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In order to assess observational evidence for potential atmospheric biosignatures on exoplanets, it will be essential to test whether spectral fingerprints from multiple gases can be explained by abiotic or biotic-only processes. Here, we develop and apply a coupled 1D atmosphere-ocean-ecosystem model to understand how primitive biospheres, which exploit abiotic sources of H2, CO and O2, could influence the atmospheric composition of rocky terrestrial exoplanets. We apply this to the Earth at 3.8 Ga and to TRAPPIST-1e. We focus on metabolisms that evolved before the evolution of oxygenic photosynthesis, which consume H2 and CO and produce potentially detectable levels of CH4. O2-consuming metabolisms are also considered for TRAPPIST-1e, as abiotic O2 production is predicted on M-dwarf orbiting planets. We show that these biospheres can lead to high levels of surface O2 (approximately 1-5 %) as a result of \ch{CO} consumption, which could allow high O2 scenarios, by removing the main loss mechanisms of atomic oxygen. Increasing stratospheric temperatures, which increases atmospheric OH can reduce the likelihood of such a state forming. O2-consuming metabolisms could also lower O2 levels to around 10 ppm and support a productive biosphere at low reductant inputs. Using predicted transmission spectral features from CH4, CO, O2/O3 and CO2 across the hypothesis space for tectonic reductant input, we show that biotically-produced CH4 may only be detectable at high reductant inputs. CO is also likely to be a dominant feature in transmission spectra for planets orbiting M-dwarfs, which could reduce the confidence in any potential biosignature observations linked to these biospheres., Comment: 29 pages, 19 figures

Hot rocky super-Earths are thought to be sufficiently irradiated by their host star to melt their surface and thus allow for long-lasting magma oceans. Some processes have been proposed for such planets to have retained primordial hydrogen captured during their formation while moving inward in the planetary system. The new generation of space telescopes such as the JWST may provide observations precise enough to characterize the atmospheres and perhaps the interiors of such exoplanets. We use a vaporization model that calculates the gas-liquid equilibrium between the atmosphere (including hydrogen) and the magma ocean, to compute the elemental composition of a variety of atmospheres for different quantities of hydrogen. The elemental composition is then used in a steady-state atmospheric model to compute the atmospheric structure and generate synthetic emission spectra. With this method, we confirm previous results showing that silicate atmospheres exhibit a thermal inversion, with notably an emission peak of SiO at 9~$\mu m$. We compare our method to the literature on the inclusion of hydrogen in the atmosphere, and show hydrogen reduces the thermal inversion, because of the formation of H2O which has a strong greenhouse potential. However planets that are significantly irradiated by their host star are sufficiently hot to dissociate H2O and thus also maintain a thermal inversion. The observational implications are twofold: 1) H2O is more likely to be detected in colder atmospheres; 2) Detecting a thermal inversion in hotter atmospheres does not a priori exclude the presence of H (in its atomic form). Due to the impact of H on the overall chemistry and atmospheric structure, and therefore observations, we emphasize the importance of including volatiles in the calculation of the gas-liquid equilibrium. Finally, we provide a criterion to determine potential targets for observation., Comment: 22 pages, 17 figures + 12 figures in appendices. Accepted for publication in Astronomy & Astrophysics

Stellar flares present challenges to the potential habitability of terrestrial planets orbiting M dwarf stars through inducing changes in the atmospheric composition and irradiating the planet's surface in large amounts of ultraviolet light. To examine their impact, we have coupled a general circulation model with a photochemical kinetics scheme to examine the response and changes of an Earth-like atmosphere to stellar flares and coronal mass ejections. We find that stellar flares increase the amount of ozone in the atmosphere by a factor of 20 compared to a quiescent star. We find that coronal mass ejections abiotically generate significant levels of potential bio-signatures such as N$_2$O. The changes in atmospheric composition cause a moderate decrease in the amount of ultraviolet light that reaches the planets surface, suggesting that while flares are potentially harmful to life, the changes in the atmosphere due to a stellar flare act to reduce the impact of the next stellar flare., Comment: 27 pages, 21 figures, accepted to MNRAS

Determining the habitability and interpreting atmospheric spectra of exoplanets requires understanding their atmospheric physics and chemistry. We use a 3-D Coupled Climate-Chemistry Model, the Met Office Unified Model with the UK Chemistry and Aerosols framework, to study the emergence of lightning and its chemical impact on tidally-locked Earth-like exoplanets. We simulate the atmosphere of Proxima Centauri b orbiting in the Habitable Zone of its M-dwarf star, but the results apply to similar M-dwarf orbiting planets. Our chemical network includes the Chapman ozone reactions and hydrogen oxide (HO$_{\mathrm{x}}$=H+OH+HO$_2$) and nitrogen oxide (NO$_{\mathrm{x}}$=NO+NO$_2$) catalytic cycles. We find that photochemistry driven by stellar radiation (177-850 nm) supports a global ozone layer between 20-50 km. We parameterise lightning flashes as a function of cloud-top height and the resulting production of nitric oxide (NO) from the thermal decomposition of N$_2$ and O$_2$. Rapid dayside convection over and around the substellar point results in lightning flash rates of up to 0.16 flashes km$^{-2}$yr$^{-1}$, enriching the dayside atmosphere below altitudes of 20 km in NO$_{\mathrm{x}}$. Changes in dayside ozone are determined mainly by UV irradiance and the HO$_{\mathrm{x}}$ catalytic cycle. ~45% of the planetary dayside surface remains at habitable temperatures (T$_{\mathrm{surf}}$>273.15 K) and the ozone layer reduces surface UV radiation levels to 15%. Dayside-nightside thermal gradients result in strong winds that subsequently advect NO$_{\mathrm{x}}$ towards the nightside, where the absence of photochemistry allows NO$_{\mathrm{x}}$ chemistry to involve reservoir species. Our study also emphasizes the need for accurate UV stellar spectra to understand the atmospheric chemistry of exoplanets., Comment: 20 pages, 14 figures, accepted for publication in MNRAS

The majority of potentially habitable exoplanets detected orbit stars cooler than the Sun, and therefore are irradiated by a stellar spectrum peaking at longer wavelengths than that incident on Earth. Here, we present results from a set of simulations of tidally-locked terrestrial planets orbiting three different host stars to isolate the effect of the stellar spectra on the simulated climate. Specifically, we perform simulations based on TRAPPIST-1e, adopting an Earth-like atmosphere and using the UK Met Office Unified Model in an idealised 'aqua-planet' configuration. Whilst holding the planetary parameters constant, including the total stellar flux (900 W/m$^2$) and orbital period (6.10 Earth days), we compare results between simulations where the stellar spectrum is that of a quiescent TRAPPIST-1, Proxima Centauri and the Sun. The simulations with cooler host stars had an increased proportion of incident stellar radiation absorbed directly by the troposphere compared to the surface. This, in turn, led to an increase in the stability against convection, a reduction in overall cloud coverage on the dayside (reducing scattering), leading to warmer surface temperatures. The increased direct heating of the troposphere also led to more efficient heat transport from the dayside to the nightside and, therefore, a reduced day-night temperature contrast. We inferred that planets with an Earth-like atmosphere orbiting cooler stars had lower dayside cloud coverage, potentially allowing habitable conditions at increased orbital radii, compared to similar planets orbiting hotter stars for a given planetary rotation rate., Comment: 12 pages, 8 figures

We present results from a set of simulations using a fully coupled three-dimensional (3D) chemistry-radiation-hydrodynamics model and investigate the effect of transport of chemical species by the large-scale atmospheric flow in hot Jupiter atmospheres. We couple a flexible chemical kinetics scheme to the Met Office Unified Model which enables the study of the interaction of chemistry, radiative transfer and fluid dynamics. We use a newly-released "reduced" chemical network comprising 30 chemical species that has been specifically developed for application in 3D atmosphere models. We simulate the atmospheres of the well-studied hot Jupiters HD~209458b and HD~189733b which both have dayside--nightside temperature contrasts of several hundred Kelvin and superrotating equatorial jets. We find qualitatively quite different chemical structures between the two planets, particularly for methane (CH$_4$), when advection of chemical species is included. Our results show that consideration of 3D chemical transport is vital in understanding the chemical composition of hot Jupiter atmospheres. 3D mixing leads to significant changes in the abundances of absorbing gas-phase species compared with what would be expected by assuming local chemical equilibrium, or from models including 1D - and even 2D - chemical mixing. We find that CH$_4$, carbon dioxide (CO$_2$) and ammonia (NH$_3$) are particularly interesting as 3D mixing of these species leads to prominent signatures of out-of-equilibrium chemistry in the transmission and emission spectra, detectable with near-future instruments., Comment: Accepted in A&A