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We present a new generation of substellar atmosphere and evolution models, appropriate for application to studies of L, T, and Y-type brown dwarfs and self-luminous extrasolar planets. The atmosphere models describe the expected temperature-pressure profiles and emergent spectra of atmospheres in radiative-convective equilibrium with effective temperatures and gravities within the ranges $200\le T_{\rm eff}\le2400\,\rm K$ and $2.5\le \log g \le 5.5$. These ranges encompass masses from about 0.5 to 85 Jupiter masses for a set of metallicities ($[{\rm M/H}] = -0.5$ to $+0.5$), C/O ratios (from 0.5 to 1.5 times that of solar), and ages. The evolution tables describe the cooling of these substellar objects through time. These models expand the diversity of model atmospheres currently available, notably to cooler effective temperatures and greater ranges in C/O. Notable improvements from past such models include updated opacities and atmospheric chemistry. Here we describe our modeling approach and present our initial tranche of models for cloudless, chemical equilibrium atmospheres. We compare the modeled spectra, photometry, and evolution to various datasets., 27 pages, 16 figures, accepted for Astrophysical Journal. Models available at https://doi.org/10.5281/zenodo.5063476

Lithium is an important element for the understanding of ultracool dwarfs because it is lost to fusion at masses above $\sim 68\, M_{\rm J}$. Hence, the presence or absence of atomic Li has served as an indicator of the nearby H-burning boundary at about $75\,M_{\rm J}$ between brown-dwarfs and very low-mass stars. Historically the "Lithium test", a search for the presence and strength of the Li line at 670.8 nm, has been a marker if an object has a substellar mass with stellar-like spectral energy distribution (e.g., a late-type M dwarf). While the Li test could in principle also be used to distinguish masses of later-type L-T dwarfs, Li is predominantly no longer found as an atomic gas, but rather a molecular species such as LiH, LiF, LiOH, and LiCl in their cooler atmospheres. L- and T-type brown dwarfs are also quite faint at 670 nm and thus challenging targets for high resolution spectroscopy. But only recently have experimental molecular line lists become available for the molecular Li species, allowing molecular Li mass discrimination. In this study, we generated the latest opacity of each of these Li-bearing molecules and performed thermochemical equilibrium atmospheric composition calculation of the abundance of these molecules. Finally, we computed thermal emission spectra for a series of radiative-convective equilibrium models of cloudy and cloudless brown dwarf atmospheres (with $T_{\rm eff}=$ 500--2400~K, and $\log g$=4.0, 4.5, 5.0) to understand where the presence or absence of atmospheric lithium-bearing species is most easily detected as a function of brown dwarf mass and age. After atomic Li, the best spectral signatures were found to be LiF at $10.5-12.5$~\micron and LiCl at $14.5-18.5$ $\micron$. LiH also shows a narrow feature at $\sim 9.38$ $\micron$., 13 pages, 7 figures, 1 table, In final revision at ApJ. Comments welcome

Observations to characterize planets larger than Earth but smaller than Neptune have led to largely inconclusive interpretations at low spectral resolution due to hazes or clouds that obscure molecular features in their spectra. However, here we show that high-resolution spectroscopy (R $\sim$ 25,000 to 100,000) enables one to probe the regions in these atmospheres above the clouds where the cores of the strongest spectral lines are formed. We present models of transmission spectra for a suite of GJ1214b-like planets with thick photochemical hazes covering 1 - 5 $\mu$m at a range of resolutions relevant to current and future ground-based spectrographs. Furthermore, we compare the utility of the cross-correlation function that is typically used with a more formal likelihood-based approach, finding that only the likelihood based method is sensitive to the presence of haze opacity. We calculate the signal-to-noise of these spectra, including telluric contamination, required to robustly detect a host of molecules such as CO, CO$_{2}$, H$_{2}$O, and CH$_{4}$, and photochemical products like HCN, as a function of wavelength range and spectral resolution. Spectra in M band require the lowest S/N$_{res}$ to detect multiple molecules simultaneously. CH$_{4}$ is only observable for the coolest models ($T_{\rm{eff}} =$ 412 K) and only in the L band. We quantitatively assess how these requirements compare to what is achievable with current and future instruments, demonstrating that characterization of small cool worlds with ground-based high resolution spectroscopy is well within reach., Comment: Submitted to AAS Journals, revised to reflect referee comments. Posting of this manuscript on the arXiv was coordinated with S. Ghandi et al

Cold brown dwarfs are excellent analogs of widely separated, gas giant exoplanets, and provide insight into the potential atmospheric chemistry and physics we may encounter in objects discovered by future direct imaging surveys. We present a low resolution R $\sim$ 300 $M$-band spectroscopic sequence of seven brown dwarfs with effective temperatures between 750 K and 250 K along with Jupiter. These spectra reveal disequilibrium abundances of carbon monoxide (CO) produced by atmospheric quenching. We use the eddy diffusion coefficient (K$_{zz}$) to estimate the strength of vertical mixing in each object. The K$_{zz}$ values of cooler gaseous objects are close to their theoretical maximum and warmer objects show weaker mixing, likely due to less efficient convective mixing in primarily radiative layers. The CO-derived K$_{zz}$ values imply that disequilibrium phosphine (PH$_{3}$) should be easily observable in all of the brown dwarfs, but none as yet show any evidence for PH$_{3}$ absorption. We find that ammonia is relatively insensitive to atmospheric quenching at these effective temperatures. We are able to improve the fit to WISE 0855's $M$-band spectrum by including both CO and water clouds in the atmospheric model., Comment: Accepted to the Astronomical Journal. 24 Pages, 16 Figures, 4 Tables. take care

Using the Keck Planet Imager and Characterizer (KPIC), we obtained high-resolution (R$\sim$35,000) $K$-band spectra of the four planets orbiting HR 8799. We clearly detected \water{} and CO in the atmospheres of HR 8799 c, d, and e, and tentatively detected a combination of CO and \water{} in b. These are the most challenging directly imaged exoplanets that have been observed at high spectral resolution to date when considering both their angular separations and flux ratios. We developed a forward modeling framework that allows us to jointly fit the spectra of the planets and the diffracted starlight simultaneously in a likelihood-based approach and obtained posterior probabilities on their effective temperatures, surface gravities, radial velocities, and spins. We measured $v\sin(i)$ values of $10.1^{+2.8}_{-2.7}$~km/s for HR 8799 d and $15.0^{+2.3}_{-2.6}$~km/s for HR 8799 e, and placed an upper limit of $< 14$~km/s of HR 8799 c. Under two different assumptions of their obliquities, we found tentative evidence that rotation velocity is anti-correlated with companion mass, which could indicate that magnetic braking with a circumplanetary disk at early times is less efficient at spinning down lower mass planets., 31 pages, 12 figures, Accepted to AJ

Stellar, substellar, and planetary atmosphere models are all highly sensitive to the input opacities. Generational differences between various state-of-the-art stellar/planetary models are primarily because of incomplete and outdated atomic/molecular line-lists. Here we present a database of pre-computed absorption cross-sections for all isotopologues of key atmospheric molecules relevant to late-type stellar, brown dwarf, and planetary atmospheres: MgH, AlH, CaH, TiH, CrH, FeH, SiO, TiO, VO, and H2O. The pressure and temperature ranges of the computed opacities are between 10$^{-6}$--3000~bar and 75--4000~K, and their spectral ranges are 0.25--330~$\mu$m for many cases where possible. For cases with no pressure-broadening data, we use collision theory to bridge the gap. We also probe the effect of absorption cross-sections calculated from different line lists in the context of Ultra-Hot Jupiter and M-dwarf atmospheres. Using 1-D self-consistent radiative-convective thermochemical equilibrium models, we report significant variations in the theoretical spectra and thermal profiles of substellar atmospheres. With a 2000 K representative Ultra-Hot Jupiter, we report variations of up to 320 and 80 ppm in transmission and thermal emission spectra, respectively. For a 3000 K M-dwarf, we find differences of up to 125$\%$ in the spectra. We find that the most significant differences arise due to the choice of TiO line-lists, primarily below 1$\mu$m. In sum, we present (1) a database of pre-computed molecular absorption cross-sections, and (2) quantify biases that arise when characterizing substellar/exoplanet atmospheres due to line list differences, therefore highlighting the importance of correct and complete opacities for eventual applications to high precision spectroscopy and photometry., Comment: accepted in ApJS. 44 pages, 17 figures, 7 tables. Comments are welcome

We highlight a physical effect that is often not considered that impacts the calculation of model spectra of planets at secondary eclipse, affecting both emission and reflection spectra. The radius of the emitting surface of the planet is not merely one value measured from a transit light curve, but is itself a function of wavelength, yet it is not directly measurable. At high precision, a similar effect is well-known in transit "transmission spectroscopy" but this related effect also impacts emission and reflection. As is well-appreciated, the photospheric radius can vary across $\sim$4-8 atmospheric scale heights, depending on atmospheric opacity and spectral resolution. This effect leads to a decreased weighting in model calculations at wavelengths where atmospheric opacity is low, and one sees more deeply into the atmosphere, to a smaller radius. The overall effect serves to mute emission spectra features for atmospheres with no thermal inversion but to enhance features for atmospheres with a thermal inversion. While this effect can be ignored for current \emph{Hubble} observations, it can lead to wavelength-dependent 10-20\% changes in planet-to-star flux ratios in the infrared at $R\sim~200-1000$ (readily achievable for JWST) for low-gravity hot Jupiters, although values of 5\% are more typical for the population. The effect is mostly controlled by the ratio of the atmospheric scale height to the planet radius, and can be important at any planetary temperature. Of known planets, the effect is largest for the cool "super-puffs" at very low surface gravity, where it can alter calculated flux ratios by over 100\%. We discuss complexities of including this photospheric radius effect in 1D and 3D atmosphere models., Submitted to ApJ Letters, revised to reflect referee comments

Low-mass M dwarfs represent the most common outcome of star formation, but their complex emergent spectra hinder detailed studies of their composition and initial formation. The measurement of isotopic ratios is a key tool that has been used to unlock the formation of our Solar System, the Sun, and the nuclear processes within more massive stars. We observed GJ 745AB, two M dwarfs orbiting in a wide binary, with the IRTF/iSHELL spectrograph. Our spectroscopy of CO in these stars at the 4.7 micron fundamental and 2.3 micron first-overtone rovibrational bandheads reveals 12C16O, 13C16O, and 12C18O in their photospheres. Since the stars are fully convective, the atomic constituents of these isotopologues should be uniformly mixed throughout the stars' interiors. We find that in these M dwarfs, both 12C/13C and 16O/18O greatly exceed the Solar values. These measurements cannot be explained solely by models of Galactic chemical evolution, but require that the stars formed from an ISM significantly enriched by material ejected from an exploding core-collape supernova. These isotopic measurements complement the elemental abundances provided by large-scale spectroscopic surveys, and open a new window onto studies of Galactic evolution, stellar populations, and individual systems., 11 pages, 4 data files, 3 figures, 2 tables. ApJ in press

We present the distance-calibrated spectral energy distribution (SED) of the d/sdL7 SDSS J14162408+1348263A (J1416A) and an updated SED for SDSS J14162408+1348263B (J1416B). We also present the first retrieval analysis of J1416A using the Brewster retrieval code base and the second retrieval of J1416B. We find that the primary is best fit by a nongray cloud opacity with a power-law wavelength dependence but is indistinguishable between the type of cloud parameterization. J1416B is best fit by a cloud-free model, consistent with the results from Line et al. Most fundamental parameters derived via SEDs and retrievals are consistent within 1σ for both J1416A and J1416B. The exceptions include the radius of J1416A, where the retrieved radius is smaller than the evolutionary model-based radius from the SED for the deck cloud model, and the bolometric luminosity, which is consistent within 2.5σ for both cloud models. The pair’s metallicity and carbon-to-oxygen ratio point toward formation and evolution as a system. By comparing the retrieved alkali abundances while using two opacity models, we are able to evaluate how the opacities behave for the L and T dwarf. Lastly, we find that relatively small changes in composition can drive major observable differences for lower-temperature objects.

The coldest brown dwarf, WISE 0855, is the closest known planetary-mass, free-floating object and has a temperature nearly as cold as the solar system gas giants. Like Jupiter, it is predicted to have an atmosphere rich in methane, water, and ammonia, with clouds of volatile ices. WISE 0855 is faint at near-infrared wavelengths and emits almost all its energy in the mid-infrared. Skemer et al. 2016 presented a spectrum of WISE 0855 from 4.5-5.1 micron (M band), revealing water vapor features. Here, we present a spectrum of WISE 0855 in L band, from 3.4-4.14 micron. We present a set of atmosphere models that include a range of compositions (metallicities and C/O ratios) and water ice clouds. Methane absorption is clearly present in the spectrum. The mid-infrared color can be better matched with a methane abundance that is depleted relative to solar abundance. We find that there is evidence for water ice clouds in the M band spectrum, and we find a lack of phosphine spectral features in both the L and M band spectra. We suggest that a deep continuum opacity source may be obscuring the near-infrared flux, possibly a deep phosphorous-bearing cloud, ammonium dihyrogen phosphate. Observations of WISE 0855 provide critical constraints for cold planetary atmospheres, bridging the temperature range between the long-studied solar system planets and accessible exoplanets. JWST will soon revolutionize our understanding of cold brown dwarfs with high-precision spectroscopy across the infrared, allowing us to study their compositions and cloud properties, and to infer their atmospheric dynamics and formation processes., 19 pages, 21 figures. Accepted for publication in ApJ

The relative abundance of deuterium and hydrogen is a potent tracer of planet formation and evolution. Jupiter and Saturn have protosolar atmospheric D/H ratios, a relic of substantial gas accretion from the nebula, while the atmospheres of Neptune and Uranus are enhanced in D by accretion of ices into their envelopes. For terrestrial planets, D/H ratios are used to determine the mechanisms of volatile delivery and subsequent atmosphere loss over the lifetime of the planet. Planets and brown dwarfs more massive than 13 M_J quickly fuse their initial D reservoir. Here, we simulate spectra for giant exoplanets and brown dwarfs (2 M_Neptune to ~10 M_Jupiter) from Teff=200--1800 K including both CH3D and HDO to determine the observability of these dominant deuterium isotopologues in mid-infrared thermal emission spectra. Colder objects have stronger molecular features in their spectra, due to the temperature-dependence of molecular cross sections. CH3D is easier to observe than HDO at all temperatures considered, due to the strength of its absorption bands and locations of features at wavelengths with few other strong absorption features. We predict that for nearby cool brown dwarfs, the CH3D abundance can be measured at high signal-to-noise with the James Webb Space Telescope; for objects from 200--800 K closer than 10 pc, a protosolar D/H ratio would be readily observable in 2.5 hours. Moderately young Jupiter-mass planets (100--300 Myr) and young Neptunes (10 Myr) may be discovered with JWST and provide the best targets for detecting deuterium on an exoplanet in the coming decade. Future telescope designs should consider the importance of isotopes for understanding the formation and evolution of planetary atmospheres., Comment: 10 pages, 5 figures, published in ApJ Letters

We present an analysis of the 0.95-14.5 micron spectral energy distributions of nine field ultracool dwarfs with spectral types ranging from L1 to T4.5. Effective temperatures, gravities, and condensate cloud sedimentation efficiencies are derived by comparing the data to synthetic spectra computed from atmospheric models that self-consistently include the formation of condensate clouds. Derived effective temperatures decrease steadily through the L1 to T4.5 spectral types and we confirm that the effective temperatures of ultracool dwarfs at the L/T transition are nearly constant, decreasing by only ~200 K from spectral types L7.5 to T4.5. The two objects in our sample with very red J-Ks colors are best fitted with synthetic spectra that have thick clouds which hints at a possible correlation between the near-infrared colors of L dwarfs and the condensate cloud properties. The fits to the two T dwarfs in our sample (T2 and T4.5) also suggest that the clouds become thinner in this spectral class, in agreement with previous studies. Restricting the fits to narrower wavelength ranges (i.e., individual photometric bands) almost always yields excellent agreement between the data and models. Limitations in our knowledge of the opacities of key absorbers such as FeH, VO, and CH4 at certain wavelengths remain obvious, however. The effective temperatures obtained by fitting the narrower wavelength ranges can show a large scatter compared to the values derived by fitting the full spectral energy distributions; deviations are typically ~200 K and in the worst cases, up to 700 K.

Opacities and chemical abundance data are crucial ingredients of ultracool dwarf and extrasolar giant planet atmosphere models. We report here on the detailed sources of molecular opacity data employed by our group for this application. We also present tables of Rosseland and Planck mean opacities which are of use in some studies of the atmospheres, interiors, and evolution of planets and brown dwarfs. For the tables presented here we have included the opacities of important atomic and molecular species, including the alkali elements, pressure induced absorption by hydrogen, and other significant opacity sources but neglect opacity from condensates. We report for each species how we have assembled molecular line data from a combination of public databases, laboratory data that is not yet in the public databases, and our own numerical calculations. We combine these opacities with abundances computed from a chemical equilibrium model using recently revised solar abundances to compute mean opacities. The chemical equilibrium calculation accounts for the settling of condensates in a gravitational field, and is applicable to ultracool dwarf and extrasolar planetary atmospheres, but not circumstellar disks. We find that the inclusion of alkali atomic opacity substantially increases the mean opacities over those currently in the literature at densities relevant to the atmospheres and interiors of giant planets and brown dwarfs. We provide our opacity tables for public use and discuss their limitations., 32 pages, 6 figures, accepted for publication in Astrphysical Journal Supplement, units revised, now includes on-line only data files (available in "source" package from "other formats" link)

We present the first analysis of an optical to mid-infrared spectrum of the T7.5 dwarf Gliese 570D with model atmospheres, synthetic spectra, and brown dwarf evolution sequences. We obtain precise values for the basic parameters of Gl 570D: Teff=800 - 820K, log g (cm/s^2)=5.09 - 5.23, and log L/Lsun= -5.525 to -5.551. The Spitzer IRS spectrum shows prominent features of ammonia (NH3) that can only be fitted by reducing the abundance of NH3 by about one order of magnitude from the value obtained with chemical equilibrium models. We model departures from chemical equilibrium in the atmosphere of Gl 570D by considering the kinetics of nitrogen and carbon chemistry in the presence of vertical mixing. The resulting model spectrum reproduces the data very well., Comment: Accepted for publication in the ApJ. 10 pages, including 3 figures

We investigate the atmosphere and interior of the new transiting planet HD 149026b, which appears to be very rich in heavy elements. We first compute model atmospheres at metallicities ranging from solar to ten times solar, and show how for cases with high metallicity or inefficient redistribution of energy from the day side, the planet may develop a hot stratosphere due to absorption of stellar flux by TiO and VO. The spectra predicted by these models are very different than cooler atmosphere models without stratospheres. The spectral effects are potentially detectable with the Spitzer Space Telescope. In addition the models with hot stratospheres lead to a large limb brightening, rather than darkening. We compare the atmosphere of HD 149026b to other well-known transiting planets, including the recently discovered HD 189733b, which we show have planet-to-star flux ratios twice that of HD 209458 and TrES-1. The methane abundance in the atmosphere of HD 189733b is a sensitive indicator of atmospheric temperature and metallicity and can be constrained with Spitzer IRAC observations. We then turn to interior studies of HD 149026b and use a grid of self-consistent model atmospheres and high-pressure equations of state for all components to compute thermal evolution models of the planet. We estimate that the mass of heavy elements within the planet is in the range of 60 to 93 M_earth. Finally, we discuss trends in the radii of transiting planets with metallicity in light of this new member of the class., Comment: Accepted to the Astrophysical Journal. 18 pages, including 10 figures. New section on the atmosphere of planet HD 189733b. Enhanced discussion of atmospheric Ti chemistry and core mass for HD 149026b

Precise intensities, self-broadenings and shifts have been obtained for the 12 C 16 O v¼ 2 0 band from simultaneous fits of lownoise, high-resolution Fourier-transform spectra at pressures from 27 to 80 kPa (200–600 Torr). Observed line shapes exhibit deviations on the order of 1% from the conventional Voigt profile, primarily due to speed-dependent broadening and secondarily to line mixing. Dicke narrowing is reduced by over an order-of-magnitude from the diffusion value, presumably because of correlations between velocity- and phase-changing collisions. 2003 Elsevier Inc. All rights reserved.

Absolute line intensities, band intensities, and Herman-Wallis parameters were measured for the (01(sup 1)2)(sub I) from (00(sup 0)0)(sub I) perpendicular band of (12)C(16)O2 centered at 5315/cm, along with the three nearby associated hot bands: (10(sup 0)2)(sub II) from (01(sup 1)0)(sub I) at 5248/cm, (02(sup 2))(sub I) from (01(sup 1)0)(sub I) at 5291/cm, and (10(sup 0)2)(sub I) from (01(sup 1)0)(sub I) at 5349/cm. The nearby parallel hot band (30(sup 0))(sub I) from (10(sup 0)0)(sub II) at 5218/cm was also included in this study.

We present new calculations of Rosseland and Planck gaseous mean opacities relevant to the atmospheres of giant planets and ultracool dwarfs. Such calculations are used in modeling the atmospheres, interiors, formation, and evolution of these objects. Our calculations are an expansion of those presented in Freedman et al. (2008) to include lower pressures, finer temperature resolution, and also the higher metallicities most relevant for giant planet atmospheres. Calculations span 1 microbar to 300 bar, and 75 K to 4000 K, in a nearly square grid. Opacities at metallicities from solar to 50 times solar abundances are calculated. We also provide an analytic fit to the Rosseland mean opacities over the grid in pressure, temperature, and metallicity. In addition to computing mean opacities at these local temperatures, we also calculate them with weighting functions up to 7000 K, to simulate the mean opacities for incident stellar intensities, rather than locally thermally emitted intensities. The chemical equilibrium calculations account for the settling of condensates in a gravitational field and are applicable to cloud-free giant planet and ultracool dwarf atmospheres, but not circumstellar disks. We provide our extensive opacity tables for public use., This version fixes a units description error that was only in the arxiv version, but is correct in the ApJS version. In equations 4 and 5 pressure is in dyne/cm2. Online tables available at the ApJS website: https://iopscience.iop.org/article/10.1088/0067-0049/214/2/25

We present three-dimensional atmospheric circulation models of GJ 1214b, a 2.7 Earth-radius, 6.5 Earth-mass super Earth detected by the MEarth survey. Here we explore the planet's circulation as a function of atmospheric metallicity and atmospheric composition, modeling atmospheres with a low mean-molecular weight (i.e., H2-dominated) and a high mean-molecular weight (i.e. water- and CO2-dominated). We find that atmospheres with a low mean-molecular weight have strong day-night temperature variations at pressures above the infrared photosphere that lead to equatorial superrotation. For these atmospheres, the enhancement of atmospheric opacities with increasing metallicity lead to shallower atmospheric heating, larger day-night temperature variations and hence stronger superrotation. In comparison, atmospheres with a high mean-molecular weight have larger day-night and equator-to-pole temperature variations than low mean-molecular weight atmospheres, but differences in opacity structure and energy budget lead to differences in jet structure. The circulation of a water-dominated atmosphere is dominated by equatorial superrotation, while the circulation of a CO2-dominated atmosphere is instead dominated by high-latitude jets. By comparing emergent flux spectra and lightcurves for 50x solar and water-dominated compositions, we show that observations in emission can break the degeneracy in determining the atmospheric composition of GJ 1214b. The variation in opacity with wavelength for the water-dominated atmosphere leads to large phase variations within water bands and small phase variations outside of water bands. The 50x solar atmosphere, however, yields small variations within water bands and large phase variations at other characteristic wavelengths. These observations would be much less sensitive to clouds, condensates, and hazes than transit observations., 12 pages, 11 figures, 2 tables, accepted to ApJ

It is now understood that the accretion of terrestrial planets naturally involves giant collisions, the moon-forming impact being a well known example. In the aftermath of such collisions the surface of the surviving planet is very hot and potentially detectable. Here we explore the atmospheric chemistry, photochemistry, and spectral signatures of post-giant-impact terrestrial planets enveloped by thick atmospheres consisting predominantly of CO2, and H2O. The atmospheric chemistry and structure are computed self-consistently for atmospheres in equilibrium with hot surfaces with composition reflecting either the bulk silicate Earth (which includes the crust, mantle, atmosphere and oceans) or Earth's continental crust. We account for all major molecular and atomic opacity sources including collision-induced absorption. We find that these atmospheres are dominated by H2O and CO2, while the formation of CH4, and NH3 is quenched due to short dynamical timescales. Other important constituents are HF, HCl, NaCl, and SO2. These are apparent in the emerging spectra, and can be indicative that an impact has occurred. The use of comprehensive opacities results in spectra that are a factor of 2 lower in surface brightness in the spectral windows than predicted by previous models. The estimated luminosities show that the hottest post-giant-impact planets will be detectable with near-infrared coronagraphs on the planned 30m-class telescopes. The 1-4um region will be most favorable for such detections, offering bright features and better contrast between the planet and a potential debris disk. We derive cooling timescales on the order of 10^5-10^6 Myrs, based on the modeled effective temperatures. This leads to the possibility of discovering tens of such planets in future surveys., 51 pages, 16 figures, preprint format; ApJ submitted

The presence of valleys on ancient terrains of Mars suggest that liquid water flowed on the martian surface 3.8 billion years ago or before. The above-freezing temperatures required to explain valley formation could have been transient, in response to frequent large meteorite impacts on early Mars, or they could have been caused by long-lived greenhouse warming. Climate models that consider only the greenhouse gases carbon dioxide and water vapor have been unable to recreate warm surface conditions, given the lower solar luminosity at that time. Here we use a one-dimensional climate model to demonstrate that an atmosphere containing 1.3-4 bar of CO2 and water vapor, along with 5 to 20 percent H2, could have raised the mean surface temperature of early Mars above the freezing point of water. Vigorous volcanic outgassing from a highly reduced early martian mantle is expected to provide sufficient atmospheric H2 and CO2, the latter from the photochemical oxidation of outgassed CH4 and CO, to form a CO2-H2 greenhouse. Such a dense early martian atmosphere is consistent with independent estimates of surface pressure based on cratering data., Comment: 48 pages, 12 figures, and 4 tables. The official Nature Geoscience version is found here: http://www.nature.com/ngeo/journal/v7/n1/full/ngeo2000.html

The absolute rotationless transition moment squared for the X1Σ+v=3←v=0 band of CO is measured to be |R3–0|2=1.713 (−20, +33)×10−7 Debye2. This value is about 8.6% smaller than the value assumed for HITRAN 2000. The measured Herman–Wallis intensity factor of this band is F=1+0.01168(11)m+0.0001065(79)m2. The determination of self-broadening coefficients is improved with the inclusion of line narrowing; self-shifts are also reported.

Recent studies have shown that clouds made of carbon dioxide ice may have warmed the surface of early Mars by reflecting not only incoming solar radiation but upwelling IR radiation as well. However, these studies have not treated scattering self-consistently in the thermal IR. Our own calculations, which treat IR scattering properly, confirm these earlier calculations but show that CO 2 clouds can also cool the surface, especially if they are low and optically thick. Estimating the actual effect of CO 2 clouds on early martian climate will require three-dimensional models in which cloud location, height, and optical depth, as well as surface temperature and pressure, are determined self-consistently. Our calculations further confirm that CO 2 clouds should extend the outer boundary of the habitable zone around a star but that there is still a finite limit beyond which above-freezing surface temperatures cannot be maintained by a CO 2 –H 2 O atmosphere. For our own Solar System, the absolute outer edge of the habitable zone is at ∼2.4 AU.

We present a radiative equilibrium model for extrasolar giant planets applied to 51 Peg b. The atmospheric model extends from 10−5 to ∼10 bar and is limited at the bottom by an optically thick cloud of silicate (Mg2SiO4 or MgSiO3) or iron (Fe) particles. Rayleigh scattering at short wavelengths and absorption by the H2–H2 and H2–He continuum and molecular bands of H2O, CO, and CH4 are included. Atmospheric heating and cooling result, respectively, from absorption of stellar flux and from infrared thermal emission. The solution temperature profiles do not show any temperature inversion, in contrast with the giant planets of the solar system. The lapse rate is subadiabatic at all levels above the cloudtop, justifying the use of radiative equilibrium. We find that, under thermochemical equilibrium, CO dominates over CH4 at all levels. The effective temperature is in the range 1150–1270 K and the Bond albedo in the range 0.15–0.42, depending on the location and reflectivity of the lower cloud deck. Mg2SiO4 or Fe clouds are weakly reflective in contrast to a MgSiO3 cloud. The thermal emission spectrum prevails over the stellar reflected component below 13,000–15,000 cm−1 (λ>0.7 μm); it shows various windows, between the H2O and CO bands, with the brightest centered at 2550 cm−1 (3.9 μm). The most prominent CO and CH4 bands occur around 2100 (4.7 μm) and 3030 cm−1 (3.3 μm. Assuming a jovian abundance for PH3, the bands around 2300 (4.3 μm) and 2450 cm−1 (4.1 μm) are clearly visible in absorption at a resolving power of ∼100. We investigated the detectability of the minor species CO and CH4 at a resolution of 4000–6000, adequate to separate the planet's absorption features from their stellar and telluric counterparts. Considering photon noise from the star as the only noise source, we find that S/N ratios of about 8 are reached on the molecular features in the 4.7- and 3.3-μm regions after ∼10 h of integration on an 8-m telescope. On the other hand, the planet-to-star contrast is as low as (2–4)×10−4.

The atmospheres of extrasolar giant planets are modeled with various effective temperatures and gravities, with and without clouds. Bond albedos are computed by calculating the ratio of the flux reflected by a planet (integrated over wavelength) to the total stellar flux incident on the planet. This quantity is useful for estimating the effective temperature and evolution of a planet. We find it is sensitive to the stellar type of the primary. For a 5 M_Jup planet the Bond albedo varies from 0.4 to 0.3 to 0.06 as the primary star varies from A5V to G2V to M2V in spectral type. It is relatively insensitive to the effective temperature and gravity for cloud--free planets. Water clouds increase the reflectivity of the planet in the red, which increases the Bond albedo. The Bond albedo increases by an order of magnitude for a 13 M_Jup planet with an M2V primary when water clouds are present. Silicate clouds, on the other hand, can either increase or decrease the Bond albedo, depending on whether there are many small grains (the former) or few large grains (the latter)., Comment: 6 pages, 9 figures, uses egs.cls and epsfig.sty, submitted to Physics and Chemistry of the Earth (proceedings of the April 1998 EGS meeting in Nice, France)

The Galileo probe net flux radiometer (NFR) measured radiation fluxes in Jupiter's atmosphere from about 0.44 to 14 bars, using five spectral channels to separate solar and thermal components. Onboard calibration results confirm that the NFR responded to radiation approximately as expected. NFR channels also responded to a superimposed thermal perturbation, which can be approximately removed using blind channel measurements and physical constraints. Evidence for the expected NH3 cloud was seen in the spectral character of spin-induced modulations of the direct solar beam signals. These results are consistent with an overlying cloud of small NH3 ice particles (0.5-0.75 microns in radius) of optical depth 1.5-2 at 0.5 microns. Such a cloud would have so little effect on thermal fluxes that NFR thermal channels provide no additional constraints on its properties. However, evidence for heating near 0.45 bar in the NFR thermal channels would seem to require either an additional opacity source beyond this small-particle cloud, implying a heterogeneous cloud structure to avoid conflicts with solar modulation results, or a change in temperature lapse rate just above the probe measurements. The large thermal flux levels imply water vapor mixing ratios that are only 6% of solar at 10 bars, but possibly increasing with depth, and significantly subsaturated ammonia at pressures less than 3 bars. If deep NH3 mixing ratios at the probe entry site are 3-4 times ground-based inferences, as suggested by probe radio signal attenuation, then only half as much water is needed to match NFR observations. No evidence of a water cloud was seen near the 5-bar level. The 5-microns thermal channel detected the presumed NH4SH cloud base near 1.35 bars. Effects of this cloud were also seen in the solar channel upflux measurements but not in the solar net fluxes, implying that the cloud is a conservative scatterer of sunlight. The minor thermal signature of this cloud is compatible with particle radii near 3 gm, but it cannot rule out smaller particles. Deeper than about 3 bars, solar channels indicate unexpectedly large absorption of sunlight at wavelengths longer than 0.6 microns, which might be due to unaccounted-for absorption by NH3 between 0.65 and 1.5 microns.

The discovery of planets around nearby stars gives us hope that life may be able to develop close to our solar system. It should also shed light on the problem of the formation of planets in general. In the past few years, we have developed theoretical evolutionary models of solar and extrasolar giant planets. With the help of these models, we discuss the nature and characteristics of these «new planets», in aid of both NASA’s and ESA’s recent plans to directly detect them.

As gas giant planets and brown dwarfs radiate away the residual heat from their formation, they cool through a spectral type transition from L to T, which encompasses the dissipation of cloud opacity and the appearance of strong methane absorption. While there are hundreds of known T-type brown dwarfs, the first generation of directly-imaged exoplanets were all L-type. Recently, Kuzuhara et al. (2013) announced the discovery of GJ 504 b, the first T dwarf exoplanet. GJ 504 b provides a unique opportunity to study the atmosphere of a new type of exoplanet with a ~500 K temperature that bridges the gap between the first directly imaged planets (~1000 K) and our own Solar System's Jupiter (~130 K). We observed GJ 504 b in three narrow L-band filters (3.71, 3.88, and 4.00 microns), spanning the red end of the broad methane fundamental absorption feature (3.3 microns) as part of the LEECH exoplanet imaging survey. By comparing our new photometry and literature photometry to a grid of custom model atmospheres, we were able to fit GJ 504 b's unusual spectral energy distribution for the first time. We find that GJ 504 b is well-fit by models with the following parameters: T_eff=544+/-10 K, g, resubmitted to ApJ with referee's comments

Of the over 800 exoplanets detected to date, over half are on non-circular orbits, with eccentricities as high as 0.93. Such orbits lead to time-variable stellar heating, which has implications for the planet's atmospheric dynamical regime. However, little is known about this dynamical regime, and how it may influence observations. Therefore, we present a systematic study of hot Jupiters on highly eccentric orbits using the SPARC/MITgcm, a model which couples a three-dimensional general circulation model with a plane-parallel, two-stream, non-grey radiative transfer model. In our study, we vary the eccentricity and orbit-average stellar flux over a wide range. We demonstrate that the eccentric hot Jupiter regime is qualitatively similar to that of planets on circular orbits; the planets possess a superrotating equatorial jet and exhibit large day-night temperature variations. We show that these day-night heating variations induce momentum fluxes equatorward to maintain the superrotating jet throughout its orbit. As the eccentricity and/or stellar flux is increased, the superrotating jet strengthens and narrows, due to a smaller Rossby deformation radius. For a select number of model integrations, we generate full-orbit lightcurves and find that the timing of transit and secondary eclipse viewed from Earth with respect to periapse and apoapse can greatly affect what we see in infrared (IR) lightcurves; the peak in IR flux can lead or lag secondary eclipse depending on the geometry. For those planets that have large day-night temperature variations and rapid rotation rates, we find that the lightcurves exhibit "ringing" as the planet's hottest region rotates in and out of view from Earth. These results can be used to explain future observations of eccentric transiting exoplanets., 20 pages, 18 figures, 2 tables; Accepted to ApJ

Motivated by recent spectroscopic evidence for carbon-rich atmospheres on some transiting exoplanets, we investigate the influence of the C/O ratio on the chemistry, composition, and spectra of extrasolar giant planets both from a thermochemical-equilibrium perspective and from consideration of disequilibrium processes like photochemistry and transport-induced quenching. We find that although CO is predicted to be a major atmospheric constituent on hot Jupiters for all C/O ratios, other oxygen-bearing molecules like H2O and CO2 are much more abundant when C/O < 1, whereas CH4, HCN, and C2H2 gain significantly in abundance when C/O > 1. Disequilibrium processes tend to enhance the abundance of CH4, NH3, HCN, and C2H2 over a wide range of C/O ratios. We compare the results of our models with secondary-eclipse photometric data from the Spitzer Space Telescope and conclude that (1) disequilibrium models with C/O ~ 1 are consistent with spectra of WASP-12b, XO-1b, and CoRoT-2b, confirming the possible carbon-rich nature of these planets, (2) spectra from HD 189733b are consistent with C/O ~< 1, but as the assumed metallicity is increased above solar, the required C/O ratio must increase toward 1 to prevent too much H2O absorption, (3) species like HCN can have a significant influence on spectral behavior in the 3.6 and 8.0 um Spitzer channels, potentially providing even more opacity than CH4 when C/O > 1, and (4) the very high CO2 abundance inferred for HD 189733b from near-infrared observations cannot be explained through equilibrium or disequilibrium chemistry in a H2-dominated atmosphere. We discuss possible formation mechanisms for carbon-rich hot Jupiters. The C/O ratio and bulk atmospheric metallicity provide important clues regarding the formation and evolution of the giant planets., accepted in the Astrophysical Journal

We present moderate-resolution (lambda/delta lambda = 300 to 370) reflectance spectra of Mars from 2.04 to 2.44 micrometers that were obtained at UKIRT during the 1993 opposition. Seven narrow absorption features were detected and found to have a Mars origin. By comparison with solar and Mars atmospheric spectra, five of these features were attributed all or in part to Mars atmospheric CO2 or CO(2.052 +/- 0.003, 2.114 +/- 0.002, 2.150 +/- 0.003, 2.331 +/- 0.001, and 2.357 +/- 0.002 micrometers). Two of the bands (2.331 +/- 0.001 and 2.357 +/- 0.002 micrometers) appear to have widths and depths that are consistent with additional, nonatmospheric absorptions, although a solar contribution cannot be entirely ruled out. Two other weak bands centered at 2.278 +/- 0.002 and 2.296 +/- 0.002 micrometers may be at least partially mineralogic in origin. The data provide no conclusive identification of the mineralogy responsible for these absorption features. However, examination of terrestrial spectral libraries and previous moderate spectral resolution mineral studies indicates that the most likely origin of these features is either (bi)carbonate or (bi)sulfate anions in framework silicates or (Fe, Mg)-OH bonds in sheet silicates. If the bands are caused by phyllosilicate minerals, then an explanation must be found for the extremely narrow widths of the cation-OH features in the Mars spectra as compared to terrestrial minerals.

We present the discovery of seven ultracool brown dwarfs identified with the Wide-field Infrared Survey Explorer (WISE). Near-infrared spectroscopy reveals deep absorption bands of H[subscript 2]O and CH[subscript 4] that indicate all seven of the brown dwarfs have spectral types later than UGPS J072227.51–054031.2, the latest-type T dwarf currently known. The spectrum of WISEP J182831.08+265037.8 is distinct in that the heights of the J- and H-band peaks are approximately equal in units of f [subscript λ], so we identify it as the archetypal member of the Y spectral class. The spectra of at least two of the other brown dwarfs exhibit absorption on the blue wing of the H-band peak that we tentatively ascribe to NH[subscript 3]. These spectral morphological changes provide a clear transition between the T dwarfs and the Y dwarfs. In order to produce a smooth near-infrared spectral sequence across the T/Y dwarf transition, we have reclassified UGPS 0722–05 as the T9 spectral standard and tentatively assign WISEP J173835.52+273258.9 as the Y0 spectral standard. In total, six of the seven new brown dwarfs are classified as Y dwarfs: four are classified as Y0, one is classified as Y0 (pec?), and WISEP J1828+2650 is classified as >Y0. We have also compared the spectra to the model atmospheres of Marley and Saumon and infer that the brown dwarfs have effective temperatures ranging from 300 K to 500 K, making them the coldest spectroscopically confirmed brown dwarfs known to date., University of California, San Diego (Chris and Warren Hellman Fellowship Program), United States. National Aeronautics and Space Administration (Postdoctoral Program)

There have been several reports of methane on Mars at the 10–60 ppbv level. Most suggest that methane is both seasonally and latitudinally variable. Here we review why variable methane on Mars is physically and chemically implausible, and then we critically review the published reports. There is no known mechanism for destroying methane chemically on Mars. But if there is one, methane oxidation would deplete the O 2 in Mars’s atmosphere in less than 10,000 years unless balanced by an equally large unknown source of oxidizing power. Physical sequestration does not raise these questions, but adsorption in the regolith or condensation in clathrates ignore competition for adsorption sites or are inconsistent with clathrate stability, respectively. Furthermore, any mechanism that relies on methane’s van der Waals’ attraction is inconsistent with the continued presence of Xe in the atmosphere at the 60 ppbv level. We then use the HITRAN database and transmission calculations to identify and characterize the absorption lines that would be present on Earth or Mars at the wavelengths of the published observations. These reveal strong competing telluric absorption that is most problematic at just those wavelengths where methane’s signature seems most clearly seen from Earth. The competing telluric lines must be removed with models. The best case for martian methane was made for the 12 CH 4 ν 3 R0 and R1 lines seen in blueshift when Mars was approaching Earth in early 2003 (Mumma, M.J., Villanueva, G.L., Novak, R.E., Hewagama, T., Bonev, B.P., DiSanti, M.A., Mandell, A.M., Smith, M.D. [2009]. Science 323, 1041–1045). For these the Doppler shift moves the two martian lines into near coincidence with telluric 13 CH 4 ν 3 R1 and R2 lines that are 10–50× stronger than the inferred martian lines. By contrast, the 12 CH 4 ν 3 R0 and R1 lines when observed in redshift do not contend with telluric 13 CH 4 . For these lines, Mumma et al.’s observations and analyses are consistent with an upper limit on the order of 3 ppbv.

The near-IR spectra of the Venus nightside emission are here simulated by means of a radiative transfer code that allows for emission, absorption, and scattering by atmospheric gases and particles. An effort is made to assess the adequacy of current gas data bases in simulating Venus' nightside near-IR spectra and, within these limitations, to derive information on gas abundances below the main clouds and these clouds' optical thickness. It is in this way established that the HITRAN data base for the permitted transitions of CO2 is completely inadequate for simulating the Venus nightside near-IR emissions.

GJ436b is a unique member of the transiting extrasolar planet population being one of the smallest and least irradiated and possessing an eccentric orbit. Because of its size, mass and density, GJ436b could plausibly have an atmospheric metallicity similar to Neptune (20-60 times solar abundances), which makes it an ideal target to study the effects of atmospheric metallicity on dynamics and radiative transfer in an extrasolar planetary atmosphere. We present three-dimensional atmospheric circulation models that include realistic non-gray radiative transfer for 1, 3, 10, 30, and 50 times solar atmospheric metallicity cases of GJ436b. Low metallicity models (1 and 3 times solar) show little day/night temperature variation and strong high-latitude jets. In contrast, higher metallicity models (30 and 50 times solar) exhibit day/night temperature variations and a strong equatorial jet. Spectra and light curves produced from these simulations show strong orbital phase dependencies in the 50 times solar case and negligible variations with orbital phase in the 1 times solar case. Comparisons between the predicted planet/star flux ratio from these models and current secondary eclipse measurements support a high metallicity atmosphere (30-50 times solar abundances) with disequilibrium carbon chemistry at play for GJ436b. Regardless of the actual atmospheric composition of GJ436b, our models serve to illuminate how metallicity influences the atmospheric circulation for a broad range of warm extrasolar planets., 25 pages, 13 figures

We present global, three-dimensional numerical simulations of HD 189733b and HD 209458b that couple the atmospheric dynamics to a realistic representation of non-gray cloud-free radiative transfer. The model, which we call the Substellar and Planetary Atmospheric Radiation and Circulation (SPARC) model, adopts the MITgcm for the dynamics and uses the radiative model of McKay, Marley, Fortney, and collaborators for the radiation. Like earlier work with simplified forcing, our simulations develop a broad eastward equatorial jet, mean westward flow at higher latitudes, and substantial flow over the poles at low pressure. For HD 189733b, our simulations without TiO and VO opacity can explain the broad features of the observed 8 and 24-micron light curves, including the modest day-night flux variation and the fact that the planet/star flux ratio peaks before the secondary eclipse. Our simulations also provide reasonable matches to the Spitzer secondary-eclipse depths at 4.5, 5.8, 8, 16, and 24 microns and the groundbased upper limit at 2.2 microns. However, we substantially underpredict the 3.6-micron secondary-eclipse depth, suggesting that our simulations are too cold in the 0.1-1 bar region. Predicted temporal variability in secondary-eclipse depths is ~1% at Spitzer bandpasses, consistent with recent observational upper limits at 8 microns. We also show that nonsynchronous rotation can significantly alter the jet structure. For HD 209458b, we include TiO and VO opacity; these simulations develop a hot (>2000 K) dayside stratosphere. Despite this stratosphere, we do not reproduce current Spitzer photometry of this planet. Light curves in Spitzer bandpasses show modest phase variation and satisfy the observational upper limit on day-night phase variation at 8 microns. (abridged), 20 pages (emulate-apj format), 21 figures, final version now published in ApJ. Includes expanded discussion of radiative-transfer methods and two new figures

We develop a new 1D photochemical kinetics code to address stratospheric chemistry and stratospheric heating in hot Jupiters. Here we address optically active S-containing species and CO2 at 1200 < T < 2000 K. HS (mercapto) and S2 are highly reactive species that are generated photochemically and thermochemically from H2S with peak abundances between 1-10 mbar. S2 absorbs UV between 240 and 340 nm and is optically thick for metallicities [SH] > 0 at T > 1200 K. HS is probably more important than S2, as it is generally more abundant than S2 under hot Jupiter conditions and it absorbs at somewhat redder wavelengths. We use molecular theory to compute an HS absorption spectrum from sparse available data and find that HS should absorb strongly between 300 and 460 nm, with absorption at the longer wavelengths being temperature sensitive. When the two absorbers are combined, radiative heating (per kg of gas) peaks at 100 microbars, with a total stratospheric heating of about 8 x 10^4 W/m^2 for a jovian planet orbiting a solar-twin at 0.032 AU. Total heating is insensitive to metallicity. The CO2 mixing ratio is a well-behaved quadratic function of metallicity, ranging from 1.6 x 10^-8 to 1.6 x 10^-4 for -0.3 < [M/H] < 1.7. CO2 is insensitive to insolation, vertical mixing, temperature (1200 < T, Astrophysical Journal Lett. in press; important revision includes effect of updated thermodynamic data and a new opacity source

We compute models of the transmission spectra of planets HD 209458b, HD 189733b, and generic hot Jupiters. We examine the effects of temperature, surface gravity, and metallicity for the generic planets as a guide to understanding transmission spectra in general. We find that carbon dioxide absorption at 4.4 and 15 microns is prominent at high metallicity, and is a clear metallicity indicator. For HD 209458b and HD 189733b, we compute spectra for both one-dimensional and three-dimensional model atmospheres and examine the differences between them. The differences are usually small, but can be large if atmospheric temperatures are near important chemical abundance boundaries. The calculations for the 3D atmospheres, and their comparison with data, serve as constraints on these dynamical models that complement the secondary eclipse and light curve data sets. For HD 209458b, even if TiO and VO gases are abundant on the day side, their abundances can be considerably reduced on the cooler planetary limb. However, given the predicted limb temperatures and TiO abundances, the model's optical opacity is too high. For HD 189733b we find a good match with some infrared data sets and constrain the altitude of a postulated haze layer. For this planet, substantial differences can exist between the transmission spectra of the leading and trailing hemispheres, which is an excellent probe of carbon chemistry. In thermochemical equilibrium, the cooler leading hemisphere is methane-dominated, and the hotter trailing hemisphere is CO-dominated, but these differences may be eliminated by non-equilibrium chemistry due to vertical mixing. It may be possible to constrain the carbon chemistry of this planet, and its spatial variation, with JWST., Comment: Revised for ApJ. Submitted 9/16/2009. 20 pages, including figures

The Martian southern hemisphere atmospheric water vapor column abundance measurements reported agree with Viking Orbiter atmospheric water detectors during early southern spring and southern autumnal equinox; profiles obtained in southern mid- and late summer, however, indicate the presence of twice as much water both in the southern hemisphere and planetwide. This discrepancy is accounted for by the high optical depths created by two global dust storms during the Viking year, while the present observations were obtained in the case of the relatively dust-free atmosphere of the 1988-1989 opposition.

We highlight the importance of gaseous TiO and VO opacity on the highly irradiated close-in giant planets. The atmospheres of these planets naturally fall into two classes that are somewhat analogous to the M- and L-type dwarfs. Those that are warm enough to have appreciable opacity due to TiO and VO gases we term the ``pM Class'' planets, and those that are cooler we term ``pL Class'' planets. We calculate model atmospheres for these planets, including pressure-temperature profiles, spectra, and characteristic radiative time constants. We show that pM Class planets have hot stratospheres $\sim$2000 K and appear ``anomalously'' bright in the mid infrared secondary eclipse, as was recently found for planets HD 149026b and HD 209458b. This class of planets absorbs incident flux and emits thermal flux from high in their atmospheres. Consequently, they will have large day/night temperature contrasts and negligible phase shifts between orbital phase and thermal emission light curves, because radiative timescales are much shorter than possible dynamical timescales. The pL Class planets absorb incident flux deeper in the atmosphere where atmospheric dynamics will more readily redistribute absorbed energy. This will lead to cooler day sides, warmer night sides, and larger phase shifts in thermal emission light curves. Around a Sun-like primary this boundary occurs at $\sim$0.04-0.05 AU. The eccentric transiting planets HD 147506b and HD 17156b alternate between the classes. Thermal emission in the optical from pM Class planets is significant red-ward of 400 nm, making these planets attractive targets for optical detection. The difference in the observed day/night contrast between ups Andromeda b (pM Class) and HD 189733b (pL Class) is naturally explained in this scenario. (Abridged.), Accepted to the Astrophysical Journal

We explore the infrared spectrum of a three-dimensional dynamical model of planet HD209458b as a function of orbital phase. The dynamical model predicts day-side atmospheric pressure-temperature profiles that are much more isothermal at pressures less than 1 bar than one-dimensional radiative-convective models have found. The resulting day-side thermal spectra are very similar to a blackbody, and only weak water absorption features are seen at short wavelengths. The dayside emission is consequently in significantly better agreement with ground-based and space-based secondary eclipse data than any previous models, which predict strong flux peaks and deep absorption features. At other orbital phases, absorption due to carbon monoxide and methane is also predicted. We compute the spectra under two treatments of atmospheric chemistry: one uses the predictions of equilibrium chemistry, and the other uses non-equilibrium chemistry, which ties the timescales of methane and carbon monoxide chemistry to dynamical timescales. As a function of orbital phase, we predict planet-to-star flux ratios for standard infrared bands and all Spitzer Space Telescope bands. In Spitzer bands, we predict 2-fold to 15-fold variation in planetary flux as a function of orbital phase with equilibrium chemistry, and 2-fold to 4-fold variation with non-equilibrium chemistry. Variation is generally more pronounced in bands from 3-10 $\mu$m than at longer wavelengths. The orbital phase of maximum thermal emission in infrared bands is 15--45 orbital degrees before the time of secondary eclipse. Changes in flux as a function of orbital phase for HD209458b should be observable with Spitzer, given the previously acheived observational error bars., Comment: Accepted to the Astrophysical Journal, 8/10/06. Includes 5 color figures

We present new infrared spectra of the T8 brown dwarf 2MASS J04151954-0935066: 2.9-4.1 micron spectra obtained with the Infrared Camera and Spectrograph on the Subaru Telescope, and 5.2-14.5 micron spectra obtained with the Infrared Spectrograph on the Spitzer Space Telescope. We use these data and models to determine an accurate bolometric luminosity of log L_bol/L_sun=-5.67 and to constrain the effective temperature, gravity, mass and age to 725-775K, log g=5.00-5.37, M=33-58 M_Jupiter and age=3-10Gyr. We perform the same analysis using published 0.6-15 micron spectra for the T7.5 dwarf 2MASS J12171110-0311131, for which we find a metal-rich composition ([Fe/H]~0.3) and log L_bol/L_sun=-5.31, T_eff=850-950K, log g=4.80-5.42, M=25-66M_Jupiter and age=1-10Gyr. These luminosities and effective temperatures straddle those determined with the same method and models for Gl 570D by Saumon et al. (2006) and make 2MASS J04151954-0935066 the coolest and least luminous T dwarf with well-determined properties. We find that synthetic spectra generated by the models reproduce the observed red through mid-infrared spectra of 2MASS J04151954-0935066 and 2MASS J12171110-0311131 very well, except for known discrepancies which are most likely due to the incomplete CH4 opacities. Both objects show evidence of departures from strict chemical equilibrium and we discuss this result in the context of other late T dwarfs where disequilibrium phenomena have been observed., Comment: Accepted for publication in the Ap. J. 35 pages, including 12 figures (10 in color)

Earth appears to have been warm during its early history despite the faintness of the young Sun. Greenhouse warming by gaseous CO 2 and H 2 O by itself is in conflict with constraints on atmospheric CO 2 levels derived from paleosols for early Earth. Here we explore whether greenhouse warming by methane could have been important. We find that a CH 4 mixing ratio of 10 -4 (100 ppmv) or more in Earth's early atmosphere would provide agreement with the paleosol data from 2.8 Ga. Such a CH 4 concentration could have been readily maintained by methanogenic bacteria, which are thought to have been an important component of the biota at that time. Elimination of the methane component of the greenhouse by oxidation of the atmosphere at about 2.3 - 2.4 Ga could have triggered the Earth's first widespread glaciation.