgäschisee, a small and well-studied lake in the Swiss lowlands. The new age-depth relationship was generated using a large number of new radiocarbon samples of terrestrial plant remains extracted from the Burgäschisee sediments and Bayesian age-depth modelling. The results reveal 2σ uncertainties of only ±19 years for the entire record covering the Early Bronze Age (3800 cal. BP) to the Early Middle Ages (1150 cal. BP). The differences between four age-depth modelling techniques (Bayesian and non-Bayesian) are minor (around 25 years) and remain stable with lower radiocarbon date availability. The maximum age offset between the preliminary previously published and the refined chronology from Burgäschisee is 225 years. Our results demonstrate the importance of a rigorous subsampling strategy that includes a careful selection of the best terrestrial plant material and avoiding radiocarbon calibration plateaus whenever possible. The new chronology from Burgäschisee now allows a more accurate site-to-site comparison with archaeological, historical and other palaeoecological evidence from the region.

Methane (CH4) is the second most important anthropogenic greenhouse gas after carbon dioxide (CO2). Main CH4 sources are linked to the human use of fossil fuels (oil, gas, coal) and human-related or natural biogenic processes such as agriculture, waste management or wetlands. While biogenic emissions of CH4 contain present-day atmospheric radiocarbon (14C) levels, CH4 derived from fossil sources is 14C-free so that 14CH4 measurements can be used as a source apportionment proxy to distinguish fossil from biogenic CH4 sources.A dedicated setup to analyze 14CH4 was developed at the Laboratory for the Analysis of Radiocarbon with AMS, University of Bern. Typical samples are 60L of atmospheric air collected in bags, which, after extraction, result in about 60 µg carbon in CH4-derived CO2 form, enough for a 14C gas measurement on a MICADAS (Mini Carbon Dating System) accelerator mass spectrometer.Since 2019, biweekly air samplings have been conducted at three sites in Switzerland: the high altitude research station Jungfraujoch (3580 m asl) considered as a European continental background station, a tall tower in Beromünster and an urban site in Bern. A fourth site (with a tall tower) in Sottens has been visited since June 2021.Beside these in situ measurements, an atmospheric 14CH4 transport model was developed to simulate 14CH4 values for each sampling. It is based on the Lagrangian transport and dispersion model FLEXPART, two CH4 emission inventories (Meteotest EKAT for Switzerland, TNO-CAMS v4.2 for the rest of Europe), a priori 14CH4 signatures for each emission type and the weather model COSMO. 14CH4 emissions from pressurized water reactors (PWR) of nuclear power plants in Switzerland and neighboring countries are also taken into consideration.This contribution will show the in situ 14CH4 measurements as well as corresponding simulations and emphasize that the sporadic transport of 14CH4 emitted from PWRs is greatly influencing the overall signal measured over the Swiss Plateau making CH4 source apportionment for this region very challenging.

The cycling of subsurface karst CO2 is not well constrained in terms of its source and transportation pathway. The classical model suggests that cave CO2 is produced by the respiration of soils and vegetation in the catchment. In contrast, several new studies have proposed that the dominant source of CO2 is from the respiration of older organic matter situated deeper within the karst, or from the degassing of supersaturated drip water.We present over a year of monitoring data from Milandre cave, northern Switzerland, whereby we evaluated the 14CO2 and δ13CO2 composition of the atmosphere in the cave catchment, catchment soil gas, well gas, and cave air. Drip waters located throughout the cave also underwent various analysis. The cave 14CO2 is more depleted compared to the soil and gas samples. The Keeling plot intercept of atmospheric and cave δ13CO2 is ~-26‰, indicating a dominant contribution from biological respiration. The dissolved inorganic carbon from various cave drips have an F14C from ~ 0.84 to 0.96 and δ13C from ~ -16‰ to -11‰. F14C and δ13C are inversely correlated. Considering both the 14C and δ 13C results, this suggests either a source of CO2 from an aged reservoir of respiring organic matter contributing to the cave gas or substantial influence from degassing of 14C fossil carbonate CO2 from drip water. These results have implications for the understanding of the subterranean carbon cycle and the interpretation of speleothem carbon isotope records for paleoclimate studies.

Perturbations to the natural carbon cycle due to anthropogenic and induced natural emissions of carbon dioxide (CO2) into the atmosphere are strongly linked with the current trend of global climate change. Efforts aiming at measuring amounts of CO2 emitted by different ecosystems and industrial activities have been increasing in the past years, in order to gather information about necessary mitigations efforts towards reduced future emissions.Radiocarbon (14C) measurements of atmospheric CO2 are unique in their capabilities to provide information on carbon sources and transport. The radiocarbon method allows an apportionment between "modern" sources, with 14CO2 signatures close to the global atmospheric average and fossil-fuel derived sources which are 14C-depleted. The capability to determine the fraction of fossil CO2 in atmospheric samples provides insight on the contribution of different emissions to the current rise in atmospheric CO2 concentration. When associated with meteorological data and atmospheric dispersion models, radiocarbon data can be used to identify fossil-fuel emissions patterns from a local to a regional scale, across time.The Radiocarbon Inventories of Switzerland (RICH) project aims to build the first database and model of the distribution and cycling of 14C at a national scale and across the atmosphere, soils, rivers and lakes of the country. The project presented here (RICH-Air) will serve to construct complementary monitoring and snapshots approaches of atmospheric 14CO2 measurement in this larger scope. For the monitoring aspect, air masses passing over Switzerland are collected and measured every two weeks at three tall tower sites situated over the populated Swiss plateau and one background site (Jungfraujoch). As for the snapshots, we focus on three industrial point sources (two cement plants, and a combined refinery-cement site) and use an Upwind-Downwind approach to have emissions and background samples at each site. As a complementary method, tree leaf samples will also be collected close to sites of interest, to have more temporally-integrated data.First results show that the seasonality has a huge influence on the monitoring of the 14CO2 signature, with a decrease in the winter months, due to limited atmospheric mixing, and accumulation of ground emissions. For the industrial hotspots, plume catching was shown to be challenging, even though an increased signal of a few ppm was generally visible.

Our current understanding of Arctic carbonaceous aerosol (CA) is rudimentary and there is a lack of long-term observations for many components, such as organic aerosol (OA), exceptions to this include equivalent black carbon (eBC) and methane sulfonic acid (MSA). To address this, we analyzed long-term measurements of organic carbon (OC), elemental carbon (EC), and source-specific organic tracers from 2017 to 2020 to constrain CA sources in the rapidly changing Arctic. We also used absorption photometer (aethalometer) measurements to constrain equivalent BC from biomass burning (eBCBB) and fossil fuel combustion (eBCFF) using Positive Matrix Factorization (PMF). Our analysis showed that organic tracers are essential to understand Arctic CA sources. For 2017 to 2020, levoglucosan had a bimodal seasonality, with a signal from residential wood combustion (RWC) in the heating season (H-season; November to May) and from wildfires (WF) in the non-heating season (NH-season; June to October), demonstrating a pronounced inter-annual variability in the WF influence. Biogenic secondary organic aerosol (BSOA) species (2-methyltetrols) from isoprene oxidation appeared only in the NH-season, peaking in July to August. Intrusions of warm air masses from Siberia in summer caused three- and ninefold increases in 2-methyltetrols compared to 2017 to 2018, in 2019 and 2020, respectively, warranting investigation of the local vs. the long-range atmospheric transport (LRT) contribution, as certain Arctic vegetation has highly temperature sensitive biogenic volatile organic compounds (BVOC) emission rates. Primary biological aerosol particles (PBAP) tracers (various sugars and sugar-alcohols) were elevated in the NH-season but evolved differently, whereas cellulose was completely decoupled from the other PBAP tracers. Peak levels of most PBAP tracers and of 2-methyltetrols were associated with WF emissions, demonstrating the importance of measuring a broad spectrum of source specific tracers to understand sources and dynamics of CA. Finally, CA seasonality is heavily influenced by long-range atmospheric transport (LRT) episodes, since background levels are extremely low. E.g., we find the OA peak in the NH-season is as strongly influenced by LRT as is EC during Arctic Haze (AH). Source apportionment of CA by Latin Hypercube Sampling (LHS) showed a mixed contribution from RWC (46 %), fossil fuel (FF) sources (27 %), and BSOA (25 %) in the H-season, whereas BSOA (56 %) prevailed over WF (26 %) and FF (15 %) in the NH-season. Source apportionment of eBC by PMF showed that FF combustion dominated eBC (70 ± 2.7 %), whereas RWC (22 ± 2.7 %) was more abundant than WF (8.0 ± 2.9 %). Modeled BC concentrations from FLEXPART attributed an almost equal share to FF (51 ± 3.1 %) and BB. Both FLEXPART and the PMF analysis concluded that RWC is a more important source than WF. However, with a modeled RWC of 30 ± 4.1 % and WF of 19 ± 2.8 %, FLEXPART suggests relatively higher contributions to eBC from these sources. We find that OA (281 ± 106 ng m−3) is a significant fraction of the Arctic PM10 aerosol particle mass, though less than sea salt aerosol (SSA) (682 ± 46.9 ng m−3) and mineral dust (MD) (613 ± 368 ng m−3) as well as typically non-sea-salt sulfate (nssSO42−) (314 ± 62.6 ng m−3), originating mainly from anthropogenic sources in winter and from natural sources in summer. FF combustion was the prevailing source of eBC, whereas RWC made a larger contribution to eBCBB than WF.

Radiocarbon (14C) analysis of carbonaceous aerosols is used for source apportionment, separating the carbon content into fossil vs. non-fossil origin, and is particularly useful when applied to subfractions of total carbon (TC), i.e. elemental carbon (EC), organic carbon (OC), water-soluble OC (WSOC), and water-insoluble OC (WINSOC). However, this requires an unbiased physical separation of these fractions, which is difficult to achieve. Separation of EC from OC using thermal–optical analysis (TOA) can cause EC loss during the OC removal step and form artificial EC from pyrolysis of OC (i.e. so-called charring), both distorting the 14C analysis of EC. Previous work has shown that water extraction reduces charring. Here, we apply a new combination of a WSOC extraction and 14C analysis method with an optimised OC/EC separation that is coupled with a novel approach of thermal-desorption modelling for compensation of EC losses. As water-soluble components promote the formation of pyrolytic carbon, water extraction was used to minimise the charring artefact of EC and the eluate subjected to chemical wet oxidation to CO2 before direct 14C analysis in a gas-accepting accelerator mass spectrometer (AMS). This approach was applied to 13 aerosol filter samples collected at the Arctic Zeppelin Observatory (Svalbard) in 2017 and 2018, covering all seasons, which bear challenges for a simplified 14C source apportionment due to their low loading and the large portion of pyrolysable species. Our approach provided a mean EC yield of 0.87±0.07 and reduced the charring to 6.5 % of the recovered EC amounts. The mean fraction modern (F14C) over all seasons was 0.85±0.17 for TC; 0.61±0.17 and 0.66±0.16 for EC before and after correction with the thermal-desorption model, respectively; and 0.81±0.20 for WSOC.

Previous research on the Neolithic cist graves of the Western Alpine region—also known under the term Chamblandes type graves—mostly focused on sites located in western Switzerland and eastern France. For the adjacent Aosta Valley (Italy), only a little information is available. Within the framework of our research project, it was possible to identify about 120 stone cist graves from 10 sites in the Aosta Valley. Due to the lack of distinctive grave goods and missing absolute dating, however, their chronological position has been unclear until now. Here we present the first extensive series of radiocarbon dates from Neolithic stone cist graves of the Aosta Valley. We analyzed 31 human bone samples from four sites, and most dates indicate an unexpected early chronological position around the first half of the 5th millennium BCE, in particular, the site of Villeneuve, dating to 4800–4550 cal BCE. This identifies these burials from the Aosta Valley as belonging to the oldest known Neolithic cist graves of the Western Alpine region discovered so far. Altogether, our study provides new evidence allowing the first time to clarify the chronology of these sites and trace the evolution of this burial practice in the Western Alps.

Radiocarbon (14C) analysis of carbonaceous aerosols is used for source apportionment, separating the carbon content into fossil vs. non-fossil origin, and is particularly useful when applied to subfractions of total carbon (TC), i.e. elemental carbon (EC), organic carbon (OC), water-soluble OC (WSOC), and water-insoluble OC (WINSOC). However, this requires an unbiased physical separation of these fractions, which is difficult to achieve. Separation of EC from OC using thermal–optical analysis (TOA) can cause EC loss during the OC removal step and form artificial EC from pyrolysis of OC (i.e. so-called charring), both distorting the 14C analysis of EC. Previous work has shown that water extraction reduces charring. Here, we apply a new combination of a WSOC extraction and 14C analysis method with an optimised OC/EC separation that is coupled with a novel approach of thermal-desorption modelling for compensation of EC losses. As water-soluble components promote the formation of pyrolytic carbon, water extraction was used to minimise the charring artefact of EC and the eluate subjected to chemical wet oxidation to CO2 before direct 14C analysis in a gas-accepting accelerator mass spectrometer (AMS). This approach was applied to 13 aerosol filter samples collected at the Arctic Zeppelin Observatory (Svalbard) in 2017 and 2018, covering all seasons, which bear challenges for a simplified 14C source apportionment due to their low loading and the large portion of pyrolysable species. Our approach provided a mean EC yield of 0.87±0.07 and reduced the charring to 6.5 % of the recovered EC amounts. The mean fraction modern (F14C) over all seasons was 0.85±0.17 for TC; 0.61±0.17 and 0.66±0.16 for EC before and after correction with the thermal-desorption model, respectively; and 0.81±0.20 for WSOC.

Carbonaceous aerosol is a dominant component of fine particles in Beijing. However, it is challenging to apportion its sources. Here, we applied a newly developed method which combined radiocarbon (14C) with organic tracers to apportion the sources of fine carbonaceous particles at an urban (IAP) and a rural (PG) site of Beijing. PM2.5 filter samples (24 h) were collected at both sites from 10 November to 11 December 2016 and from 22 May to 24 June 2017. 14C was determined in 25 aerosol samples (13 at IAP and 12 at PG) representing low pollution to haze conditions. Biomass burning tracers (levoglucosan, mannosan, and galactosan) in the samples were also determined using gas chromatography–mass spectrometry (GC-MS). Higher contributions of fossil-derived OC (OCf) were found at the urban site. The OCf / OC ratio decreased in the summer samples (IAP: 67.8 ± 4.0 % in winter and 54.2 ± 11.7 % in summer; PG: 59.3 ± 5.7 % in winter and 50.0 ± 9.0 % in summer) due to less consumption of coal in the warm season. A novel extended Gelencsér (EG) method incorporating the 14C and organic tracer data was developed to estimate the fossil and non-fossil sources of primary and secondary OC (POC and SOC). It showed that fossil-derived POC was the largest contributor to OC (35.8 ± 10.5 % and 34.1 ± 8.7 % in wintertime for IAP and PG, 28.9 ± 7.4 % and 29.1 ± 9.4 % in summer), regardless of season. SOC contributed 50.0 ± 12.3 % and 47.2 ± 15.5 % at IAP and 42.0 ± 11.7 % and 43.0 ± 13.4 % at PG in the winter and summer sampling periods, respectively, within which the fossil-derived SOC was predominant and contributed more in winter. The non-fossil fractions of SOC increased in summer due to a larger biogenic component. Concentrations of biomass burning OC (OCbb) are resolved by the extended Gelencsér method, with average contributions (to total OC) of 10.6 ± 1.7 % and 10.4 ± 1.5 % in winter at IAP and PG and 6.5 ± 5.2 % and 17.9 ± 3.5 % in summer, respectively. Correlations of water-insoluble OC (WINSOC) and water-soluble OC (WSOC) with POC and SOC showed that although WINSOC was the major contributor to POC, a non-negligible fraction of WINSOC was found in SOC for both fossil and non-fossil sources, especially during winter. In summer, a greater proportion of WSOC from non-fossil sources was found in SOC. Comparisons of the source apportionment results with those obtained from a chemical mass balance model were generally good, except for the cooking aerosol.

This study aims to critically evaluate the source apportionment of fine particles by multiple receptor modelling approaches, including carbon mass balance modelling of filter-based radiocarbon (14C) data, Chemical Mass Balance (CMB) and Positive Matrix Factorization (PMF) analysis on filter-based chemical speciation data, and PMF analysis on Aerosol Mass Spectrometer (AMS-PMF) or Aerosol Chemical Speciation Monitor (ACSM-PMF) data. These data were collected as part of the APHH-Beijing (Atmospheric Pollution and Human Health in a Chinese Megacity) field observation campaigns from 10th November to 12th December in winter 2016 and from 22nd May to 24th June in summer 2017. 14C analysis revealed the predominant contribution of fossil fuel combustion to carbonaceous aerosols in winter compared with non-fossil fuel sources, which is supported by the results from other methods. An extended Gelencs´er (EG) method incorporating 14C data, as well as the CMB and AMS/ACSM-PMF methods, generated a consistent source apportionment for fossil fuel related primary organic carbon. Coal combustion, traffic and biomass burning POC were comparable for CMB and AMS/ACSM-PMF. There are uncertainties in the EG method when estimating biomass burning and cooking OC. The POC from cooking estimated by different methods was poorly correlated, suggesting a large uncertainty when differentiating this source type. The PM2.5 source apportionment results varied between different methods. Through a comparison and correlation analysis of CMB, PMF and AMS/ACSM-PMF, the CMB method appears to give the most complete and representative source apportionment of Beijing aerosols. Based upon the CMB results, fine aerosols in Beijing were mainly secondary inorganic ion formation, secondary organic aerosol formation, primary coal combustion and from biomass burning emissions.

Lake Victoria is the largest tropical lake on the planet. Located in East Africa at an altitude of 1135 m asl, it lies across the limits between two major climatic zones with a temperature and moisture gradient and associated tropical biomes, the rain forest, and the savanna. At higher altitudes > 1200–2500 m a.s.l. temperatures are significantly lower and vegetation forms an Afromontane belt. Primarily triggered by climate shifts, these three biomes and fire regimes have been dynamically interspersing over the last 17,000 years.Here, we present a robust 14C chronology mainly based on macroscopic charcoal using the MICADAS system of LARA at the University of Bern, new palynological data used as biostratigraphic control, and the first continuous charcoal record in Lake Victoria to establish the fire history.Our pollen and macro–charcoal records, support the assumption that throughout time regional fire dynamics are controlled by biome’s changes, and that climate was the main driver of these vegetation shifts at least until the Iron Age. Our results indicate that during the Last Glacial Maxima and Heinrich Stadial 1, under dry and colder climates the savanna was dominating, with low fire regimes before 15,000 cal yr BP and increased fire occurrence between 15,000 and 14,000 cal yr BP. After this period, the Afromontane forest started to expand, and warmer and humid climates promoted the growth of rain forests and reduced fire events, which is particularly observed in the African Humid Period (between ca. 11,500 and 5000 cal yr BP). Subsequently, our records indicate a global maximum of fire occurrence at 5000 cal yr BP, followed by unexpectedly low fire regimes during the Iron Age and the subsequent periods.This work is part of a SINERGIA project funded by the Swiss National Foundation which seeks to unravel the long-term causes and consequences of Lake Victoria’s ecosystem dynamics with a special focus on the evolution of fish species and other biotas from the late Pleistocene to the present.

The response of terrestrial ecosystems to anthropogenic climate change remains poorly understood and constitutes a major source of uncertainty in future climate projections. Stalagmites are a well-established terrestrial climate archive (Wong and Breecker, 2015), and may also serve as a sensitive recorder of surface ecosystem processes, as they are fed by dripping water that percolates through the soil zone. Coupled climate-ecosystem paleorecords from stalagmites could prove invaluable sources of information on the response of terrestrial ecosystems to past climatic shifts and their sensitivity to climate variability exceeding the instrumental range.Here we present results from a method development study carried out at the Laboratory for the Analysis of Radiocarbon with AMS (LARA) at the University of Bern. Our results are based on a previous protocol by Lechleitner et al. (2019), which describes a rapid, low contamination method for carbon isotope analysis (δ13C and 14C) of the speleothem non-purgeable organic carbon (NPOC) fraction for small samples (3). Decarbonation of acid digested carbonate samples is followed by wet chemical oxidation of the NPOC and analysis of the resulting headspace CO2 via mass spectrometry to determine its isotopic composition.We have made significant progress in resolving the main issues that precluded the routine application of the method as presented in Lechleitner et al. (2019), namely incomplete removal of inorganic carbon from the sample solutions, and contamination from extraneous carbon at different method stages. Apart from an updated pre-cleaning protocol for stalagmite samples and extensive blank assessment, a new needle setup was installed, allowing reduction of the sample amount needed, and the CO2 flow is now being monitored during decarbonation to ensure complete removal of inorganic carbon prior to the oxidation step.These results reiterate the great promise of this method to provide accurate, ecosystem-level information on past terrestrial environments at comparatively high temporal resolution. References:Lechleitner, F.A., Lang, S.Q., Haghipour, N., McIntyre, C., Baldini, J.U.L., Prufer, K.M., Eglinton, T.I., 2019. Towards organic carbon isotope records from stalagmites: coupled d13C and 14C analysis using wet chemical oxidation. Radiocarbon 61, 749–764. doi:10.1017/RDC.2019.35Wong, C.I., Breecker, D.O., 2015. Advancements in the use of speleothems as climate archives. Quat. Sci. Rev. 127, 1–18. doi:10.1016/j.quascirev.2015.07.019

Terrestrial ecosystems, including soil and the biosphere, represent important reservoirs of carbon sources and cycling (IPCC, 2000). However, the reaction of terrestrial ecosystems to the changing climate remains poorly constrained. Over the past 20 years, interest in the organic matter (OM) fraction of speleothems, typically comprising 0.01-0.3% of the total carbon (Blyth et al., 2016), has increased due to its potential to offer information about past ecosystems. The sources of speleothem OM are not fully understood and are likely to be a combination of contributions from overlying vegetation, soil, microbial activity within the karst system, and cave fauna. Due to the link that the inner cave environment has with the karst, the signal of non purgeable organic carbon (NPOC) sourced from the overlying soil, vadose zone, or within the cave itself may be preserved within speleothems (Blyth et al., 2013). Hence, the isotopic characterisation (𝛿13C and 14C) of stalagmite NPOC has the potential to give information about past ecological and climactic state of the surrounding region (Blyth et al., 2013).Presented here are the first results of a high-resolution process study of organic and inorganic carbon fluxes in the Milandre cave (Switzerland), whereby the main carbon source reservoirs will be monitored for two years. The total organic carbon content of cave waters ranges from 0.6 -1.3mg/L. The 𝛿13C of CO2 in gas samples from atmospheric air (-9.24 ‰), soil air (-12.68 - -27.20‰), gas well air (-24.97- -25.78‰), and cave air (-14.29 - -25.32‰) were analysed. The soil air, well air and cave air have 𝛿13C values which range from close to atmospheric 𝛿13C to the most 𝛿13C depleted cave air end member which suggests differing levels of gas mixing throughout the system. Ultimately, this information will be used to constrain the source of speleothem NPOC and allow the assessment of its suitability as a proxy for ecosystem change. Blyth, A., Hartland, A. and Baker, A., 2016. Organic proxies in speleothems – New developments, advantages and limitations. Quaternary Science Reviews, 149, pp.1-17.Blyth, A., Smith, C., and Drysdale, R., 2013. A new perspective on the 13C signal preserved in speleothems using LC-IRMS analysis of bulk organic matter and compound specific stable isotope analysis. Quaternary Science Reviews, 75, pp. 143-149.IPCC, 2000: Land Use, Land-Use Change and Forestry. (R.Watson, I.Noble, B Bolin, N.H. Ravindranath,D.J. Verardo and D.J. Dokken (eds.)). Cambridge University Press, UK, pp.375

Anthropogenic eutrophication and spreading anoxia in freshwater systems is a global concern. Little is known about anoxia in earlier historic times under weaker human impact, or under prehistoric natural conditions with different trophic, land cover and climatic regimes. We use a novel approach that combines high‐resolution hyperspectral imaging with μ‐XRF and HPLC‐pigment data, which allows us to assess chloropigments (productivity) and bacteriopigments (anoxia) at seasonal subvarve‐scale resolution. Our ~9700 cal a BP varved sediment record from NE Poland suggests that productivity increased stepwise from oligotrophic Early Holocene conditions (until ~9200 cal a BP) to mesotrophic conditions in the Mid‐ and Late Holocene. Natural eutrophication was mainly a function of progressing landscape evolution with intense weathering under dense forest and warm‐moist climatic conditions. Generally, anoxia increased with increasing productivity. Seasonal anoxia and some multi‐decadal periods of meromixis were the common mixing patterns throughout the Holocene except for a period of persisting meromixis between ~5200 and 2000 cal a BP. Anthropogenic deforestation around 400 cal a BP resulted in substantially better lake oxygenation despite high productivity. In this small lake, aquatic productivity and lakeshore forest cover (wind shield) were more important factors controlling oxic/anoxic conditions than Holocene temperature variability.

A multiproxy workflow was used to assess >60 plant protection products (PPPs) in sediment samples from a Swiss lake under heavy agricultural pressure. The results show the appearance of PPPs for the first time in the early 1960s with an overall detection of 34 PPPs and with herbicides and fungicides found in equal proportions. Paleolimnological data [e.g., chronology, hyperspectral imaging of sedimentary green pigments, and semiquantitative elemental composition (μXRF scans)] suggest that PPP concentrations and fluxes to the sediment over time are not related to land surface processes such as soil erosion or lake biogeochemistry but are attributed mainly to PPP application (inferred from sales) or regulatory measures (bans). Additional compounds with similar sources of contamination as the target PPPs captured by nontarget trend analysis (≥2000 unknown profiles) reveal significant inputs of contaminants to the lake starting in the 1970s, followed by a decrease of contamination at the beginning of the 1990s and a constant increase by ∼28% of the unknown compounds since the year 2000. An ecological risk assessment conducted on detected PPPs indicates that since the 1980s, the sediment quality is insufficient with risk quotient values displaying maximum levels in the most recent sediments (∼2010) despite bans of specific PPPs and environmental regulations.

We present the current performance of the in situ radiocarbon (14C) extraction line at the University of Bern with an improved extraction and combustion system. After three major steps of improvement, the extraction of sample CO2gas now takes place inside a platinum crucible, supported by an outer quartz-glass crucible. This setup allows us to operate the line as a closed system for several samples without breaking the vacuum. Measurements of procedural blanks and samples from our reference strewn field, Jiddat al Harasis 073, performed in our system all show a good reproducibility and, for the strewn field samples, consistency with published data. We describe each improvement step in detail, discussing the advantages and disadvantages of all tested setups. By sharing our knowledge, we aim to inform and prevent others from making the same or similar detours in establishing14C extraction systems for extraterrestrial samples.

Compound-specific radiocarbon analysis (CSRA) was developed to identify and quantify gaseous 14C-bearing carbon compounds at the pico- to femtomolar concentration range and employed in a corrosion experiment with small specimens of irradiated steel. The approach is based on gas chromatographic separation of single 14C-bearing carbon compounds, their oxidation to 14CO2, sampling with a custom-made fraction collector and quantification by accelerator mass spectrometry (AMS). In addition to CSRA, a method allowing the quantification of the total 14C content of the gas phase was developed and tested. After validation of the two set-ups with standards, the gaseous 14C-bearing carbon compounds produced during alkaline anoxic corrosion of irradiated steel were quantified. Small hydrocarbons (HCs) like methane (14CH4) and ethane (14C2H6) were the only 14C-bearing compounds identified in the gas phase above the detection limit. 14CH4 was the main species (on average 5.4 × 10-14 mol L-1 gas) and contributed >90% to the total 14C content, whereas the concentration of 14C2H6 was much lower (7.9 × 10-16 mol L-1 gas). To our knowledge, this is the first study reporting CSRA of gaseous 14C-bearing HCs produced during anoxic corrosion of irradiated metallic radioactive waste at ultra-low concentrations.

Excavation of the Late Neolithic dolmen of Oberbipp BE, Steingasse in the Swiss Central Plateau provided a unique opportunity for a comprehensive study of the archaeological and anthropological evidence. In multidisciplinary studies, we investigated the processes at work during construction, use, and abandonment of the megalithic structure, as well as the dietary habits, subsistence strategy, and possible mobility of the Neolithic population. Archaeological methods included micromorphology, archaeobiology, typology, use-wear analysis, and geology. The anthropological investigation was complemented by an analysis of stable isotope ratios and palaeogenetics. Local topography and the cover of alluvial sediments ensured an extraordinary conservation of the monument. It allowed the preservation of the human remains of at least 42 individuals of both sexes and all ages. The observation of the sedimentary and post-depositional processes, supplemented by an extensive series of radiocarbon dates, allowed us to reconstruct the history of the dolmen in its environment and the definition of at least two deposition phases. We found genetic evidence of lactase intolerance, a local population with a mixed ancestry of early Anatolian farmers and Western hunter-gatherers, and a crop-based diet. Sparse remains of a nearby Late Neolithic settlement sustain the interpretation that this is the burial site of a local farming community. Evidence of higher mobility of females and kinship over three generations solely in the paternal line suggests a virilocal community. Bone-altering pathologies support the assumption of a caring society. 1. Introduction 1.1. Context 1.2. Discovery and excavation 1.3. Topography and geology 1.4. Aim of the study 2. Materials and methods 2.1. Archaeology 2.2. Soil micromorphology and geology 2.3. Archaeobotany and archaeozoology 2.4. Anthropology and molecular genetics 2.5. Radiocarbon dating 3. Results 3.1. Site occupation 3.2. The monument 3.3. The burials 3.4. Associated artefacts 3.5. Archaeozoology and archaeobotany 4. Discussion 4.1. Limitations of the study 4.2. Landscape history 4.3. The regional burial tradition in the late fourth millennium 4.4. Construction and use of the monument 4.5. Standing stones and further monuments 4.6. Animal activity, human disturbances, erosion, and destruction 4.7. Population and mobility 4.8. Conclusions

The repeated expansion of East Asian steppe cultures was a key driver of Eurasian history, forging new social, economic, and biological links across the continent. Climate has been suggested as important driver of these poorly understood cultural expansions, but paleo-climate records from the Mongolian Plateau often suffer from poor age control or ambiguous proxy interpretation. Here, we use a combination of geochemical analyses and comprehensive radiocarbon dating to establish the first robust and detailed record of paleo-hydrological conditions for Lake Telmen, Mongolia, covering the past ~4000 years. Our record shows that humid conditions coincided with solar minima, and hydrological modelling confirms the high sensitivity of the lake to paleo-climate changes. Careful comparisons with archaeological and historical records suggest that in the vast semi-arid grasslands of eastern Eurasia, solar minima led to reduced temperatures, less evaporation, and high biomass production, expanding the power base for pastoral economies and horse cavalry. Our findings suggest a crucial link between temperature dynamics in the Eastern Steppe and key social developments, such as the emergence of pastoral empires, and fuel concerns that global warming enhances water scarcity in the semi-arid regions of interior Eurasia. 1. Introduction 2. Results 2.1 Sediment core chronology 2.2 Sedimentological and geochemical analyses 2.3 Isotope analyses, evaporation index (EI), and paleohydrology 3. Discussion 3.1 External forcing on the regional climate 3.2 Hydrological modelling 3.3 Climate impact on human history in Mongolia Methods

The repeated expansion of East Asian steppe cultures was a key driver of Eurasian history, forging new social, economic, and biological links across the continent. Climate has been suggested as important driver of these poorly understood cultural expansions, but paleoclimate records from the Mongolian Plateau often suffer from poor age control or ambiguous proxy interpretation. Here, we use a combination of geochemical analyses and comprehensive radiocarbon dating to establish the first robust and detailed record of paleohydrological conditions for Lake Telmen, Mongolia, covering the past ~ 4000 years. Our record shows that humid conditions coincided with solar minima, and hydrological modeling confirms the high sensitivity of the lake to paleoclimate changes. Careful comparisons with archaeological and historical records suggest that in the vast semi-arid grasslands of eastern Eurasia, solar minima led to reduced temperatures, less evaporation, and high biomass production, expanding the power base for pastoral economies and horse cavalry. Our findings suggest a crucial link between temperature dynamics in the Eastern Steppe and key social developments, such as the emergence of pastoral empires, and fuel concerns that global warming enhances water scarcity in the semi-arid regions of interior Eurasia.

Understanding the sources of light-absorbing organic (brown) carbon (BrC) and its interaction with black carbon (BC) and other non-refractory particulate matter (NR-PM) fractions is important for reducing uncertainties in the aerosol direct radiative forcing. In this study, we combine multiple filter-based techniques to achieve long-term, spectrally resolved, source- and species-specific atmospheric absorption closure. We determine the mass absorption efficiency (MAE) in dilute bulk solutions at 370 nm to be equal to 1.4 m2 g−1 for fresh biomass smoke, 0.7 m2 g−1 for winter-oxygenated organic aerosol (OA), and 0.13 m2 g−1 for other less absorbing OA. We apply Mie calculations to estimate the contributions of these fractions to total aerosol absorption. While enhanced absorption in the near-UV has been traditionally attributed to primary biomass smoke, here we show that anthropogenic oxygenated OA may be equally important for BrC absorption during winter, especially at an urban background site. We demonstrate that insoluble tar balls are negligible in residential biomass burning atmospheric samples of this study and thus could attribute the totality of the NR-PM absorption at shorter wavelengths to methanol-extractable BrC. As for BC, we show that the mass absorption cross-section (MAC) of this fraction is independent of its source, while we observe evidence for a filter-based lensing effect associated with the presence of NR-PM components. We find that bare BC has a MAC of 6.3 m2 g−1 at 660 nm and an absorption Ångström exponent of 0.93 ± 0.16, while in the presence of coatings its absorption is enhanced by a factor of ∼ 1.4. Based on Mie calculations of closure between observed and predicted total light absorption, we provide an indication for a suppression of the filter-based lensing effect by BrC. The total absorption reduction remains modest, ∼ 10 %–20 % at 370 nm, and is restricted to shorter wavelengths, where BrC absorption is significant. Overall, our results allow an assessment of the relative importance of the different aerosol fractions to the total absorption for aerosols from a wide range of sources and atmospheric ages. When integrated with the solar spectrum at 300–900 nm, bare BC is found to contribute around two-thirds of the solar radiation absorption by total carbonaceous aerosols, amplified by the filter-based lensing effect (with an interquartile range, IQR, of 8 %–27 %), while the IQR of the contributions by particulate BrC is 6 %–13 % (13 %–20 % at the rural site during winter). Future studies that will directly benefit from these results include (a) optical modelling aiming at understanding the absorption profiles of a complex aerosol composed of BrC, BC and lensing-inducing coatings; (b) source apportionment aiming at understanding the sources of BC and BrC from the aerosol absorption profiles; (c) global modelling aiming at quantifying the most important aerosol absorbers., Atmospheric Chemistry and Physics, 21 (17), ISSN:1680-7375, ISSN:1680-7367

Funder: Tromsø Research Foundation : A31720, The Fram Strait is the only deep gateway between the Arctic Ocean and the Nordic Seas and thus is a key area to study past changes in ocean circulation and the marine carbon cycle. Here, we study deep ocean temperature, δ18O, carbonate chemistry (i.e., carbonate ion concentration [CO32−]), and nutrient content in the Fram Strait during the late glacial (35,000–19,000 years BP) and the Holocene based on benthic foraminiferal geochemistry and carbon cycle modeling. Our results indicate a thickening of Atlantic water penetrating into the northern Nordic Seas, forming a subsurface Atlantic intermediate water layer reaching to at least ∼2,600 m water depth during most of the late glacial period. The recirculating Atlantic layer was characterized by relatively high [CO32−] and low δ13C during the late glacial, and provides evidence for a Nordic Seas source to the glacial North Atlantic intermediate water flowing at 2,000–3,000 m water depth, most likely via the Denmark Strait. In addition, we discuss evidence for enhanced terrestrial carbon input to the Nordic Seas at ∼23.5 ka. Comparing our δ13C and qualitative [CO32−] records with results of carbon cycle box modeling suggests that the total terrestrial CO2 release during this carbon input event was low, slow, or directly to the atmosphere.

National parks are supposed to protect large-scale ecological processes, along with species and ecosystems. Detailed knowledge about past vegetation and disturbance regimes therefore forms an important basis for appropriate management. In the Bavarian Forest National Park in SE Germany, we therefore studied fossil pollen, spores and macrofossils from lake Rachelsee, a nearby mire, and Stangenfilz mire, all lying at higher elevations. Results indicate that deciduous forest on lower slopes (ca. 500–1,000 m a.s.l.) were first affected by humans in Neolithic times ca. 4500 bc with marked declines of Tilia, Ulmus and Fraxinus. High-montane mixed forests (1,000–1,450 m a.s.l.) were in a near-natural state consisting of Picea, Abies and Fagus in comparable proportions up to ca. 500 bc (a natural baseline condition), after which they were impacted by forest grazing and/or logging, starting between early-Roman times to early-Medieval times depending on location. Abies especially declined markedly. Forest partially recovered during the migration period fifth-eighth century ad, especially Carpinus, but not Abies. Subsequently, deforestation increased at lower elevation for food production, and forest grazing and wood extraction at higher elevation led to a further strong decline of Abies around ad 1000 near Rachelsee. After that, nutrient levels increased continually at all elevations, and a forest fire occurred in the 13th century near Stangenfilz. During the 19th century, forests around Rachelsee recovered partially whereas overgrazing of Stangenfilz resulted in a hiatus. Forests declined further in the 20th century around the study sites, but after ca. ad 1960 less so around Rachelsee thanks to local conservation measures. Historically recorded large-scale bark-beetle infestations following heavy storms, such as in the ad 1870s and 1980s, hardly left traces in the pollen data. From a palaeoecological perspective the Park’s no-intervention management strategy is well-suited to facilitate recovery of original forest functioning and diversity, as it is slowly leading to renewal of natural mixed forest of Abies, Picea and Fagus. This development may have considerable influence on the future disturbance regime, and the insights obtained will be important for the park management.

This study provides new data on the evolution of the landscape in south-western Amazonia during the Holocene and the impact of climate change and fluvial dynamics on the region's ecosystems. South-western Amazonia is covered by an extensive seasonally flooded savannah, known as the Llanos de Moxos. Severe drought during the southern hemisphere winter, followed by months of permanent waterlogging, means that forests only grow on the most elevated parts of the landscape, mostly river and paleoriver levees and crevasse splays. Paleoclimate reconstructions from surrounding areas show that a shift to wetter conditions at around 4 kyr BP caused an increase in forest cover. However, the impact that this change in climate had on the landscape of the Llanos de Moxos is unknown. Published lacustrine archives from the area only cover the last 2 kyr. Here we present new data from the analysis of paleosols located along a 300 km transect across the central Llanos. The analyses of stable carbon isotopes, from 36 paleosols, and biogenic silica, from 29 paleosols, show that the patchwork of forests and savannahs that we see today was established after the 4 kyr BP climate change. During the dry period between 8 and 4 kyr BP, most of the central Llanos de Moxos, nowadays covered with seasonally flooded savannah, were covered by Cerrado-like savannah in the west and by forest in the east. However, results also suggest that, at both regional and local scales, vegetation cover has been influenced by changes in topography resulting from the region's river dynamics.

The Lessepsian invasion – the largest marine biological invasion – followed the opening of the Suez Canal in 1869 (81 years BP). Shortly afterwards, tropical species also distributed in the Red Sea appeared on Mediterranean shores: it was the dawn of what would become the invasion of several hundred tropical species. The time of the Suez Canal opening coincided with an acceleration in natural history exploration and description, but the eastern sectors of the Mediterranean Sea lagged behind and were thoroughly explored only in the second half of the 20th century. Many parts are still insufficiently studied today. Baseline information on pre-Lessepsian ecosystem states is thus scarce. This knowledge gap has rarely been considered by invasion scientists: every new finding of species belonging to tropical clades has been assumed to be a Lessepsian invader.We here question this assumption by radiocarbon dating seven individual tests of miliolids – imperforated calcareous foraminifera – belonging to five alleged non-indigenous species. Tests were found in two sediment cores collected at 30 and 40 m depth off Ashqelon, on the Mediterranean Israeli shelf. We dated one Cribromiliolinella milletti (core at 40 m, 20 cm sediment depth), three Nodophthalmidium antillarum (core at 40 m, 35 cm sediment depth), one Miliolinella cf. fichteliana (core at 30 m, 110 cm sediment depth), one Articulina alticostata (core at 40 m, 35 cm sediment depth) and one Spiroloculina antillarum (core at 30 m, 110 cm sediment depth). All foraminiferal tests proved to be of Holocene age, with a median calibrated age spanning between 749 and 8285 years BP. Only one test of N. antillarum showed a 2-sigma error overlapping the time of the opening of the Suez Canal, but with a median age of 1123 years BP. Additionally, a thorough literature search resulted in a further record of S. antillarum in a core interval dated 1820–2064 years BP in Turkey.Therefore, these foraminiferal species are not introduced, but native species. They are all circumtropical or Indo-Pacific and in the Mediterranean distributed mostly in the eastern sectors (only S. antillarum occurs also in the Adriatic Sea). Two hypotheses can explain our results: these species are Tethyan relicts that survived the Messinian salinity crisis (5.97–5.33 Ma) and the glacial periods of the Pleistocene in the Eastern Mediterranean, which may have never desiccated completely during the Messinian crisis and which may have worked as a warm-water refugium in the Pleistocene; or they entered the Mediterranean Sea from the Red Sea more recently but before the opening of the Suez Canal, for example during the Last Interglacial (MIS5e) high-stand (125,000 years BP) when the flooded Isthmus of Suez enabled exchanges between the Mediterranean and the Indo-Pacific fauna. The recognition that some alleged Lessepsian invaders are in fact native species influences our understanding of the invasion process, its rates and environmental correlates.

The advance and retreat of the Greenland, Innuitian and Laurentide ice sheets (GIS, IIS, LIS) which surrounded Baffin Bay (West of Greenland) have been studied using numerous methods to gain insight into past ice sheet and ice stream dynamics. However, the exact timings, movements and relationships to climate events are still somewhat debated. Utilising osmium isotopes (187Os/188Os) as part of a multi-proxy strategy coupled with absolute age models, an enhanced understanding of the palaeoceanography and palaeoglaciology of this region for last ~40 kyrs is presented. Carbonate-enriched layers recorded in many cores across Baffin Bay (Baffin Bay detrital carbonate - BBDC) are thought to be sourced from Palaeozoic carbonate rich rocks in the north/north-west of the bay which were covered by the IIS and LIS. Age modelling indicates that core JR175 records BBDC 0 and BBDC 1. Coincident with the BBDC events, hydrogenous 187Os/188Os compositions abruptly become more radiogenic. This suggests that alongside the carbonate delivery from the north of the bay, there is also a radiogenic Os source. Radiogenic Os derives from typically older, continental inputs, such as the Archean/Proterozoic terrains of western Greenland and Baffin Island. The seemingly sudden nature (within 1000 years) of the increase in 187Os/188Os would suggest a catastrophic ice sheet break-up and a period of increased iceberg discharge, or a sudden advance of the glacier outlets closer to the core site from the GIS and/or LIS.These events are also coincident with the Younger Dryas (~12.8 ka BP) and the end of the Oldest Dryas/ beginning of the Bølling–Allerød interstadial (~14.7 ka BP). During periods of low carbonate enrichment, the 187Os/188Os values are less radiogenic. We invoke this to be a baseline during lower continental erosion periods and/or iceberg delivery, and more influence of oceanic Os from the Atlantic. Indeed, during the last 10 kyrs, 187Os/188Os values gradually decrease to compositions similar to the present day North Atlantic Ocean (~1.0). This could represent increased mixing of marine Atlantic waters into Baffin Bay and/or a decrease in sediment delivery from all ice sheets representing the gradual retreat of the ice sheets through the Holocene. In summary our data provide further insight into ice sheet advance, retreat, and sediment provenance within Baffin Bay during the past 40 kyrs, suggesting asynchronous behaviour of the surrounding ice sheets during theYounger Dryas and the end of the Oldest Dryas/ beginning of the Bølling–Allerød interstadial.

Drainage for agriculture has turned peatlands from a net sink to a net source of carbon (C). In order to reduce the environmental footprint of agricultural peatland drainage, and to counteract soil subsidence, mineral soil coverage is becoming an increasingly used practice in Switzerland. To explore the effect of mineral soil coverage on soil C loss and the source of CO2 from peatland drained for agriculture, we utilized the radiocarbon signature (F14C) of soil C and emitted CO2 in the field. The experiment, located in the Swiss Rhine Valley, was carried out on two adjacent drained organic soils, either without mineral soil cover (reference 'Ref'), or covered with mineral soil (thickness ~ 40 cm) (coverage 'Cov') 13 years ago. Drainage already commenced 130 years ago and the site was managed as meadow since the 1970ies. Drainage induced 41-75 kg C m-2 loss, which is equivalent to annual C loss rates of 0.49-0.58 kg C m-2 yr-1 and 0.31-0.63 kg C m-2 yr-1 for Cov and Ref, respectively. Mineral soil coverage had no significant effect on the amount of heterotrophic respiration, however, at Cov, the radiocarbon signature of heterotrophic CO2 was significantly (p

The archaeological site of Sovjan is situated on the edge of the Korce Basin, southeastern Albania. Its remarkably long and well investigated stratigraphic sequence, spanning from the Neolithic till the Iron Age, makes it an important type- and reference-site for the whole region. At different periods of prehistory it was located on the shores of the former Lake Maliq that once filled the Korce Basin, but was definitely drained in the 1940′s. These permanent wetland conditions on the site allowed for a high degree of preservation of organic material, especially wood. Based on the current knowledge, level 8 of Sovjan contains the best-preserved wooden material of all the Early Bronze Age sites in the Balkans. Through the combination of dendrochronology and Bayesian modelling, i.e. wiggle-matching, a floating 269-years long tree-ring chronology was constructed, with an absolute end-date range falling between 2158 and 2142 cal BC (2σ). It was possible to establish that the dwellings and the trackway associated with the last occupation phase of level 8 are contemporaneous. Additionally, with the help of the new dendrochronological data and based on previously published charcoal dates, the absolute chronology of the subsequent level 7 is being narrowed-down to a range from the mid-22nd to mid-20th c. cal BC (2σ). The Early Bronze Age layers of the archaeological site of Sovjan, which are particularly pertinent for the 3rd millennium chronology of the southwestern Balkans, can now be dated with high precision for the first time and hence offer a major chronological reference point in the region.

Specialized and systematic underwater fieldwork at the prehistoric site of Ploča Mičov Grad at Gradište (North Macedonia) on the eastern shore of Lake Ohrid was undertaken in 2018 and 2019. It has substantiated the archeological site's outstanding preservation condition, and furthermore proven the numerous construction timbers’ suitability for dendrochronological analysis. Dendrochronological analysis on archaeological timbers was applied, combined with radiocarbon dating. Bayesian radiocarbon modeling allowed to ‘wiggle match’ the dendrochronological mean curves, i.e. allowed the precise chronological anchoring of ‘floating’ tree-ring sequences. Furthermore, radiocarbon dates of plant remains from the site's main archaeological layer are statistically evaluated. Based on the new findings, the strikingly high density of wooden piles at the site can be attributed to several construction phases of Neolithic (middle of 5th millennium BC) and Bronze Age (2nd millennium BC: 1800, 1400 and 1300 BCE) settlements. Intense settlement activity is furthermore evidenced by a cultural layer of mainly organic material under the lakebed up to 1.7 m in thickness, which accumulated during the Neolithic occupation of the bay in the middle of the 5th millennium BC. The presented research enables precise absolute dating of a series of settlement phases at Ploča Mičov Grad from the Neolithic and the Bronze Age, and hence provides important reference points for an absolute chronological framework for the prehistory of the southwestern Balkans. The investigations underline the potential of future research on waterlogged prehistoric settlements in the region., Journal of Archaeological Science: Reports, 38