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Solid solution strengthened (SSS) Ni-based superalloys, such as A617, show superior creep resistance at 700°C. Established for many years in land- and aero-based gas turbines, these materials are increasingly being considered for use in high-temperature thermal power plants. Apart from SSS, the creep strength in A617 stems from γ' and carbide precipitates. In this work, a microstructurally based creep model for A617 is presented. Mobile dislocations in the model interact with fine grain-interior precipitates, and grain boundaries act as dislocation sources/sinks. The model is capable of simulating creep curves and time-to-rupture (TTR) diagrams based on the evolution of mobile dislocations. At lower stresses, the accuracy of modelled TTR can be improved by adding diffusion creep to dislocation creep. The simulated evolution of dislocation densities is realistic compared to the literature data. The reduction of area of ruptured samples was included in a damage factor, enabling the consideration of creep ductility. [ABSTRACT FROM AUTHOR]

A thermokinetic computational framework for precipitate transformation simulations in Ta-containing martensitic Z-steels was developed, including Calphad thermodynamics, diffusion mobility data from the literature, and a kinetic parameter setup that considered precipitation sites, interfacial energies and dislocation density evolution. The thermodynamics of Ta-containing subsystems were assessed by atomic solubility data and enthalpies from the literature as well as from the experimental dissolution temperature of Ta-based Z-phase CrTaN obtained from differential scanning calorimetry. Accompanied by a comprehensive transmission electron microscopy analysis of the microstructure, thermokinetic precipitation simulations with a wide-ranging and well-documented set of input parameters were carried out in MatCalc for one sample alloy. A special focus was placed on modelling the transformation of MX into the Z-phase, which was driven by Cr diffusion. The simulation results showed excellent agreement with experimental data in regard to size, number density and chemical composition of the precipitates, showing the usability of the developed thermokinetic simulation framework.