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Durante la erupción del volcán de Cumbre Vieja, en la isla de La Palma en 2021, la Agencia Estatal de Meteorología (AEMET), en calidad de Servicio Nacional y Autoridad Meteorológica del Estado, prestó diferentes servicios de apoyo al Comité Científico y al Comité Asesor del Plan de Emergencias Volcánicas de Canarias (PEVOLCA). Parte de sus actividades abarcaron la vigilancia y predicción meteorológica, la monitorización y predicción del transporte del penacho volcánico, y la valoración del impacto de las emisiones de gases y cenizas de la erupción volcánica en la calidad del aire en la isla de La Palma y en la región de Canarias.

Editors: Emilio Cuevas, Celia Milford and Oksana Tarasova. [EN]The Izaña Atmospheric Research Center (IARC), which is part of the State Meteorological Agency of Spain (AEMET), is a site of excellence in atmospheric science. It manages four observatories in Tenerife including the high altitude Izaña Atmospheric Observatory. The Izaña Atmospheric Observatory was inaugurated in 1916 and since that date has carried out uninterrupted meteorological and climatological observations, contributing towards a unique 100-year record in 2016. This reports are a summary of the many activities at the Izaña Atmospheric Research Center to the broader community. The combination of operational activities, research and development in state-of-the-art measurement techniques, calibration and validation and international cooperation encompass the vision of WMO to provide world leadership in expertise and international cooperation in weather, climate, hydrology and related environmental issues. [ES]El Centro de Investigación Atmosférica de Izaña (CIAI), que forma parte de la Agencia Estatal de Meteorología de España (AEMET), representa un centro de excelencia en ciencias atmosféricas. Gestiona cuatro observatorios en Tenerife, incluido el Observatorio de Izaña de gran altitud, inaugurado en 1916 y que desde entonces ha realizado observaciones meteorológicas y climatológicas ininterrumpidas y se ha convertido en una estación centenaria de la OMM. Estos informes resumen las múltiples actividades llevadas a cabo por el Centro de Investigación Atmosférica de Izaña. El liderazgo del Centro en materia de investigación y desarrollo con respecto a las técnicas de medición, calibración y validación de última generación, así como la cooperación internacional, le han otorgado una reputación sobresaliente en lo que se refiere al tiempo, el clima, la hidrología y otros temas ambientales afines.

Nitrogen oxides (NOx≡NO+NO2) in the NOx-limited upper troposphere (UT) are long-lived and so have a large influence on the oxidizing capacity of the troposphere and formation of the greenhouse gas ozone. Models misrepresent NOx in the UT, and observations to address deficiencies in models are sparse. Here we obtain a year of near-global seasonal mean mixing ratios of NO2 in the UT (450–180 hPa) at 1∘×1∘ by applying cloud-slicing to partial columns of NO2 from TROPOMI. This follows refinement of the cloud-slicing algorithm with synthetic partial columns from the GEOS-Chem chemical transport model. TROPOMI, prior to cloud-slicing, is corrected for a 13 % underestimate in stratospheric NO2 variance and a 50 % overestimate in free-tropospheric NO2 determined by comparison to Pandora total columns at high-altitude free-tropospheric sites at Mauna Loa, Izaña, and Altzomoni and MAX-DOAS and Pandora tropospheric columns at Izaña. Two cloud-sliced seasonal mean UT NO2 products for June 2019 to May 2020 are retrieved from corrected TROPOMI total columns using distinct TROPOMI cloud products that assume clouds are reflective boundaries (FRESCO-S) or water droplet layers (ROCINN-CAL). TROPOMI UT NO2 typically ranges from 20–30 pptv over remote oceans to >80 pptv over locations with intense seasonal lightning. Spatial coverage is mostly in the tropics and subtropics with FRESCO-S and extends to the midlatitudes and polar regions with ROCINN-CAL, due to its greater abundance of optically thick clouds and wider cloud-top altitude range. TROPOMI UT NO2 seasonal means are spatially consistent (R=0.6–0.8) with an existing coarser spatial resolution (5∘ latitude × 8∘ longitude) UT NO2 product from the Ozone Monitoring Instrument (OMI). UT NO2 from TROPOMI is 12–26 pptv more than that from OMI due to increase in NO2 with altitude from the OMI pressure ceiling (280 hPa) to that for TROPOMI (180 hPa), but possibly also due to altitude differences in TROPOMI and OMI cloud products and NO2 retrieval algorithms. The TROPOMI UT NO2 product offers potential to evaluate and improve representation of UT NOx in models and supplement aircraft observations that are sporadic and susceptible to large biases in the UT.

Presentación realizada en: Nordic Ozone Group Meeting (2021), celebrado el 21 de abril de 2021 de manera virtual.

Nitrogen oxides (NOx ≡ NO + NO2) in the NOx-limited upper troposphere (UT) are long-lived and so have a large influence on the oxidizing capacity of the troposphere and formation of the greenhouse gas ozone. Models misrepresent NOx in the UT and observations to address deficiencies in models are sparse. Here we obtain a year of near-global seasonal mean mixing ratios of NO2 in the UT (450–180 hPa) at 1 ° x 1° by applying cloud-slicing to partial columns of NO2 from TROPOMI. This follows refinement of the cloud-slicing algorithm with synthetic partial columns from the GEOS-Chem chemical transport model. We find that synthetic cloud-sliced UT NO2 are spatially consistent (R = 0.64) with UT NO2 calculated across the same cloud pressure range and scenes as are cloud-sliced (“true” UT NO2), but the cloud-sliced UT NO2 is 11–22 % more than the "true" all-sky seasonal mean. The largest contributors to differences between synthetic cloud-sliced and “true” UT NO2 are target resolution of the cloud-sliced product and uniformity of overlying stratospheric NO2. TROPOMI, prior to cloud-slicing, is corrected for a 13 % underestimate in stratospheric NO2 variance and a 50 % overestimate in free tropospheric NO2 determined by comparison to Pandora total columns at high-altitude sites in Mauna Loa, Izaña and Altzomoni, and MAX-DOAS and Pandora tropospheric columns at Izaña. Two cloud-sliced seasonal mean UT NO2 products for June 2019 to May 2020 are retrieved from corrected TROPOMI total columns using distinct TROPOMI cloud products that assume clouds are reflective boundaries (FRESCO-S) or water droplet layers (ROCINN-CAL). TROPOMI UT NO2 typically ranges from 20-30 pptv over remote oceans to > 80 pptv over locations with intense seasonal lightning. Spatial coverage is mostly in the tropics and subtropics with FRESCO-S and extends to the midlatitudes and polar regions with ROCINN-CAL, due to its greater abundance of optically thick clouds and wider cloud top altitude range. TROPOMI UT NO2 seasonal means are spatially consistent (R = 0.6–0.8) with an existing coarser spatial resolution (5° latitude x 8° longitude) UT NO2 product from the Ozone Monitoring Instrument (OMI). UT NO2 from TROPOMI is 12–26 pptv more than that from OMI due to increase in NO2 with altitude from the OMI pressure ceiling (280 hPa) to that for TROPOMI (180 hPa), but possibly also systematic altitude differences between the TROPOMI and OMI cloud products. The TROPOMI UT NO2 product offers potential to evaluate and improve representation of UT NOx in models and supplement aircraft observations that are sporadic and susceptible to large biases in the UT.

This paper presents the tools and methodology for performing a routine comprehensive monitoring of consistency and quality of IASI (Infrared Atmospheric Sounding Interferometer) trace gas Level 2 (L2) products (O3, CO, N2O, CH4, and CO2) generated at EUMETSAT (European Organisation for the Exploitation of Meteorological Satellites) using ground-based observations at the Izaña Atmospheric Observatory (IZO, Tenerife). As a demonstration the period 2010–2014 was analysed, covering the version 5 of the IASI L2 processor. Firstly, we assess the consistency between the total column (TC) observations from the IASI sensors on board the EUMETSAT Metop-A and Metop-B meteorological satellites (IASI-A and IASI-B respectively) in the subtropical North Atlantic region during the first 2 years of IASI-B operations (2012–2014). By analysing different timescales, we probe the daily and annual consistency of the variability observed by IASI-A and IASI-B and thereby assess the suitability of IASI-B for continuation of the IASI-A time series. The continuous intercomparison of both IASI sensors also offers important diagnostics for identifying inconsistencies between the data records and for documenting their temporal stability. Once the consistency of IASI sensors is documented we estimate the overall accuracy of all the IASI trace gas TC products by comparing to coincident ground-based Fourier transform infrared spectrometer (FTS) measurements performed at IZO from 2010 to 2014. The IASI L2 products reproduce the ground-based FTS observations well at the longest temporal scales, i.e. annual cycles and long-term trends for all the trace gases considered (Pearson correlation coefficient, R, larger than 0.95 and 0.75 for long-term trends and annual cycles respectively) with the exception of CO2. For CO2 acceptable agreement is only achieved for long-term trends (R ∼ 0.70). The differences observed between IASI and FTS observations can be in part attributed to the different vertical sensitivities of the two remote sensing instruments and also to the degree of maturity of the IASI products: O3 and CO are pre-operational, while N2O, CH4, and CO2 are, for the period covered by this study, aspirational products only and are not considered mature. Regarding shorter timescales (single or daily measurements), only the O3 product seems to show good sensitivity to actual atmospheric variations (R ∼ 0.80), while the CO product is only moderately sensitive (R ∼ 0.50). For the remainder of the trace gases, further improvements would be required to capture the day-to-day real atmospheric variability.

Presentación realizada en: European Conference on Solar UV Monitoring-ECUVM, celebrada en Viena del 12 al 14 de septiembre de 2018.

The Baseline Surface Radiation Network (BSRN) was implemented by the World Climate Research Programme (WRCP) starting observations with 9 stations in 1992, under the auspices of the World Meteorological Organization (WMO). Currently, 59 BSRN stations submit their data to the WRCP. One of these stations is the Izaña station (Station: IZA, #61) that enrolled in this network in 2009. This is a high-mountain station located in Tenerife (Canary Islands, Spain; at 28.3°N, 16.5°W, 2373ma.s.l.) and is a representative site of the subtropical North Atlantic free troposphere. It contributes with basic-BSRN radiation measurements, such as, global shortwave radiation (SWD), direct radiation (DIR), diffuse radiation (DIF) and longwave downward radiation (LWD) and extended-BSRN measurements, including ultraviolet ranges (UV-A and UV-B), shortwave upward radiation (SWU) and longwave upward radiation (LWU) and other ancillary measurements, such as vertical profiles of temperature, humidity and wind obtained from radiosonde (WMO, station #60018) and total column ozone from Brewer spectrophotometer. The IZA measurements present high quality standards since more than 98% of the data are within the limits recommended by the BSRN. There is an excellent agreement in the comparison between SWD, DIR and DIF (instantaneous and daily) measurements with simulations obtained with the LibRadtran radiative transfer model. The root mean square error (RMSE) for SWD is 2.28% for instantaneous values and 1.58% for daily values, while the RMSE for DIR is 2.00% for instantaneous values and 2.07% for daily values. IZA is a unique station that provides very accurate solar radiation data in very contrasting scenarios: most of the time under pristine sky conditions, and periodically under the effects of the Saharan Air Layer characterized by a high content of mineral dust. A detailed description of the BSRN program at IZA, including quality control and quality assurance activities, is given in this work. The IZA BSRN program has benefited from results obtained within POLARMOON project funded by the Ministerio de Economía y Competividad from Spain, CTM2015-66742-R.

Póster presentado en: 9th International Workshop on Sand/Duststorms and Associated Dustfall, celebrado en Tenerife del 22 al 24 de mayo de 2018. This work has been performed within the framework of COST Action ES1207 “The European Brewer Network” (EUBREWNET), supported by COST (European Cooperation in Science and Technology). Part of this work has been developed within the IDEAS+ project of the European Space Agency, in collaboration with LuftBlick Earth Observation Technologies. This work has been supported by the European Metrology Research Programme (EMRP) within the joint research project ENV59 “Traceability for atmospheric total column ozone” (ATMOZ). The EMRP is jointly funded by the EMRP participating countries within EURAMET and the European Union. These activities have been partially developed in the WMO-CIMO Testbed for Aerosols and Water Vapor Remote Sensing Instruments (Izaña, Spain). We also acknowledge the support of the Ministry of Economy and Competitiveness of Spain and the European Regional Development Fund (ERDF) under the POLARMOON (CTM2015-66742-R) and AEROATLAN (CGL2015-66299-P) projects. Stratospheric ozone and spectral UV baseline monitoring in the United Kingdom is supported by DEFRA, The Department for the Environment, Food, and Rural Affairs, since 2003. Some of the AERONET sun photometers used in this work have been calibrated within the AERONET Europe TNA, supported by the European Community-Research Infrastructure Action under the Horizon 2020 research and innovation program, ACTRIS-2 grant agreement No. 654109. We gratefully the acknowledge the PIs of the Madrid, Izaña, and Tamanrasset AERONET stations.

Póster presentado en: ATMOS 2018, celebrado en Salzburgo (Austria) del 26 al 29 de noviembre de 2018. In this work we present the validation results of almost one year of TROPOMI Near Real Time (NRTI) and OFFLine (OFFL) data against ground-based quality-assured Brewer and Dobson total ozone column (TOC) measurements deposited in the World Ozone and Ultraviolet Radiation Data Center (WOUDC). Additionally, comparisons to Brewer measurements from the European Brewer Network (EUBREWNET) and the Canadian Network are performed, as well as to twilight zenith-sky measurements obtained with ZSL-DOAS (Zenith Scattered Light Differential Optical Absorption Spectroscopy) instruments, that form part of the SAOZ network (Système d'Analyse par Observation Zénitale) of the Network for the Detection of Atmospheric Composition Change (NDACC). Through the comparison of the TROPOMI measurements to the total ozone ground-based measurements from stations that are distributed globally, as the background truth, the dependence of the new instrument on latitude, cloud properties, solar zenith and viewing angles, among others, is examined. Validation results show that the mean bias and the standard deviation of the percentage difference between TROPOMI and QA ground TOC meet the product requirements.

A 7-year comparison study between measured and simulated LDR under cloud-free conditions has been performed at the BSRN Izaña. Results show an excellent agreement with a mean bias (simulated-measured)

Presentación realizada en: ATMOZ workshop at 11th RBCC-E, celebrado en El Arenosillo, Huelva, el 1 de junio de 2017.

Comunicación presentada en: Brewer Ozone Spectrophotometer/Metrology Open Workshop celebrado del 17 al 20 de mayo de 2016 en Ponta Delgada, Azores, Portugal. This work has been supported by the European Metrology Research Programme (EMRP) within the joint research project ENV59 "Traceability for atmospheric total column ozone" (ATMOZ)

Final Publishable JRP Report. Issued: November 2017. Version V1.0 Ozone in the earth’s upper atmosphere absorbs ultraviolet radiation, preventing most of it reaching the ground.This is important because ultraviolet radiation can harm life on earth, and for example lead to skin cancer.Since the 1980s, it has been known that human-produced chlorofluorocarbons (CFCs) have led to recurring losses of total ozone in the Antarctic (the ozone hole), and these have also been recently observed in the Arctic, while in middle-latitudes, moderate ozone depletion has been observed. The Montreal Protocol on Substances that Deplete the Ozone Layer is an international treaty signed in 1994 designed to protect the ozone layer by phasing out the production of substances that are responsible for ozone depletion, and it has been successful in reducing the emission of ozone-depleting substances. However, monitoring of the recovery of the ozone layer requires accurate long-term observations with reliable and well understood instruments and the development of future instrumentation. This project characterised key reference and network instruments for the traceability of ozone retrievals (or measurements), developed new instruments and devices for in-field characterisation of the existing network instruments and new ozone monitoring instruments, and generated new datasets for ozone absorption crosssections and extra-terrestrial solar reference spectrum. The EMRP is jointly funded by the EMRP participating countries within EURAMET and the European Union.

Presentación realizada en: ATMOZ workshop at 11th RBCC-E, celebrado en El Arenosillo, Huelva, el 1 de junio de 2017. This work has been supported by the European Metrology Research Programme (EMRP) within the joint research project ENV59 “Traceability for atmospheric total column ozone” (ATMOZ). The EMRP is jointly funded by the EMRP participating countries within EURAMET and the European Union.

Presentación realizada en: ATMOZ workshop at 11th RBCC-E, celebrado en El Arenosillo, Huelva, el 1 de junio de 2017.