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The use of functionalized dental adhesives that might prevent degradation of the dentin hybrid layer has been proposed. The aim of the study was to characterize the physicochemical properties and the potential to induce mineral precipitation of methacrylate-based resins containing methacryl-functionalized polyhedral oligomeric silsesquioxane (MA-POSS-8). In total, six different compositions of resins based on bisphenol A glycerolate dimethacrylate (BisGMA, 40 to 60 wt.%), triethylene glycol dimethacrylate (TEGDMA, 5 to 35 wt.%) and 2-hydroxyethyl methacrylate (HEMA, 25 or 35 wt.%) were prepared and infiltrated with 5 wt.% MA-POSS-8. Unfilled resins served as control. Degree of conversion, viscosity, Martens hardness, indentation modulus, water sorption, and sol fraction were investigated. Polymerized specimens were examined by SEM/EDX for the presence of Ca/P precipitates after immersion in artificial saliva for 28 days at 37 °C. Statistical analysis was performed with two-way ANOVA and Tukey’s post-hoc test (p &lt, 0.05). The degree of conversion ranged from 55.0 to 59.8% and was not affected by the addition of MA-POSS-8. Viscosity ranged from 60.0 to 422.3 mPa*s and was not affected by MA-POSS-8 except for one methacrylate-based resin with 60 wt.% BisGMA. Martens hardness and indentation modulus ranged from 161.3 to 138.1 N/mm2 and 4.2 to 3.9 kN/mm2 and were affected by MA-POSS-8 in only one resin (50 wt.% BisGMA, 25 wt.% TEGDMA, 25 wt.% HEMA). Water sorption was not affected by MA-POSS-8, sol fraction was below the detection limit. Formation of Ca/P precipitates was observed on all specimens of test and control groups. Material properties were not affected adversely by MA-POSS-8 except for slight differences in Martens hardness, indention modulus, viscosity in some groups. However, bioactive properties could not be improved by MA-POSS-8.

The study aimed to compare the repair bond strength of aged composite and amalgam repaired with resin composite after various mechanical and adhesive surface treatments. Specimens were aged by thermal cycling (10,000 cycles, 5-55°C) and randomly subjected to one of three surface treatments: diamond bur abrasion, aluminum oxide air abrasion, or silica coating. Conventional bonding or a universal adhesive with incorporated silane was applied afterward (each n = 16) and resin composite was attached. In the control groups (each n = 16), resin composite was attached using one of the above adhesives without prior mechanical surface conditioning. After further thermal cycling, the shear bond strength (SBS) and failure modes were assessed. Statistical analyses were performed using ANOVA, Weibull statistics, two sample t-tests, and Chi2-test (P < 0.05). The SBS of the repaired amalgam was significantly lower than that of the composite and mechanical pretreatment significantly increased SBS. The universal adhesive significantly improved the SBS of the repaired amalgam compared to the conventional bonding agent and mechanical pretreatment increased the number of cohesive/mixed failures. Amalgam restorations may be repaired using resin composites, but the resulting SBS is lower than that obtained with composite Open-Access-Publikationsfonds 2019 peerReviewed

The aim of the study was to examine the applicability of bioactive and antibacterial nanoparticles to an experimental adhesive. The adhesive (60 wt% BisGMA, 15 wt% TEGDMA, 25 wt% HEMA) was mixed with combinations of 5 wt% methacryl-functionalized polyhedral oligomeric silsesquioxane (MA-POSS) and one kind of bioactive/antibacterial nanoparticles: 1 wt% core-shell silica-silver nanoparticle (SiO2@Ag), 1 wt% bioactive glass with bismuth (BAG-Bi) or 1 wt% calcium phosphate (CAP). Pure adhesive served as control. The physicochemical (degree of conversion (DC), linear shrinkage (LS), shear and complex viscosity, water sorption (WS), sol fraction (SF)), biological (antimicrobial effect) and bioactive (mineral precipitation) properties were investigated. DC and LS remained unchanged. The combination of BAG-Bi/MA-POSS resulted in a significantly increased WS and SF compared to control. In addition, the combination of CAP/MA-POSS slightly increased the shear viscosity of the adhesive. The addition of the nanoparticles did not influence the antimicrobial effects compared to the pure adhesive. Improved mineral inducing capacity could be detected in all nanoparticle combinations. The combination of bioactive and/or antibacterial nanoparticles showed improved mineral inducing capacity, but no antibacterial properties. The material properties were not or only slightly affected.

Objectives To investigate the effect of methacrylate polyhedral oligomeric silsesquioxane (POSS-8) particles on the polymerization process, dentin bond strength, and mineral precipitation of universal dental adhesives. Methods Five universal adhesives (Adhese Universal, CLEARFIL Universal Bond, Futurabond U, iBOND Universal, Scotchbond Universal) were filled with POSS-8 particles (10 wt%, additionally 2 wt% and 5 wt% in Scotchbond Universal). The particle size and dispersion in ethanol and acetone were examined by dynamic light scattering. Degree of conversion, linear shrinkage, and shear bond strength to dentin treated with the filled and pure adhesives (controls) were measured. Growth of calcium phosphate (Ca/P) precipitates on the adhesive specimens immersed in artificial saliva for up to 28 days was analyzed by energy-dispersive X-ray spectroscopy and scanning electron microscopy. Statistical analyses were performed using ANOVA and Tukey's post-hoc tests (p Results The hydrodynamic radius of the particles in acetone (1.4 ± 0.4 nm) and ethanol (1.1 ± 0.4 nm) revealed their good dispersion. POSS-8 did not change the degree of conversion and dentin bond strength of any adhesive. Ca/P precipitates formed on iBOND Universal specimens doped with POSS-8 after 4 weeks of immersion, but were not detected on the unfilled adhesive. The mineral precipitation of all other adhesives was not improved by POSS-8. Significance POSS-8 particles did not compromise polymerization and bonding of universal adhesives. Ca/P precipitation was stimulated by POSS-8 only in iBOND Universal.