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Voltametric sensors formed by the combination of a sulfur-substituted zinc phthalocyanine (ZnPc RS ) and gold nanoparticles capped with tetraoctylammonium bromide (AuNP tOcBr ) have been developed. The influence of the nature of the interaction between both components in the response towards catechol has been evaluated. Electrodes modified with a mixture of nanoparticles and phthalocyanine (AuNP tOcBr /ZnPc RS ) show an increase in the intensity of the peak associated with the reduction of catechol. Electrodes modified with a covalent adduct-both component are linked through a thioether bond-(AuNP tOcBr -S-ZnPc R ), show an increase in the intensity of the oxidation peak. Voltammograms registered at increasing scan rates show that charge transfer coefficients are different in both types of electrodes confirming that the kinetics of the electrochemical reaction is influenced by the nature of the interaction between both electrocatalytic materials. The limits of detection attained are 0.9 × 10 -6 mol∙L -1 for the electrode modified with the mixture AuNP tOcBr /ZnPc RS and 1.3 × 10 -7 mol∙L -1 for the electrode modified with the covalent adduct AuNP tOcBr -S-ZnPc R . These results indicate that the establishment of covalent bonds between nanoparticles and phthalocyanines can be a good strategy to obtain sensors with enhanced performance, improving the charge transfer rate and the detection limits of voltammetric sensors.