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Understanding of the pre-development, baseline denudation rates that deliver sediment to the Great Barrier Reef (GBR) has been elusive. Cosmogenic 10Be in sediment is a useful integrator of denudation rates and sediment yields averaged over large spatial and temporal scales. This study presents 10Be data from 71 sites across 11 catchments draining to the GBR: representing 80% of the GBR catchment area and provide background sediment yields for the region. Modern, short-term, sediment yields derived from suspended load concentrations are compared to the 10Be data to calculate an Accelerated Erosion Factor (AEF) that highlights denudation "hot-spots" where sediment yields have increased over the long-term background values. The AEF results show that 58% basins have higher modern sediment yields than long-term yields. The AEF is considered a useful approach to help prioritise on-ground investments in remediation and the additional measured empirical data in this paper will help support future predictive models.

SIRIUS – a 6 MV pelletron accelerator at ANSTO was delivered and installed in 2014–2015. After initial testing and commissioning phase we have now moved into routine operations. Quality assurance data from the past 2 years demonstrates the excellent performance and SIRIUS is now our preferred instrument for 10Be, 26Al and 36Cl analyses.

We present our first 14C in-situ results for calibration and system blanks from the recently completed Australian Nuclear Science and Technology Organisation (ANSTO) – University of Wollongong (UOW) in-situ 14C extraction system. System performance parameters and quality is evidenced by low 14C blanks and good reproducibility for multiple targets from different reference materials. The 14C extraction scheme exploits the high temperature phase transformation of quartz to cristobalite in order to quantitatively extract the carbon as CO2. The in-situ 14C extraction system comprises three independently operated and modular units that are used for initial in-vacuo removal of meteoric 14C, followed by offline high-temperature heating of quartz to release trapped cosmogenic in-situ 14C, and finally CO2 gas purification and mass measurement. The design allows for rapid sample throughput of about 6 samples per week with samples masses ranging between 0.5 and 4 g of clean quartz. Other features include single-pass catalytic oxidation using mixed copper (I,II) oxide as catalyst, use of UHV-compatible components and of vacuum annealed copper tubing. We present results for sets of purified quartz samples prepared from CRONUS-A, CRONUS-R and CRONUS-N inter-comparison materials, with final averages consistent with published values. Following extraction and cleaning, CO2 gas aliquots for some of the samples were analysed using the ETH Zurich CO2 gas ion source at the ETH MICADAS AMS facility in addition to CO2 being graphitised using the ANSTO laser-heated graphitisation micro-furnace and then analysed on ANSTO’s ANTARES AMS facility. System blanks using either CO2 or graphite ion-sources at both facilities are on the order of ∼1 × 104 atoms.

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Cosmogenic production rates (PRs) are the essential conversion factor between AMS cosmogenic concentrations and absolute exposure ages. The accuracy of cosmogenic glacial chronologies and reliability in their comparison to other paleoclimate systems is largely contingent on the precision and accuracy of the adopted production rate. This is particularly critical in determining past glacial geochronologies at the scale of millennial temporal resolution. Most PR calibrations are carried out at deglaciation sites where radiocarbon provides the independent chronometric control usually based on 14C ages in basal sediments or varves from lake or bog cores which is assumed to represent the minimum age for glacial retreat. Under these conditions and hence provide PRs as maximum values. Given that today most AMS facilities can deliver 10-Be, 26-Al and 36-Cl data with total analytical errors less than 2% ( for 10 ka exposure), the precision of a PR remains largely dependent on the error in the independent chronology and accuracy of AMS standards. The history over the past 20 years of the ever-decreasing value of SLHL 10-Be cosmogenic spallation PRs from initial estimates of about 7 atoms/g/a to the current ‘accepted‘ (global average) values of ~4 atoms/g/a, is an interesting story in itself and demonstrates the complexity in such determinations. Over the past few years new web-based calculators are now available to calculate uniformly new production rates from either new data or combinations of any set of published data (CRONUS-Earth, CRONUS-UW, CosmoCalc, ICE-D, CREp). This delivers a means by which new production rates can be seamlessly integrated and compared using identical constants, methods and statistics that were used to generate (currently accepted) global average or regional production rates. For the British Isles, there are a number of 10-Be reference sites that give PRs (Lm scheme) between 3.89±3% atoms/g/a (Putnam, QG, v50, 2019) to 4.20±1% atoms/g/a (Small, JQS, v30, 2015) which convert to 3.95 and 4.28, respectively, using datasets in the ICE-D calculator). This difference in 10-Be spallation PRs has recently raised some debate and challenges for the timing of the local-LGM and demise of the British Ice Sheet. This work provides a new British Isles site specific 10Be PR from the Arenig Mountains in North Wales where radiocarbon dating of basal sediments from a bog core associated with a series of nearby cirque moraines provides independent age control. Similarly in the South Island of New Zealand, the current accepted 10Be PR is 3.76±2% (Putnam, QG 2009; converts to 3.94±1% using ICE-D) and is the only available PR that is used for these southern hemispheric glacial sites. This work provides a new Australasian site specific 10Be PR from Arthurs Pass retreat moraines where radiocarbon dating of basal sediments from three cores extracted from a bog impounded by the moraine provides independent age control.

We present two carbonate oxygen and carbon isotope records from late Miocene – early Pleistocene stratigraphic sections from the southern flank of the Issyk Kul basin, Kyrgyz Tien Shan. The two sections are 700 and 500 m thick and composed of fluvial and lacustrine sediments. They were dated using magnetostratigraphy (Roud et al., G-Cubed, in review) and 26Al/10Be isochron burial dating (presented here).Carbonate stable isotope data is useful for reconstruction of climate in Asia over the Cenozoic. Oxygen isotopes are commonly used to detect moisture sources and their interaction with topography. Pedogenic carbon isotopes are used to reconstruct past atmospheric CO2 levels or the spread of C4 vegetation.The environment of Central Asia is primarily affected by the northern mid-latitude westerlies − winds transporting moisture eastward across Eurasia. Issyk Kul basin is situated on the windward side of the northern Tien Shan. Published data suggest that the Tien Shan mountain ranges interacted with the westerlies since late Oligocene and reorganized Central Asian climate during Neogene (Caves et al., 2017; Charreau et al., 2012; Macaulay et al., 2016; Wang, et al., 2020). The amount of existing published paleoclimate data from northern Central Asia is scarce compared to interior China, and therefore the influence of the Tien Shan uplift on climate in Asia during the Cenozoic is poorly reconstructed.Our data provide new insight into the role of the range and its interaction with the westerlies in forming climate on the windward side of the northern Tien Shan in the late Neogene. We combine our data with published stratigraphically-older sections nearby (Macaulay et al., 2016) to complete the Neogene stable isotope record of the Issyk Kul basin and study how the evolution of the basin influenced regional climate.Our d18O and d13C values show slightly positive trends, unlike stratigraphically-older data from the Issyk Kul basin. The preliminary interpretation suggests that the circulation pattern within the range was changed in late Miocene possibly reflecting active tectonic uplift northward of the basin and an increase in aridification.

Cosmogenic 10Be and 26Al exposure ages from 20 erratic samples collected from Cadair Idris (893 m), a mountain in southern Snowdonia, Wales, provide evidence for the timing of deglaciation from summits to cirques at the end of the Late Pleistocene. The summit of the mountain is characterised by intensely modified frost-shattered surfaces that have long been identified as a representing a former nunatak. Numerous glacially-transported quartz boulders on the highest ground indicate that ice overran the summit at some point in the Pleistocene. Two quartz boulders, one with preserved striations, sampled at c. 856 m near the summit of Cadair Idris yielded consistent 10Be and 26Al paired exposure ages of 75 ka to 60 ka (using a high-latitude sea level 10Be spallation production rate of 4.20 at/g/y, scaled by the Lal/Stone scheme). A glacially polished bedrock quartzite outcrop at 735 m gave an age of 17.5 ka. Immediately below this, cirque and down-valley recessional moraine ages, covering an elevation of 480 m to 350 m ranged from 10 to 15 ka respectively.These results confirm that Cadair Idris was overridden by the Welsh Ice Cap during marine isotope stage (MIS) 4, when ice was thicker than at the global last glacial maximum (LGM) in MIS 2. This is consistent with findings from northern Snowdonia. The highest Welsh summits, including Cadair Idris, emerged above a thinning Welsh Ice Cap (British Irish Ice Sheet) during the transition from MIS 4 to 3. The summit area above ~800 m then stood as nunataks above the LGM ice sheet surface in MIS 2. The Welsh Ice Cap then rapidly thinned over Cadair Idris at ~20-17 ka based on ages from high-level ice-moulded bedrockThis is supported by more new ages from high-level paired erratics and bedrock samples on several other mountains throughout Snowdonia, leading to a phase of alpine-style deglaciation. Valley glaciers initiated their retreat up-valley from ~17 to 14 ka after Heinrich Event 1. A later phase of glacier stabilisation or still stand formation produced classic cirque moraines near the rim of a present cirque lake basin (480 m elevation) yielding 10Be ages of 13-10 ka during the Younger Dryas.

Reworking of old sediment in the Murray-Darling implies alteration of environmental signals traveling from source to sink., Understanding how sediment transport and storage will delay, attenuate, and even erase the erosional signal of tectonic and climatic forcings has bearing on our ability to read and interpret the geologic record effectively. Here, we estimate sediment transit times in Australia’s largest river system, the Murray-Darling basin, by measuring downstream changes in cosmogenic 26Al/10Be/14C ratios in modern river sediment. Results show that the sediments have experienced multiple episodes of burial and reexposure, with cumulative lag times exceeding 1 Ma in the downstream reaches of the Murray and Darling rivers. Combined with low sediment supply rates and old sediment blanketing the landscape, we posit that sediment recycling in the Murray-Darling is an important and ongoing process that will substantially delay and alter signals of external environmental forcing transmitted from the sediment’s hinterland.

Cosmogenic production rates (PRs) are the essential conversion factor between AMS cosmogenic concentrations and absolute exposure ages. The accuracy of cosmogenic glacial chronologies and reliability in their comparison to other plaeoclimate systems is largely contingent on the precision and accuracy of the adopted production rate. This is particularly critical in determining past glacial geochronologies at the scale of millennial temporal resolution. Most PR calibrations are carried out at deglaciation sites where radiocarbon provides the independent chronometric control usually based on calibrated 14C ages in basal sediments or varves from lake or bog cores which is assumed to represent the minimum age for glacial retreat. Under these conditions PRs should be considered as maximum-limiting values. Given that today most AMS facilities can deliver 10-Be, 26-Al and 36-Cl data with analytical errors less than 2%, the accuracy of a PR for a given scaling method (ie transfer function of the site-specific production rate to a reference sea-level high latitude (SLHL) PR) remains largely dependent on the error in the independent chronology and accuracy of AMS standards. The history over the past 20 years of the ever-changing value of SLHL 10-Be cosmogenic spallation PRs with a continual decreasing value from initial estimates of about 7 atoms/g/a to the current ‘accepted ‘ value of ~4 atoms/g/a, is an interesting story in itself and demonstrates the complexity in such determinations. Today there are both global (average) SLHL PRs and also regional-specific PR values (referenced to SLHL). For the British Isles, there are a number of 10-Be ‘British Isles’ choices that, for the Lm scaling scheme, range between 3.92±0.11 atoms/g/a (Putnam et al., QG, v50, 2019) to 4.41±0.25 atoms/g/a (Small et al., JQS, v30, 2015). This range in 10-Be spallation PRs has recently raised some debate and challenges for the assumed extent and timing of the local-LGM and demise of the British Ice Sheet. This work provides a new British Isles site specific 10-Be PR from the Arenig Mountains in North Wales. We have measured 10-Be concentrations in 13 selected moraine boulders that are tentatively mapped as outer and inner Younger Dryas deglacial deposits hugging a cirque lake, Llyn Arenig Fach, just below the head wall at Arenig Fach. Radiocarbon dating of basal sediments from a number of intermorainal core bogs has provided independent age control. We will present our results and compare them to the current collection of other British Isles 10-Be production rates.

The eastern seaboard of Australia is characterized by a passive margin and a continental divide that separates the inland-draining rivers from those that drain to the Coral and Tasman seas. Seaward of this divide lies the Great Escarpment (GE) of Australia that separates a moderate relief coastal plain from a low relief, high elevation plateau. Quantifying the spatial variation of erosion rates from temperate New England (NE), NSW and tropical Bellenden Ker (BK), Queensland, two regions with distinctly different climates and escarpment embayment, could help constrain erosional controls that contribute to escarpment form. In this study, we compared forty detrital 10Be samples collected from sediments in the main trunk and tributaries of five major rivers: the Macleay, Bellinger, and Clarence in NE and the Russel-Mulgrave and North Johnstone in BK. We then traced the escarpment position in ARCGIS and calculated a sinuosity ratio to better compare the degree of embayment in each region. Across both datasets we found that for NE, which has deep gorges cutting into the plateau, the degree of embayment was twice that of BK, where the escarpment position is significantly less embayed and erosion rates significantly more variable (ratio of .18 vs .38). Erosion rates in low slope areas, such as on the plateau, were universally low with no other significant controlling factors. There was no correlation between erosion rates and catchment area, and that our data echo previous studies that find that once mean rainfall passes an approximate threshold (around 2000mm/yr) basin characteristics that are known to control erosion rates, such as slope and lithology, are subdued. In temperate NE, where rainfall ranges from approximately 800-1200mm/yr, there was a moderate linear correlation with mean catchment rainfall and erosion rates (R2 .50), which is likely due to a strong orographic effect due to the escarpment. Erosion rates from tributaries below the plateau were highly variable and ranged from 5m/Ma up to 60m/Ma and correlated strongly with mean catchment slope (R2 .86). In addition, there were moderate inverse linear correlations between erosion rate and the catchment total percent granite and sedimentary rock (R2 .53 and .63 respectively) and a moderate correlation between erosion rate and catchment total percent metamorphic rock (R2 .57). Similar to previous studies, these data suggest that in temperate climates with moderate amounts of annual rainfall, individual basin characteristics play a significant role in controlling basin wide erosion rates.In contrast, data from tropical BK, where mean rainfall amounts are in excess of 2000mm/yr, erosion rates from tributaries below the plateau were significantly less variable than NE. Rates had a mean of 37m/Ma ± 9 (standard deviation 5m/Ma, N=10) and were not significantly correlated with mean catchment slope nor catchment lithology. The mean erosion rate of BK is similar to that of other studies in the region, though with slightly less variability, and possibly reinforces the hypothesis from other researchers that in tropical climates with significant mean rainfall, soil depth effectively armors hillslopes and prevents bedrock erosion from occurring.

Rupture associated with the 25 April 2015 M w 7.8 Gorkha (Nepal) earthquake highlighted our incomplete understanding of the structural architecture and seismic cycle processes that lead to Himalayan mountain building in Central Nepal. In this paper we investigate the style and kinematics of active mountain building in the Himalayan hinterland of Northwest India, approximately 400 km to the west of the hypocenter of the Nepal earthquake, via a combination of landscape metrics and long- (Ma) and short-term (ka) erosion rate estimates (from low temperature thermochronometry and basin-wide denudation rate estimates from 10 Be concentrations). We focus our analysis on the area straddling the PT 2 , the physiographic transition between the Lesser and High Himalaya that has yielded important insights into the nature of hinterland deformation across much of the Himalaya. Our results from Northwest India reveal a distinctive PT 2 that separates a Lesser Himalaya region with moderate relief (∼1000 m) and relatively slow erosion ( 2 has persisted in the same relative position since at least the past 1.5 Ma. We interpret these observations to suggest that strain accumulation in this hinterland region throughout at least the past 1.5 Ma has been accomplished both by crustal thickening via duplexing and overthrusting along transient emergent faults. Despite the >400 km distance between them, similar spatiotemporal patterns of erosion and deformation observed in Northwest India and Central Nepal suggest both regions experience similar styles of active strain accumulation and both are susceptible to large seismic events.

There is growing interest in geochronological applications of terrestrial in situ-produced cosmogenic nuclides, with the most commonly measured being 10Be and 26Al in quartz. To extract and then separate these radionuclides from quartz and prepare them in the oxide form suitable for accelerator mass spectrometry (AMS) requires extensive and careful laboratory processing. Here we discuss the suitability of a crushed, sieved and etched, sub-aerially exposed vein quartz specimen (CoQtz-N) to act as a reference material for chemical laboratory preparation and AMS measurements. Splits of CoQtz-N were distributed to eleven target preparation laboratories. The CoQtz-N 10Be targets were then measured at seven different AMS facilities and five of the preparation laboratories had their 26Al targets measured at four different AMS facilities. We show that CoQtz-N splits are sufficiently homogeneous with regard to nuclide concentrations, that it has been cleaned of any atmospheric derived (i.e. meteoric) 10Be and that it has low concentrations of the major elements that can interfere with Be and Al extraction chemistry and AMS measurements. We derive preliminary concentrations for 10Be and 26Al in CoQtz-N as 2.53 ± 0.09 × 106 at/g and 15.6 ± 1.6 × 106 at/g, respectively, at the 95% confidence limit.

Rivers draining the semiarid Transhimalayan Ranges at the western Tibetan Plateau margin underwent alternating phases of massive valley infill and incision in Pleistocene times. The effects of these cut-and-fill cycles on millennial sediment fluxes have remained largely elusive. We investigate the timing and geomorphic consequences of headward incision of the Zanskar River, a tributary to the Indus, which taps the >250-m thick More Plains valley fill that currently plugs the endorheic high-altitude basins of Tso Kar and Tso Moriri. In situ 10Be exposure dating and topographic analyses show that a phase of valley infill gave way to net dissection and the NW Himalaya's first directly dated stream capture in late Marine Isotope Stage (MIS) 6, ∼135 ka ago. Headwaters of the Indus are currently capturing headwaters of the Sutlej, and rivers have eroded >14.7 km3 of sediment from the Zanskar headwaters since, mobilising an equivalent of ∼8% of the Indus' contemporary sediment storage volume from only 0.3% of its catchment area. The resulting specific sediment yields are among the rarely available rates averaged over the 105-yr timescale, and surpass 10Be-derived denudation rates from neighbouring catchments three- to tenfold. We conclude that recycling of Pleistocene valley fills has fed Transhimalayan headwaters with more sediment than liberated by catchment denudation, at least since the last glacial cycle began. This protracted release of sediment from thick Pleistocene valley fills might bias estimates of current sediment loads and long-term catchment denudation.

Hillslopes stand at the top of the geomorphic conveyor belt that produces and transports mass throughout landscapes. Quantification of the tempo of hillslope evolution is key to identifying primary sediment production and understanding how surface processes shape topography. We measured cosmogenic 10Be and 26Al on three desert hillslopes in postorogenic central Australia and quantified their soil dynamics and evolution. We found that hillslope morphology is governed by lithological factors, and differing nuclide abundances reflect the main sediment transport processes. Slope wash is widespread, and shrink-swell soil processes drive downslope creep and upward migration of gravels detached from underlying bedrock. We applied Monte Carlo-based inversion modeling to reconstruct soil production and the exhumation histories of stony mantle gravels. Underlying silty soils derive from eolian dust inputs dating to at least 0.2 Ma and possibly more than 1 Ma, in line with intensified aridity. Exposed bedrock erodes at ~0.2-7 m/m.y., and under soil, it erodes at maximum rates of < 0.1 m/m.y. up to 10 m/m.y. Accordingly, particles spend 2-6 m.y. or more in the upper 0.6 m of the bedrock column and an additional ~0.2-2 m.y. or more within hillslope soils. Such long periods near the surface result in surface particles acquiring inherently low 26Al/10Be ratios. Bedrock erodibility underpins regional variations in erosion rate, and the slow tempo of hillslope evolution is largely independent of base level. This suggests a distinctive top-down evolution among postorogenic hillslopes set by authigenic rates of sediment production, rather than by fluvial incision as in tectonically active settings.

We present initial results of in situ 14 C system blank and calibration sample measurements obtained using the in situ 14 C extraction scheme developed at the University of Cologne. The 14 C extraction scheme specifically exploits the phase transformation of quartz to cristobalite in order to quantitatively extract the carbon as CO 2 and follows a scheme that is different to that of existing extraction systems. Features are offline furnace extraction, single pass catalytic oxidation using mixed copper (I,II) oxide as catalyst, the use of UHV-compatible components and of vacuum annealed copper tubing. The design allows a relatively rapid sample throughput – two samples per day as opposed to the current 2 days per sample that can be done on other lines – and can accommodate samples ranging between 0.5 and 4 g of clean quartz. Following extraction and cleaning, the CO 2 gas is measured using the gas ion source of the MICADAS AMS facility at ETH Zurich. The extraction system yields low systems blanks (10 +16 / −10 × 10 3 atoms 14 C, ±1 σ ) and the initial results indicate that further improvements are achievable. Measurements of the CRONUS-A standard sample show a good reproducibility and results are consistent with published values. We also present the first in situ 14 C results for the CRONUS-R standard material.

Conventional methods for the determination of past soil erosion provide only average rates of erosion of the sediment's source areas and are unable to determine the rate of at-a-site soil loss. In this study, we report in-situ produced cosmogenic 10Be, and 14C measurements from erratic boulders and two depth-profiles from Younger Dryas moraines in Scotland, and assess the extent to which these data allow the quantification of the amount and timing of site-specific Holocene soil erosion at these sites. The study focuses on two sites located on end moraines of the Loch Lomond Readvance (LLR): Wester Cameron and Inchie Farm, both near Glasgow. The site near Wester Cameron does not show any visible signs of soil disturbance and was selected in order to test (i) whether a cosmogenic nuclide depth profile in a sediment body of Holocene age can be reconstructed, and (ii) whether in situ 10Be and 14C yield concordant results. Field evidence suggests that the site at Inchie Farm has undergone soil erosion and this site was selected to explore whether the technique can be applied to determine the broad timing of soil loss. The results of the cosmogenic 10Be and 14C analyses at Wester Cameron confirm that the cosmogenic nuclide depth-profile to be expected from a sediment body of Holocene age can be reconstructed. Moreover, the agreement between the total cosmogenic 10Be inventories in the erratics and the Wester Cameron soil/till samples indicate that there has been no erosion at the sample site since the deposition of the till/moraine. Further, the Wester Cameron depth profiles show minimal signs of homogenisation, as a result of bioturbation, and minimal cosmogenic nuclide inheritance from previous exposure periods. The results of the cosmogenic 10Be and 14C analyses at Inchie Farm show a clear departure from the zero-erosion cosmogenic nuclide depth profiles, suggesting that the soil/till at this site has undergone erosion since its stabilisation. The LLR moraine at the Inchie Farm site is characterised by the presence of a sharp break in slope, suggesting that the missing soil material was removed instantaneously by an erosion event rather than slowly by continuous erosion. The results of numerical simulations carried out to constrain the magnitude and timing of this erosion event suggest that the event was relatively recent and relatively shallow, resulting in the removal of circa 20–50 cm of soil at a maximum of ∼2000 years BP. Our analyses also show that the predicted magnitude and timing of the Inchie Farm erosion event are highly sensitive to the assumptions that are made about the background rate of continuous soil erosion at the site, the stabilisation age of the till, and the density of the sedimentary deposit. All three parameters can be independently determined a priori and so do not impede future applications to other localities. The results of the sensitivity analyses further show that the predicted erosion event magnitude and timing is very sensitive to the 14C production rate used and to assumptions about the contribution of muons to the total production rate of this nuclide. Thus, advances in this regard need to be made for the method presented in this study to be applicable with confidence to scenarios similar to the one presented here.

Most laboratories prepare carbonates samples for radiocarbon analysis by acid decomposition in evacuated glass tubes and subsequent reduction of the evolved CO2 to graphite in self-made reduction manifolds. This process is time consuming and labor intensive. In this work, we have tested a new approach for the preparation of carbonate samples, where any high-vacuum system is avoided and helium is used as a carrier gas. The liberation of CO2 from carbonates with phosphoric acid is performed in a similar way as it is often done in stable isotope ratio mass spectrometry where CO2 is released with acid in septum sealed tube under helium atmosphere. The formed CO2 is later flushed in a helium flow by means of a double-walled needle mounted from the tubes to the zeolite trap of the automated graphitization equipment (AGE). It essentially replaces the elemental analyzer normally used for the combustion of organic samples. The process can be fully automated from sampling the released CO2 in the septum-sealed tubes with a commercially available auto-sampler to the graphitization with the automated graphitization. The new method yields in low sample blanks of about 50000 years. Results of processed reference materials (IAEA-C2, FIRI-C) are in agreement with their consensus values.

The new AMS facility at the University of Cologne (CologneAMS), Germany, was established in 2010 with the delivery of the HVE 6 MV Tandetron AMS, which will be used for 14C, 26Al, 36Cl, 41Ca, 129I, 239U and 244Pu analyses. Parallel to the AMS installation the radiocarbon group has started to set up and test sample preparation methods and instruments for different materials. We present first results of reference and standard materials that have been processed and graphitized in our lab and measured at the ETH and CologneAMS facilities. The graphitization blank and its influence on small samples sizes processed with an automated graphitization system have been determined. Work on isolation of individual organic compounds with a preparative gas chromatography system has been started. The focus of our future work will be on reducing process blank levels and sample sizes as well as on the application of compound-specific radiocarbon analyses in (paleo-) environmental research.

Cosmogenic nuclide exposure dating of glacial clasts is becoming a common and robust method for reconstructing the history of glaciers and ice sheets. In Antarctica, however, many samples exhibit cosmogenic nuclide ‘inheritance’ as a result of sediment recycling and exposure to cosmic radiation during previous ice free periods. In-situ cosmogenic 14C, in combination with longer lived nuclides such as 10Be, can be used to detect inheritance because the relatively short half-life of 14C means that in-situ 14C acquired in exposure during previous interglacials decays away while the sample locality is covered by ice during the subsequent glacial. Measurements of in-situ 14C in clasts from the last deglaciation of the Framnes Mountains in East Antarctica provide deglaciation ages that are concordant with existing 26Al and 10Be ages, suggesting that in this area, the younger population of erratics contain limited inheritance.

In this paper, we describe improvements to the in situ cosmogenic radiocarbon extraction system at SUERC made since 2004, highlighting the factors that potentially control the reduction of analytical variability. We also present new results on system blanks and of measurements of in situ14C in shielded quartz and a surface quartz sample used at the University of Arizona as an in situ14C standard (PP-4). The SUERC in situ14C extraction system was built in 2001 and is based on a combustion technique following the design of the extraction system at the University of Arizona. Our preliminary results suggest that the continuous running of the extraction system and the monitoring of gas collecting time and of the temperature of the cryogenic traps used in the gas cleaning steps are key to maintaining low and stable system blanks. Our latest average system blank is 2.02 ± 0.23 x 10514C atoms. This is consistent with those recently published by the University of Arizona and ETH in situ14C labs. Measurements of in situ14C concentrations in sample PP-4 yield an average of 3.82 ± 0.23 x 105 atoms g–1 quartz, again consistent with published values.