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In response to escalating environmental concerns and the imperative to institute effective energy management strategies, the pursuit of alternative fuels has emerged as a pivotal endeavor for realizing sustainable energy solutions. Methanol and ammonia have surfaced as particularly promising and environmentally friendly liquid fuels, holding significant potential for aiding in the attainment of decarbonization objectives and addressing global energy requirements. This research proposes and scrutinizes a sophisticated cogeneration system integrating solid oxide fuel cells (SOFCs), gas turbine (GT), steam Rankine cycle, and organic Rankine cycle. Direct utilization of ammonia and methanol as fuel in this intricate system is examined, with the design and modeling facilitated through the utilization of Aspen HYSYS V.12.1. The thermodynamic performance of the proposed system is rigorously assessed by employing the foundational principles of the first and second laws of thermodynamics. The direct SOFCs fueled by ammonia and methanol exhibit notable energy efficiencies of 64.25 % and 58.42 %, respectively. Remarkably, the amalgamated systems showcase heightened energy efficiencies, witnessing a commendable increase of 12.64 % and 10.66 % when powered by ammonia and methanol, respectively, as compared to individual SOFC systems. Examination of exergy destruction reveals the SOFC as the principal contributor, with electrochemical and chemical processes constituting the primary sources of irreversibility. Additionally, explicit values for exergy destruction in the GT, afterburner, and heat exchanger components are provided. A comprehensive parametric study underscores the pivotal role of the fuel utilization factor (Uf), identifying a value of 0.85 as optimal and significantly augmenting the thermodynamic efficiency of the system. This analysis not only substantiates the potential of ammonia and methanol as effective carriers for hydrogen but also underscores the efficacy of waste heat recovery as a viable strategy for enhancing the overall thermodynamic performance of an SOFC system. The findings presented herein contribute valuable insights, paving the way for the strategic utilization of alternative fuels and cogeneration systems in the broader context of sustainable and environmentally conscious energy solutions. [ABSTRACT FROM AUTHOR]