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We report on the far-infrared, temperature-dependent optical properties of a CrI3 transition metal halide single crystal, a van der Waals ferromagnet (FM) with a Curie temperature of 61 K. In addition to the expected phonon modes determined by the crystalline symmetry, the optical reflectance and transmittance spectra of CrI3 single crystals show many other excitations as a function of temperature as a consequence of the combination of a strong lattice anharmonicity and spin–phonon coupling. This complex vibrational spectrum highlights the presence of entangled interactions among the different degrees of freedom in CrI3.

Neutral silicon vacancy centers (SiV0) in diamond are promising candidates for quantum networks because of their long spin coherence times and stable, narrow optical transitions. However, stabilizing SiV0 requires high purity, boron doped diamond, which is not a readily available material. Here, we demonstrate an alternative approach via chemical control of the diamond surface. We use low-damage chemical processing and annealing in a hydrogen environment to realize reversible and highly stable charge state tuning in undoped diamond. The resulting SiV0 centers display optically detected magnetic resonance and bulk-like optical properties. Controlling the charge state tuning via surface termination offers a route for scalable technologies based on SiV0 centers, as well as charge state engineering of other defects.

We synthesize and characterize the magnetic and thermodynamic properties of the quasi one-dimensional organic-inorganic hybrid ANiCl

IrTe2I and RhTe2I were prepared by high-pressure synthesis, with a non-centrosymmetric, non-symmorphic, layered structure. Characterization reveals their diamagnetic, semiconducting behavior.

Electronic structure calculations indicate that the Sr2FeSbO6 double perovskite has a flat-band set just above the Fermi level that includes contributions from ordinary sub-bands with weak kinetic electron hopping plus a flat sub-band that can be attributed to the lattice geometry and orbital interference. To place the Fermi energy in that flat band, electron doped samples with formulas Sr2-xLaxFeSbO6 (0 < x < 0.3) were synthesized and their magnetism and ambient temperature crystal structures determined by high-resolution synchrotron X-ray powder diffraction. All materials appear to display an antiferromagnetic-like maximum in the magnetic susceptibility, but the dominant spin coupling evolves from antiferromagnetic to ferromagnetic on electron doping. Which of the three sub-bands or combinations is responsible for the behavior has not been determined., 31 pages, 8 figures

Geometrically frustrated lattices combined with magnetism usually host quantum fluctuations that suppress magnetic orders and generate highly entangled ground states. Three-dimensionally (3D) frustrated magnets generally exist in the diamond and pyrochlore lattices, while two-dimensionally (2D) frustrated geometries contain Kagomé, triangular, and honeycomb lattices. In this work, we reported using chemical pressure to tune the magnetism of the pyrochlore lattice in LiYbSe

In two-dimensional (2D) NbSe2 crystal, which lacks inversion symmetry, strong spin-orbit coupling aligns the spins of Cooper pairs to the orbital valleys, forming Ising Cooper pairs (ICPs). The unusual spin texture of ICPs can be further modulated by introducing magnetic exchange. Here, we report unconventional supercurrent phase in van der Waals heterostructure Josephson junctions (JJs) that couples NbSe2 ICPs across an atomically thin magnetic insulator (MI) Cr2Ge2Te6. By constructing a superconducting quantum interference device (SQUID), we measure the phase of the transferred Cooper pairs in the MI JJ. We demonstrate a doubly degenerate nontrivial JJ phase (ϕ), formed by momentum-conserving tunneling of ICPs across magnetic domains in the barrier. The doubly degenerate ground states in MI JJs provide a two-level quantum system that can be utilized as a new dissipationless component for superconducting quantum devices. Our work boosts the study of various superconducting states with spin-orbit coupling, opening up an avenue to designing new superconducting phase-controlled quantum electronic devices. Van der Waals structures provide a new platform to explore novel physics of superconductor/ferromagnet interfaces. Here, NbSe2 Josephson junction with Cr2Ge2Te6 enables non-trivial Josephson phase by spin-dependent interaction, boosting the study of superconducting states with spin-orbit coupling and phase-controlled quantum electronic device.

We describe the crystal structure and elementary magnetic properties of a previously unreported ternary intermetallic compound, Cr4PtGa17, which crystallizes in a rhombohedral unit cell in the noncentrosymmetric space group R3m. The crystal structure is closely related to those of XYZ half-Heusler compounds, where X, Y and Z are reported to be single elements only, occupying three different face-centered cubic sublattices. The new material, Cr4PtGa17, can be most straightforwardly illustrated by writing the formula as (PtGa2)(Cr4Ga14)Ga (X=PtGa2, Y = Cr4Ga14, Z = Ga), that is, the X and Y sites are occupied by clusters instead of single elements. The magnetic Cr occupies a breathing pyrochlore lattice. Ferromagnetic ordering is found below TC ~61 K, by both neutron diffraction and magnetometer studies, with a small, saturated moment of ~0.25 muB/Cr observed at 2 K, making Cr4PtGa17 the first ferromagnetically ordered material with a breathing pyrochlore lattice. A magnetoresistance of ~140% was observed at 2 K. DFT calculations suggest that the material has a nearly-half-metallic electronic structure. The new material, Cr4PtGa17, the first realization of both a half-Heusler-type structure and a breathing pyrochlore lattice, might pave a new way to achieve novel types of half-Heusler compounds., 26 pages, 6 figures, 3 tables

In lead(II) halide compounds including virtually all lead halide perovskites, the Pb2+ 6s lone pair results in distorted octahedra, in accordance with the pseudo-Jahn-Teller effect, rather than generating hemihedral coordination polyhedra. Here, in contrast, we report the characterization of an organic-inorganic hybrid material consisting of one-dimensional edge-sharing chains of Pb-Br square pyramids, separated by [Mn(DMF)6]2+ (DMF = dimethylformamide) octahedra. Molecular orbital analysis and density-functional theory calculations indicate that square pyramidal coordination about Pb2+ results from the occupancy of the empty ligand site by a Pb2+ lone pair that has both s and p orbital character rather than the exclusively 6s lone pair. These results demonstrate that a Pb2+ lone pair can be exploited to behave like a ligand in lead halide compounds, greatly expanding the realm of possible lead halide materials to include extended solids with nonoctahedral coordination environments.

Two-dimensional van der Waals magnetic semiconductors display emergent chemical and physical properties and hold promise for novel optical, electronic and magnetic "few-layers" functionalities. Transition-metal iodides such as CrI

Bulk CsEuBr$_3$ and CsEuCl$_3$ are experimentally shown to be magnetic semiconductors that order antiferromagnetically at Neel temperatures of 2.0 K and 1.0 K respectively. Given that nanoparticles and thin films of CsEuCl$_3$ have been reported to order ferromagnetically at a similar temperature, our observation of antiferromagnetic ordering in CsEuBr$_3$ and CsEuCl$_3$ expands the possible applications of halide perovskites to now include spintronic devices where both ferromagnetic and antiferromagnetic devices can be fabricated from a single material. The conclusion that CsEuCl$_3$ can be used as a switchable magnetic material is also supported by our density-functional theory calculations., 21 pages, 3 figures, 6 additional figures

The strange metal (SM) state, characterized by a linear-in-temperature resistivity, is often seen in the normal state of high temperature superconductors. It is believed that the SM state is one of the keys to understand the underlying mechanism of high-Tc superconductivity. Here we report the first observation of the concurrent breakdown of the SM normal state and superconductivity at a pressure-induced quantum critical point in an iron-pnictide superconductor, Ca10(Pt4As8)((Fe0.97Pt0.03)2As2)5. We find that, upon suppressing the superconducting state by applying pressure, the power exponent changes from 1 to 2, and the corresponding coefficient A, the slope of the temperature-linear resistivity per FeAs layer, gradually diminishes. At a critical pressure (12.5 GPa), A and Tc go to zero concurrently,where a quantum phase transition (QPT) from a superconducting state with a SM normal state to a non-superconducting Fermi liquid state takes place. Scaling analysis on the results obtained from the pressurized 1048 superconductor reveals that A and Tc have a positive relation, which exhibits a similarity with that is seen in other chemically-doped unconventional superconductors, regardless of the type of the tuning method (doping or pressurizing), the crystal structure, the bulk or film superconductors and the nature of dopant. These results suggest that there is a simple but powerful organizational principle of connecting the SM normal state with the high-Tc superconductivity., 16 pages, 4 figures

We describe the spontaneous chiral self-assembly of C70 with SnI4 as well as a mixture of C60 and C70 with SnI4. Macroscopic single crystals with the formula (C70)x(C60)1-x(SnI4)2 (x = 0-1) are reported. C60, which is spherical, and C70, which is ellipsoidal, form a solid solution in these crystals, and the cubic lattice parameter of the chiral phase linearly increases as x grows from 0 to 1 in accordance with Vegard's law. Our results demonstrate that nonspherical particles and polydispersity are not an impediment to the growth of chiral crystals from high-symmetry achiral precursors, providing a route to assemble achiral particles including colloidal nanocrystals and engineered nanostructures into chiral materials without the need to use external templates or forces.

In strongly correlated materials, quasiparticle excitations can carry fractional quantum numbers. An intriguing possibility is the formation of fractionalized, charge-neutral fermions, e.g., spinons and fermionic excitons, that result in neutral Fermi surfaces and Landau quantization in an insulator. While previous experiments in quantum spin liquids, topological Kondo insulators, and quantum Hall systems have hinted at charge-neutral Fermi surfaces, evidence for their existence remains far from conclusive. Here we report experimental observation of Landau quantization in a two dimensional (2D) insulator, i.e., monolayer tungsten ditelluride (WTe$_{2}$), a large gap topological insulator. Using a detection scheme that avoids edge contributions, we uncover strikingly large quantum oscillations in the monolayer insulator's magnetoresistance, with an onset field as small as ~ 0.5 tesla. Despite the huge resistance, the oscillation profile, which exhibits many periods, mimics the Shubnikov-de Haas oscillations in metals. Remarkably, at ultralow temperatures the observed oscillations evolve into discrete peaks near 1.6 tesla, above which the Landau quantized regime is fully developed. Such a low onset field of quantization is comparable to high-mobility conventional two-dimensional electron gases. Our experiments call for further investigation of the highly unusual ground state of the WTe$_{2}$ monolayer. This includes the influence of device components and the possible existence of mobile fermions and charge-neutral Fermi surfaces inside its insulating gap., 33 pages, 4 Main Figures + 10 Extended Data Figures + 1 SI Figure

Erbium-doped materials can serve as spin-photon interfaces with optical transitions in the telecom C-band, making them an exciting class of materials for long-distance quantum communication. However, the spin and optical coherence times of Er3+ ions are limited by currently available host materials, motivating the development of new Er3+-containing materials. Here, we demonstrate the use of ion implantation to efficiently screen prospective host candidates, and show that disorder introduced by ion implantation can be mitigated through post-implantation thermal processing to achieve inhomogeneous linewidths comparable to bulk linewidths in as-grown samples. We present optical spectroscopy data for each host material, which allows us to determine the level structure of each site, allowing us to compare the environments of Er3+ introduced via implantation and via doping during growth. We demonstrate that implantation can generate a range of local environments for Er3+, including those observed in bulk-doped materials, and that the populations of these sites can be controlled with thermal processing.

We report a comprehensive study on the elastic properties of a hexanary high-entropy alloy superconductor (ScZrNbTa)$_{0.685}$[RhPd]$_{0.315}$ at room and cryogenic temperatures, by Resonant Ultrasound Spectroscopy experiments. The derived elastic constants are bulk modulus $K=132.7$ GPa, Young's modulus $E=121.0$ GPa, shear modulus $G=44.9$ GPa, and Poisson's ratio $\nu$=0.348 for room temperature. The Young's and shear moduli are $\sim 10\%$ larger than those in NbTi superconductor with similar $T_c$, while the ductility is comparable. Moreover, the mechanical performance is further enhanced at cryogenic temperature. Our work confirms the advantageous mechanical properties of high-entropy alloy superconductors and suggests the application prospects., Comment: 11 pages, 3 figures, 1 table

Lithium-ion batteries are essential for portable technology and are now poised to disrupt a century of combustion-based transportation. The electrification revolution could eliminate our reliance o...

Copper indium disulfide (CuInS2) is a semiconductor with a direct energy band gap of 1.53 eV—an optimal value for highly efficient thin-film solar cells. But it has reached only ∼11% power conversi...

The design of new chiral materials usually requires stereoselective organic synthesis to create molecules with chiral centers. Less commonly, achiral molecules can self-assemble into chiral materia...

Electronic states of iron in the lower mantle's dominant mineral, (Mg,Fe,Al)(Fe,Al,Si)O3 bridgmanite, control physical properties of the mantle including density, elasticity, and electrical and thermal conductivity. However, the determination of electronic states of iron has been controversial, in part due to different interpretations of Mössbauer spectroscopy results used to identify spin state, valence state, and site occupancy of iron. We applied energy-domain Mössbauer spectroscopy to a set of four bridgmanite samples spanning a wide range of compositions: 10–50% Fe/total cations, 0–25% Al/total cations, 12–100% Fe3+/total Fe. Measurements performed in the diamond-anvil cell at pressures up to 76 GPa below and above the high to low spin transition in Fe3+ provide a Mössbauer reference library for bridgmanite and demonstrate the effects of pressure and composition on electronic states of iron. Results indicate that although the spin transition in Fe3+ in the bridgmanite B-site occurs as predicted, it does not strongly affect the observed quadrupole splitting of 1.4 mm/s, and only decreases center shift for this site to 0 mm/s at ~70 GPa. Thus center shift can easily distinguish Fe3+ from Fe2+ at high pressure, which exhibits two distinct Mössbauer sites with center shift ~1 mm/s and quadrupole splitting 2.4–3.1 and 3.9 mm/s at ~70 GPa. Correct quantification of Fe3+/total Fe in bridgmanite is required to constrain the effects of composition and redox states in experimental measurements of seismic properties of bridgmanite. In Fe-rich, mixed-valence bridgmanite at deep-mantle-relevant pressures, up to ~20% of the Fe may be a Fe2.5+ charge transfer component, which should enhance electrical and thermal conductivity in Fe-rich heterogeneities at the base of Earth's mantle.

Superconductivity is reported in an endohedral aluminide compound, RuAl6, with Tc = 1.21 K. The normalized heat capacity jump at Tc, ΔC/γTc = 1.58, confirms bulk superconductivity. The Ginzburg–Lan...

Photoelectrochemical catalysts are often plagued by ineffective interfacial charge transfer or nonideal optical conversion properties. To overcome this challenge, strategically pairing a catalytica...

The Luttinger liquid (LL) model of one-dimensional (1D) electronic systems provides a powerful tool for understanding strongly correlated physics including phenomena such as spin-charge separation. Substantial theoretical efforts have attempted to extend the LL phenomenology to two dimensions (2D), especially in models of closely packed arrays of 1D quantum wires, each being described as a LL. Such coupled-wire models have been successfully used to construct 2D anisotropic non-Fermi liquids, quantum Hall states, topological phases, and quantum spin liquids. However, an experimental demonstration of high-quality arrays of 1D LLs suitable for realizing these models remains absent. Here we report the experimental realization of 2D arrays of 1D LLs with crystalline quality in a moir\'e superlattice made of twisted bilayer tungsten ditelluride (tWTe$_{2}$). Originating from the anisotropic lattice of the monolayer, the moir\'e pattern of tWTe$_{2}$ hosts identical, parallel 1D electronic channels, separated by a fixed nanoscale distance, which is tunable by the interlayer twist angle. At a twist angle of ~ 5 degrees, we find that hole-doped tWTe$_{2}$ exhibits exceptionally large transport anisotropy with a resistance ratio of ~ 1000 between two orthogonal in-plane directions. The across-wire conductance exhibits power-law scaling behaviors, consistent with the formation of a 2D anisotropic phase that resembles an array of LLs. Our results open the door for realizing a variety of correlated and topological quantum phases based on coupled-wire models and LL physics., Comment: 29 pages, 4 Main Figures + 13 Extended Data Figures

Van der Waals ferromagnets are thrilling materials from both a fundamental and technological point of view. VI3 is an interesting example, with a complex magnetism that differentiates it from the first reported Cr based layered ferromagnets. Here, we show in an indirect way through angle resolved photoemission spectroscopy experiments, the importance of spin–orbit coupling setting the electronic properties of this material. Our light polarized photoemission measurements point to a ground state with a half-filled [Formula: see text] doublet, where a gap opening is triggered by spin–orbit coupling enhanced by electronic correlations.