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1. Origin of the intermolecular forces that produce donor–acceptor stacks in π-conjugated charge-transfer complexes

Author

Seiji Tsuzuki, Ryota Ono, Satoru Inoue, Satoshi Matsuoka, and Tatsuo Hasegawa

Subjects
Chemistry, QD1-999
Abstract

Abstract The attraction between π-conjugated planar electron donor and acceptor molecules that form many stable charge-transfer (CT) complexes has been explained by quantum chemical CT interactions, although the fundamental origin remains unclear. Here, we demonstrate the mechanism of CT complex formation by potential energy map analysis for TTF–CA and BTBT–TCNQ, using energy decomposition of intermolecular interaction by symmetry-adapted perturbation theory (SAPT) combined with coupled cluster calculation. We find that the source of attraction between donor and acceptor molecules is ascribed primarily to the dispersion force and also to the electrostatic force. In contrast, the contribution of CT interactions to the attractive forces is minimal. We demonstrate that the highly directional feature of the exchange repulsion force, coupled with the attractive dispersion and electrostatic forces, is crucial in determining the intermolecular arrangements of actual CT crystals. These findings are key for understanding the unique structural and electronic properties of π-conjugated CT complexes.

Published
2024
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3. Highly stable and isomorphic donor–acceptor stacking in a family of n-type organic semiconductors of BTBT–TCNQ derivatives

Author

Satoshi Matsuoka, Kazuma Ogawa, Ryota Ono, Kiyoshi Nikaido, Satoru Inoue, Toshiki Higashino, Mutsuo Tanaka, Jun'ya Tsutsumi, Ryusuke Kondo, Reiji Kumai, Seiji Tsuzuki, Shunto Arai, and Tatsuo Hasegawa

Subjects
Materials Chemistry, General Chemistry
Abstract

Herein, we present the common structural features of a family of semiconducting molecular donor–acceptor (DA) compounds based on alkylated fused-ring thieno-acenes. Crystal structure analyses were conducted for 22 DA compounds of variously substituted benzothieno[3,2-b][1]benzothiophenes (BTBTs), unsubstituted dithieno[3,2-b:2’,3’-d]thiophene, and unsubstituted benzo[1,2-b:4,5-b’]dithiophene as donors, which were combined with 7,7,8,8-tetracyanoquinodimethane (TCNQ) and its fluorinated derivatives (FmTCNQ, m = 0, 1, 2, 4) as acceptors. Fourteen DA compounds of (substituted BTBT)(TCNQ derivative) formed isomorphous layered molecular packing, where the intermolecular stacking arrangements between the planar skeletons of BTBT and TCNQ were common to each other, and the various substituents played supplementary roles. Density functional theory calculations were conducted to investigate the intermolecular forces between π-electron cores along the DA stacks. Dispersion interactions were the dominant intermolecular attraction, showing weak stacking position dependence, while the short-range orbit–orbit interaction was always repulsive, irrespective of stacking. An important finding is that the orbit–orbit interaction has a relatively strong position dependence and leads to common structural features in the DA compounds. We discuss the origin of the isostructural nature of molecular DA compounds, which is crucial in searching for and exploring unique combinations of molecules with superior semiconducting characteristics., Journal of Materials Chemistry C, 10(43), pp.16471-16479; 2022

Published
2022

5. Impact of Hemoglobin Levels on Composite Cardiac Arrest or Stroke Outcome in Patients With Respiratory Failure Due to COVID-19

Author

Shi Nan Feng, BSPH, Thu-Lan Kelly, PhD, John F. Fraser, MD, PhD, Gianluigi Li Bassi, MD, PhD, Jacky Suen, PhD, Akram Zaaqoq, MD, MPH, Matthew J. Griffee, MD, Rakesh C. Arora, MD, Nicole White, PhD, Glenn Whitman, MD, Chiara Robba, MD, PhD, Denise Battaglini, MD, PhD, Sung-Min Cho, DO, MHS, on behalf of COVID-19 Critical Care Consortium (CCCC), Robert Bartlett, John F. Fraser, Gianluigi Li Bassi, Jacky Y. Suen, Heidi J. Dalton, John Laffey, Daniel Brodie, Eddy Fan, Antoni Torres, Davide Chiumello, Alyaa Elhazm, Carol Hodgson, Shingo Ichiba, Carlos Luna, Srinivas Murthy, Alistair Nichol, Pauline Yeung Ng, Mark Ogino, Aidan Burrell, Antonio Pesenti, Tala Al-Dabbous, Huda Alfoudri, Mohammed Shamsah, Subbarao Elapavaluru, Ashley Berg, Christina Horn, Yunis Mayasi, Stephan Schroll, Dan Meyer, Jorge Velazco, Ludmyla Ploskanych, Wanda Fikes, Rohini Bagewadi, Marvin Dao, Haley White, Alondra Berrios Laviena, Ashley Ehlers Maysoon, Shalabi-McGuire, Trent Witt, Lorenzo Grazioli, Luca Lorini, E. Wilson Grandin, Jose Nunez, Tiago Reyes, Diarmuid O’Briain, Stephanie Hunter, Mahesh Ramanan, Julia Affleck, Hemanth Hurkadli Veerendra, Sumeet Rai, Josie Russell-Brown, Mary Nourse, Mark Joseph, Brook Mitchell, Martha Tenzer, Ryuzo Abe, Hwa Jin Cho, In Seok Jeong, Nadeem Rahman, Vivek Kakar, Andres Oswaldo Razo Vazquez, Nicolas Brozzi, Omar Mehkri, Sudhir Krishnan Abhijit, Duggal Stuart Houltham, Jerónimo Graf, Roderigo Diaz, Roderigo Orrego, Camila Delgado, Joyce González, Maria Soledad Sanchez, Michael Piagnerelli, Josefa Valenzuela Sarrazin, A/Prof. Gustavo Zabert, Lucio Espinosa, Paulo Delgado, Victoria Delgado, Diego Fernando, Bautista Rincón, Angela Maria Marulanda Yanten, Melissa Bustamante Duque, Alyaa Elhazmi, Abdullah Al-Hudaib, Maria Callahan, M. Azhari Taufik, Elizabeth Yasmin Wardoyo, Margaretha Gunawan, Nurindah S Trisnaningrum, Vera Irawany, Muhammad Rayhan, Mauro Panigada, Alberto Zanella, Giacomo Grasselli, Sebastiano Colombo, Chiara Martinet, Gaetano Florio, Massimo Antonelli, Simone Carelli, Domenico L. Grieco, Motohiro Asaki, Kota Hoshino, Leonardo Salazar, Mary Alejandra Mendoza Monsalve, Bairbre McNicholas, David Cosgrave, Joseph McCaffrey, Allison Bone, Yusuff Hakeem, James Winearls, Mandy Tallott, David Thomson, Christel Arnold-Day, Jerome Cupido, Zainap Fanie, Malcom Miller, Lisa Seymore, Dawid van Straaten, Ali Ait Hssain, Jeffrey Aliudin, Al-Reem Alqahtani, Khoulod Mohamed, Ahmed Mohamed, Darwin Tan, Joy Villanueva, Ahmed Zaqout, Ethan Kurtzman, Arben Ademi, Ana Dobrita, Khadija El Aoudi, Juliet Segura, Gezy Giwangkancana, Shinichiro Ohshimo, Javier Osatnik, Anne Joosten, Minlan Yang, Ana Motos, Francisco Arancibia, Virginie Williams, Alexandre Noel, Nestor Luque, Marina Fantini, Ruth Noemi Jorge García, Enrique Chicote Alvarez, Anna Greti, Adrian Ceccato, Angel Sanchez, Ana Loza Vazquez, Ferran Roche-Campo, Diego Franch-Llasat, Divina Tuazon, Marcelo Amato, Luciana Cassimiro, Flavio Pola, Francis Ribeiro, Guilherme Fonseca, Heidi Dalton, Mehul Desai, Erik Osborn Hala Deeb, Antonio Arcadipane, Gennaro Martucci, Giovanna Panarello, Chiara Vitiello, Claudia Bianco, Giovanna Occhipinti, Matteo Rossetti, Raffaele Cuffaro, Sung-Min Cho, Glenn Whitman, Hiroaki Shimizu, Naoki Moriyama, Jae-Burm Kim, Nobuya Kitamura, Johannes Gebauer, Toshiki Yokoyama, Abdulrahman Al-Fares, Sarah Buabbas, Esam Alamad, Fatma Alawadhi, Kalthoum Alawadi, Hiro Tanaka, Satoru Hashimoto, Masaki Yamazaki, Tak-Hyuck Oh, Mark Epler, Cathleen Forney, Louise Kruse, Jared Feister, Joelle Williamson, Katherine Grobengieser, Eric Gnall, Sasha Golden, Mara Caroline, Timothy Shapiro, Colleen Karaj, Lisa Thome, Lynn Sher, Mark Vanderland, Mary Welch, Sherry McDermott, Matthew Brain, Sarah Mineall, Dai Kimura, Luca Brazzi, Gabriele Sales, Giorgia Montrucchio, Tawnya Ogston, Dave Nagpal, Karlee Fischer, Roberto Lorusso, Rajavardhan Rangappa, Sujin Rai, Argin Appu, Mariano Esperatti, Nora Angélica Fuentes, Maria Eugenia Gonzalez, Edmund G. Carton, Ayan Sen, Amanda Palacios, Deborah Rainey, Gordan Samoukoviv, Josie Campisi, Lucia Durham, Emily Neumann, Cassandra Seefeldt, Octavio Falcucci, Amanda Emmrich, Jennifer Guy, Carling Johns, Kelly Potzner, Catherine Zimmermann, Angelia Espinal, Nina Buchtele, Michael Schwameis, Andrea Korhnfehl, Roman Brock, Thomas Staudinger, Stephanie-Susanne, Stecher Michaela Barnikel, Sófia Antón, Alexandra Pawlikowski, Akram Zaaqoq, Lan Anh Galloway, Caitlin Merley, Marc Csete, Luisa Quesada, Isabela Saba, Daisuke Kasugai, Hiroaki Hiraiwa, Taku Tanaka, Eva Marwali, Yoel Purnama, Santi Rahayu Dewayanti, Ardiyan, Dafsah Arifa Juzar, Debby Siagian, Yih-Sharng Chen, Indrek Ratsep, Andra-Maris Post, Piret Sillaots, Anneli Krund, Merili-Helen Lehiste, Tanel Lepik, Frank Manetta, Effe Mihelis, Iam Claire Sarmiento, Mangala Narasimhan, Michael Varrone, Mamoru Komats, Julia Garcia-Diaz, Catherine Harmon, S. Veena Satyapriya, Amar Bhatt, Nahush A. Mokadam, Alberto Uribe, Alicia Gonzalez, Haixia Shi, Johnny McKeown, Joshua Pasek, Juan Fiorda, Marco Echeverria, Rita Moreno, Bishoy Zakhary, Marco Cavana, Alberto Cucino, Giuseppe Foti, Marco Giani, Benedetta Fumagalli, Valentina Castagna, Andrea Dell’Amore, Paolo Navalesi, Hoi-Ping Shum, Alain Vuysteke, Asad Usman, Andrew Acker, Benjamin Smood, Blake Mergler, Federico Sertic, Madhu Subramanian, Alexandra Sperry, Nicolas Rizer, Erlina Burhan, Menaldi Rasmin, Ernita Akmal, Faya Sitompul, Navy Lolong, Bhat Naivedh, Simon Erickson, Peter Barrett, David Dean, Julia Daugherty, Antonio Loforte, Irfan Khan, Mohammed Abraar Quraishi, Olivia DeSantis, Dominic So, Darshana Kandamby, Jose M. Mandei, Hans Natanael, Eka YudhaLantang, Anastasia Lantang, Surya Oto Wijaya, Anna Jung, George Ng, Wing Yiu Ng, Shu Fang, Alexis Tabah, Megan Ratcliffe, Maree Duroux, Shingo Adachi, Shota Nakao, Pablo Blanco, Ana Prieto, Jesús Sánchez, Meghan Nicholson, Warwick Butt, Alyssa Serratore, Carmel Delzoppo, Pierre Janin, Elizabeth Yarad, Richard Totaro, Jennifer Coles, Bambang Pujo, Robert Balk, Andy Vissing, Esha Kapania, James Hays, Samuel Fox, Garrett Yantosh, Pavel Mishin, Saptadi Yuliarto, Kohar Hari Santoso, Susanthy Djajalaksana, Arie Zainul Fatoni, Masahiro Fukuda, Keibun Liu, Paolo Pelosi, Denise Battaglini, Juan Fernando Masa Jiménez, Diego Bastos, Sérgio Gaião, Desy Rusmawatiningtyas, Young-Jae Cho, Su Hwan Lee, Tatsuya Kawasaki, Laveena Munshi, Pranya Sakiyalak, Prompak Nitayavardhana, Tamara Seitz, Rakesh Arora, David Kent, Daniel Marino, Swapnil Parwar, Andrew Cheng, Jennene Miller, Shigeki Fujitani, Naoki Shimizu, Jai Madhok, Clark Owyang, Hergen Buscher, Claire Reynolds, Olavi Maasikas, Aleksan Beljantsev, Vladislav Mihnovits, Takako Akimoto, Mariko Aizawa, Kanako Horibe, Ryota Onodera, Meredith Young, Timothy George, Kiran Shekar, Niki McGuinness, Lacey Irvine, Brigid Flynn, Tomoyuki Endo, Kazuhiro Sugiyama, Keiki Shimizu, Kathleen Exconde, Leslie Lussier, Gösta Lotz, Maximilian Malfertheiner, Lars Maier, Esther Dreier, Neurinda Permata Kusumastuti, Colin McCloskey, Al-Awwab Dabaliz, Tarek B Elshazly, Josiah Smith, Konstanty S. Szuldrzynski, Piotr Bielański, Keith Wille, Ken Kuljit, S. Parhar, Kirsten M. Fiest, Cassidy Codan, Anmol Shahid, Mohamed Fayed, Timothy Evans, Rebekah Garcia, Ashley Gutierrez, Tae Song, Rebecca Rose, Suzanne Bennett, Denise Richardson, Giles Peek, Lovkesh Arora, Kristina Rappapport, Kristina Rudolph, Zita Sibenaller, Lori Stout, Alicia Walter, Daniel Herr, Nazli Vedadi, Shaun Thompson, Julie Hoffman, Xiaonan Ying, Ryan Kennedy, Muhammed Elhadi, Matthew Griffee, Anna Ciullo, Yuri Kida, Ricard Ferrer Roca, JordI Riera, Sofia Contreras, Cynthia Alegre, Christy Kay, Irene Fischer, Elizabeth Renner, Hayato Taniguci, John Fraser, Jacky Suen, Adrian Barnett, Nicole White, Kristen Gibbons, Simon Forsyth, Amanda Corley, India Pearse, Samuel Hinton, Gabriella Abbate, Halah Hassan, Silver Heinsar, Varun A Karnik, Katrina Ki, Hollier F. O’Neill, Nchafatso Obonyo, Leticia Pretti Pimenta, Janice D. Reid, Kei Sato, Aapeli Vuorinen, Karin S. Wildi, Emily S. Wilson, Stephanie Yerkovich, James Lee, Daniel Plotkin, Barbara Wanjiru Citarella, Laura Merson, Emma Hartley, Bastian Lubis, Takanari Ikeyama, Balu Bhaskar, Jae-Seung Jung, Shay McGuinness, Glenn Eastwood, Sandra Rossi Marta, Fabio Guarracino, Stacy Gerle, Emily Coxon, Bruno Claro, Daniel Loverde, Namrata Patil, Vieri Parrini, Angela McBride, Kathryn Negaard, Angela Ratsch, Ahmad Abdelaziz, Juan David Uribe, Adriano Peris, Mark Sanders, Dominic Emerson, Muhammad Kamal, Pedro Povoa, Roland Francis, Ali Cherif, Sunimol Joseph, Matteo Di Nardo, Micheal Heard, Kimberly Kyle, Ray A Blackwell, Patrick Biston, Hye Won Jeong, Reanna Smith, Yogi Prawira, Arturo Huerta Garcia, Nahikari Salterain, Bart Meyns, Marsha Moreno, Rajat Walia, Amit Mehta, Annette Schweda, Moh Supriatna, Cenk Kirakli, Melissa Williams, Kyung Hoon Kim, Alexandra Assad, Estefania Giraldo, Wojtek Karolak, Martin Balik, Elizabeth Pocock, Evan Gajkowski, Kanamoto Masafumi, Nicholas Barrett, Yoshihiro Takeyama, Sunghoon Park, Faizan Amin, Fina Meilyana Andriyani, Serhii Sudakevych, Magdalena Vera, Rodrigo Cornejo, Patrícia Schwarz, Ana Carolina Mardini, Thais de Paula, Ary Serpa Neto, Andrea Villoldo, Alexandre Siciliano Colafranceschi, Alejandro Ubeda Iglesias, Juan Granjean, Lívia Maria Garcia Melro, Giovana Fioravante Romualdo, Diego Gaia, Helmgton Souza, Filomena Galas, Rafael Máñez Mendiluce, Alejandra Sosa, Ignacio Martinez, Hiroshi Kurosawa, Juan Salgado, Beate Hugi-Mayr, Eric Charbonneau, Vitor Salvatore Barzilai, Veronica Monteiro, Rodrigo Ribeiro de Souza, Michael Harper, Hiroyuki Suzuki, Celina Adams, Jorge Brieva, George Nyale, Faisal Saleem Eltatar, Jihan Fatani, Husam Baeissa, Ayman AL Masri, Ahmed Rabie, Mok Yee Hui, Masahiro Yamane, Hanna Jung, Ayorinde Mojisola Margaret, Newell Nacpil, Katja Ruck, Rhonda Bakken, Claire Jara, Tim Felton, Lorenzo Berra, Bobby Shah, Arpan Chakraborty, Monika Cardona, Gerry Capatos, Bindu Akkanti, Abiodun Orija, Harsh Jain, Asami Ito, Brahim Housni, Sennen Low, Koji Iihara, Joselito Chavez, Kollengode Ramanathan, Gustavo Zabert, Krubin Naidoo, Ian Seppelt, Marlice VanDyk, Sarah MacDonald, Randy McGregor, Teka Siebenaler, Hannah Flynn, Kristi Lofton, Toshiyuki Aokage, Kazuaki Shigemitsu, Andrea Moscatelli, Giuseppe Fiorentino, Matthias Baumgaertel, Serge Eddy Mba, Jana Assy, Amelya Hutahaean, Holly Roush, Kay A Sichting, Francesco Alessandri, Debra Burns, Gavin Salt, Carl P. Garabedian, Jonathan Millar, Malcolm Sim, Adrian Mattke, Danny McAuley, Jawad Tadili, Tim Frenzel, Yaron Bar-Lavie, Aaron Blandino Ortiz, Jackie Stone, Antony Attokaran, Michael Farquharson, Brij Patel, Derek Gunning, Kenneth Baillie, Pia Watson, Kenji Tamai, Gede Ketut Sajinadiyasa, Dyah Kanyawati, Marcello Salgado, Assad Sassine, Bhirowo Yudo, Scott McCaul, Bongjin Lee, Sang Min Lee, Arnon Afek, Yoshiaki Iwashita, Bambang Pujo Semedi, Jack Metiva, Nicole Van Belle, Ignacio Martin-Loeches, Lenny Ivatt, Chia Yew Woon, Hyun Mi Kang, Timothy Smith, Erskine James, Nawar Al-Rawas, Yudai Iwasaki, Kenny Chan King-Chung, Vadim Gudzenko, Fabio Taccone, Fajar Perdhana, Yoan Lamarche, Joao Miguel Ribeiro, Nikola Bradic, Klaartje Van den Bossche, Oude Lansink, Gurmeet Singh, Gerdy Debeuckelaere, Henry T. Stelfox, Cassia Yi, Jennifer Elia, Thomas Tribble, Shyam Shankar, Raj Padmanabhan, Bill Hallinan, Luca Paoletti, Yolanda Leyva, Tatuma Fykuda, Jenelle Badulak, Jillian Koch, Amy Hackman, Lisa Janowaik, Deb Hernandez, Jennifer Osofsky, Katia Donadello, Aizah Lawang, Josh Fine, and Benjamin Davidson

Subjects
Medical emergencies. Critical care. Intensive care. First aid, RC86-88.9
Abstract

OBJECTIVES:. Anemia has been associated with an increased risk of both cardiac arrest and stroke, frequent complications of COVID-19. The effect of hemoglobin level at ICU admission on a composite outcome of cardiac arrest or stroke in an international cohort of COVID-19 patients was investigated. DESIGN:. Retrospective analysis of prospectively collected database. SETTING:. A registry of COVID-19 patients admitted to ICUs at over 370 international sites was reviewed for patients diagnosed with cardiac arrest or stroke up to 30 days after ICU admission. Anemia was defined as: normal (hemoglobin ≥ 12.0 g/dL for women, ≥ 13.5 g/dL for men), mild (hemoglobin 10.0–11.9 g/dL for women, 10.0–13.4 g/dL for men), moderate (hemoglobin ≥ 8.0 and < 10.0 g/dL for women and men), and severe (hemoglobin < 8.0 g/dL for women and men). PATIENTS:. Patients older than 18 years with acute COVID-19 infection in the ICU. INTERVENTIONS:. None. MEASUREMENTS AND MAIN RESULTS:. Of 6926 patients (median age = 59 yr, male = 65%), 760 patients (11.0%) experienced stroke (2.0%) and/or cardiac arrest (9.4%). Cardiac arrest or stroke was more common in patients with low hemoglobin, occurring in 12.8% of patients with normal hemoglobin, 13.3% of patients with mild anemia, and 16.7% of patients with moderate/severe anemia. Time to stroke or cardiac arrest by anemia status was analyzed using Cox proportional hazards regression with death as a competing risk. Covariates selected through clinical knowledge were age, sex, comorbidities (diabetes, hypertension, obesity, and cardiac or neurologic conditions), pandemic era, country income, mechanical ventilation, and extracorporeal membrane oxygenation. Moderate/severe anemia was associated with a higher risk of cardiac arrest or stroke (hazard ratio, 1.32; 95% CI, 1.05–1.67). CONCLUSIONS:. In an international registry of ICU patients with COVID-19, moderate/severe anemia was associated with increased hazard of cardiac arrest or stroke.

Published
2024
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6. Room-Temperature Type-II Multiferroic Phase Induced by Pressure in Cupric Oxide

Author

Noriki Terada, Dmitry D. Khalyavin, Pascal Manuel, Fabio Orlandi, Christopher J. Ridley, Craig L. Bull, Ryota Ono, Igor Solovyev, Takashi Naka, Dharmalingam Prabhakaran, and Andrew T. Boothroyd

Subjects
General Physics and Astronomy
Abstract

According to previous theoretical work, the binary oxide CuO can become a room-temperature multiferroic via tuning of the superexchange interactions by application of pressure. Thus far, however, there has been no experimental evidence for the predicted room-temperature multiferroicity. Here, we show by neutron diffraction that the multiferroic phase in CuO reaches 295 K with the application of 18.5 GPa pressure. We also develop a spin Hamiltonian based on density functional theory and employing superexchange theory for the magnetic interactions, which can reproduce the experimental results. The present Letter provides a stimulus to develop room-temperature multiferroic materials by alternative methods based on existing low temperature compounds, such as epitaxial strain, for tunable multifunctional devices and memory applications.

Published
2022

7. Thinking 2050: Bioengineering of Science and Art

Author

Nima Rezaei, Amene Saghazadeh, Alejandro Salado, Amine Harbi, Ana Itzel Casarrubias-Jaimez, Carlo Brentari, Christian Hugo Hoffmann, Christopher A. Haines, Cristiane Maria Cornelia Gottschalk, Dustin Hellberg, Eva Reyes-Gacitúa, Fernando Ramos-Quintana, Gabriel Vacariu, Giuseppe Zollo, Grace Anywar, Harah Chon, Helen Kopnina, Jude Likori, Julio Juan Ruiz, Khasankhonova Nodira Isametdinovna, Kim Poldner, Leander Penaso Marquez, Louise Mackenzie, Luca Iandoli, Marco Toscano, María Antonia González Valerio, Mark Reybrouck, Marko Pajević, Mauro Scalercio, Mihai Vacariu, Mirko Di Bernardo, Paola Lopreiato, Patricia Olga Caratozzolo Martelliti, Reto Gubelmann, Roberto Franzini Tibaldeo, Rogelio Jiménez Marce, Ryota Ono, Sergey Horujy, Stefania Achella, Stephen Spain, Tamás Lajtner, Trevor J. Tebbs, Ulrich Richter, and Wojciech Krysztofiak

Published
2022

8. Magnetically Induced Polarization in Centrosymmetric Bonds

Author

Ryota Ono, S. V. Nikolaev, and Igor Solovyev

Subjects
POLARIZATION, Bond vector, MAGNETIC ORDERS, FOS: Physical sciences, General Physics and Astronomy, Spin current, Induced polarization, TRANSFER INTEGRAL, Condensed Matter - Strongly Correlated Electrons, Mathematics::Probability, KRAMERS DOUBLET, Mesoscale and Nanoscale Physics (cond-mat.mes-hall), COPPER OXIDES, DENSITY FUNCTIONAL THEORY, POSITION OPERATORS, Physics, Condensed Matter - Materials Science, Condensed Matter - Mesoscale and Nanoscale Physics, Strongly Correlated Electrons (cond-mat.str-el), MOTT INSULATORS, INDEPENDENT CONTRIBUTIONS, Magnetic order, High Energy Physics::Phenomenology, Materials Science (cond-mat.mtrl-sci), INDUCED POLARIZATION, Coupling (probability), Crystallography, ELECTRIC POLARIZATION, BAND STRUCTURE, Condensed Matter::Strongly Correlated Electrons, CENTROSYMMETRIC, NONCOLLINEAR
Abstract

We reveal the microscopic origin of electric polarization $\vec{P}$ induced by noncollinear magnetic order. We show that in Mott insulators, such $\vec{P}$ is given by all possible combinations of position operators $\hat{\vec{r}}_{ij} = (\vec{r}_{ij}^{\, 0},\vec{\boldsymbol{r}}_{ij}^{\phantom{0}})$ and transfer integrals $\hat{t}_{ij} = (t_{ij}^{0},\boldsymbol{t}_{ij}^{\phantom{0}})$ in the bonds, where $\vec{r}_{ij}^{\, 0}$ and $t_{ij}^{0}$ are spin-independent contributions in the basis of Kramers doublet states, while $\vec{\boldsymbol{r}}_{ij}^{\phantom{0}}$ and $\boldsymbol{t}_{ij}^{\phantom{0}}$ stem solely from the spin-orbit interaction. Among them, the combination $t_{ij}^{0} \vec{\boldsymbol{r}}_{ij}^{\phantom{0}}$, which couples to the spin current, remains finite in the centrosymmetric bonds, thus yielding finite $\vec{P}$ in the case of noncollinear arrangement of spins. The form of the magnetoelectric coupling, which is controlled by $\vec{\boldsymbol{r}}_{ij}^{\phantom{0}}$, appears to be rich and is not limited to the phenomenological law $\vec{P} \sim \boldsymbol{\epsilon}_{ij} \times [\boldsymbol{e}_{i} \times \boldsymbol{e}_{j}]$ with $\boldsymbol{\epsilon}_{ij}$ being the bond vector connecting the spins $\boldsymbol{e}_{i}$ and $\boldsymbol{e}_{j}$. Using density-functional theory, we illustrate how the proposed mechanism work in the spiral magnets CuCl$_2$, CuBr$_2$, CuO, and $\alpha$-Li$_2$IrO$_3$, providing consistent explanation to available experimental data., Comment: 6 pages, 3 figures

Published
2021

9. Surface band characters of the Weyl semimetal candidate material MoTe2 revealed by one-step angle-resolved photoemission theory

Author

Ryota Ono, Jan Minár, Peter Krüger, Hubert Ebert, Yoshitaka Nakata, Eike F. Schwier, Kazuyuki Sakamoto, Jürgen Braun, Alberto Marmodoro, and Jakub Schusser

Subjects
Physics, Condensed matter physics, Photoemission spectroscopy, Weyl semimetal, Angle-resolved photoemission spectroscopy, 02 engineering and technology, 021001 nanoscience & nanotechnology, 01 natural sciences, Semimetal, Atomic orbital, Condensed Matter::Superconductivity, 0103 physical sciences, Condensed Matter::Strongly Correlated Electrons, Density functional theory, 010306 general physics, 0210 nano-technology, Ground state, Electronic band structure
Abstract

The layered two-dimensional material ${\mathrm{MoTe}}_{2}$ in the ${T}_{d}$ crystal phase is a semimetal which has theoretically been predicted to possess topologically nontrivial bands corresponding to Weyl fermions. Clear experimental evidence by angle-resolved photoemission spectroscopy (ARPES) is, however, lacking, which calls for a careful examination of the relation between ground state band structure calculations and ARPES intensity plots. Here we report a study of the near-Fermi-energy band structure of ${\mathrm{MoTe}}_{2}({T}_{d})$ by means of ARPES measurements, density functional theory, and one-step-model ARPES calculations. Good agreement between theory and experiment is obtained. We analyze the orbital character of the surface bands and its relation to the ARPES polarization dependence. We find that light polarization has a major effect on which bands can be observed by ARPES. For $s$-polarized light, the ARPES intensity is dominated by subsurface Mo $d$ orbitals, while $p$-polarized light reveals the bands mainly derived from Te $p$ orbitals. Suitable light polarization for observing either an electron or hole pocket are determined.

Published
2021

10. Fingerprints of spin-current physics on magnetoelectric response in the spin- 12 magnet Ba2CuGe2O7

Author

Sergey A. Nikolaev, Igor Solovyev, and Ryota Ono

Subjects
Physics, Wannier function, Crystallographic point group, Condensed matter physics, Lattice (group), Order (ring theory), 02 engineering and technology, 021001 nanoscience & nanotechnology, 01 natural sciences, Orientation (vector space), Polarization density, 0103 physical sciences, Spin model, Condensed Matter::Strongly Correlated Electrons, 010306 general physics, 0210 nano-technology, Spin-½
Abstract

As is well known, the single-site anisotropy vanishes in the spin-$\frac{1}{2}$ compounds as a consequence of the fundamental Kramers degeneracy. We argue, rather generally, that a similar property holds for the magnetically induced electric polarization $\mathbit{P}$, which should depend only on the relative orientation of spins in the bonds but not on the direction of each individual spin. Thus, for insulating multiferroic compounds, $\mathbit{P}$ can be decomposed in terms of pairwise isotropic, antisymmetric, and anisotropic symmetric contributions, which can be rigorously derived in the framework of the superexchange (SE) theory, in analogy with the spin Hamiltonian. The SE theory also allows us to identify the microscopic mechanism that stands behind each contribution. The most controversial and intriguing one---concerning the form, appearances, and implications for the properties of real compounds---is the antisymmetric or spin-current mechanism. In this work, we propose that, within the SE theory, the disputed magnetoelectric (ME) properties of tetragonal ${\mathrm{Ba}}_{2}\mathrm{Cu}{\mathrm{Ge}}_{2}{\mathrm{O}}_{7}$, representing the lattice of magnetic ${\mathrm{Cu}}^{2+}$ ions in the tetrahedral environment, can be explained solely by the spin-current mechanism, while other contributions are either small or forbidden by symmetry. First, after analysis of the symmetry properties of the SE Hamiltonian and corresponding parameters of electric polarization, we explicitly show how the cycloidal spin order induces the experimentally observed electric polarization in the direction perpendicular to the tetragonal plane, which can be naturally explained by the spin-current mechanism operating in the out-of-plane bonds. Then, we unveil the previously overlooked ME effect, where the application of the magnetic field perpendicular to the plane not only causes the incommensurate-commensurate transition, but also flips the electric polarization into the plane due to the spin-current mechanism operating in the neighboring bonds within this plane. In both cases, the magnitude and direction of $\mathbit{P}$ can be controlled by rotating the spin pattern in the tetragonal plane. Our analysis is based on a realistic spin model, which was rigorously derived from first-principles electronic structure calculations and supplemented with a new algorithm for the construction of localized Wannier functions obeying the crystallographic symmetry of ${\mathrm{Ba}}_{2}\mathrm{Cu}{\mathrm{Ge}}_{2}{\mathrm{O}}_{7}$.

Published
2020

11. Introducing Futures Concepts to Experts in Public Services in Developing Countries

Author

Ryota Ono

Subjects
Economic growth, Political science, 05 social sciences, 0211 other engineering and technologies, Developing country, 021107 urban & regional planning, 02 engineering and technology, 0509 other social sciences, 050905 science studies, Futures contract
Abstract

This article describes my teaching of futures to experts in public services such as water supply, power supply, and waste treatment in developing countries. These experts come to Japan to participate in the training course of their field of service, which is offered by a state-run organization in Japan. At the end of the course, they prepare an action plan, which is to be implemented after they return to their countries. In the course, I give them three lectures on futures to help them make their action plans more future-oriented. Experts are quite different from university students in that they carry the burden and responsibility to make services better and more effective in the future. Most of them assume, in their planning, that data and information in the past and present form the foundation on which they project the future of their services. As a result, their plans are always based on a probable future and not on possible futures. I teach them futures to point out the risks of such planning approach, and to open their eyes to an alternative one, which I call “Futures planning.” By following the three lectures in chronological order, this article clarifies characteristics of my futures teaching and its impact on the experts from developing countries.

Published
2018

12. A One-Dimensional Model for Photoemission Calculations from Plane-Wave Band Structure Codes

Author

Ryota Ono and Peter Krüger

Subjects
Materials science, Condensed matter physics, Graphene, Plane wave, Bioengineering, Dimensional modeling, 02 engineering and technology, Surfaces and Interfaces, 021001 nanoscience & nanotechnology, Condensed Matter Physics, 01 natural sciences, Surfaces, Coatings and Films, law.invention, Mechanics of Materials, law, 0103 physical sciences, 010306 general physics, 0210 nano-technology, Electronic band structure, Biotechnology
Published
2018

13. Characterization of basket-forceps-type micro-flow-sensor for breathing measurements in small airway

Author

Ryota Ono, Tsutomu Kawabe, Mitsuhiro Shikida, Yoshihiro Hasegawa, Naoaki Harada, and Miyoko Matsushima

Subjects
animal structures, Materials science, Calibration curve, Acoustics, Forceps, Airflow, 02 engineering and technology, 01 natural sciences, Reciprocating motion, Flow sensor, Electrical and Electronic Engineering, business.industry, 010401 analytical chemistry, Electrical engineering, 021001 nanoscience & nanotechnology, Condensed Matter Physics, 0104 chemical sciences, Electronic, Optical and Magnetic Materials, body regions, nervous system, Flow velocity, Hardware and Architecture, embryonic structures, Breathing, 0210 nano-technology, business, Airway
Abstract

We previously proposed a basket-forceps-type flow sensor, in which a flexible thermal flow sensor is mounted onto basket forceps to fix the flow sensor onto the inside surface of the airway. The basket-forceps-type flow sensor has an asymmetrical structure to prevent reciprocating airflow; thus, we investigated the characteristics of the basket-forceps-type flow sensor under both expired- and inspired-airflow conditions in this study. The thermal flow sensor was fabricated on a flexible polyimide film and mounted onto a guide tube of a basket-forceps. Two heaters and their electrical wiring patterns were designed to produce symmetric heat distribution over the heaters. The effects of the basket structure and guide tube on flow-rate measurement were experimentally evaluated, and it was confirmed that they did not affect sensor output. Conversely, sensor output decreased with the increase in tube diameter due to the reduction in the average flow velocity with the diameter increase. Thus, we carried out a procedure to construct a calibration curve under an arbitrary tube diameter. Finally, we applied the basket-forceps-type flow sensor in an animal experiment in which it successfully detected the breathing properties in the airway of a rat.

Published
2017

14. Proposal for Identification Scheme of Driver and Impostor based on Acceleration Data

Author

Katsuhiro Naito, Takaya Yamazato, Takuya Mitani, Ryota Ono, and Yuki Mori

Subjects
0209 industrial biotechnology, 020901 industrial engineering & automation, Identification scheme, Computer science, business.industry, 0202 electrical engineering, electronic engineering, information engineering, Experimental data, 020201 artificial intelligence & image processing, Pattern recognition, 02 engineering and technology, Artificial intelligence, business, Classifier (UML)
Abstract

This paper proposes a continuous identification scheme monitoring a driver's behavior and a detection scheme for an impostor. The proposed scheme uses Long Short-Term Memory (LSTM) to create a classifier of the driver's behavior according to acceleration data and classifies a driver. Additionally, it also detects an impostor according to statistical information of output from the classifier. Experimental results show that an acceleration sensor on a real vehicle is enough to classify 15 drivers according to real-time driver's behavior. Additionally, the proposed scheme can detect an impostor through the verification of real experimental data.

Published
2019

16. The Future Internet : Alternative Visions

Author

Jenifer Winter, Ryota Ono, Jenifer Winter, and Ryota Ono

Subjects
Internet--Philosophy, Internet, Internet--Social aspects
Abstract

Readers seeking to gain a handle on the internet's global expansion will find this book rich in scholarly foundations combined with cutting-edge discussion of emerging ICTs and services and the complex societal contexts in which they are embedded. To explore possibilities to the fullest extent, a sociotechnical systems approach is employed, focusing on the interplay of technical, social, cultural, political, and economic dynamics to explore alternative futures (ones that are not part of the dominant discourse about the internet). These shared perspectives are not well addressed elsewhere in current discussions. Awareness of these dynamics, and the fluidity of the future, is important, as humankind moves forward into the uncertain future. Due to the sociotechnical complexity of the Internet, policymakers, businesspeople, and academics worldwide have struggled to keep abreast of developments. This volume's approach is intended to stimulate dialogue between academics and practitioners on a topic that will affect most aspects of human life in the near-term future.

Published
2015

18. Basket forceps with flow sensor for evaluating breathing characteristics in small airway

Author

Ryota Ono, Mitsuhiro Shikida, Naoaki Harada, Tsutomu Kawabe, and Miyoko Matsushima

Subjects
Materials science, Acoustics, Forceps, Breathing, Response time, Tube (fluid conveyance), Bending, Flow sensor, Airway, Volumetric flow rate
Abstract

We developed a basket forceps with a flow sensor for evaluating the breathing characteristics in small airways. The flow sensor, fabricated using mirco-eletro-mechanical systems technologies, was integrated into a guide wire with the basket forceps. The fundamental sensor characteristics, response time and flow rate vs. sensor output curve, were experimentally confirmed. The sensor was successfully fixed to the inside surface of a small tube by using the bending arms of the basket forceps. We confirmed that the breathing properties of a rat were successfully detected with the integrated flow sensor.

Published
2015

19. Conclusion: Three Stages of the Future Internet

Author

Jenifer Sunrise Winter and Ryota Ono

Subjects
Vision, Government, Futures studies, business.industry, Order (exchange), Political science, Sustainability, The Internet, Public relations, business, Futures contract
Abstract

In The Future Internet: Alternative Visions, a diverse group of futures researchers explore alternative visions of the future Internet, highlighting key uncertainties that are not well addressed in the current discourse about technology and policy developments. Corporate, academic, and policy visions associated with the future Internet present a techno-utopian view, focusing on the integration of myriad computational objects into the everyday environment in order to enable economic growth, strengthen security, enhance business and government efficiency, and promote environmental sustainability and personal convenience. Contributors to this volume probed the underlying values, beliefs, and thinking that are influencing those futures, and presented a compelling array of alternative visions about the future Internet. In this concluding chapter, we perform a macroanalysis of the scenarios presented in the preceding chapters from predictive, cultural, and critical futures studies perspectives and discuss the role of futures studies and images of the future as a means to help stakeholders make truly “better” decisions about the future of the Internet.

Published
2015

20. Introduction to the Future Internet: Alternative Visions

Author

Jenifer Sunrise Winter and Ryota Ono

Subjects
Futures studies, Vision, business.industry, Political science, Technical standard, The Internet, Computational intelligence, Systems thinking, Everyday life, business, Futures contract, Data science
Abstract

Many of the visions that shape the Internet’s development and use are driven by research institutions, corporations, and governments, enabling consensus about research and policy problems. While there is not a single vision of the future Internet, there are a number of overlapping, and influential, visions shared between academic and corporate researchers and governments. These all point towards the embedding of computational intelligence into many aspects of everyday life and the growth of technical standards enabling machine-to-machine (M2M) intelligence. The first part of this chapter introduces the dominant techno-utopian vision of the future Internet. Then, the field of futures studies is introduced as a means to perform systematic thinking about alternative futures. Finally, we introduce the individual chapters in this volume.

Published
2015

22. The Future Internet

Author

Jenifer Sunrise Winter and Ryota Ono

Subjects
business.industry, Internet research, Internet privacy, The Internet, Sociology, business, Sociology of the Internet
Published
2015

23. Learning from young people’s image of the future: a case study in Taiwan and the US

Author

Ryota Ono

Subjects
Sociology and Political Science, Multimedia, Computer science, ComputingMethodologies_IMAGEPROCESSINGANDCOMPUTERVISION, Development, Business and International Management, computer.software_genre, Data science, computer, Image (mathematics)
Abstract

An image of the future that an individual holds determines what attitude he/she holds towards the future and how he/she behaves in the present. These in turn would increase the probability to make the image realized as imagined in the future. As young people will be the builders of a society in the future, investigating their images of the future has significant implications for the future. With a survey of two groups of university students in Taiwan and the U.S., this study looked into various aspects of images, explored message sources influencing the formation of the images, identified values embedded in the images, and explored the relationship between the images and the students’ understanding of the present.

Published
2003

26. Assessing the validity of the Delphi technique

Author

Dan J. Wedemeyer and Ryota Ono

Subjects
Sociology and Political Science, Operations research, Computer science, Delphi method, Development, Business and International Management, Wideband delphi, Futures contract, Technology forecasting, Field (computer science)
Abstract

Forecasting is an essential factor in policy formulation and planning. It helps determine the direction of future actions. While a number of forecasting techniques are utilized to forecast the future, it is important to know just how valid those forecasting techniques can be. The Delphi technique has been called the ‘cornerstone of futures research’. This study reports the results of the assessment of the accuracy of the forecasts derived from the Delphi technique. Twenty-five experts in the communication field assessed 24 trends and 17 events in the state of Hawaii as of 1991. The expert assessments were then compared with the forecasts made by utilizing the Delphi technique 16 years earlier. The results showed that the trend forecasts were significantly correlated with the trend assessment. They also showed that the Delphi technique had accurately forecast approximately half the events that could be evaluated as of 1991. Results from this study lend support to the use of the Delphi technique in long-range forecasting and reveal some interesting findings in forecasting the developments in communication in Hawaii.

Published
1994

27. Local strain-dependent Zeeman splitting in GaN:Eu

Author

Tomohiro Okuno, Ryota Onoda, Lisa Toyoshima, Kasumi Miyata, Hiroto Sekiguchi, Akihiro Wakahara, and Toshihiro Nakaoka

Subjects
Physics, QC1-999
Abstract

The electronic spins of rare-earth materials are attractive candidates for spin qubits and quantum memories. To access individual spins, tuning of the g-factor is desirable. Here, we report on local strain-dependent g-factors of the 5D0–7F2 transitions of Eu3+ centers in GaN:Eu thin films. We have found a clear correlation between the effective g-factor and the emission energy shift induced by the local strain. The combination of micro-photoluminescence and scanning electron microscope/electron backscattering diffraction measurements has revealed that the compressive strain of 0.2%–0.4%, relative to a surrounding reference point, induces an energy shift of about 3 meV. The strain decreases the g-factor of the emission at 1.991 eV from 2.5 to 1.5, while the strain increases the g-factor of the emission at 1.994 eV from 1.1 to 1.7. The result suggests that the g-factor can be tuned by the local strain. On the basis of the strain-induced energy shift and the g-factor, we have identified the optical sites. The 5D0–7F2 transitions observed in this study consist of three optical sites with C3v symmetry and one site with C1h symmetry.

Published
2022
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28. Improving development assistance for telecommunications

Author

Ryota Ono

Subjects
Economics and Econometrics, business.industry, Communication, Developing country, Library and Information Sciences, Management, Monitoring, Policy and Law, Telecommunications, business, Developed country, Information Systems, Management Information Systems, Variety (cybernetics)
Abstract

The stable development of telecommunications in the developing countries has been hindered by a variety of difficulties. Development assistance by the developed countries and a number of organizations has an important role in helping the developing countries overcome these difficulties and promote their telecommunications development. This paper examines different kinds of development assistance and suggests that the role of the ITU will be crucial to any improvement in coordination of assistance.

Published
1990

30. Assessment of 28-Day In-Hospital Mortality in Mechanically Ventilated Patients With Coronavirus Disease 2019: An International Cohort Study

Author

Gianluigi Li Bassi, MD, PhD, Jacky Y. Suen, BSc, PhD, Nicole White, PhD, Heidi J. Dalton, MD, MCCM, Jonathon Fanning, BSc, MBBS, PhD, FANZCA, FCICM, Amanda Corley, RN, Sally Shrapnel, MBBS, BMedSc, MSc, PhD, FRACGP, Samuel Hinton, PhD, Simon Forsyth, PhD, Rex Parsons, BSc, MMedStats, John G. Laffey, MD, Eddy Fan, MD, PhD, Robert Bartlett, MD, Daniel Brodie, MD, Aidan Burrell, MD, PhD, Davide Chiumello, MD, Alyaa Elhazmi, MD, Giacomo Grasselli, MD, Carol Hodgson, PT, PhD, Shingo Ichiba, MD, Carlos Luna, MD, Eva Marwali, MD, Laura Merson, Bsc, Srinivas Murthy, MD, Alistair Nichol, MD, PhD, Mauro Panigada, MD, Paolo Pelosi, MD, FERS, Antoni Torres, MD, PhD, FERS, Pauline Yeung Ng, MD, Mark Ogino, MD, John F. Fraser, MBChB, PhD, FRCP(Glas), FFARCSI, FRCA, FCICM, on behalf of the COVID-19 Critical Care Consortium, Tala Al-Dabbous, Huda Alfoudri, Mohammed Shamsah, Subbarao Elapavaluru, Ashley Berg, Christina Horn, Stephan Schroll, Jorge Velazco, Ludmyla Ploskanych, Wanda Fikes, Dan Meyer, Ashley Ehlers, Maysoon Shalabi-McGuire, Trent Witt, Lorenzo Grazioli, Luca Lorini, E. Wilson Grandin, Jose Nunez, Tiago Reyes, Diarmuid O’Briain, Stephanie Hunter, Mahesh Ramanan, Julia Affleck, Hemanth Hurkadli Veerendra, Sumeet Rai, Josie Russell-Brown, Mary Nourse, Mark Joseph, Brook Mitchell, Martha Tenzer, Carilion Clinic, Ryuzo Abe, Hwa Jin Cho, In Seok Jeong, Nicolas Brozzi, Omar Mehkri, Sudhir Krishnan, Abhijit Duggal, Stuart Houltham, Jerónimo Graf, Roderigo Diaz, Camila Delgado, Joyce González, Maria Soledad Sanchez, Diego Fernando Bautista Rincón, Angela Maria Marulanda Yanten, Melissa Bustamante Duque, Daniel Brodie, Desy Rusmawatiningtyas, Maria Callahan, M. Azhari Taufik, Elizabeth Yasmin Wardoyo, Margaretha Gunawan, Nurindah S Trisnaningrum, Vera Irawany, Muhammad Rayhan, Mauro Panigada, Antonia Pesenti, Alberto Zanella, Michela Leone, Giacomo Grasselli, Silvia Coppola, Sebastiano Colombo, Massimo Antonelli, Simone Carelli, Domenico L. Grieco, Motohiro Asaki, Kota Hoshino, Leonardo Salazar, Laura Duarte, John Laffey, Bairbre McNicholas, David Cosgrave, Joseph McCaffrey, Allison Bone, Yusuff Hakeem, James Winearls, Mandy Tallott, David Thomson, Christel Arnold-Day, Jerome Cupido, Zainap Fanie, Malcom Miller, Lisa Seymore, Dawid van Straaten, Ali Ait Hssain, Jeffrey Aliudin, Al-Reem Alqahtani, Khoulod Mohamed, Ahmed Mohamed, Darwin Tan, Joy Villanueva, Ahmed Zaqout, Ethan Kurtzman, Arben Ademi, Ana Dobrita, Khadija El Aoudi, Juliet Segura, Gezy Giwangkancana, Shinichiro Ohshimo, Koji Hoshino, Saito Hitoshi, Javier Osatnik, Anne Joosten, Antoni Torres, Minlan Yang, Ana Motos, Carlos Luna, Francisco Arancibia, Virginie Williams, Alexandre Noel, Nestor Luque, Trieu Huynh Trung, Sophie Yacoub, Marina Fantini, Ruth Noemi Jorge García, Enrique Chicote Alvarez, Anna Greti, Adrian Ceccato, Angel Sanchez, Ana Loza Vazquez, Ferran Roche-Campo, Diego Franch-Llasat, Divina Tuazon, Marcelo Amato, Luciana Cassimiro, Flavio Pola, Francis Ribeiro, Guilherme Fonseca, Heidi Dalton, Mehul Desai, Erik Osborn, Hala Deeb, Antonio Arcadipane, Gennaro Martucci, Giovanna Panarello, Chiara Vitiello, Claudia Bianco, Giovanna Occhipinti, Matteo Rossetti, Raffaele Cuffaro, Sung-Min Cho Johns, Hiroaki Shimizu, Naoki Moriyama, Jae-Burm Kim, Nobuya Kitamura, Alyaa Elhazmi, Abdullah Al-Hudaib, Johannes Gebauer, Toshiki Yokoyama, Abdulrahman Al-Fares, Sarah Buabbas, Esam Alamad, Fatma Alawadhi, Kalthoum Alawadi, Hiro Tanaka, Satoru Hashimoto, Masaki Yamazaki, Tak-Hyuck Oh, Mark Epler, Cathleen Forney, Louise Kruse, Jared Feister, Joelle Williamson, Katherine Grobengieser, Eric Gnall, Sasha Golden, Mara Caroline, Timothy Shapiro, Colleen Karaj, Lisa Thome, Lynn Sher, Mark Vanderland, Mary Welch, Sherry McDermott, Matthew Brain, Sarah Mineall, Dai Kimura, Luca Brazzi, Gabriele Sales, Tawnya Ogston, Dave Nagpal, Karlee Fischer, Roberto Lorusso, Mariano Esperatti, Edmund G. Carton, Ayan Sen, Amanda Palacios, Deborah Rainey, Gordan Samoukoviv, Josie Campisi, Emily Neumann, Cassandra Seefeldt, Lucia Durham, Octavio Falcucci, Amanda Emmrich, Jennifer Guy, Carling Johns, Nina Buchtele, Michael Schwameis, Stephanie-Susanne Stecher, Delila Singh, Michaela Barnikel, Lukas Arenz, Akram Zaaqoq, Lan Anh Galloway, Caitlin Merley, Marc Csete, Luisa Quesada, Isabela Saba, Daisuke Kasugai, Hiroaki Hiraiwa, Taku Tanaka, Eva Marwali, Yoel Purnama, Santi Rahayu Dewayanti, Ardiyan, Dafsah Arifa Juzar, Debby Siagian, Kita Jakarta, Yih-Sharng Chen, Mark Ogino, Indrek Ratsep, Getter Oigus, Kristo Erikson, Andra-Maris Post, Lauri Enneveer, Piret Sillaots, Frank Manetta, Effe Mihelis, Iam Claire Sarmiento, Mangala Narasimhan, Michael Varrone, Mamoru Komats, S. Veena Satyapriya, Amar Bhatt, Nahush A. Mokadam, Alberto Uribe, Alicia Gonzalez, Haixia Shi, Johnny McKeown, Joshua Pasek, Juan Fiorda, Marco Echeverria, Rita Moreno, Bishoy Zakhary, Marco Cavana, Alberto Cucino, Giuseppe Foti, Marco Giani, Vincenzo Russotto, Davide Chiumello, Valentina Castagna, Andrea Dell’Amore, Paolo Navalesi, Hoi-Ping Shum, Alain Vuysteke, Asad Usman, Andrew Acker, Benjamin Smood, Blake Mergler, Federico Sertic, Madhu Subramanian, Alexandra Sperry, Nicolas Rizer, Erlina Burhan, Menaldi Rasmin, Ernita Akmal, Faya Sitompul, Navy Lolong, Bhat Naivedh, Simon Erickson, Peter Barrett, David Dean, Julia Daugherty, Antonio Loforte, Irfan Khan, Mohammed Abraar Quraishi, Olivia DeSantis, Dominic So, Darshana Kandamby, Jose M. Mandei, Hans Natanael, Eka YudhaLantang, Anastasia Lantang, Surya Oto Wijaya, Anna Jung, George Ng, Wing Yiu Ng, Pauline Yeung Ng, Alexis Tabah, Megan Ratcliffe, Maree Duroux, Shingo Adachi, Shota Nakao, Pablo Blanco, Ana Prieto, Jesús Sánchez, Meghan Nicholson, Warwick Butt, Alyssa Serratore, Carmel Delzoppo, Pierre Janin, Elizabeth Yarad, Richard Totaro, Jennifer Coles, Bambang Pujo, Robert Balk, Andy Vissing, Esha Kapania, James Hays, Samuel Fox, Garrett Yantosh, Pavel Mishin, Saptadi Yuliarto, Kohar Hari Santoso, Susanthy Djajalaksana, Arie Zainul Fatoni, Masahiro Fukuda, Keibun Liu, Paolo Pelosi, Denise Battaglini, Diego Bastos, Sérgio Gaião, Jessica Buchner, Young-Jae Cho, Su Hwan Lee, Pranya Sakiyalak, Prompak Nitayavardhana, Tamara Seitz, Rakesh Arora, David Kent, Swapnil Parwar, Andrew Cheng, Jennene Miller, Shigeki Fujitani, Naoki Shimizu, Jai Madhok, Clark Owyang, Hergen Buscher, Claire Reynolds, Olavi Maasikas, Aleksan Beljantsev, Vladislav Mihnovits, Takako Akimoto, Mariko Aizawa, Kanako Horibe, Ryota Onodera, Carol Hodgson, Aidan Burrell, Meredith Young, Kiran Shekar, Niki McGuinness, Lacey Irvine, Brigid Flynn, Kazuhiro Sugiyama, Keiki Shimizu, Eddy Fan, Kathleen Exconde, Shingo Ichiba, Leslie Lussier, Gösta Lotz, Lars Maier, Esther Dreier, Neurinda Permata Kusumastuti, Colin McCloskey, Al-Awwab Dabaliz, Tarek B Elshazly, Josiah Smith, Konstanty S. Szuldrzynski, Piotr Bielański, Keith Wille, Srinivas Murthy, Ken Kuljit S. Parhar, Kirsten M. Fiest, Cassidy Codan, Anmol Shahid, Mohamed Fayed, Timothy Evans, Rebekah Garcia, Ashley Gutierrez, Tae Song, Rebecca Rose, Suzanne Bennett, Denise Richardson, Lovkesh Arora, Kristina Rappapport, Kristina Rudolph, Zita Sibenaller, Lori Stout, Alicia Walter, Daniel Herr, Nazli Vedadi, Robert Bartlett, Antonio Pesenti, Shaun Thompson, Lace Sindt, Sean Rajnic, Cale Ewald, Julie Hoffman, Matthew Griffee, Anna Ciullo, Yuri Kida, Ricard Ferrer Roca, JordI Riera, Sofia Contreras, Cynthia Alegre, Christy Kay, Irene Fischer, Elizabeth Renner, Hayato Taniguci, John Fraser, Gianluigi Li Bassi, Jacky Suen, Adrian Barnett, Nicole White, Kristen Gibbons, Simon Forsyth, Amanda Corley, India Pearse, Samuel Hinton, Gabriella Abbate, Halah Hassan, Silver Heinsar, Varun A Karnik, Katrina Ki, Hollier F. O’Neill, Nchafatso Obonyo, Janice D. Reid, Kei Sato, Aapeli Vuorinen, Karin S. Wildi, Emily S. Wood, Stephanie Yerkovich, James Lee, Daniel Plotkin, Laura Merson, Emma Hartley, Bastian Lubis, Takanari Ikeyama, Balu Bhaskar, Jae-Seung Jung, Shay McGuinness, Glenn Eastwood, Sandra Rossi Marta, Fabio Guarracino, Stacy Gerle, Emily Coxon, Bruno Claro, Gonzo Gonzalez-Stawinski, Daniel Loverde, Namrata Patil, Vieri Parrini, Angela McBride, Kathryn Negaard, Angela Ratsch, Ahmad Abdelaziz, Juan David Uribe, Adriano Peris, Mark Sanders, Dominic Emerson, Muhammad Kamal, Pedro Povoa, Roland Francis, Ali Cherif, Sunimol Joseph, Matteo Di Nardo, Micheal Heard, Kimberly Kyle, Ray A Blackwell, Michael Piagnerelli, Patrick Biston, Hye Won Jeong, Reanna Smith, Yogi Prawira, Giorgia Montrucchio, Nadeem Rahman, Vivek Kakar, Josefa Valenzuela Sarrazin, Arturo Huerta Garcia, Nahikari Salterain, Bart Meyns, Marsha Moreno, Rajat Walia, Amit Mehta, Annette Schweda, Moh Supriatna, Bhirowo Yudo, Cenk Kirakli, Melissa Williams, Kyung Hoon Kim, Alexandra Assad, Estefania Giraldo, Wojtek Karolak, Martin Balik, Elizabeth Pocock, Evan Gajkowski, Kanamoto Masafumi, Nicholas Barrett, Yoshihiro Takeyama, Sunghoon Park, Faizan Amin, Fina Meilyana Andriyani, Serhii Sudakevych, Magdalena Vera, Rodrigo Cornejo, Patrícia Schwarz, Ana Carolina Mardini, Ary Serpa Neto, Andrea Villoldo, Alexandre Siciliano Colafranceschi, Alejandro Ubeda, Juan Granjean, Lívia Maria Garcia Melro, Giovana Fioravante Romualdo, Diego Gaia, Helmgton Souza, Filomena Galas, Rafael Máñez Mendiluce, Alejandra Sosa, Ignacio Martinez, Hiroshi Kurosawa, Juan Salgado, Beate Hugi-Mayr, Eric Charbonneau, Vitor Salvatore Barzilai, Veronica Monteiro, Rodrigo Ribeiro de Souza, Michael Harper, Hiroyuki Suzuki, Celina Adams, Jorge Brieva, George Nyale, Faisal Saleem Eltatar, Jihan Fatani, Husam Baeissa, Ayman AL Masri, Ahmed Rabie, Mok Yee Hui, Masahiro Yamane, Hanna Jung, Ayorinde Mojisola, Margaret, Newell Nacpil, Katja Ruck, Rhonda Bakken, Claire Jara, Tim Felton, Lorenzo Berra, Bobby Shah, Arpan Chakraborty, Monika Cardona, Gerry Capatos, Bindu Akkanti, Abiodun Orija, Harsh Jain, Asami Ito, Brahim Housni, Sennen Low, Koji Iihara, Joselito Chavez, Kollengode Ramanathan, Gustavo Zabert, Krubin Naidoo, Ian Seppelt, Marlice VanDyk, Sarah MacDonald, Randy McGregor, Teka Siebenaler, Hannah Flynn, Julia Garcia-Diaz, Catherine Harmon, Kristi Lofton, Toshiyuki Aokage, Kazuaki Shigemitsu, Andrea Moscatelli, Giuseppe Fiorentino, Matthias Baumgaertel, Serge Eddy Mba, Jana Assy, Amelya Hutahaean, Holly Roush, Kay A Sichting, Francesco Alessandri, Debra Burns, Gavin Salt, Carl P. Garabedian, Jonathan Millar, Malcolm Sim, Adrian Mattke, Danny McAuley, Jawad Tadili, Tim Frenzel, Yaron Bar-Lavie, Aaron Blandino Ortiz, Jackie Stone, Antony Attokaran, Michael Farquharson, Brij Patel, Derek Gunning, Kenneth Baillie, Pia Watson, Kenji Tamai, Gede Ketut Sajinadiyasa, Dyah Kanyawati, Marcello Salgado, Assad Sassine, Scott McCaul, Bongjin Lee, Sang Min Lee, Arnon Afek, Yoshiaki Iwashita, Laveena Munshi, Bambang Pujo Semedi, Neurinda Permata, Kusumastuti, Jack Metiva, Nicole Van Belle, Daniel Marino, Ignacio Martin-Loeches, Lenny Ivatt, Chia Yew Woon, Hyun Mi Kang, Timothy Smith, Erskine James, Nawar Al-Rawas, Tomoyuki Endo, Yudai Iwasaki, Kenny Chan King-Chung, Vadim Gudzenko, Fabio Taccone, Fajar Perdhana, Yoan Lamarche, Joao Miguel Ribeiro, Nikola Bradic, Klaartje Van den Bossche, Oude Lansink, Gurmeet Singh, Gerdy Debeuckelaere, Henry T. Stelfox, Cassia Yi, Jennifer Elia, Shu Fang, Thomas Tribble, Shyam Shankar, Raj Padmanabhan, Bill Hallinan, Luca Paoletti, Yolanda Leyva, Tatuma Fykuda, Jenelle Badulak, Jillian Koch, Amy Hackman, Lisa Janowaik, Deb Hernandez, Jennifer Osofsky, Katia Donadello, Aizah Lawang, Josh Fine, Benjamin Davidson, and Andres Oswaldo Razo Vazquez

Subjects
Medical emergencies. Critical care. Intensive care. First aid, RC86-88.9
Abstract

IMPORTANCE:. Factors associated with mortality in coronavirus disease 2019 patients on invasive mechanical ventilation are still not fully elucidated. OBJECTIVES:. To identify patient-level parameters, readily available at the bedside, associated with the risk of in-hospital mortality within 28 days from commencement of invasive mechanical ventilation or coronavirus disease 2019. DESIGN, SETTING, AND PARTICIPANTS:. Prospective observational cohort study by the global Coronavirus Disease 2019 Critical Care Consortium. Patients with laboratory-confirmed coronavirus disease 2019 requiring invasive mechanical ventilation from February 2, 2020, to May 15, 2021. MAIN OUTCOMES AND MEASURES:. Patient characteristics and clinical data were assessed upon ICU admission, the commencement of invasive mechanical ventilation and for 28 days thereafter. We primarily aimed to identify time-independent and time-dependent risk factors for 28-day invasive mechanical ventilation mortality. RESULTS:. One-thousand five-hundred eighty-seven patients were included in the survival analysis; 588 patients died in hospital within 28 days of commencing invasive mechanical ventilation (37%). Cox-regression analysis identified associations between the hazard of 28-day invasive mechanical ventilation mortality with age (hazard ratio, 1.26 per 10-yr increase in age; 95% CI, 1.16–1.37; p < 0.001), positive end-expiratory pressure upon commencement of invasive mechanical ventilation (hazard ratio, 0.81 per 5 cm H2O increase; 95% CI, 0.67–0.97; p = 0.02). Time-dependent parameters associated with 28-day invasive mechanical ventilation mortality were serum creatinine (hazard ratio, 1.28 per doubling; 95% CI, 1.15–1.41; p < 0.001), lactate (hazard ratio, 1.22 per doubling; 95% CI, 1.11–1.34; p < 0.001), Paco2 (hazard ratio, 1.63 per doubling; 95% CI, 1.19–2.25; p < 0.001), pH (hazard ratio, 0.89 per 0.1 increase; 95% CI, 0.8–14; p = 0.041), Pao2/Fio2 (hazard ratio, 0.58 per doubling; 95% CI, 0.52–0.66; p < 0.001), and mean arterial pressure (hazard ratio, 0.92 per 10 mm Hg increase; 95% CI, 0.88–0.97; p = 0.003). CONCLUSIONS AND RELEVANCE:. This international study suggests that in patients with coronavirus disease 2019 on invasive mechanical ventilation, older age and clinically relevant variables monitored at baseline or sequentially during the course of invasive mechanical ventilation are associated with 28-day invasive mechanical ventilation mortality hazard. Further investigation is warranted to validate any causative roles these parameters might play in influencing clinical outcomes.

Published
2021
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32. [Untitled]

Author

Ryota Ono

Subjects
Media Technology, Electrical and Electronic Engineering, Computer Science Applications
Published
2002

33. Magnetically Induced Polarization in Centrosymmetric Bonds.

Author

Igor Solovyev, Ryota Ono, and Nikolaev, Sergey

Subjects
*INDUCED polarization, *SPIN-orbit interactions, *COPPER oxide, *MAGNETS
Abstract

We reveal the microscopic origin of electric polarization → P induced by noncollinear magnetic order. We show that in Mott insulators, such → P is given by all possible combinations of position operators → rij = (→ r0ij, →rij) and transfer integrals tij = (t0ij, tij) in the bonds, where →r0ij and t0ij are spin-independent contributions in the basis of Kramers doublet states, while → rij and tij stem solely from the spin-orbit interaction. Among them, the combination t0ij → rij, which couples to the spin current, remains finite in the centrosymmetric bonds, thus yielding finite → P in the case of noncollinear arrangement of spins. The form of the magnetoelectric coupling, which is controlled by → rij, appears to be rich and is not limited to the phenomenological law → P ∼ ε ij × [ei ×ej] with ε ij being the bond vector connecting the spins ei and ej. Using density-functional theory, we illustrate how the proposed mechanism works in the spiral magnets CuCl2, CuBr2, CuO, and α − Li 2 IrO3, providing a consistent explanation for the available experimental data. [ABSTRACT FROM AUTHOR]

Published
2021
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34. Regulatory and programming foundations for expanding the broadcasting sector in Bhutan : a proposal modelled on Singapore

Author

Thinley Tobgay Dorji., Wee Kim Wee School of Communication and Information, and Ryota Ono

Subjects
Social sciences::Mass media::Media law, ethics and policy [DRNTU]
Abstract

The only established broadcast medium in Bhutan is the national radio. However, other channels of broadcast such as satellite and free-to-air television from neighbouring countries have already started making a mark in several parts of Bhutan. The Internet is also poised to be introduced soon. In order to expand its own broadcasting services for developmental, social and political purposes while containing the excessive infiltration of these channels of broadcast, Bhutan plans to launch a national television station in the near future. ​Master of Mass Communication

Published
1999

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