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Fragmentation is an important decay mechanism for polycyclic aromatic hydrocarbons (PAHs) under harsh interstellar conditions and represents a possible formation pathway for small molecules such as H2, C2H2, C2H4. Our aim is to investigate the dissociation mechanism of superhydrogenated PAHs that undergo energetic processing and the formation pathway of small hydrocarbons. We obtain, experimentally, the mass distribution of protonated tetrahydropyrene (C16H15 , py+5H+) and protonated hexahydropyrene (C16H17+, py+7H+) upon collision induced dissociation (CID). The IR spectra of their main fragments are recorded by infrared multiple-photon dissociation (IRMPD). Extended tight-binding (GFN2-xTB) based molecular dynamics simulations are performed in order to provide the missing structure information in experiment and identify fragmentation pathways. The pathways for fragmentation are further investigated at a hybrid-density functional theory (DFT) and dispersion corrected level. A strong signal for loss of 28 mass units of py+7H+ is observed both in the CID experiment and the MD simulation, while py+5H+ shows negligible signal for the product corresponding to a mass loss of 28. The 28 mass loss from py+7H+ is assigned to the loss of ethylene (C2H4) and a good fit between the calculated and experimental IR spectrum of the resulting fragment species is obtained. Further DFT calculations show favorable kinetic pathways for loss of C2H4 from hydrogenated PAH configurations involving three consecutive CH2 molecular entities. This joint experimental and theoretical investigation proposes a chemical pathway of ethylene formation from fragmentation of superhydrogenated PAHs. This pathway is sensitive to hydrogenated edges (e.g. the degree of hydrogenation and the hydrogenated positions). The inclusion of this pathway in astrochemical models may improve the estimated abundance of ethylene., 11 pages, 6 figures

Experimental data showing superhydrogation of neutral polycyclic aromatic hydrocarbons (PAHs) coronene, pentacene and pentacenequinone is presented. PAH monolayers were prepared on a highly oriented pyrolytic graphite surface and subsequently exposed to a beam of atomic hydrogen. The superhydrogenated PAH species were examined via temperature programmed desorption measurements. Stable intermediate superhydrogenation degrees as well as fully superhydrogenated species are observed and the initial reaction cross section for coronene has been determined.

Experimental data showing superhydrogenation of neutral polycyclic aromatic hydrocarbons (PAHs) coronene, pentacene and pentacenequinone is presented. PAH monolayers were prepared on a highly oriented pyrolytic graphite surface and subsequently exposed to a beam of atomic hydrogen. The superhydrogenated PAH species were examined via temperature programmed desorption measurements. Stable intermediate superhydrogenation degrees as well as fully superhydrogenated species are observed and the initial reaction cross section for coronene has been determined.