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We report a study on the relationship between structure and electron transport properties of nanoscale graphene/pentacene interfaces. We fabricated graphene/pentacene interfaces from 10-30 nm thick needle-like pentacene nanostructures down to two-three layers (2L-3L) dendritic pentacene islands, and we measured their electron transport properties by conductive atomic force microscopy (C-AFM). The energy barrier at the interfaces, i.e. the energy position of the pentacene highest occupied molecular orbital (HOMO) with respect to the Fermi energy of the graphene and the C-AFM metal tip, are determined and discussed with the appropriate electron transport model (double Schottky diode model and Landauer-Buttiker model, respectively) taking into account the voltage-dependent charge doping of graphene. In both types of samples, the energy barrier at the graphene/pentacene interface is slightly larger than that at the pentacene/metal tip interface, resulting in 0.47-0.55 eV and 0.21-0.34 eV, respectively, for the 10-30 nm thick needle-like pentacene islands, and in 0.92-1.44 eV and 0.67-1.05 eV, respectively, for the 2L-3L thick dendritic pentacene nanostructures. We attribute this difference to the molecular organization details of the pentacene/graphene heterostructures, with pentacene molecules lying flat on the graphene in the needle-like pentacene nansotructures, while standing upright in 2L-3L dendritic islands, as observed from Raman spectroscopy., Comment: Paper and its supplementary information

Hybrid van der Waals heterostructures based on 2D materials and/or organic thin films are being evaluated as potential functional devices for a variety of applications. In this context, the graphene/organic semiconductor (Gr/OSC) heterostructure could represent the core element to build future vertical organic transistors based on two back-to-back Gr/OSC diodes sharing a common graphene sheet, which functions as the base electrode. However, the assessment of the Gr/OSC potential still requires a deeper understanding of the charge carrier transport across the interface as well as the development of wafer-scale fabrication methods. This work investigates the charge injection and transport across Au/OSC/Gr vertical heterostructures, focusing on poly(3-hexylthiophen-2,5-diyl) as the OSC, where the PMMA-free graphene layer functions as the top electrode. The structures are fabricated using a combination of processes widely exploited in semiconductor manufacturing and therefore are suited for industrial upscaling. Temperature-dependent current-voltage measurements and impedance spectroscopy show that the charge transport across both device interfaces is injection-limited by thermionic emission at high bias, while it is space charge limited at low bias, and that the P3HT can be assumed fully depleted in the high bias regime. From the space charge limited model, the out-of-plane charge carrier mobility in P3HT is found to be equal to μ ≈ 2.8 × 10

International audience; Among the family of 2D materials, graphene is the ideal candidate as top or interlayer electrode for hybrid van der Waals heterostructures made of organic thin films and 2D materials due to its high conductivity and mobility and its inherent ability of forming neat interfaces without diffusing in the adjacent organic layer. Understanding the charge injection mechanism at graphene/organic semiconductor interfaces is therefore crucial to develop organic electronic devices. In particular, Gr/C60 interfaces are promising building blocks for future n-type vertical organic transistors exploiting graphene as tunneling base electrode in a two back-to-back Gr/C60 Schottky diode configuration. This work delves into the charge transport mechanism across Au/C60/Gr vertical heterostructures fabricated on Si/SiO2 using a combination of techniques commonly used in the semiconductor industry, where a resist-free CVD graphene layer functions as a top electrode. Temperature-dependent electrical measurements show that the transport mechanism is injection limited and occurs via Fowler–Nordheim tunneling at low temperature, while it is dominated by a nonideal thermionic emission at room and high temperatures, with energy barriers at room temperature of ca. 0.58 and 0.65 eV at the Gr/C60 and Au/C60 interfaces, respectively. Impedance spectroscopy confirms that the organic semiconductor is depleted, and the energy band diagram results in two electron blocking interfaces. The resulting rectifying nature of the Gr/C60 interface could be exploited in organic hot electron transistors and vertical organic permeable-base transistors.

Hybrid graphene-colloidal PbS quantum dots (QDs) phototransistors are promising to overcome the geometrical restrictions of photodetectors to flat substrates. While compatible with conformal manufacturing, the experimental demonstration of their application to curved surfaces remains elusive. This work demonstrates the seamless integration of an infrared (IR) photodetector to a polymer optical fiber (POF) by wrapping graphene around the POF of 1 mm in diameter and, subsequently, inkjet printing of PbS QDs onto the curved surface. The device acts as a functional coating and detects infrared light propagating through the POF without interrupting the waveguide. The formulated α-terpineol and hexane co-solvent ink supports drop-on-demand placement with a resolution of 50 µm and is colloidally stable over 7 months. A responsivity map over gate voltage and temperature (300 to 80 K) of a device, fabricated on a common flat substrate, reveals a responsivity of R ≈ 1 × 10³AW⁻¹ (irradiance ≈1 µW cm⁻²) and a detectivity of D* ≈ 1 × 10¹⁰ Jones at 1.6 µm wavelength. This work brings the integration of this cost-effective and adaptable hybrid detector approach closer to multifunctional e-textiles and will, notably, help to improve the interfacing of the skin as desired for wearable and non-invasive healthcare applications., Advanced Materials Technologies, 8 (9), ISSN:2365-709X

Ultrasonic, non-contact defect detection for polymer pipes can provide an easy and reliable method to establish on site quality control without destructive mechanical testing and finally may help to prevent damage from leaking pipes. The target is to inspect thin walled polymer pipes made of PVDF and PP with small defects in the pipe wall. Air coupled transducers with a nominal frequency of 200 kHz are used to excite Lamb waves in the pipe wall that interact with potential defects. A reference measurement on a flawless part of the pipe helps to mitigate the effects of geometrical and material inhomogeneities. The possibility to excite only the A0 Lamb wave mode in thin plates and pipes using air coupled transducers is shown. Defects attenuate the propagating Lamb waves, resulting in a characteristic pattern in the receiver signal. Simulations on the Lamb wave propagation help to identify the dispersion parameters and allow to understand the effect of defects better. The detection of defects is challenging because of other imperfections in the specimen. With a reference measurement the detection of defects down to a size of 1 mm is possible.

Polymer light-emitting electrochemical cells (PLECs) and light-emitting diodes (PLEDs) receive interest for large-area lighting and signage applications. During operation of a PLEC, a p-i-n junction develops where electrons and holes are injected into the film and are transported along n- and p-doped regions to the intrinsic (i) region, where they recombine under light emission. Conceptually, this resembles the PLED device architecture equipped with Ohmic charge-injection and transport layers. The similarity between the i-region of the PLEC and the emissive layer of the PLED is obvious; however, implication of this has not been examined in detail so far. For example, for PLEDs it is known that electron traps hinder the electron transport, and that hole trap formation dictates the long-term durability. Here, for PLECs the electrical and optical response to electrical driving and breaks are studied, the current response to external light irradiation is probed, and degradation is followed with long-term absorption and capacitance measurements. The electron traps in PLECs are identified and it is found that hole trap formation limits the device lifetime, in the same manner as established for PLEDs. It is concluded that charge traps in semiconducting polymers present important, but so far overlooked intrinsic performance limitations for PLECs.

Graphene nanogaps are considered as essential building blocks of two-dimensional electronic circuits, as they offer the possibility to interconnect a broad range of atomic-scale objects. Here we provide an insight into the microscopic processes taking place during the formation of graphene nanogaps through the detailed analysis of their low-frequency noise properties. Following the evolution of the noise level, we identify the fundamentally different regimes throughout the nanogap formation. By modeling the resistance and bias dependence of the noise, we resolve the major noise-generating processes: atomic-scale junction-width fluctuations in the nanojunction regime and sub-atomic gap-size fluctuations in the nanogap regime. As a milestone toward graphene-based atomic electronics, our results facilitate the automation of an optimized electrical breakdown protocol for high yield graphene nanogap fabrication., npj 2D Materials and Applications, 5 (1), ISSN:2397-7132

Atomically precise graphene nanoribbons (GNRs) are a promising emerging class of designer quantum materials with electronic properties that are tunable by chemical design. However, many challenges remain in the device integration of these materials, especially regarding contacting strategies. We report on the device integration of uniaxially aligned and non-aligned 9-atom wide armchair graphene nanoribbons (9-AGNRs) in a field-effect transistor geometry using electron beam lithography-defined graphene electrodes. This approach yields controlled electrode geometries and enables higher fabrication throughput compared to previous approaches using an electrical breakdown technique. Thermal annealing is found to be a crucial step for successful device operation resulting in electronic transport characteristics showing a strong gate dependence. Raman spectroscopy confirms the integrity of the graphene electrodes after patterning and of the GNRs after device integration. Our results demonstrate the importance of the GNR-graphene electrode interface and pave the way for GNR device integration with structurally well-defined electrodes.

In this work, we model ACU transmission in delaminations, with focus in the interference effects resulting from multiple ultrasonic reflections within the delamination layers and the resulting changes in the amplitude and time of flight. For this purpose, we propose a simplified analytical model, which we cross-validate with full-wave finite-difference time-domain (FDTD) simulations. Both models show a very high agreement on the predicted ultrasound waveforms, with amplitude deviations less than 0.15 dB and time deviations below 0.1 μs. The reduction of ultrasound signal amplitude at debonding was validated with experiments. A simple engineering formula in function of delamination gap and transducer frequency was sufficient to model experimental transmission values for a gap thickness range from 70 to 2000 μm with an uncertainty below 2 dB. Furthermore, consistent resonance frequencies were identified in both experiments and simulations. The use of pulsed ultrasound signals reduces undesired resonances and provides a consistent amplitude reduction across the full range of delamination gaps. Apart from interference effects, the effect of the finite size of the ultrasound transducers as well as diffraction effects were empirically investigated. As a result of these, the lateral resolution is reduced and the sound tends to propagate through the bonded region next to the delamination. Diffraction effects are strongly influenced by wood anisotropy, with lower lateral resolution in the grain direction.

This study presents an investigation of the heat transfer characteristics of the urea-water spray (UWS) impingement on a stainless steel plate under typical diesel exhaust flow conditions. The rear side temperature of the spray-impinged plate has been measured by infrared thermography with high temporal and spatial resolution. The spray impinged side temperature and heat flux distributions have been computed by solving the 3D inverse heat conduction in the plate with the sequential function specification method. Measurements show that the instantaneous plate temperature determines the heat transferred during the spray impingement. Based on the plate temperature, different regimes (film boiling, transition boiling and nucleate boiling) have been identified. At high plate temperatures, film boiling and Leidenfrost effect are prevailing and the heat transferred from the plate to the liquid is low. With decreasing plate temperatures, the critical heat flux regime is approached and the heat transferred increases substantially. At lower plate temperatures, nucleate boiling occurs limiting the heat transferred to low values. The critical heat flux and temperature found for UWS are reported and in good agreement with the trend in previous studies for water.

By a customer providing industry electronics, we were faced to repeated failures of a small power transistor. However, nearly all samples were burnt and no conclusion could be drawn from device analysis. We took the next step forward towards system analysis. The electronic board with the transistor was mounted at the end of a big solenoid. The metal baseplate of the board holder also served as a heatsink for the power transistor. The board was mounted into a plastic housing, which has been damaged in many cases. It turned out that, when the big solenoid's core was running against its mechanical end stop, the mechanical impulse knocked the electronic board to the end of the plastic housing, thus deforming the heatsink plate in a manner that it lost the thermal contact to the transistor after some time of use. In result, the transistor overheated and failed. This case study is a nice example showing the need of a system-related failure analysis for root-cause finding.

This study presents an experimental investigation of the heat transfer characteristics of the spray/wall interaction in diesel selective catalytic reduction (SCR) systems. The work was performed with a commercial 3-Hole pressure-driven injector dosing into a flow channel under typical diesel exhaust flow conditions. Infrared thermography captured the surface temperature of the wall around the impingement area with high temporal and spatial resolution. The resulting temperatures have been used for assessing the heat extracted from the wall. Phase Doppler Anemometry (PDA) was applied to measure the droplet sizes and velocities prior to the wall impingement, providing information on the kinetic properties of the impinging droplets. Based on these, the influence of the gas flow conditions on the heat transfer characteristics is deduced. The spray impingement leads to a substantial and rapid temperature drop on the wall, resulting in a maximum heat flux of several MW/m2 during the injection duration. The spray cooling effect decreases with increasing exhaust gas flow rate due to the increased entrainment of spray droplets in the flow prior to impingement. Increase in gas flow temperature affects the heat transfer by increasing the wall temperature. At lower wall temperatures, the principal spray/wall interaction regime is deposition. With increasing wall temperature, there is a shift to rebound and thermal breakup. The shorter contact times in the rebound and thermal breakup regimes result in decreased spray/wall heat transfer.

This study investigates the application of air-coupled ultrasonics for nondestructive, non-contact characterization of polymer and polymer-matrix composite samples. A lot of progress has been made with this technique which does not require any liquid couplant, hence water sensitive samples can be studied without deterioration. We demonstrate the power of highly focused transducers for topography imaging of structured polymer surfaces such as a craquelure, fingerprint or an acoustic lens with a lateral resolution up to 0.1 mm and an elevation resolution of 2 μm. With a further technique, transmission resonance, the thickness of plates can be imaged with a resolution of 3 μm. Air-coupling is also used for checking the integrity of a polymer-matrix composite plate, revealing invisible internal impact damage. Finally, a single-sided Lamb-wave technique is used to detect sub-wavelength artificial defects such as notches and through-holes in plates.

Air-coupled ultrasound (ACU) is increasingly used for nondestructive testing (NDT). With ACU, no contact or coupling agent (e.g., water and ultrasound gel) is needed between transducers and test sample, which provides high measurement reproducibility. However, for testing in production, a minimum separation is often necessary between the sample and the transducers to avoid contamination or transducer damage. Due to wave diffraction, the collimation of the ultrasound beam decreases for larger propagation distances, and ACU images become blurred and show lower defect lateral resolution with increasing sample–transducer separation. This is especially critical to thick composites, where large-size planar sources are used to bridge the large ACU transmission loss with good collimation. In this work, ACU reradiation in unbounded media is extended to NDT of multilayered composites. The extended method is named ACU time reversal (ACU-TR) and significantly improves the defect resolution of ACU imaging. With ACU-TR, the complete pressure distribution radiated by large ACU source is measured with point receivers (RXs) in one plane arbitrarily separated from the sample. By applying acoustic holography physics, it is then possible to quantitatively reconstruct the pressure field directly at arbitrary sample defect planes, which compensates for undesired diffraction phenomena and improves minimum detectable defect size, thereby achieving subwavelength lateral resolution. We tested the method on complex wood-based composite samples based on the ACU far-field measurements at a separation of 160 mm between the sample and the RX transducer. With the proposed method, it is possible to detect surface defects as well as inner defects within composite boards. In the future, by using point RX arrays instead of a scanned microphone, both data acquisition and evaluation can be potentially implemented in real time.

Quantitative and reproducible air-coupled ultrasound (ACU) testing requires characterization of the volumetric pressure fields radiated by ACU probes. In this paper, a closed-form reradiation method combining the Rayleigh–Sommerfeld integral and time-reversal acoustics is proposed, which allows calculation of both near- field and far-field based on a single-plane measurement. The method was validated for both 3-D (circular, square) and 2-D (rectangular) planar transducers in the 50–230 kHz range. The pressure fields were scanned with a calibrated microphone. The measurement window was at least four times the size of the transducer area and the grid step size was one third of the wavelength. Best results were observed by acquiring the measurement plane at near-field distance. The method accurately reproduces pulsed ultrasound waveforms and pressure distributions (RMSE

Reactive nano-multilayers (RNMLs), which are able to undergo a self-heating exothermal reaction, can, e.g., be utilised as a local heat source for soldering or brazing. Upon joining with RNMLs, the heat produced by the exothermal reaction must be carefully adjusted to the joining system in order to provide sufficient heat for bond formation while avoiding damaging of the joining components by excessive heat. This heat balance strongly depends on the thermal properties of the joining components: a low thermal conductivity leads to heat concentration within the joining zone adjacent to the RNML, while a high thermal conductivity leads to fast heat dissipation into the components. The quality of the joint is thus co-determined by the thermal properties of the joining components. This work provides a systematic study on the influence of the thermal properties upon reactive joining for a set of substrate materials with thermal conductivities ranging from very low to very high. In particular, the evolution of the microstructure within the joining zone as a function of the specific time-temperature-profile for the given component material is investigated, focusing on the interaction between solder, RNML foil and surface metallisations, and the associated formation of intermetallic phases. Finally, the specific microstructure of the joints is related to their mechanical performance upon shear testing, and suggestions for optimum joint design are provided.

The goal of the current study was to investigate the physical and mechanical properties of mycowood as a high quality tone-wood, obtained from Norway spruce by treatment of the white rot fungus Physisporinus vitreus as a function of the treatment time. In focus was the stiffness to weight ratio, which is often considered a main criterion for tone-wood selection. The vibro-mechanical properties were tested by non-destructive methods. The change of color and density were also measured after 4–12 months of fungal incubation. Density decreased up to 5% after 12 months of fungal treatment. Sound velocity was measured in small size specimens by means of the free-free vibration approach, while in large specimens the air-coupled ultrasound method was applied. The two techniques gave similar results and indicated that the sound velocity decreased in mycowood. Internal damping was increased in mycowood to a higher extent than the reduction in the specific modulus of elasticity (E/ρ) and thus the sound velocity in the material. The sound velocity was decreasing with increasing incubation times and scattering of data with this regard was larger in the transversal than in the longitudinal direction. The sound radiation coefficient and the characteristic impedance were enhanced in mycowood and its color was more brownish and richer in tone., Holzforschung, 70 (6), ISSN:0018-3830, ISSN:1437-434X

Reliable non-destructive testing (NDT) ultrasound systems for timber composite structures require quantitative understanding of the propagation of ultrasound beams in wood. A finite-difference time-domain (FDTD) model is described, which incorporates local anisotropy variations of stiffness, damping and density in timber elements. The propagation of pulsed air-coupled ultrasound (ACU) beams in normal and slanted incidence configurations is reproduced by direct definition of material properties (gas, solid) at each model pixel. First, the model was quantitatively validated against analytical derivations. Time-varying wavefronts in unbounded timber with curved growth rings were accurately reproduced, as well as the acoustic properties (velocity, attenuation, beam skewing) of ACU beams transmitted through timber lamellas. An experimental sound field imaging (SFI) setup was implemented at NDT frequencies (120 kHz), which for specific beam incidence positions allows spatially resolved ACU field characterization at the receiver side. The good agreement of experimental and modeled beam shifts across timber laminates allowed extrapolation of the inner propagation paths. The modeling base is an orthotropic stiffness dataset for the desired wood species. In cross-grain planes, beam skewing leads to position-dependent wave paths. They are well-described in terms of the growth ring curvature, which is obtained by visual observation of the laminate. Extraordinary refraction phenomena were observed, which lead to well-collimated quasi-shear wave coupling at grazing beam incidence angles. The anisotropic damping in cross-grain planes is satisfactorily explained in terms of the known anisotropic stiffness dataset and a constant loss tangent. The incorporation of high-resolution density maps (X-ray computed tomography) provided insight into ultrasound scattering effects in the layered growth ring structure. Finally, the combined potential of the FDTD model and the SFI setup for material property and defect inversion in anisotropic materials was demonstrated. A portable SFI demonstrator was implemented with a multi-sensor MEMs receiver array that captures and compensates for variable wave propagation paths in glued laminated timber, and improves the imaging of lamination defects.

The objective of this chapter is to provide an overview of novel non-destructive testing methodologies for bonding quality assessment in glued laminated timber developed within a recently completed Swiss National Science Foundation research project (Sanabria, 2012). The focus is set on air-coupled ultrasound testing, which has previously been applied to wood-based panels typically up to 50 mm thick. A novel prototype capable of transmitting ultrasound signals through up to 500 mm thick glulam was developed. A computerized-scanning system allowed imaging of the position and geometry of defects within the bonding planes. A normal transmission setup allows a global assessment of defective bonding planes stacks. Latest results are as well shown for a recently patented slanted lateral transmission setup, which allows separate assessment of individual bonding planes with unlimited beam height and length. The investigations allowed an improved understanding of the wave propagation phenomena in thick laminated timber components through both analytical calculations and finite-difference numerical simulations. An overview of the main findings is as well provided. Future research is planned to combine the developed theoretical and experimental tools in a tomographic inspection method.

Non-destructive assessment of delaminations in glued laminated timber structures is required during their full life cycle. A novel air-coupled ultrasound (ACU) method has been developed, which is able to separately detect delaminations in individual bonding planes of arbitrarily high and long laminated stacks and typically 200 mm wide. The 120 kHz ACU transmitter–receiver pair is positioned at two opposite lateral faces of the sample, with a small inclination with respect to the inspected bonding planes, so that an ultrasound beam is excited at a user-defined refraction angle within the sample, interacting with defects in a limited height portion of the stack. The attenuation of the ultrasound beam transmitted across the defect (negative detection) provided better sensitivity to defects than the scattered fields (positive detection), which are masked by spurious fields. Dedicated finite-difference time-domain (FDTD) simulations provided understanding on the wave propagation and defect detectability limits, with respect to the heterogeneous anisotropic material structure introduced by the curvature of the annual rings in individual timber lamellas. A simplified analytical expression was derived to calculate refraction angles in timber in function of insonification angle and ring angle. Experimental results show that the method is able to detect >20% wide defects in both isotropic material and in glulam with straight year rings, and >50% wide and 100 mm long defects in commercial glulam beams. The discrimination of defects from background variability is optimized by normalizing the images with respect to reference defect-free sample sections (normalization) or previous measurements (difference imaging), and by combining readings obtained with distinct ultrasound beam refraction angles (spatial diversity). Future work aims at the development of a tomographic defect inspection by combining the described theoretical and experimental methods.

Holzforschung, 65 (3), ISSN:0018-3830, ISSN:1437-434X

Non-destructive assessment of glulam laminations is necessary in order to prevent security hazards. Air-coupled ultrasound (ACU) is sensitive to delamination, reproducible and allows for high scanning resolution. In this work we developed a novel ACU imaging system in normal transmission for inspection of up to 280 mm high glulam. The coupling and propagation of ACU waves in glulam were investigated with plane wave theory applied to an orthotropic model of wood as a function of grain and ring angles. Finite Difference Time Domain (FDTD) simulations were also carried out. The systematic amplitude heterogeneity in defect-free regions was linked to energy flux shifts and mode conversion phenomena, and compensated for in the images. Specific amplitude tracking and difference imaging algorithms allowed successful imaging of bonding and saw cut defects.

The joining of macroscopic films of vertically aligned multiwalled carbon nanotubes (CNTs) to titanium substrates is demonstrated by active vacuum brazing at 820 °C with a Ag–Cu–Ti alloy and at 880 °C with a Cu–Sn–Ti–Zr alloy. The brazing methodology was elaborated in order to enable the production of highly electrically and thermally conductive CNT/metal substrate contacts. The interfacial electrical resistances of the joints were measured to be as low as 0.35 Ω. The improved interfacial transport properties in the brazed films lead to superior electron fieldemission properties when compared to the as-grown films. An emission current of 150 μA was drawn from the brazed nanotubes at an applied electric field of 0.6 V μm−1. The improvement in electron field-emission is mainly attributed to the reduction of the contact resistance between the nanotubes and the substrate. The joints have high re-melting temperatures up to the solidus temperatures of the alloys; far greater than what is achievable with standard solders, thus expanding the application potential of CNT films to high-current and high-power applications where substantial frictional or resistive heating is expected

This work reports on a method to open nanoscale gaps in h-shaped graphene nano-constrictions by electrical breakdown at room temperature and pressure below 10−5 mbar. The method was validated on 275 devices, fabricated on eight different chips, using Chemical Vapor Deposition (CVD)-grown graphene from in-house production and from two commercial sources. The gap width was estimated by fitting the I–V traces after electrical breakdown with the Simmons model for the intermediate-voltage range. The statistics on the collected data demonstrates that the method results in normally distributed nanoscale gaps in h-shaped graphene nano-constrictions, with an estimated average width centered around 1 nm and a gap fabrication yield of 95%.