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Seaweeds are well known to concentrate metals from seawater and have been employed as monitors of metal pollution in coastal waters and estuaries. However, research showing that various intrinsic and extrinsic factors can influence metal accumulation, raises doubts about the basis for using seaweeds in biomonitoring programmes. The thallus of brown seaweeds of the order Laminariales (kelps) is morphologically complex but there is limited information about the variation in metal accumulation between the different parts, which might result in erroneous conclusions being drawn if not accounted for in the biomonitoring protocol. To assess patterns of individual metals in the differentiated parts of the thallus (blade, stipe, holdfast), concentrations of a wide range of essential and non-essential metals (Fe, Cr, Cu, Zn, Mn, Pb, Cd, Ni and Al) were measured in the kelp Lessonia trabeculata. Seaweeds were collected from three sampling stations located at 5, 30 and 60 m from an illegal sewage outfall close to Ventanas, Chile and from a pristine location at Faro Curaumilla. For the majority of metals the highest concentrations in bottom sediment and seaweed samples were found at the site closest to the outfall, with concentrations decreasing with distance from the outfall and at control stations; the exception was Cd, concentrations of which were higher at control stations. The patterns of metal concentrations in different thallus parts were metal specific and independent of sampling station. These results and the available literature suggest that biomonitoring of metals using seaweeds must take account of differences in the accumulation of metals in thallus parts of complex seaweeds, Comment: Research article

We study the connection between the X-ray and UV properties of the broad absorption line (BAL) wind in the highly X-ray variable quasar PG 2112+059 by comparing Chandra-ACIS data with contemporaneous UV HST/STIS spectra in three different epochs. We observe a correlation whereby an increase in the equivalent-widths (EWs) of the BALs is accompanied by a redder UV spectrum. The growth in the BALs EWs is also accompanied by a significant dimming in soft X-ray emission (<2 keV), consistent with increased absorption. Variations in the hard X-ray emission (>2 keV) are only accompanied by minor spectral variations of the UV-BALs and do not show significant changes in the EW of BALs. These trends suggest a wind-shield scenario where the outflow inclination with respect to the line of sight is decreasing and/or the wind mass is increasing. These changes elevate the covering fraction and/or column densities of the BALs and are likely accompanied by a nearly contemporaneous increase in the column density of the shield., Comment: 15 pages, 9 figures, accepted in MNRAS

We present the results and the source catalog of the NuSTAR survey in the UKIDSS Ultra Deep Survey (UDS) field, bridging the gap in depth and area between NuSTAR's ECDFS and COSMOS surveys. The survey covers a $\sim 0.6$ deg$^2$ area of the field for a total observing time of $\sim$ 1.75 Ms, to a half-area depth of $\sim$ 155 ks corrected for vignetting at $3-24$ keV, and reaching sensitivity limits at half-area in the full ($3-24$ keV), soft ($3-8$ keV) and hard ($8-24$ keV) bands of $2.2 \times 10^{-14}$ erg cm$^{-2}$ s$^{-1}$, $1.0 \times 10^{-14}$ erg cm$^{-2}$ s$^{-1}$, and $2.7 \times 10^{-14}$ erg cm$^{-2}$ s$^{-1}$, respectively. A total of 67 sources are detected in at least one of the three bands, 56 of which have a robust optical redshift with a median of $\langle z\rangle \sim 1.1$. Through a broadband ($0.5-24$ keV) spectral analysis of the whole sample combined with the NuSTAR hardness ratios, we compute the observed Compton-thick (CT; $N_{\rm H} > 10^{24}$ cm$^{-2}$) fraction. Taking into account the uncertainties on each $N_{\rm H}$ measurement, the final number of CT sources is $6.8\pm1.2$. This corresponds to an observed CT fraction of $(11.5\pm2.0)\%$, providing a robust lower limit to the intrinsic fraction of CT AGN and placing constraints on cosmic X-ray background synthesis models., Comment: 23 pages, accepted for publication in The Astrophysical Journal Supplement Series

We present a study of the average X-ray spectral properties of the sources detected by the NuSTAR extragalactic survey, comprising observations of the E-CDFS, EGS and COSMOS fields. The sample includes 182 NuSTAR sources (64 detected at 8-24 keV), with 3-24 keV fluxes ranging between $f_{\rm 3-24 keV}\approx10^{-14}$ and $6\times10^{-13}$ erg/cm$^2$/s ($f_{\rm 8-24 keV}\approx3\times10^{-14}-3\times10^{-13}$ erg/cm$^2$/s) and redshifts of $z=0.04-3.21$. We produce composite spectra from the Chandra+NuSTAR data ($E\approx2-40$ keV, rest frame) for all the sources with redshift identifications (95%) and investigate the intrinsic, average spectra of the sources, divided into broad-line (BL) and narrow-line (NL) AGN, and also in different bins of X-ray column density and luminosity. The average power-law photon index for the whole sample is $\Gamma=1.65_{-0.03}^{+0.03}$, flatter than $\Gamma\approx1.8$ typically found for AGN. While the spectral slope of BL and X-ray unabsorbed AGN is consistent with typical values ($\Gamma=1.79_{-0.01}^{+0.01}$), a significant flattening is seen in NL AGN and heavily-absorbed sources ($\Gamma=1.60_{-0.05}^{+0.08}$ and $\Gamma=1.38_{-0.12}^{+0.12}$, respectively), likely due to the effect of absorption and to the contribution from Compton reflection to the high-energy flux (E>10 keV). We find that the typical reflection fraction in our spectra is $R\approx0.5$ (for $\Gamma=1.8$), with a tentative indication of an increase of the reflection strength with column density. While there is no significant evidence for a dependence of the photon index with X-ray luminosity in our sample, we find that $R$ decreases with luminosity, with relatively high levels of reflection ($R\approx1.2$) for $L_{\rm 10-40 keV}<10^{44}$ erg/s and $R\approx0.3$ for $L_{\rm 10-40 keV}>10^{44}$ erg/s AGN, assuming $\Gamma=1.8$., Comment: 19 pages, 14 figures, 4 tables. Accepted for publication in ApJ

We identify sources with extremely hard X-ray spectra (i.e., with photon indices of Gamma<0.6 in the 13 sq. deg. NuSTAR serendipitous survey, to search for the most highly obscured AGNs detected at >10 keV. Eight extreme NuSTAR sources are identified, and we use the NuSTAR data in combination with lower energy X-ray observations (from Chandra, Swift XRT, and XMM-Newton) to characterize the broad-band (0.5-24 keV) X-ray spectra. We find that all of the extreme sources are highly obscured AGNs, including three robust Compton-thick (CT; N_H > 1.5e24 cm^-2) AGNs at low redshift (z<0.1), and a likely-CT AGN at higher redshift (z=0.16). Most of the extreme sources would not have been identified as highly obscured based on the low energy (<10 keV) X-ray coverage alone. The multiwavelength properties (e.g., optical spectra and X-ray/MIR luminosity ratios) provide further support for the eight sources being significantly obscured. Correcting for absorption, the intrinsic rest-frame 10-40 keV luminosities of the extreme sources cover a broad range, from ~ 5 x 10^42 to 10^45 erg s^-1. The estimated number counts of CT AGNs in the NuSTAR serendipitous survey are in broad agreement with model expectations based on previous X-ray surveys, except for the lowest redshifts (z<0.07) where we measure a high CT fraction of f_CT^obs = 30 (+16 -12) %. For the small sample of CT AGNs, we find a high fraction of galaxy major mergers (50 +/- 33%) compared to control samples of "normal" AGNs., Comment: 19 pages, 15 figures, 5 tables; Accepted for publication in ApJ; Author list updated

We present an axially symmetric formula to calculate the probability of finding gravitational arcs in galaxy clusters, being induced by their massive dark matter haloes, as a function of clusters redshifts and virial masses. The formula includes the ellipticity of the clusters dark matter potential by using a pseudo-elliptical approximation. The probabilities are calculated and compared for two dark-matter halo profiles, the Navarro, Frenk and White (NFW) and the Non-Singular-Isothermal-Sphere (NSIS). We demonstrate the power of our formulation through a Kolmogorov-Smirnov (KS) test on the strong lensing statistics of an X-ray bright sample of low redshift Abell clusters. This KS test allows to establish limits on the values of the concentration parameter for the NFW profile ($c_\Delta$) and the core radius for the NSIS profile (\rc), which are related to the lowest cluster redshift ($z_{\rm cut}$) where strong arcs can be observed. For NFW dark matter profiles, we infer cluster haloes with concentrations that are consistent to those predicted by $\Lambda$CDM simulations. As for NSIS dark matter profiles, we find only upper limits for the clusters core radii and thus do not rule out a purely SIS model. For alternative mass profiles, our formulation provides constraints through $z_{\rm cut}$ on the parameters that control the concentration of mass in the inner region of the clusters haloes. We find that $z_{\rm cut}$ is expected to lie in the 0.0--0.2 redshift, highlighting the need to include very low-$z$ clusters in samples to study the clusters mass profiles., Comment: 15 pages, 14 figures, MNRAS accepted

PG1247+267 is one of the most luminous known quasars at $z\sim2$ and is a strongly super-Eddington accreting SMBH candidate. We obtained NuSTAR data of this intriguing source in December 2014 with the aim of studying its high-energy emission, leveraging the broad band covered by the new NuSTAR and the archival XMM-Newton data. Several measurements are in agreement with the super-Eddington scenario for PG1247+267: the soft power law ($\Gamma=2.3\pm0.1$); the weak ionized Fe emission line and a hint of the presence of outflowing ionized gas surrounding the SMBH. The presence of an extreme reflection component is instead at odds with the high accretion rate proposed for this quasar. This can be explained with three different scenarios; all of them are in good agreement with the existing data, but imply very different conclusions: i) a variable primary power law observed in a low state, superimposed on a reflection component echoing a past, higher flux state; ii) a power law continuum obscured by an ionized, Compton thick, partial covering absorber; and iii) a relativistic disk reflector in a lamp-post geometry, with low coronal height and high BH spin. The first model is able to explain the high reflection component in terms of variability. The second does not require any reflection to reproduce the hard emission, while a rather low high-energy cutoff of $\sim100$ keV is detected for the first time in such a high redshift source. The third model require a face-on geometry, which may affect the SMBH mass and Eddington ratio measurements. Deeper X-ray broad-band data are required in order to distinguish between these possibilities., Comment: 12 pages, 10 figure. Accepted for publication in A&A

To provide the census of the sources contributing to the X-ray background peak above 10 keV, NuSTAR is performing extragalactic surveys using a three-tier "wedding cake" approach. We present the NuSTAR survey of the COSMOS field, the medium sensitivity and medium area tier, covering 1.7 deg2 and overlapping with both Chandra and XMM-Newton data. This survey consists of 121 observations for a total exposure of ~3 Ms. To fully exploit these data, we developed a new detection strategy, carefully tested through extensive simulations. The survey sensitivity at 20% completeness is 5.9, 2.9 and 6.4 x 10^-14 erg/cm2/s in the 3-24 keV, 3-8 keV and 8-24 keV bands, respectively. By combining detections in 3 bands, we have a sample of 91 NuSTAR sources with 10^42 -10^45.5 erg/s luminosities and redshift z=0.04-2.5. Thirty two sources are detected in the 8-24 keV band with fluxes ~100 times fainter than sources detected by Swift-BAT. Of the 91 detections, all but four are associated with a Chandra and/or XMM-Newton point-like counterpart. One source is associated with an extended lower energy X-ray source. We present the X-ray (hardness ratio and luminosity) and optical-to-X-ray properties. The observed fraction of candidate Compton-thick AGN measured from the hardness ratio is between 13-20%. We discuss the spectral properties of NuSTAR J100259+0220.6 (ID 330) at z=0.044, with the highest hardness ratio in the entire sample. The measured column density exceeds 10^24 /cm2, implying the source is Compton-thick. This source was not previously recognized as such without the >10 keV data., Comment: 20 pages, published in the Astrophysical Journal

We present initial results and the source catalog from the NuSTAR survey of the Extended Chandra Deep Field South (hereafter, ECDFS) - currently the deepest contiguous component of the NuSTAR extragalactic survey program. The survey covers the full ~30 arcmin x 30 arcmin area of this field to a maximum depth of ~360 ks (~220 ks when corrected for vignetting at 3-24 keV), reaching sensitivity limits of ~1.3 x 10^-14 erg/cm2/s (3-8 keV), ~3.4 x 10^-14 erg/cm2/s (8-24 keV) and ~3.0 x 10^-14 erg/cm2/s (3-24 keV). Fifty four (54) sources are detected over the full field, although five of these are found to lie below our significance threshold once contaminating flux from neighboring (i.e., blended) sources is taken into account. Of the remaining 49 that are significant, 19 are detected in the 8-24 keV band. The 8-24 keV to 3-8 keV band ratios of the twelve sources that are detected in both bands span the range 0.39-1.7, corresponding to a photon index range of Gamma ~ 0.5-2.3, with a median photon index of 1.70 +/- 0.52. The redshifts of the 49 sources in our main sample span the range z = 0.21-2.7, and their rest-frame 10-40 keV luminosities (derived from the observed 8-24 keV fluxes) span the range L(10-40 keV) ~ (0.7-300) x 10^43 erg/s, sampling below the "knee" of the X-ray luminosity function out to z ~ 0.8-1. Finally, we identify one NuSTAR source that has neither a Chandra nor an XMM-Newton counterpart, but that shows evidence of nuclear activity at infrared wavelengths, and thus may represent a genuine, new X-ray source detected by NuSTAR in the ECDFS., Comment: 20 pages, published in the Astrophysical Journal

We present the first direct measurements of the rest-frame 10-40 keV X-ray luminosity function (XLF) of Active Galactic Nuclei (AGNs) based on a sample of 94 sources at 0.1 < z <3, selected at 8-24 keV energies from sources in the NuSTAR extragalactic survey program. Our results are consistent with the strong evolution of the AGN population seen in prior, lower-energy studies of the XLF. However, different models of the intrinsic distribution of absorption, which are used to correct for selection biases, give significantly different predictions for the total number of sources in our sample, leading to small, systematic differences in our binned estimates of the XLF. Adopting a model with a lower intrinsic fraction of Compton-thick sources and a larger population of sources with column densities N_H ~ 10^{23-24} /cm2 or a model with stronger Compton reflection component (with a relative normalization of R ~ 2 at all luminosities) can bring extrapolations of the XLF from 2-10 keV into agreement with our NuSTAR sample. Ultimately, X-ray spectral analysis of the NuSTAR sources is required to break this degeneracy between the distribution of absorbing column densities and the strength of the Compton reflection component and thus refine our measurements of the XLF. Furthermore, the models that successfully describe the high-redshift population seen by NuSTAR tend to over-predict previous, high-energy measurements of the local XLF, indicating that there is evolution of the AGN population that is not fully captured by the current models., Comment: 14 pages, accepted for publication in the Astrophysical Journal

We present VLT VIMOS, Keck DEIMOS and Keck LRIS multi-object spectra of 367 sources in the field of the z ~ 3.09 protocluster SSA22. Sources are spectroscopically classified via template matching, allowing new identifications for 206 extragalactic sources, including 36 z > 2 Lyman-break galaxies (LBGs) and Lyman-\alpha\ emitters (LAEs), 8 protocluster members, and 94 X-ray sources from the ~ 400 ks Chandra deep survey of SSA22. Additionally, in the area covered by our study, we have increased by ~ 4, 13, and 6 times the number of reliable redshifts of sources at 1.0 < z < 2.0, at z > 3.4, and with X-Ray emission, respectively. We compare our results with past spectroscopic surveys of SSA22 to investigate the completeness of the LBGs and the X-Ray properties of the new spectroscopically-classified sources in the SSA22 field., Comment: 27 pages, 14 figures, 6 tables. Paper has been accepted for publication in MNRAS

We report NuSTAR observations of a sample of six X-ray weak broad absorption line (BAL) quasars. These targets, at z=0.148-1.223, are among the optically brightest and most luminous BAL quasars known at z<1.3. However, their rest-frame 2 keV luminosities are 14 to >330 times weaker than expected for typical quasars. Our results from a pilot NuSTAR study of two low-redshift BAL quasars, a Chandra stacking analysis of a sample of high-redshift BAL quasars, and a NuSTAR spectral analysis of the local BAL quasar Mrk 231 have already suggested the existence of intrinsically X-ray weak BAL quasars, i.e., quasars not emitting X-rays at the level expected from their optical/UV emission. The aim of the current program is to extend the search for such extraordinary objects. Three of the six new targets are weakly detected by NuSTAR with <45 counts in the 3-24 keV band, and the other three are not detected. The hard X-ray (8-24 keV) weakness observed by NuSTAR requires Compton-thick absorption if these objects have nominal underlying X-ray emission. However, a soft stacked effective photon index ({\Gamma}~1.8) for this sample disfavors Compton-thick absorption in general. The uniform hard X-ray weakness observed by NuSTAR for this and the pilot samples selected with <10 keV weakness also suggests that the X-ray weakness is intrinsic in at least some of the targets. We conclude that the NuSTAR observations have likely discovered a significant population (>33%) of intrinsically X-ray weak objects among the BAL quasars with significantly weak <10 keV emission. We suggest that intrinsically X-ray weak quasars might be preferentially observed as BAL quasars., Comment: 11 pages, 4 figures. ApJ in press

The Circinus galaxy is one of the nearest obscured AGN, making it an ideal target for detailed study. Combining archival Chandra and XMM-Newton data with new NuSTAR observations, we model the 2-79 keV spectrum to constrain the primary AGN continuum and to derive physical parameters for the obscuring material. Chandra's high angular resolution allows a separation of nuclear and off-nuclear galactic emission. In the off-nuclear diffuse emission we find signatures of strong cold reflection, including high equivalent-width neutral Fe lines. This Compton-scattered off-nuclear emission amounts to 18% of the nuclear flux in the Fe line region, but becomes comparable to the nuclear emission above 30 keV. The new analysis no longer supports a prominent transmitted AGN component in the observed band. We find that the nuclear spectrum is consistent with Compton-scattering by an optically-thick torus, where the intrinsic spectrum is a powerlaw of photon index $\Gamma = 2.2-2.4$, the torus has an equatorial column density of $N_{\rm H} = (6-10)\times10^{24}$cm$^{-2}$ and the intrinsic AGN $2-10$ keV luminosity is $(2.3-5.1)\times 10^{42}$ erg/s. These values place Circinus along the same relations as unobscured AGN in accretion rate-vs-$\Gamma$ and $L_X$-vs-$L_{IR}$ phase space. NuSTAR's high sensitivity and low background allow us to study the short time-scale variability of Circinus at X-ray energies above 10 keV for the first time. The lack of detected variability favors a Compton-thick absorber, in line with the the spectral fitting results., Comment: Accepted for publication in ApJ

We present high-energy (3--30 keV) {\it NuSTAR} observations of the nearest quasar, the ultraluminous infrared galaxy (ULIRG) Markarian 231 (Mrk 231), supplemented with new and simultaneous low-energy (0.5--8 keV) data from {\it Chandra}. The source was detected, though at much fainter levels than previously reported, likely due to contamination in the large apertures of previous non-focusing hard X-ray telescopes. The full band (0.5--30 keV) X-ray spectrum suggests the active galactic nucleus (AGN) in Mrk 231 is absorbed by a patchy and Compton-thin (N$_{\rm H} \sim1.2^{+0.3}_{-0.3}\times10^{23}$ cm$^{-2}$) column. The intrinsic X-ray luminosity (L$_{\rm 0.5-30 keV}\sim1.0\times10^{43}$ erg s$^{1}$) is extremely weak relative to the bolometric luminosity where the 2--10 keV to bolometric luminosity ratio is $\sim$0.03% compared to the typical values of 2--15%. Additionally, Mrk 231 has a low X-ray-to-optical power law slope ($\alpha_{\rm OX}\sim-1.7$). It is a local example of a low-ionization broad absorption line (LoBAL) quasar that is intrinsically X-ray weak. The weak ionizing continuum may explain the lack of mid-infrared [O IV], [Ne V], and [Ne VI] fine-structure emission lines which are present in sources with otherwise similar AGN properties. We argue that the intrinsic X-ray weakness may be a result of the super-Eddington accretion occurring in the nucleus of this ULIRG, and may also be naturally related to the powerful wind event seen in Mrk 231, a merger remnant escaping from its dusty cocoon., Comment: 15 pages in ApJ style including 6 figures and 1 table. Accepted for publication in ApJ

We report on the first ten identifications of sources serendipitously detected by the NuSTAR to provide the first sensitive census of the cosmic X-ray background (CXB) source population at >10 keV. We find that these NuSTAR-detected sources are ~100x fainter than those previously detected at >10 keV and have a broad range in redshift and luminosity (z=0.020-2.923 and L_10-40 keV~4x10^{41}-5x10^{45} erg/s); the median redshift and luminosity are z~0.7 and L_10-40 keV~3x10^{44} erg/s, respectively. We characterize these sources on the basis of broad-band ~0.5-32 keV spectroscopy, optical spectroscopy, and broad-band ultraviolet-to-mid-infrared SED analyzes. We find that the dominant source population is quasars with L_10-40 keV>10^{44} erg/s, of which ~50% are obscured with N_H>10^{22} cm^{-2}. However, none of the ten NuSTAR sources are Compton thick (N_H>10^{24} cm^{-2}) and we place a 90% confidence upper limit on the fraction of Compton-thick quasars (L_10-40 keV>10^{44} erg/s) selected at >10 keV of ~33% over the redshift range z=0.5-1.1. We jointly fitted the rest-frame ~10-40 keV data for all of the non-beamed sources with L_10-40 keV>10^{43} erg/s to constrain the average strength of reflection; we find R<1.4 for \Gamma=1.8, broadly consistent with that found for local AGNs observed at >10 keV. We also constrain the host galaxy masses and find a median stellar mass of ~10^{11} M_sun, a factor ~5 times higher than the median stellar mass of nearby high-energy selected AGNs, which may be at least partially driven by the order of magnitude higher X-ray luminosities of the NuSTAR sources. Within the low source-statistic limitations of our study, our results suggest that the overall properties of the NuSTAR sources are broadly similar to those of nearby high-energy selected AGNs but scaled up in luminosity and mass., Comment: ApJ, in press; 22 pages, 12 figures, 5 tables