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Useful materials must satisfy multiple objectives, where the optimization of one objective is often at the expense of another. The Pareto front reports the optimal trade-offs between competing objectives. Here we report a self-driving laboratory, "Ada", that defines the Pareto front of conductivities and processing temperatures for palladium films formed by combustion synthesis. Ada identified previously untested combustion synthesis conditions that resulted in the discovery of lower processing temperatures (below 200 {\deg}C) relative to the prior art for this technique (250 {\deg}C), a temperature difference that makes the coating of different commodity plastic materials possible (e.g., Nafion, polyethersulfone). These conditions enabled us to use combustion synthesis to spray coat uniform palladium films with moderate conductivity (1.1 $\times$ 10$^5$ S m$^{-1}$) at 191 {\deg}C. Spray coating at 226 {\deg}C yielded films with conductivities (2.0 $\times$ 10$^6$ S m$^{-1}$) comparable to those of sputtered films (2.0 to 5.8 $\times$ 10$^6$ S m$^{-1}$). This work shows how self-driving laboratories can discover materials satisfying multiple objectives.

Discovering and optimizing commercially viable materials for clean energy applications typically takes over a decade. Self-driving laboratories that iteratively design, execute, and learn from material science experiments in a fully autonomous loop present an opportunity to accelerate this research. We report here a modular robotic platform driven by a model-based optimization algorithm capable of autonomously optimizing the optical and electronic properties of thin-film materials by modifying the film composition and processing conditions. We demonstrate this platform by using it to maximize the hole mobility of organic hole transport materials commonly used in perovskite solar cells and consumer electronics. This demonstration highlights the possibilities of using autonomous laboratories to discover organic and inorganic materials relevant to materials sciences and clean energy technologies., Comment: 43 pages, 9 figures