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Achieving the ideal replacement for robust biological tissues requires biocompatible materials with a nuanced blend of characteristics, including organ specific toughness, durability, self-repairing capability, and a well-defined structure. Hydrogels, structured with high water containing 3D-crosslinked polymeric networks, present a promising avenue in biomedical applications due to their close resemblance to natural tissues. However, their mechanical performance often falls short, limiting their clinical applications. Recent research has been focused on developing biocompatible hydrogel materials for therapeutic applications. Recent advancements have spurred researchers to develop biocompatible hydrogels having acceptable mechanical toughness. While it is now possible to tailor the mechanical properties of synthetic gels to mimic those of natural tissues, critical aspects such as biocompatibility and crosslinking strategies are frequently neglected. This review scrutinizes the structural and crosslinking techniques designed to improve the toughness of hydrogels, focusing especially on innovative efforts to integrate these enhancements into natural-based hydrogels. By thoroughly examining these methodologies, the review sheds light on the complexities of strengthening hydrogels for biomedical applications and will propose valuable insights for the development of next-generation tissue substitutes. [ABSTRACT FROM AUTHOR]

Polypyrrole (PPy)-based nanocomposite materials are of great interest to the scientific community owing to their usefulness in designing state-of-the-art industrial applications, such as fuel cells, catalysts and sensors, energy devices, and especially batteries. However, the commercialization of these materials has not yet reached a satisfactory level of implementation. More research is required for the design and synthesis of PPy-based composite materials for numerous types of battery applications. Due to the rising demand for environmentally friendly, cost-effective, and sustainable energy, battery applications are a significant solution to the energy crisis, utilizing suitable materials like PPy-based composites. Among the conducting polymers, PPy is considered an important class of materials owing to their ease of synthesis, low cost, environmentally friendly nature, and so on. In this context, PPy-based nanocomposites may be very promising due to their nanostructural properties and distinct morphological topography, which are vital concerns for their applications for battery applications. Such features of PPy-based nanocomposites make them particularly promising for next-generation electrode materials. However, the design and fabrication of appropriate PPy-based nanocomposites for battery applications is still a challenging area of research. This review paper describes the current progress on the synthesizing of PPy-based composites for battery applications along with their morphological topography. We discussed here the recent progress on the synthesis of different PPy-based composites, including PPy/S, PPy/MnOx, MWCNT/PPy, V2O5/PPy, Cl-doped PPy/rGO, and Fe/α-MnO2@PPy composites, by a polymerization approach for numerous battery applications. The insights presented in this review aim to provide a comprehensive reference for the future development of PPy-based composites in battery technology. [ABSTRACT FROM AUTHOR]

Biodegradable polymers play an important role in environmental concerns compared to non-biodegradable polymers. Polyvinyl alcohol (PVA) is a biodegradable polymer with film-forming properties with antimicrobial and antioxidant activities and are considered for numerous practical applications in the industry, like food packaging, pharmaceuticals, and so on. The synthesis of PVA with promising properties like rheology, morphology, and mechanical performance is significant from the application point of view in industrial sectors. It is vital to realize the drawbacks and promising prospects associated with PVA rheology, morphology, and mechanical properties and how to address the problems concerning these properties. The present review describes the contemporary advancement of numerous synthesis approaches of PVA-based composite films and their rheology, morphology, and mechanical properties. This comprehensive review offers a comprehensive discussion of various strategies to enhance the rheology, morphology, and mechanical properties of composite films. It emphasizes modifications using environmentally friendly materials such as nanoparticles, metal oxides, polymers, and others. Additionally, existing challenges and the potential for forthcoming advancements in the properties of such composite films are discussed. The correlation between the PVA-based composite films and their promising properties like rheology, morphology, and mechanical performance may provide a reference for new insights into their applications in industrial sectors. [ABSTRACT FROM AUTHOR]

In recent years, numerous applications of hydrogels using polysaccharides have evolved, benefiting from their widespread availability, excellent biodegradability, biocompatibility, and nonpoisonous nature. These natural polymers are typically sourced from renewable materials or from manufacturing processes, contributing collaboratively to waste management and demonstrating the potential for enhanced and enduring sustainability. In the field of novel bioactive molecule carriers for biotherapeutics, natural polymers are attracting attention due to their inherent properties and adaptable chemical structures. These polymers offer versatile matrices with a range of architectures and mechanical properties, while retaining the bioactivity of incorporated biomolecules. However, conventional polysaccharide-based hydrogels suffer from inadequate mechanical toughness with large swelling properties, which prohibit their efficacy in real-world applications. This review offers insights into the latest advancements in the development of diverse polysaccharide-based hydrogels for biotherapeutic administrations, either standalone or in conjunction with other polymers or drug delivery systems, in the pharmaceutical and biomedical fields., Competing Interests: The authors declare no competing financial interest., (© 2024 The Authors. Published by American Chemical Society.)