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Developing high‐performance infrared (IR) radiation materials with desired broadband emissivity, excellent thermal stability, and scalable fabrication processes is highly desirable for energy‐saving applications and heat dissipation. However, it remains a grand challenge to concurrently meet these requirements in existing IR radiation materials. Herein, a high‐entropy (HE) approach is employed to advance the IR radiation performance of spinel oxide. This strategy efficiently narrows the bandgap due to the enhanced electron transitions and the introduction of oxygen vacancies (Ov), variable‐valence behavior, and orbital hybridization. In addition, the lattice distortion effect lowers the symmetry of lattice vibration. Therefore, the resulting HE spinel oxide exhibits near‐blackbody radiation performance, with its emissivity approximately three times higher than that of the binary spinel oxide. Moreover, the entropy‐dominating phase stabilization effect contributes to impressive thermal stability (stable at 1300 °C for 100 h). This makes it suitable for high‐temperature thermal radiation applications, such as energy conservation in industrial high‐temperature furnaces. More importantly, the HE spinel oxide can be readily spray‐coated on various substrates. And the coating on stainless steel reaches an outstanding emissivity of 0.943 in the 0.78−16 µm wavelength range. All these merits render the HE approach competitive for the development of high‐emissivity and thermally stable thermal radiation materials. [ABSTRACT FROM AUTHOR]

Based on an in-homogeneity adjusted dataset of the monthly mean temperature, minimum and maximum temperature, this paper analyzes the temporal characteristics of Urban Heat Island (UHI) intensity at Wuhan Station, and its impact on the long-term trend of surface air temperature change recorded during 1961-2015 by using an urban-rural method. Results show that UHI effect is obvious near Wuhan Station in the past 55 years, especially for minimum temperature. The strongest UHI intensity occurs in summer and the weakest in winter. For the period 1961-2004, UHI intensity undergoes a significant increase near the urban station, with the increase especially large for the period 1988-2004, but the last 10 years witness a significant decrease, with the decrease in minimum temperature being more significant than that of maximum temperature. The annual mean urban warming and its contribution to overall warming are 0.18 C/10yr and 48.8% respectively for the period 1961-2015, with a more significant and larger urbanization effect seen in Tmin than Tmax. Thus, a large proportion warming, about half of the overall increase in annual mean temperature, as observed at the urban station, can be attributed to the rapid urbanization in the past half a century. [ABSTRACT FROM AUTHOR]

Four Zn(II) complexes, [ZnL2(SO4)]n (1), [ZnL4(H2O)2]•2(NO3)•4EtOH (2), [ZnL2Cl2]•L (3), and [ZnL2Br2]•L (4) (L = uniconazole), were synthesized using a hydrothermal method and characterized by elemental analysis, FT‐IR spectroscopy, and single‐crystal XRD. Complex 1 formed a one‐dimensional polymer chain. However, complexes 2‐4 were obtained as zero‐dimensional mononuclear coordination compounds. The antifungal activities of these complexes were then evaluated against four selected fungi using the mycelial growth rate method. The resulting data indicate that all complexes show better antifungal activities than their ligands and mixtures. In addition, the interactions between the metal salts of complexes 1‐4 and uniconazole seem to be synergistic. Furthermore, the polymer chain structure of complex 1 significantly enhanced the bioactivity, especially against Botryosphaeria ribis (I). Density functional theory (DFT) calculations were carried out to help explain the enhanced bioactivity after the formation of Zn(II) complexes. The resulting data show that the HOMO–LUMO energy gaps of complexes 1‐4 (0.0578, 0.0946, 0.1053, and 0.1245 eV) are smaller than that of the free ligand (0.1247 eV) and correlate with the antifungal activity of the zinc complexes. [ABSTRACT FROM AUTHOR]

The impact of orbital parameters on the climate of China in the Holocene is simulated from 11kaBP to 0kaBP with an interval of 1ka using National Center for Atmospheric Research (NCAR) Community Atmosphere Model version 2 (CAM2). The geographic distributions of summer precipitation around both 9kaBP and 4kaBP were realistically captured by CAM2, compared to the proxy data collected from 80 stations. Among all orbital parameters, the precession plays a major role in computing solar radiation, which dominates the variations of summer precipitation over China during the Holocene. The summers around 9kaBP were the wettest in China. Later on, the precipitation gradually reduced to the minimum around 0kaBP by about 10%. This tremendous change occurred from the Northeast China and the eastern Inner Mongolia extending southwestwards to the Qinghai-Tibet Plateau, especially over the Qinghai-Tibet Plateau. [ABSTRACT FROM AUTHOR]