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In recent years, hybrid light-emitting diodes based on quantum dots and organic emitters (QD-OLEDs) have been extensively researched. QD-OLEDs have promising applications in the fields of lighting and displays due to the advantages, such as high efficiency, stable emission, high brightness, and superior color rendering properties. In this paper, we have summarized the state-of-the-art concepts to achieve high-performance QD-OLEDs. First, we introduce the emission principles of QDs and organic emitters and clarify their advantages in QD-OLEDs. In addition, we summarize the main approaches to realize QD-OLEDs, which combine the use of organic emitting materials with cadmium-containing QDs, InP-based QDs, perovskite QDs, or other sulfide-based QDs. Then, we conclude the typical methods to improve the device performance, including the regulation of the thickness of organic emitting layers, optimization of hole injection layers, selection of anode materials, and manipulation of QDs concentration. Finally, according to the current development status of QD-OLED technology, an outlook is provided regarding its future development trends and potential directions for further optimization. • This is the first paper to comprehensively review the development of hybrid LEDs based on QDs and organic emitters. • State-of-the-art concepts to achieve high-performance QD-OLEDs are summarized. • Typical methods to improve the device performance are highlighted. [ABSTRACT FROM AUTHOR]

This paper aims to investigate the effects of stress aging treatment on the microstructure, mechanical properties and corrosion behavior of Al-Zn-Mg-Cu alloy. The alloys were subjected to SAT and stress-free aging treatment (SFAT) at 175 °C under different aging stress and aging time conditions. Various analytical techniques, including scanning electron microscopy (SEM), electron back-scatter diffraction (EBSD), transmission electron microscopy (TEM), slow strain rate tensile, X-ray Diffraction (XRD) and potentiodynamic polarization, were employed to obtain results. The findings demonstrate heightened strength, improved corrosion resistance under SAT conditions in contrast to SFAT. The alloys subjected to SAT exhibit higher strength compared to SFAT, attributed to the diffusion of stress-induced dislocations and extensive nucleation of matrix precipitates. Furthermore, the presence of large-sized and discontinuous grain boundary precipitates impedes the anodic dissolution of grain boundaries and the expansion of stress corrosion, contributing to the enhanced corrosion resistance of the alloy. • The strength of the alloys showed an increasing and then decreasing trend with increasing applied stress, the correct application of SAT can improve the strength of alloys. • SAT results in lower I corr values compared to SFAT. S100 exhibits a larger capacitance arc in the Nyquist plots, indicative of superior corrosion resistance. • SAT improves the mechanical properties of the alloy. Applied stress facilitates dislocation diffusion and aggregation, creating additional nucleation sites that promote the nucleation and growth of precipitated phases. • SAT improves the corrosion resistance of the alloy. Applying aging stress beyond a specific threshold and extending the aging time both facilitated Gbps growth and widened the PFZ. Thereby enhancing the alloy's corrosion resistance. [ABSTRACT FROM AUTHOR]

• A clockwise P–T path was established for Chachahe eclogites in North Qaidam UHP belt, NW China. • The Chachahe eclogites experienced a 1.92 Ga metamorphic event prior to eclogitization at ∼ 450 Ma. • Overriding plate material can enter subduction channel via tectonic erosion and be carried to mantle depths of ≥ 85 km. Although numerical modelling and marine seismic data show that overriding plate material can enter subduction channel and even recycle to mantle, and finally contribute to mantle heterogeneity and arc magmas, protoliths of the majority of high pressure (HP) and ultrahigh pressure (UHP) metamorphic rocks on the earth's surface originate from the subducting plate. Whether overriding plate material can enter subduction channel and their fate in subduction channel remain enigmas. The North Qaidam UHP Metamorphic Belt (NQUB), located in northwestern China, was formed by north-dipping subduction of the Qaidam Block beneath the Quanji block in the Early Paleozoic. In this paper, we report that some eclogites in Chachahe area, NQUB experienced a 1.92 Ga low-grade metamorphism prior to eclogitization at ∼ 450 Ma. This Paleoproterozoic metamorphic event is not reported in the subducted Qaidam Block but widespread in the overriding Quanji Block, indicating that protoliths of Chachahe eclogites originated from the overriding plate. A clockwise P–T path from 12 kbar/520 °C to near UHP conditions of 25.5 kbar/690 °C, followed by isothermal decompression, was estimated for the Early Paleozoic metamorphism using a combination of garnet major and trace element zoning, phase equilibrium modelling and thermobarometry. This P–T path pattern is similar to other eclogites in this area, protoliths of which originated from the subducted plate. These results clearly show that overriding plate material can enter subduction channel and be carried to mantle depths of at least 85 km and exhume fast along subduction channel with other slices from subducted slab. [ABSTRACT FROM AUTHOR]

An integrated study including petrography, mineral chemistry, metamorphic P–T path modelling, and zircon U–Pb dating was conducted on a granitic gneiss and enclosed eclogite from South Dulan, North Qaidam UHP (ultrahigh-pressure) belt. The result shows that the granitic gneiss underwent a clockwise P–T path with a peak-P stage at 655–745°C, 30–34 kbar, and a subsequent peak-T stage at 815–870°C, 14–18 kbar, which is similar to the P–T estimates reported for coesite-bearing continental-type eclogites in this region. The enclosed eclogite resembles an olivine–pyroxene-rich cumulate in Qaidam block. It has a similar prograde P–T path with the country gneiss and experienced a peak-P stage of 682–748°C at 27–34 kbar. Zircon U–Pb dating yields an eclogite-facies metamorphic age of 447 ± 2 Ma for the granitic gneiss and 445 ± 6 Ma for the enclosed eclogite. These ages agree with metamorphic ages obtained from paragneisses (427–439 Ma), coesite-bearing continental-type eclogites (430–451 Ma), and UHPM (ultrahigh-pressure metamorphic) oceanic crust–mantle sequence (440–445 Ma) from South Dulan, as well as UHP eclogites, garnet peridotite, and gneisses from other units (460–420 Ma) within this belt reported by others. Similar metamorphic ages as well as P–T evolution documented in gneisses and intercalated eclogites imply that both rocks experienced a coeval UHP event. Summarizing all the published geochronology data, we argue that the North Qaidam UHP belt was mainly formed by continental deep subduction at ~460 to ~420 Ma. The UHPM oceanic crust-mantle sequence in South Dulan may represent oceanic lithosphere in the transition zone between oceanic and continental crust, which was dragged upward by the exhumed continental rocks after break-off of the dense oceanic crust. [ABSTRACT FROM PUBLISHER]

Flexible printed carbon-nanotube-thin-film-transistors (CNT-TFTs) with characteristics of low cost, low operating voltage, low power consumption, and signal amplification have great potential for emerging electronics powered by self-powered systems or low-power density thin-film solar cells. In this work, we have fabricated flexible printed CNT-TFTs using the printing process to selectively deposit semiconducting CNTs in device channels as channel materials, printed silver electrodes as side gates, and printed ion gel as the dielectric layer. The as-prepared TFTs exhibited an extremely high sensitivity to H 2 S (up to 1565% ppm-1) at room temperature (25 ℃) and the relative humidity (RH) of 5%, excellent signal amplification (response increased from 1% to 4045.5% towards 2 ppm H 2 S), ultra-low working power consumption (1.03 nW under 2 ppm H 2 S), excellent selectivity, fast response/recovery time (10 s/26 s) and great mechanical flexibility (stable after 10,000 times bending with 5 mm radius). The outstanding improvement of sensor characteristics was related to the enrichment and absorption of H 2 S by ionic liquids, and the resistor-mode device's response to 2 ppm H 2 S increased from ~1% to 80% after the device channel was covered by ion gel. To the best of our knowledge, our H 2 S sensors demonstrated the recorded low power consumption (1.03 nW) and high response (4045.4%) when exposed to 2 ppm H 2 S at room temperature, making our sensors a promising candidate for portable applications in gas detection. • High sensitivity ~1565 % ppm-1, and high response of 4045.4 % H 2 S sensors at room temperature have been developed. • Response of H 2 S sensors based on CNT-TFTs could be 3 orders of magnitude larger than resistor-mode sensors. • Ion gels used in our sensor, have great signal amplification ability and high-efficiently absorption and accumulation of H 2 S. • The power consumption of H 2 S sensors we fabricated is about 1.03 nW under 2 ppm H 2 S, which is the recorded lowest. [ABSTRACT FROM AUTHOR]

Two-dimensional (2D) nanocrystals are promising for optoelectronic and microelectronic technologies. However, the performance of 2D nanocrystal light-emitting diodes (LEDs) remains limited. Here, exciton dynamics are rationally controlled by both shell engineering and device engineering, obtaining colloidal quantum well LEDs (CQW-LEDs) with superior performance. The formation of CQW films on charge transport layers shows an excellent photoluminescence quantum yield of 76.63%. An unreported relationship among Auger lifetime, electron confinement energy, and external quantum efficiency (EQE) in 2D nanocrystal devices is directly observed. The optimized CQW-LEDs possess a maximum power efficiency of 6.04 lm W−1 and a current efficiency of 9.20 cd A−1, setting record efficiencies for 2D nanocrystal red LEDs. Additionally, a remarkable EQE of 13.43% has been achieved, accompanied by an exceptionally low efficiency roll-off. Significantly, EQE for flexible CQW-LEDs is 42-fold higher than the previous best results. Furthermore, active-matrix CQW-LEDs on printed circuit boards are developed. The findings not only unlock new possibilities for controlling exciton dynamics but also provide an alternative strategy to achieve high-performance 2D nanocrystal based applications. [ABSTRACT FROM AUTHOR]

• Some eclogites experienced ca. 929–916 Ma amphibolite-facies and ca. 439–430 UHP metamorphism. • The Neoproterozoic metamorphism is related to the assembly of the supercontinent Rodinia. • Mesoproterozoic to early Paleozoic tectonic evolution of the NQOB is reconstructed. • The Qaidam Block was probably the eastward extension of the Tarim Block during the Neoproterozoic. Eclogites documenting two orogenic cycles not only contain essential information on subduction and exhumation mechanisms during the most recent orogenic cycle, but can also provide insights into the earlier cycle. Such rocks are ideal for deciphering the tectonic evolution of orogenic belts with a multi-orogenic history. This is the case for the North Qaidam orogenic belt (NQOB) in northwest China where, for the first time, we have discovered eclogites that preserve a record of two orogenic cycles. The first orogenic event occurred at ca. 929–916 Ma and the second at ca. 439–430 Ma. The metamorphic P–T conditions of these two events were 5.0–7.0 kbar/616–669 °C and 29.0–32.5 kbar/620–670 °C, respectively. Zircon U–Pb dating yielded protolith ages of 1280–1070 Ma for these eclogites, which are much older than the protolith ages for other eclogites in the NQOB. The eclogites exhibit chondrite-normalized rare earth element patterns that are flat or depleted in light rare earth elements, similar to present-day N- and E-MORB. Magmatic zircon cores from the eclogites have high ε Hf (t) values of 8.4 ± 4.0 to 18.1 ± 1.1, comparable to depleted mantle within uncertainty, and indicating a juvenile crustal origin. Our data show that the eclogite protoliths were probably pre-Rodinia Mesoproterozoic oceanic crust that was emplaced in an active continental margin during oceanic subduction, and experienced Neoproterozoic metamorphism related to the amalgamation of Rodinia and early Paleozoic continental deep subduction. Using published data for all eclogites and their host gneisses, we reconstructed the Mesoproterozoic to early Paleozoic tectonic evolution of the NQOB. Given the similar Meso–Neoproterozoic evolution of the NQOB and adjacent Tarim Block, we suggest that the Qaidam Block was the eastward extension of the Tarim Block during the Neoproterozoic. [ABSTRACT FROM AUTHOR]

The North Qaidam is an Early Paleozoic UHP metamorphic belt located at the north margin of the Tibet plateau. Eclogites in this belt contain both continental‐and oceanic‐type ones. In which, the continental‐type eclogites have protolith ages of 750–850 Ma and WPB or CFB geochemical signatures and are believed to have formed in a continental rift or an incipient oceanic basin setting related to the breakup of the Rodinia supercontinent, their metamorphic ages (421–458 Ma) and P–T paths are comparable to their host gneisses; oceanic‐type eclogites have cumulate gabbro or E‐MORB geochemical signatures, their protolith and metamorphic ages are 510–516 Ma and 425–450 Ma, respectively(Zhang et al., 2008). Therefore, the North Qaidam UHP belt was thought to record the whole Neoprotoerozoic–Paleozoic Wilson cycle (Song et al., 2014). In this study, we reported three new kinds of eclogites: kyanite‐bearing eclogite, lawsonite pseudomorph‐bearing eclogite and double mineral eclogite. They occur as big lentoid blocks in regional granitic gneiss in the western part of the belt. Phase equilibrium modelling and zircon LA‐ICPMS U‐Pb dating show that all these three eclogites experienced a clockwise P–T path with peak metamorphic conditions close to or fall in the coesite stability field, and their peak metamorphic age were around 436‐439 Ma, similar to those continental‐type eclogites in this belt. But their protolith ages are between 1273 and 1070 Ma, and some of them recorded an amphibolite facies metamorphic age of 927 Ma, and geochemical data and zircon Lu‐Hf and O isotope analysis indicate these eclogites have features of present day N‐MORB. Combined with the existing results, we propose that the North Qaidam is a polycyclic composite orogenwhich recorded tectonic evolution of Mesoproterozoic ocean floor spreading, assembly and breakup of Rodinia supercontinent, Early Paleozoic oceanic deep subduction and subsequently continental deep subduction. [ABSTRACT FROM AUTHOR]

• Three episodes granitic magmatism at ca. 1420 Ma, ca. 900 Ma and 780–750 Ma were identified in drill cores from the Qaidam basin. • Ca. 1.8–1.1 Ga, 1.0–0.9 Ga and 850–750 Ma three tectonic-thermal events of the Qaidam block correspond to the fragmentation of Columbia and the assembly and breakup of Rodinia. • The Qaidam block and Tarim craton likely constituted a unified block, and located at interior of Columbia but peripheral of Rodinia during Meso–Neoproterozoic. As a micro-continent lying at the junction of the North China, Yangtze, and Tarim Cratons in northwest China, the composition and tectonic-thermal history of the Qaidam Block not only are crucial for determining its tectonic attribute and relationships with surrounding cratons, but also can provide key constraints on convergence, fragmentation, and paleogeographic reconstruction of Columbia and Rodinia. In this study, systematic petrology, geochemistry, and zircon U–Pb–Hf isotope analyses were conducted on newly discovered Meso-Neoproterozoic granitic rocks from drill cores in the Qaidam basin and three stages granitic magmatism at ca. 1420 Ma, ca. 900 Ma and 780–750 Ma are yielded. The ca. 1420 Ma granitic rocks exhibit characteristics of highly fractionated I-type granites, with high Yb but low Sr contents, low Sr/Y and La/Yb ratios, high zircon saturation temperatures (774–831 ℃), and positive ε Hf (t) values (–0.04 to +11.35) with T DM2 values of 2178–1468 Ma, suggesting that they were mainly derived from the ancient crust with mantle magma input under an extensional setting. The ca. 900 Ma granitic rocks have high A/CNK values (1.01–1.21) and variable zircon ε Hf (t) values (–1.93 to + 6.58) with T DM2 ages between 1402 and 1910 Ma, indicating they are S-type granites formed by partial melting of sedimentary rocks in thickened crust. The ca. 780–750 Ma granites have high Zr + Nb + Ce + Y contents, 10000* Ga/Al ratios, and crystallization temperatures (mean = 808 ℃), belonging to the A 1 -type granite formed in a continental rift setting. Combined with the previous researches, the Meso-Neoproterozoic tectonic-thermal events in the Qaidam Block can be divided into three stages, 1.8–1.1 Ga, 1.0–0.9 Ga and 850–750 Ma, corresponding to the fragmentation of Columbia, and the assembly and breakup of Rodinia, respectively. Comparing the Qaidam Block with the surrounding blocks and the major cratons in Columbia and Rodinia, it is considered that the Qaidam Block was splited from the Tarim Craton and they may have occupied an interior position in Columbia but a peripheral position in Rodinia, connecting to the India and East Antarctica. [ABSTRACT FROM AUTHOR]

• Single-cell sequencing reveals that natural killer cells are most responsive to and damaged by the moxifloxacin environment. • Moxifloxacin environment promotes elevated cytokine and chemokine expression and activation of their signaling pathways in natural killer cells. • Moxifloxacin induces apoptosis by reducing mitochondrial DNA and inhibiting mitochondrial respiratory chain complex function in natural killer cells. • Moxifloxacin environment can activate immediate early response gene expression and mediate early activation response of natural killer cells. As antibiotics become more prevalent, accuracy and safety are critical. Moxifloxacin (MXF) have been reported to have immunomodulatory effects on a variety of immune cells and even anti-proliferative and pro-apoptotic effects, but the mechanism of action is not fully clear. Peripheral blood mononuclear cells (PBMC) from experimental groups of healthy adults (n = 3) were treated with MXF (10ug/ml) in vitro for 24 h. Single-cell sequencing was performed to investigate differences in the response of each immune cell to MXF. Flow cytometry determined differential gene expression in subsets of most damaged NK cells. Pseudo-time analysis identified drivers that influence MXF-stimulated cell differentiation. Detection of mitochondrial DNA and its involvement in the mitochondrial respiratory chain pathway clarifies the origin of MXF-induced stress injury. Moxifloxacin-environmental NK cells are markedly reduced: a new subset of NK cells emerges, and immediate-early-response genes in this subset indicate the presence of an early activation response. The inhibitory receptor-dominant subset shows enhanced activation, leading to increased expression of cytokines and chemokines. The near-mature subset showed greater cytotoxicity and the most pronounced cellular damage. CD56bright cells responded by antagonizing the regulation of activation and inhibitory signals, demonstrating a strong cleavage capacity. The severe depletion of mitochondrial genes was focused on apoptosis induced by the mitochondrial respiratory chain complex. NK cells exhibit heightened sensitivity to the MXF environment. Different NK subsets upregulate the expression of cytokines and chemokines through different activation pathways. Concurrently, MXF induces impairment of the mitochondrial oxidative phosphorylation system, culminating in apoptosis. [ABSTRACT FROM AUTHOR]

The North Qaidam Belt (NQDB) is an Early Paleozoic continental ultrahigh-pressure (UHP) metamorphic belt between the Qaidam Block and South Qilian Belt (SQB) in northwest China, and the UHP metamorphic rocks recorded differential/diachronous exhumation and anatexis histories. To constrain the multi-stage exhumation and the associated magmatism of the NQDB and its adjacent areas, an integrated study of petrology, geochemistry, zircon U Pb and Lu Hf isotopes was conducted on the OIB-like dolerite and A-type dacite porphyry from the SQB. The OIB-like dolerite is enriched in light rare-earth elements (LREEs), large ion lithophile elements (LILEs), and high field strength elements (HFSEs), and depleted in heavy rare-earth elements (HREEs), with a crystallization age of 425 ± 7 Ma and zircon ε Hf (t) values ranging from −4.2 to 0.3. Given that the oceanic/continental deep subduction occurred in this area during Early Paleozoic, the fertile mantle source of OIB-like dolerite was likely formed by the crust-mantle interaction between the oceanic crust and juvenile lithospheric mantle at the instability field of rutile above the subduction zone. The A-type dacite porphyry is enriched in Al, Fe, LILEs and LREEs, depleted in Ca, Mg, Ba, Sr, Eu and HFSEs, and is characterized by high Zr concentrations (231–271 ppm), 10,000*Ga/Al ratios (2.51–2.73) and crystallization temperatures (738–836 °C). Zircon U Pb and Lu Hf isotopic data reveal the dacite porphyry crystalized at 423 ± 5 Ma with zircon ε Hf (t) values ranging from −8.9 to −3.3. The inherited magmatic zircons gave a formation age of 472 ± 8 Ma with ε Hf (t) values ranging from −3.9 to −1.9, contemporaneous with the oceanic subduction-related magmatism in the NQDB, indicating the dacite porphyry may be derived from the Early Paleozoic arc. Combined with the previous studies on the UHP metamorphism (ca. 458–420 Ma), retrograde metamorphism (ca. 432–397 Ma), and anatexis (ca. 436–417 Ma) in the NQDB, we conclude that the breakoff of the oceanic lithosphere from the continental lithosphere triggered the thermal perturbation from the asthenosphere upwelling at ca. 425 Ma and the subsequent partial melting of the fertile metasomatized mantle and Early Paleozoic arc, forming the OIB-like dolerite and A-type dacite porphyry in the SQB. Moreover, the coeval mafic and felsic magmatism indicates an important tectonic transformation that the subducted continental crust experienced a localized detachment/exhumation before ca. 425 Ma and entire exhumation after slab breakoff. • Coeval (425–423 Ma) dolerite and dacite porphyry in the South Qilian Belt. • These magmas were caused by the slab breakoff. • The subducted continental plate experienced two stages of exhumation in the NQDB. [ABSTRACT FROM AUTHOR]

The North Qaidam orogenic belt (NQOB) lies at the northeast margin of Tibet Plateau, between the Qilian massif to the north and Qaidam massif to the south. It consists of predominantly gneisses and marbles with minor eclogite and garnet peridotite, and is known as an Early Paleozoic continental deep subduction ultrahigh pressure (UHP) metamorphic belt in northwest China. Recently some studies suggest that the NQOB experienced oceanic deep subduction prior to the continental deep subduction. However, the records of ocean events are rarely preserved because of the complex multi‐stage transformation. Therefore, whether the Early Paleozoic ocean exists and the formation, nature and evolution of the Early Paleozoic ocean in North Qaidam are still in controversies. In this contribution, we report a new discovered SSZ‐type ophiolite suite in Kaipinggou area, the western segment of the NQOB. The ophiolite is mainly composed of peridotite, gabbro, basalt, boninite, andesitic porphyrite and plagiogranite. In which, the basalt and homogeneous gabbro are both enriched in LILE and depleted in HFSE, and display flat or LREE‐depleted REE patterns, similar to the MORB‐like geochemical characteristics of fore‐arc basalts; the boninite exhibits characteristics of fore‐arc boninites with high Si and Mg, but low Ti and Ca contents; the andesitic porphyrite is enriched in LILE but depleted in HFSE, similar to island arc magmatic rocks. Rock assemblage and their geochemical characteristics suggest that this SSZ‐type ophiolite was formed in fore‐arc setting of intra‐oceanic arc. The plagiogranite is a low‐potassium tholeiite metaluminous granite with low trace elements contents, slight enrichment of LREE, depletion of HREE and positive Eu anomaly; combining with ∊Hf (t) values (13.8–17.1) of zircons, the plagiogranite could be originated from partial melting of gabbros. LA–ICP–MS zircon U–Pb dating yielded the crystallization ages of 535±2 Ma, 513±3 Ma and 510±3 Ma for two cumulate gabbros and one homogeneous gabbro, respectively, and a formation age of 492±8 Ma for the plagiogranite. All these data suggest the existence of an Early Paleozoic ocean in the North Qaidam, and the initial subduction of the oceanic slab occurred earlier than 535Ma. [ABSTRACT FROM AUTHOR]

The North Qaidam orogenic belt (NQOB) lies at the northeast margin of Tibet Plateau, between the Qilian massif to the north and Qaidam massif to the south. It consists of predominantly gneisses and marbles with minor eclogite and garnet peridotite, and is known as an Early Paleozoic continental deep subduction ultrahigh pressure (UHP) metamorphic belt in northwest China. Recently some studies suggest that the NQOB experienced oceanic deep subduction prior to the continental deep subduction. However, the records of ocean events are rarely preserved because of the complex multi‐stage transformation. Therefore, whether the Early Paleozoic ocean exists and the formation, nature and evolution of the Early Paleozoic ocean in North Qaidam are still in controversies. In this contribution, we report a new discovered SSZ‐type ophiolite suite in Kaipinggou area, the western segment of the NQOB. The ophiolite is mainly composed of peridotite, gabbro, basalt, boninite, andesitic porphyrite and plagiogranite. In which, the basalt and homogeneous gabbro are both enriched in LILE and depleted in HFSE, and display flat or LREE‐depleted REE patterns, similar to the MORB‐like geochemical characteristics of fore‐arc basalts; the boninite exhibits characteristics of fore‐arc boninites with high Si and Mg, but low Ti and Ca contents; the andesitic porphyrite is enriched in LILE but depleted in HFSE, similar to island arc magmatic rocks. Rock assemblage and their geochemical characteristics suggest that this SSZ‐type ophiolite was formed in fore‐arc setting of intra‐oceanic arc. The plagiogranite is a low‐potassium tholeiite metaluminous granite with low trace elements contents, slight enrichment of LREE, depletion of HREE and positive Eu anomaly; combining with ∊Hf (t) values (13.8–17.1) of zircons, the plagiogranite could be originated from partial melting of gabbros. LA–ICP–MS zircon U–Pb dating yielded the crystallization ages of 535±2 Ma, 513±3 Ma and 510±3 Ma for two cumulate gabbros and one homogeneous gabbro, respectively, and a formation age of 492±8 Ma for the plagiogranite. All these data suggest the existence of an Early Paleozoic ocean in the North Qaidam, and the initial subduction of the oceanic slab occurred earlier than 535Ma. [ABSTRACT FROM AUTHOR]

The lack of long-term air-stable and solution-processed n-doping methods for printed single-walled carbon nanotube (SWCNT) thin film transistors (TFTs) limits their integrations into printed complementary metal-oxide-semiconductor (CMOS) circuits. In this paper, a new chemically modified epoxy amine ink was developed as the chemical dopant and encapsulant to enable the uniform n-type SWCNT-TFTs with long-term air stability (6 months). The epoxy amine inks were dropped onto the printed p-type TFT device channels in a single-step solution process. As a result, printed top-contact n-type SWCNT-TFTs were obtained with well-balanced electrical chararcteristics comparable to their p-type counterparts. The matched p-type and n-type SWCNT-TFTs were thus integrated into the printed CMOS inverters and NAND gates, which have both achieved proper logic operation at supply voltages below 1 V. In particular, the CMOS inverters could operate with V DD down to 0.3V with associated peak power consumption of 0.06 μW, showing full rail-to-rail output swings with voltage gains up to 22, trip voltages of ∼V DD /2, and maximum noise margin of 0.42 V at V DD = 1.1 V (∼76.4% of V DD /2). Furthermore, the static characteristics of CMOS inverters could be maintained for 3 months with negligible changes, proving the feasibility of this long-term air-stable n-doping method. A novel epoxy-amine ink was developed as the chemical dopant and encapsulant to enable the uniform and long-term air-stable n-type SWCNT-TFTs, which showed well-balanced electrical properties comparable to their p-type counterparts. These matched p-type and n-type SWCNT-TFTs could be intergrated into the high air-stable and good-performance printed CMOS inverters and NAND gates. The CMOS inverters could operate with V DD down to 0.3 V with associated peak power consumption of 0.06 μW, showing full rail-to-rail output swings with voltage gains up to 22, trip voltages of ∼V DD /2, and maximum noise margin of 0.42 V at V DD = 1.1 V (∼76.4% of V DD /2). In addition, the NAND gates can work well without any voltage loss at input voltages of 1 V. Image 1 [ABSTRACT FROM AUTHOR]

• The Hudian monzonitic granite and its dark enclaves were formed at ca. 1.77–1.78 Ga and metamorphosed at ca. 400 Ma. • The Hudian pluton was formed in the southern North China Craton (NCC) in a continental rift environment. • The Hudian monzonitic granite was involved in the North Qinling Orogen Belt (NQOB) at ca. 400 Ma. Before this convergent process, the NQOB has no relation to the NCC. The Hudian gneissic monzonitic granite with lentoid dark enclaves and foliated mafic dykes was exposed in the western segment of the North Qinling Orogenic Belt (NQOB). It has long been considered as an intrusion into the Kuanping Complex, the northernmost component of the NQOB. LA–ICP–MS zircon dating yields consistent formation age of ca. 1.77 Ga for the granite and dark enclaves and the same metamorphic age of ca. 400 Ma for the granite and the mafic dykes. The formation age of ca. 1.77 Ga of the Hudian pluton is much older than the deposition age (<530 Ma) of its wall-rock Kuanping clastic rocks and no detrital zircon age of ca. 1.77 Ga was found in the Kuanping clastic rocks, suggesting that the Hudian monzonitic granite is not an intrusion in the clastic rocks, and the pluton was far apart when the Kuanping clastic rocks were deposited. The granite is low in Al 2 O 3 , CaO, MgO and Mg# high in SiO 2 , Na 2 O + K 2 O, Fe 2 O 3 T, Zr and 10,000*Ga/Al, and displays slightly right dipping "gull-wing" shaped rare earth element patterns, agreeing well with the features of A-type granites; the dark enclaves are basalt-andesitic rocks and show characteristics of crust-contaminated continental within-plate basaltic rocks, all suggesting a tectonic setting of extension. The major and trace element compositions of the Hudian monzonitic granite and its dark enclaves and the zircon ε Hf (t) values (−12.1 to −7.1) of the Hudian monzonitic granite all show strong comparability to the 1.75–1.8 Ga A-type granites and coeval intermediate-basic rocks of the Xiong'er Group in the southern North China Craton (NCC), indicating that the Hudian pluton maybe initially formed in the southern NCC. Considering the absence of obvious 1.75–1.8 Ga detrital zircon records in the Kuanping Complex, and the common metamorphic age of ca. 400 Ma in the Kuanping Complex and Hudian pluton as well as other units of the NQOB, we propose that the NCC has no affinity to the NQOB and the Hudian pluton was involved in the NQOB during the collision between the southern NCC and the NQOB at ca. 400 Ma. [ABSTRACT FROM AUTHOR]

The long prism/needle‐shaped polycrystalline quartz aggregates and square/parallelogram‐shaped singlephase quartz inclusions in omphacite and garnet of ultrahigh pressure eclogite were first discovered from the Jiangalesayi area, South Altyn UHP belt. Based on their morphology, these quartz inclusions are quartz paramorphs after stishovite. The minimum peak pressure of the eclogite is estimated to be >8–9 GPa at 800– 1000 °C based on the stability field of stishovite. This new evidence, together with previous stishovite exsolution microstructure in the gneiss from the same region, suggests an ultra‐deep subduction and exhumation of the South Altyn continental rocks to/from mantle depths in stishovite stability field. Evidence of ultra‐deep subduction of continental materials might be more common and diverse than previous thought. Exhumation of subducted continental rocks from≥300 km has been considered impossible because they are denser than mantle at these depths. How did the stishovite bearing continental rocks of the South Altyn exhumated? As we all know, the densities of stishovite (4.3 g/cm3) are much higher than coesite (2.9 g/cm3), and stishovite transforms into coesite with temperature increases. Density calculations were performed for subducted continental rocks along phase transition of stishovite to coesite, using the third‐order Birch‐Murnaghan equation of state based on mineral fractions obtained from experiments and Perple_X. The results show that the density of Siliceous rocks decrease remarkably, lower than the surrounding mantle in coesite stability field, whereas the density of Oligosiliceous and Silicon unsaturated rocks is higher than surrounding mantle. Thus, we propose that the thermal induced transformation could provide an initial driven force for the exhumation of ultra‐deep subducted silica‐enriched felsic continental rocks. Temperature increase could be derived from an increased geothermal gradient from convective mantle or mantle plume. Mafic to ultra‐mafic rocks and silica‐deficient rocks may be captured by the upwelling subducted continental rocks and exhumated together. [ABSTRACT FROM AUTHOR]