1. An algorithm to calculate the cationic composition of soil solutions. 2. Parameterisation and test
- Author
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Reid, Jeff B., Trolove, Stephen N., and Tan, Yong
- Subjects
Cations -- Analysis ,Climate models -- Usage ,Soil acidity -- Analysis ,Algorithms -- Usage ,Algorithm ,Agricultural industry ,Earth sciences - Abstract
This paper presents a parameterisation and test of an algorithm to calculate distributions of the major nutrient cations between the solution and exchangeable phases of soil when cation exchange capacity (c) may vary. Two contrasting soils were considered: a volcanic subsoil where c is dominated by variable-charge surfaces, and an alluvial silt loam topsoil with stable c. Experimental treatments consisted of applying either water or solutions of Ca[Cl.sub.2], KC1, Mg[Cl.sub.2], or NaCl. Solution concentrations of [Ca.sup.2+], [K.sup.+], [Mg.sup.2+], and [Na.sup.+] varied by up to two orders of magnitude, and were simulated well, particularly when using logi0-transformed data. The ratios of the solution concentrations of [K.sup.+], [Mg.sup.2+], and [Na.sup.+] to [Ca.sup.2+] also were generally simulated well. However, the algorithm's description of soil acidity needs further checking. For the variable-charge soil, cation concentrations were strongly influenced by fitted parameters associated with anion exchange. For the alluvial soil, fitted parameters had little influence, and the cation calculations were dominated by information gathered front the initial (equilibrium) distributions between phases. The algorithm has strong potential for forecasting changes in solution concentrations of the major nutrient cations, using relatively small amounts of fitting data. Keywords: anion exchange, cation exchange, model, soil solution, variable-charge soil., Introduction Although plant uptake of the major nutrient cations is strongly affected by their concentrations in the solution around the roots, soil fertility testing rarely involves analysis of the soil [...]
- Published
- 2021
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