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The goal of this paper is to determine the respective importance of solid state vs. gas phase reactions for the formation of dimethyl ether. This is done by a detailed analysis of the excitation properties of the ground state and the torsionally excited states, v11=1 and v15=1, toward the high-mass star-forming region G327.3-0.6. With the Atacama Pathfinder EXperiment 12 m submillimeter telescope, we performed a spectral line survey. The observed spectrum is modeled assuming local thermal equilibrium. CH3OCH3 has been detected in the ground state, and in the torsionally excited states v11=1 and v15=1, for which lines have been detected here for the first time. The emission is modeled with an isothermal source structure as well as with a non-uniform spherical structure. For non-uniform source models one abundance jump for dimethyl ether is sufficient to fit the emission, but two components are needed for the isothermal models. This suggests that dimethyl ether is present in an extended region of the envelope and traces a non-uniform density and temperature structure. Both types of models furthermore suggest that most dimethyl ether is present in gas that is warmer than 100 K, but a smaller fraction of 5%-28% is present at temperatures between 70 and 100 K. The dimethyl ether present in this cooler gas is likely formed in the solid state, while gas phase formation probably is dominant above 100 K. Finally, the v11=1 and v15=1 torsionally excited states are easily excited under the density and temperature conditions in G327.3-0.6 and will thus very likely be detectable in other hot cores as well., Comment: 12 pages (excluding appendices), 8 figures, A&A in press

The physical structure of hot molecular cores, where forming massive stars have heated up dense dust and gas, but have not yet ionized the molecules, poses a prominent challenge in the research of high-mass star formation and astrochemistry. We aim at constraining the spatial distribution of density, temperature, velocity field, and chemical abundances in the hot molecular core G10.47+0.03. With the Submillimeter Array (SMA), we obtained high spatial and spectral resolution of a multitude of molecular lines at different frequencies, including at 690 GHz. At 345 GHz, our beam size is 0.3", corresponding to 3000 AU. We analyze the data using the three-dimensional dust and line radiative transfer code RADMC-3D, and myXCLASS for line identification. We find hundreds of molecular lines from complex molecules and high excitations. Even vibrationally excited HC15N at 690 GHz is detected. The HCN abundance at high temperatures is very high. Absorption against the dust continuum occurs in twelve transitions, whose shape implies an outflow along the line-of-sight. Outside the continuum peak, the line shapes are indicative of infall. Dust continuum and molecular line emission are resolved at 345 GHz, revealing central flattening and rapid radial falloff of the density outwards of 10^4 AU, best reproduced by a Plummer radial profile of the density. No fragmentation is detected, but modeling of the line shapes of vibrationally excited HCN suggests the density to be clumpy. We conclude that G10.47+0.03 is characterized by beginning of feedback from massive stars, while infall is ongoing. Large gas masses (hundreds of Msun) are heated to high temperatures, aided by diffusion of radiation in a high-column-density environment. The increased thermal, radiative, turbulent, and wind-driven pressure drives expansion in the central region and is likely responsible for the central flattening of the density., Comment: 22 pages, 22 figures, accepted for publication in A&A

Massive stars form deeply embedded in dense molecular gas, which they stir and heat up and ionize. During an early phase, the ionization is confined to hypercompact HII regions, and the stellar radiation is entirely absorbed by dust, giving rise to a hot molecular core. To investigate the innermost structure of such high-mass star-forming regions, we observed vibrationally excited HCN (via the direct $\ell$-type transition of v2=1, $\Delta J$=0, J=13, which lies 1400 K above ground) toward the massive hot molecular cores G10.47+0.03, SgrB2-N, and SgrB2-M with the Very Large Array (VLA) at 7 mm, reaching a resolution of about 1000 AU (0.1"). We detect the line both in emission and in absorption against HII regions. The latter allows to derive lower limits on the column densities of hot HCN, which are several times $10^{19}$ cm$^{-2}$. We see indication of expansion motions in G10.47+0.03 and detect velocity components in SgrB2-M at 50, 60, and 70 km/s relative to the Local Standard of Rest. The emission originates in regions of less than 0.1 pc diameter around the hypercompact HII regions G10.47+0.03 B1 and SgrB2-N K2, and reaches brightness temperatures of more than 200 K. Using the three-dimensional radiative transfer code RADMC-3D, we model the sources as dense dust cores heated by stars in the HII regions, and derive masses of hot (>300 K) molecular gas of more than 100 solar masses (for an HCN fractional abundance of 10$^{-5}$), challenging current simulations of massive star formation. Heating only by the stars in the HII regions is sufficient to produce such large quantities of hot molecular gas, provided that dust is optically thick to its own radiation, leading to high temperatures through diffusion of radiation., Comment: 12 pages, 14 figures, accepted for publication in A&A

To investigate the accretion and feedback processes in massive star formation, we analyze the shapes of emission lines from hot molecular cores, whose asymmetries trace infall and expansion motions. The high-mass star forming region SgrB2(M) was observed with Herschel/HIFI (HEXOS key project) in various lines of HCN and its isotopologues, complemented by APEX data. The observations are compared to spherically symmetric, centrally heated models with density power-law gradient and different velocity fields (infall or infall+expansion), using the radiative transfer code RATRAN. The HCN line profiles are asymmetric, with the emission peak shifting from blue to red with increasing J and decreasing line opacity (HCN to H$^{13}$CN). This is most evident in the HCN 12--11 line at 1062 GHz. These line shapes are reproduced by a model whose velocity field changes from infall in the outer part to expansion in the inner part. The qualitative reproduction of the HCN lines suggests that infall dominates in the colder, outer regions, but expansion dominates in the warmer, inner regions. We are thus witnessing the onset of feedback in massive star formation, starting to reverse the infall and finally disrupting the whole molecular cloud. To obtain our result, the THz lines uniquely covered by HIFI were critically important., Comment: A&A, HIFI special issue, accepted

Observations of HDO are an important complement for studies of water, because they give strong constraints on the formation processes -- grain surfaces versus energetic process in the gas phase, e.g. in shocks. The HIFI observations of multiple transitions of HDO in Sgr~B2(M) presented here allow the determination of the HDO abundance throughout the envelope, which has not been possible before with ground-based observations only. The abundance structure has been modeled with the spherical Monte Carlo radiative transfer code RATRAN, which also takes radiative pumping by continuum emission from dust into account. The modeling reveals that the abundance of HDO rises steeply with temperature from a low abundance ($2.5\times 10^{-11}$) in the outer envelope at temperatures below 100~K through a medium abundance ($1.5\times 10^{-9}$) in the inner envelope/outer core, at temperatures between 100 and 200~K, and finally a high abundance ($3.5\times 10^{-9}$) at temperatures above 200~K in the hot core., Comment: A&A HIFI special issue, accepted

We have analyzed sensitive high spatial resolution archival radio continuum data at 1.3, 2.0, 3.6 and 6.0 cm as well as the H2O maser molecular line data obtained using the Very Large Array (VLA) in its hybrid AB configuration toward the high-mass star-forming region IRAS 17233-3606 (G351.78-0.54). We find nine compact radio sources associated with this region, six of them are new radio detections. We discuss the characteristics of these sources based mostly on their spectral indices and find that most of them appear to be optically thin or thick ultra- and hyper-compact HII regions ionized by B ZAMS stars. Furthermore, in a few cases the radio emission may arise from optically thick dusty disks and/or cores, however more observations at different wavelengths are necessity to firmly confirm their true nature. In addition, we compared our centimeter maps with the mid-infrared images fromthe Spitzer Space Observatory GLIMPSE survey revealing a cluster of young protostars in the region together with multiple collimated outflows some of whom might be related with the compact centimeter objects., Comment: Accepted by The Astronomical Journal

We present APEX observations of HCN (9-8) and (4-3) lines toward a sample of hot cores. The spectral shapes of the main transitions are asymmetric and self-absorbed, as expected for high optical depth in a possibly infalling envelope. For spherical symmetry, the large column densities of these sources would mean that the central region is obscured by dust above a certain frequency. However, we detected the vibrationally excited satellite lines (v_2=1; J=9-8) at 797 GHz, which originate from the inner regions. This indicates that high-frequency ALMA observations of hot core centers will be feasible., Comment: 4 pages, 3 figures, to appear in "Science with ALMA: a new era for Astrophysics" Conference Proceedings (to be published by Springer "Astrophysics and Space Science (ApSS)")