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12 results on '"Reactive Materials for Electrochemical Systems (LCMCP-RMES )"'

1. Molten Salts‐Driven Discovery of a Polar Mixed‐Anion 3D framework at the nanoscale: Zn4Si2O7Cl2, Charge Transport and Photoelectrocatalytic Water Splitting

Author

Kumar, Ram, Song, Yang, Ghoridi, Anissa, Boullay, Philippe, Rousse, Gwenaelle, Gervais, Christel, Diogo, Cristina Coelho, Kabbour, Houria, Sassoye, Capucine, Beaunier, Patricia, Castaing, Victor, Viana, Bruno, Ruiz Gonzalez, Maria Luisa, Calbet, José Gonzalez, Laberty-Robert, Christel, Portehault, David, Novel Advanced Nano-Objects (LCMCP-NANO), Matériaux Hybrides et Nanomatériaux (LCMCP-MHN), Laboratoire de Chimie de la Matière Condensée de Paris (LCMCP), Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Laboratoire de Chimie de la Matière Condensée de Paris (LCMCP), Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS), Laboratoire de cristallographie et sciences des matériaux (CRISMAT), Université de Caen Normandie (UNICAEN), Normandie Université (NU)-Normandie Université (NU)-École Nationale Supérieure d'Ingénieurs de Caen (ENSICAEN), Normandie Université (NU)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche sur les Matériaux Avancés (IRMA), Normandie Université (NU)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Rouen Normandie (UNIROUEN), Normandie Université (NU)-Institut national des sciences appliquées Rouen Normandie (INSA Rouen Normandie), Institut National des Sciences Appliquées (INSA)-Normandie Université (NU)-Institut National des Sciences Appliquées (INSA)-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Rouen Normandie (UNIROUEN), Institut National des Sciences Appliquées (INSA)-Normandie Université (NU)-Institut National des Sciences Appliquées (INSA)-Centre National de la Recherche Scientifique (CNRS), Chimie du solide et de l'énergie (CSE), Collège de France (CdF (institution))-Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS), Spectroscopie, Modélisation, Interfaces pour L'Environnement et la Santé (LCMCP-SMiLES), Fédération de Chimie et Matériaux de Paris-Centre (FCMat), Ecole Nationale Supérieure de Chimie de Paris - Chimie ParisTech-PSL (ENSCP), Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Ecole Superieure de Physique et de Chimie Industrielles de la Ville de Paris (ESPCI Paris), Université Paris sciences et lettres (PSL)-Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS), Unité de Catalyse et Chimie du Solide - UMR 8181 (UCCS), Université d'Artois (UA)-Centrale Lille-Institut de Chimie du CNRS (INC)-Université de Lille-Centre National de la Recherche Scientifique (CNRS), Laboratoire de Réactivité de Surface (LRS), Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS), Institut de Recherche de Chimie Paris (IRCP), Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Ministère de la Culture (MC), Université Paris sciences et lettres (PSL), Universidad Complutense de Madrid = Complutense University of Madrid [Madrid] (UCM), Reactive Materials for Electrochemical Systems (LCMCP-RMES ), and CNRS-CEA METSA network, Department of Energy (DOE) Office of Science User Facility operated for the DOE Office of Science by Argonne National Laboratory under Contract No. DE-AC02-06CH11357, GENCI-IDRIS (Grant 097535). Région Ile de France - SESAME

Subjects
electron crystallography, mixed anions, photoelectrocatalysis, molten salts, [CHIM.CRIS]Chemical Sciences/Cristallography, oxychloride, [CHIM.MATE]Chemical Sciences/Material chemistry, [CHIM.CATA]Chemical Sciences/Catalysis
Abstract

International audience; Mixed-anion compounds widen the chemical space of attainable materials compared to single anionic compounds, but the exploration of their structural diversity is limited by common synthetic paths. Especially, oxychlorides rely mainly on layered structures, which suffer from low stability during photo(electro)catalytic processes. Herein we report a strategy to design a new polar 3D tetrahedral framework with composition Zn4Si2O7Cl2. We use a molten salt medium to enable low temperature crystallization of nanowires of this new compound, by relying on tetrahedral building units present in the melt to build the connectivity of the oxychloride. These units are combined with silicon-based connectors from a non-oxidic Zintl phase to enable precise tuning of the oxygen content. This structure brings high chemical and thermal stability, as well as strongly anisotropic hole mobility along the polar axis. These features, associated with the ability to adjust the transport properties by doping, enable to tune water splitting properties for photoelectrocatalytic H2 evolution and water oxidation. This work then paves the way to a new family of mixed-anion solids

Published
2023
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2. Advanced Functional Hybrid Proton Exchange Membranes Robust and Conductive at 120 °C

Author

Jason Richard, Fatima Haidar, Madeline K. Alzamora, Manuel Maréchal, Natalia Rovira, Christophe Vacquier, Clément Sanchez, Christel Laberty‐Robert, Reactive Materials for Electrochemical Systems (LCMCP-RMES ), Matériaux Hybrides et Nanomatériaux (LCMCP-MHN), Laboratoire de Chimie de la Matière Condensée de Paris (LCMCP), Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Laboratoire de Chimie de la Matière Condensée de Paris (LCMCP), Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS), SYstèmes Moléculaires et nanoMatériaux pour l’Energie et la Santé (SYMMES), Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche Interdisciplinaire de Grenoble (IRIG), Direction de Recherche Fondamentale (CEA) (DRF (CEA)), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Direction de Recherche Fondamentale (CEA) (DRF (CEA)), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Grenoble Alpes (UGA), Symbio, Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS), Institut d’Etudes Avancées de l’Université de Strasbourg - Institute for Advanced Study (USIAS), Université de Strasbourg (UNISTRA), Réseau sur le stockage électrochimique de l'énergie (RS2E), Aix Marseille Université (AMU)-Université Toulouse III - Paul Sabatier (UT3), Université de Toulouse (UT)-Université de Toulouse (UT)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Collège de France (CdF (institution))-Université de Picardie Jules Verne (UPJV)-Ecole Nationale Supérieure de Chimie de Paris - Chimie ParisTech-PSL (ENSCP), Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Université de Pau et des Pays de l'Adour (UPPA)-Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Institut National Polytechnique (Toulouse) (Toulouse INP), Université de Toulouse (UT)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP ), Université Grenoble Alpes (UGA)-Université Grenoble Alpes (UGA)-Nantes Université (Nantes Univ)-Université de Montpellier (UM)-Ecole Nationale Supérieure de Chimie de Montpellier (ENSCM), and Université de Montpellier (UM)

Subjects
Mechanics of Materials, Mechanical Engineering, [CHIM.MATE]Chemical Sciences/Material chemistry
Abstract

International audience

Published
2022
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3. Hydroxyapatites as Versatile Inorganic Hosts of Unusual Pentavalent Manganese Cations

Author

María Hernando, José M. González-Calbet, Marina Parras, Christel Laberty-Robert, Aurea Varela, Gwenaëlle Rousse, José Luis Martínez, Laura Serrador, David Portehault, María Teresa Fernández-Díaz, Francisco Gonell, E. Matesanz, Clément Sanchez, Isabel Gómez-Recio, Almudena Torres-Pardo, Universidad Complutense de Madrid = Complutense University of Madrid [Madrid] (UCM), Institut Laue-Langevin (ILL), ILL, Laboratoire des Sciences du Numérique de Nantes (LS2N), IMT Atlantique Bretagne-Pays de la Loire (IMT Atlantique), Institut Mines-Télécom [Paris] (IMT)-Institut Mines-Télécom [Paris] (IMT)-Université de Nantes - UFR des Sciences et des Techniques (UN UFR ST), Université de Nantes (UN)-Université de Nantes (UN)-École Centrale de Nantes (ECN)-Centre National de la Recherche Scientifique (CNRS), Novel Advanced Nano-Objects (LCMCP-NANO), Matériaux Hybrides et Nanomatériaux (LCMCP-MHN), Laboratoire de Chimie de la Matière Condensée de Paris (LCMCP), Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Laboratoire de Chimie de la Matière Condensée de Paris (LCMCP), Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS), Sorbonne Université (SU), Chaire Chimie des matériaux hybrides, and Reactive Materials for Electrochemical Systems (LCMCP-RMES )

Subjects
Chemistry, General Chemical Engineering, chemistry.chemical_element, [CHIM.MATE]Chemical Sciences/Material chemistry, 02 engineering and technology, General Chemistry, Manganese, 010402 general chemistry, 021001 nanoscience & nanotechnology, 01 natural sciences, 0104 chemical sciences, Polymer chemistry, Materials Chemistry, Hydroxyapatites, 0210 nano-technology
Abstract

International audience; Contrary to molecular species, only very few solids are reported to host manganese (V) species. Herein, we report three new compounds with a hydroxyapatite structural backbone built on the Mn V O 4 3− anion: Sr 5 [(Mn 1−x Si x)O 4 ] 3 (OH) 1−3x (x =0 and 0.053), Sr 5 (MnO 4) 3 (OH) 1−y F y (y = 0.90), and Sr 5 [(Mn 1−x Si x)-O 4 ] 3 F 1−3x (x = 0.058). These solids are fully characterized using powder X-ray and neutron powder diffraction, scanning transmission electron microscopy, electron energy loss spectroscopy (EELS), thermogravimetric analysis, and magnetic measurements. Especially, we report for the first time EELS Mn−L 2,3 spectra of manganese with the oxidation state (V). Contrary to other Mn(V) oxides, these solids and the nominal compound Sr 5 (MnO 4) 3 OH do not comprise Ba 2+ cations but rely only on Sr 2+ cations, showing that barium is not a required element to stabilize Mn(V) species in inorganic solids. We show that by tuning soft chemistry conditions on the one hand and post-treatment topological transformation conditions on the other hand, Mn(V) and hydroxyl groups can be substituted by Si(IV) and fluoride ions, respectively. Hence, we deliver solids with a potentially wide composition range. These compounds show significant oxygen anionic conduction, thus suggesting the emergence of new functional materials built from high-oxidation state manganese cations.

Published
2020
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4. Native Collagen: Electrospinning of Pure, Cross-Linker-Free, Self-Supported Membrane

Author

Nicolas Debons, Frank Wien, Christel Laberty-Robert, Julien Rodrigues da Silva, Carole Aimé, Marie-Claire Schanne-Klein, Natacha Krins, Yong Chen, Christophe Hélary, Laurent Muller, Marion Marchand, Dounia Dems, Matériaux et Biologie (LCMCP-MATBIO), Laboratoire de Chimie de la Matière Condensée de Paris (LCMCP), Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS), Synchrotron SOLEIL (SSOLEIL), Centre National de la Recherche Scientifique (CNRS), Centre interdisciplinaire de recherche en biologie (CIRB), Labex MemoLife, École normale supérieure - Paris (ENS Paris), Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Collège de France (CdF (institution))-Ecole Superieure de Physique et de Chimie Industrielles de la Ville de Paris (ESPCI Paris), Université Paris sciences et lettres (PSL)-École normale supérieure - Paris (ENS Paris), Université Paris sciences et lettres (PSL)-Institut National de la Santé et de la Recherche Médicale (INSERM)-Centre National de la Recherche Scientifique (CNRS), Laboratoire d'optique et biosciences (LOB), École polytechnique (X)-Institut National de la Santé et de la Recherche Médicale (INSERM)-Centre National de la Recherche Scientifique (CNRS), Reactive Materials for Electrochemical Systems (LCMCP-RMES ), Matériaux Hybrides et Nanomatériaux (LCMCP-MHN), Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Laboratoire de Chimie de la Matière Condensée de Paris (LCMCP), Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Ecole Superieure de Physique et de Chimie Industrielles de la Ville de Paris (ESPCI Paris), Université Paris sciences et lettres (PSL)-Collège de France (CdF (institution))-École normale supérieure - Paris (ENS Paris), and Université Paris sciences et lettres (PSL)-Collège de France (CdF (institution))-Institut National de la Santé et de la Recherche Médicale (INSERM)-Centre National de la Recherche Scientifique (CNRS)

Subjects
hierarchical organization, Biomedical Engineering, Nanotechnology, 02 engineering and technology, 010402 general chemistry, 01 natural sciences, Biomaterials, Tissue engineering, Native state, second harmonic generation microscopy, Cross linker, electrospinning, chemistry.chemical_classification, Biomolecule, Biochemistry (medical), [CHIM.MATE]Chemical Sciences/Material chemistry, General Chemistry, Second Harmonic Generation Microscopy, 021001 nanoscience & nanotechnology, Electrospinning, 0104 chemical sciences, Membrane, chemistry, extra-cellular matrix, tissue engineering, Collagen, 0210 nano-technology
Abstract

International audience; Rebuilding biological environments is crucial when facing the challenges of fundamental and biomedical research. Thus, preserving the native state of biomolecules is essential. We use electrospinning (ES), which is an extremely promising method for the preparation of fibrillar membranes to mimic the ECM of native tissues. Here, we report for the first time (1) the ES of pure and native collagen into a self-supported membrane in absence of crosslinker and polymer support, (2) the preservation of the membrane integrity in hydrated media in absence of crosslinker and (3) the preservation of the native molecular structure and recovery of the hierarchical assembly of collagen. We use a multiscale approach to characterize collagen native structure at the molecular level using circular dichroism, and to investigate collagen hierarchical organization within the self-supported membrane using a combination of multiphoton and electron microscopies. Finally, we show that the membranes are perfectly suited for cell adhesion and spreading, making them very promising candidates for the development of biomaterials and finding applications in biomedical research.

Published
2022
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5. Spark plasma sintering of nanostructured ZnS ceramics: Grain growth control and improved hardness

Author

Julie Cédelle, Damien Bregiroux, Reactive Materials for Electrochemical Systems (LCMCP-RMES ), Matériaux Hybrides et Nanomatériaux (LCMCP-MHN), Laboratoire de Chimie de la Matière Condensée de Paris (LCMCP), Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Laboratoire de Chimie de la Matière Condensée de Paris (LCMCP), Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS), Laboratoire Energétique Mécanique Electromagnétisme (LEME), and Université Paris Nanterre (UPN)

Subjects
010302 applied physics, Materials science, Mechanical Engineering, Metallurgy, Spark plasma sintering, Sintering, 02 engineering and technology, [CHIM.MATE]Chemical Sciences/Material chemistry, 021001 nanoscience & nanotechnology, Condensed Matter Physics, 01 natural sciences, Indentation hardness, Grain size, Grain growth, Mechanics of Materials, visual_art, 0103 physical sciences, visual_art.visual_art_medium, General Materials Science, Ceramic, 0210 nano-technology, ComputingMilieux_MISCELLANEOUS
Abstract

The densification and grain growth behavior of a ZnS nanopowder during spark plasma sintering (SPS) were investigated under the pressure of 125 MPa and constant heating rate of 25 °C min−1. At a sintering temperature of 550 °C, almost fully dense ZnS ceramics (98.2%) could be obtained with grain size as low as 75 nm. At higher temperature, ZnS is subject of a very important grain growth that is detrimental to the mechanical properties. A maximum Vickers microhardness of 4.2 GPa was measured, which is 70% higher than the current state of the art. Retaining the grain size below 100 nm appears to be the key to developing competitive ZnS functional ceramics.

Published
2021
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6. Dysprosium doping of Ca2MnO4: Effect on crystal structure at room temperature and thermal behavior

Author

M. Allani, D. Bregiroux, A. Bahezre, G. Wallez, Christel Laberty-Robert, Gwenaëlle Rousse, Reactive Materials for Electrochemical Systems (LCMCP-RMES ), Matériaux Hybrides et Nanomatériaux (LCMCP-MHN), Laboratoire de Chimie de la Matière Condensée de Paris (LCMCP), Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Laboratoire de Chimie de la Matière Condensée de Paris (LCMCP), Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS), Chimie du solide et de l'énergie (CSE), Collège de France (CdF (institution))-Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS), Institut de Recherche de Chimie Paris (IRCP), Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Ecole Nationale Supérieure de Chimie de Paris - Chimie ParisTech-PSL (ENSCP), and Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Ministère de la Culture (MC)

Subjects
Range (particle radiation), Materials science, Doping, Analytical chemistry, chemistry.chemical_element, 02 engineering and technology, Crystal structure, 010402 general chemistry, 021001 nanoscience & nanotechnology, Condensed Matter Physics, 01 natural sciences, 0104 chemical sciences, chemistry, Thermal, Thermoelectric effect, Dysprosium, [CHIM.CRIS]Chemical Sciences/Cristallography, General Materials Science, 0210 nano-technology, ComputingMilieux_MISCELLANEOUS
Abstract

Dysprosium-doped Ruddlesden−Popper calcium manganates with compositions of Ca2-xDyxMnO4 are potential candidates for high temperature thermoelectric applications. The effect of dysprosium doping on the crystal structure of Ca2-xDyxMnO4 at room temperature and its thermal behavior between RT and 800 °C were investigated in the range 0

Published
2021
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7. Phase selective synthesis of nickel silicide nanocrystals in molten salts for electrocatalysis of the oxygen evolution reaction

Author

Ovidiu Ersen, Ram Kumar, Mounib Bahri, Christel Laberty-Robert, Cyril Thomas, Yang Song, David Portehault, Francisco Gonell, Clément Sanchez, Portehault, David, Novel Advanced Nano-Objects (LCMCP-NANO), Matériaux Hybrides et Nanomatériaux (LCMCP-MHN), Laboratoire de Chimie de la Matière Condensée de Paris (LCMCP), Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Laboratoire de Chimie de la Matière Condensée de Paris (LCMCP), Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS), Institut de Physique et Chimie des Matériaux de Strasbourg (IPCMS), Université de Strasbourg (UNISTRA)-Centre National de la Recherche Scientifique (CNRS)-Matériaux et Nanosciences Grand-Est (MNGE), Université de Strasbourg (UNISTRA)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Institut National de la Santé et de la Recherche Médicale (INSERM)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Université de Strasbourg (UNISTRA)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Institut National de la Santé et de la Recherche Médicale (INSERM)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Réseau nanophotonique et optique, Université de Strasbourg (UNISTRA)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Centre National de la Recherche Scientifique (CNRS)-Université de Strasbourg (UNISTRA)-Centre National de la Recherche Scientifique (CNRS), Laboratoire de Réactivité de Surface (LRS), Université Pierre et Marie Curie - Paris 6 (UPMC)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Chaire Chimie des matériaux hybrides, Reactive Materials for Electrochemical Systems (LCMCP-RMES ), Université de Strasbourg (UNISTRA)-Matériaux et nanosciences d'Alsace (FMNGE), Institut de Chimie du CNRS (INC)-Université de Strasbourg (UNISTRA)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Institut National de la Santé et de la Recherche Médicale (INSERM)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université de Strasbourg (UNISTRA)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Institut National de la Santé et de la Recherche Médicale (INSERM)-Centre National de la Recherche Scientifique (CNRS)-Centre National de la Recherche Scientifique (CNRS)-Réseau nanophotonique et optique, and Centre National de la Recherche Scientifique (CNRS)-Université de Strasbourg (UNISTRA)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Centre National de la Recherche Scientifique (CNRS)-Université de Strasbourg (UNISTRA)

Subjects
[PHYS]Physics [physics], chemistry.chemical_classification, [CHIM.MATE] Chemical Sciences/Material chemistry, Materials science, Oxygen evolution, Intermetallic, chemistry.chemical_element, Salt (chemistry), [CHIM.MATE]Chemical Sciences/Material chemistry, 02 engineering and technology, 010402 general chemistry, 021001 nanoscience & nanotechnology, Electrocatalyst, 01 natural sciences, [PHYS] Physics [physics], 0104 chemical sciences, Sodium silicide, chemistry.chemical_compound, Nickel, chemistry, Chemical engineering, General Materials Science, Iridium, 0210 nano-technology, Eutectic system
Abstract

International audience; We report phase selective synthesis of intermetallic nickel silicide nanocrystals in inorganic molten salts. NiSi and Ni2Si nanocrystals are obtained by reacting a nickel (II) salt and sodium silicide Na4Si4 in the molten LiI-KI inorganic eutectic salt mixture. We report that nickel silicide nanocrystals are precursors to active electrocatalysts in the oxygen evolution reaction (OER) and may be low-cost alternatives to iridium-based electrocatalysts.

Published
2020
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8. Structure–Activity Relationship in Manganese Perovskite Oxide Nanocrystals from Molten Salts for Efficient Oxygen Reduction Reaction Electrocatalysis

Author

David Portehault, Vincent Vivier, Carlos M. Sánchez-Sánchez, Christel Laberty-Robert, Francisco Gonell, Christophe Méthivier, Novel Advanced Nano-Objects (LCMCP-NANO), Matériaux Hybrides et Nanomatériaux (LCMCP-MHN), Laboratoire de Chimie de la Matière Condensée de Paris (LCMCP), Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Laboratoire de Chimie de la Matière Condensée de Paris (LCMCP), Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS), Laboratoire Interfaces et Systèmes Electrochimiques (LISE), Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS), Laboratoire de Réactivité de Surface (LRS), Université Pierre et Marie Curie - Paris 6 (UPMC)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), and Reactive Materials for Electrochemical Systems (LCMCP-RMES )

Subjects
Materials science, General Chemical Engineering, Oxide, Nanoparticle, chemistry.chemical_element, 02 engineering and technology, Manganese, 010402 general chemistry, Electrocatalyst, 01 natural sciences, 7. Clean energy, chemistry.chemical_compound, Materials Chemistry, Structure–activity relationship, Oxygen reduction reaction, [CHIM]Chemical Sciences, Perovskites, Redox reactions, Perovskite (structure), Oxides, General Chemistry, Transition metals, 021001 nanoscience & nanotechnology, 0104 chemical sciences, Chemical engineering, Nanocrystal, chemistry, Nanoparticles, 0210 nano-technology
Abstract

International audience; We report a synthesis pathway in molten salts toward ligand-free nanoparticles of the layered perovskite La0.5Sr1.5MnO4 (l-LSMO) and of the pseudocubic perovskite La0.7Sr0.3MnO3 (pc-LSMO). These particles are readily implemented as oxygen reduction reaction (ORR) electrocatalysts in alkaline conditions. They show high ORR selectivity for the 4-electron reduction of O2 in water. Among these two materials, pc-LSMO nanocrystals of 20 nm diameter exhibit high mass-normalized ORR activity for a perovskite material (21.4 A g–1oxide at 0.8 V/RHE) thanks to their relatively large surface area, high crystallinity, and electron mobility. These features provide pc-LSMO nanocrystals with remarkable stability compared to state-of-the-art perovskites, for instance, only a 5% increase of the overpotential at −0.05 mA cm–2oxide over 40 h. Thus, pc-LSMO nanocrystals are the most stable perovskite ORR electrocatalyst reported to date. This performance combined with high activity, high selectivity, and the absence of precious metals make La0.7Sr0.3MnO3 nanocrystals one of the best compromises for alkaline oxygen reduction reaction.

Published
2020
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9. 31P MAS NMR and DFT study of crystalline phosphate matrices

Author

Thibault Charpentier, Karin Popa, Attila Kovács, Damien Bregiroux, Laura Martel, European Commission - Joint Research Centre [Karlsruhe] (JRC), Reactive Materials for Electrochemical Systems (LCMCP-RMES ), Matériaux Hybrides et Nanomatériaux (LCMCP-MHN), Laboratoire de Chimie de la Matière Condensée de Paris (LCMCP), Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Laboratoire de Chimie de la Matière Condensée de Paris (LCMCP), Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS), Laboratoire Structure et Dynamique par Résonance Magnétique (LCF) (LSDRM), Nanosciences et Innovation pour les Matériaux, la Biomédecine et l'Energie (ex SIS2M) (NIMBE UMR 3685), Institut Rayonnement Matière de Saclay (IRAMIS), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Paris-Saclay-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Paris-Saclay-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Institut Rayonnement Matière de Saclay (IRAMIS), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Paris-Saclay-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Paris-Saclay-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Paris-Saclay-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Institut Rayonnement Matière de Saclay (IRAMIS), and Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Paris-Saclay-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)

Subjects
Nuclear and High Energy Physics, phosphates, Chemical substance, Materials science, Crystal structure, [CHIM.INOR]Chemical Sciences/Inorganic chemistry, 010402 general chemistry, DFT calculations, 01 natural sciences, Divalent, chemistry.chemical_compound, Cluster (physics), cluster model, 31P NMR, Anisotropy, Instrumentation, chemistry.chemical_classification, Radiation, 010405 organic chemistry, Chemical shift, Isotropy, General Chemistry, Phosphate, 0104 chemical sciences, chemistry, Physical chemistry, Yavapaiite
Abstract

International audience; We present the study of the phosphorus local environment by using 31 P MAS NMR in a series of seven double monophosphates M II M IV (PO 4) 2 (M II and M IV being divalent and tetravalent cations, respectively) of yavapaiite and low-yavapaiite type crystal structures. Solid-state and cluster DFT calculations were found to be efficient for predicting the 31 P isotropic chemical shift and chemical shift anisotropy. To achieve this performance, however, a proper computational optimisation of the experimental structural data was required. From the three optimisation methods tested, the full optimisation provided the best reference structure for the calculation of the NMR parameters of the studied phosphates. Also, a better prediction of the chemical shifts was possible by using a correction to the GIPAW calculated shielding.

Published
2020
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10. Multicationic Sr4Mn3O10 mesostructures: molten salt synthesis, analytical electron microscopy study and reactivity

Author

Irma N. González-Jiménez, Juan C. Hernández-Garrido, Christel Laberty-Robert, David Portehault, Clément Sanchez, Miguel López-Haro, Almudena Torres-Pardo, José M. González-Calbet, Marina Parras, Simon Rano, José J. Calvino, Aurea Varela, Universidad Complutense de Madrid = Complutense University of Madrid [Madrid] (UCM), Chaire Chimie des matériaux hybrides, Laboratoire de Chimie de la Matière Condensée de Paris (LCMCP), Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS), Reactive Materials for Electrochemical Systems (LCMCP-RMES ), Matériaux Hybrides et Nanomatériaux (LCMCP-MHN), Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Laboratoire de Chimie de la Matière Condensée de Paris (LCMCP), Universidad de Cádiz (UCA), and Novel Advanced Nano-Objects (LCMCP-NANO)

Subjects
Materials science, Nanostructure, Process Chemistry and Technology, Electron energy loss spectroscopy, 02 engineering and technology, [CHIM.INOR]Chemical Sciences/Inorganic chemistry, 010402 general chemistry, 021001 nanoscience & nanotechnology, 01 natural sciences, Surface energy, 0104 chemical sciences, chemistry.chemical_compound, Electron tomography, chemistry, Chemical engineering, Mechanics of Materials, Transmission electron microscopy, Strontium hydroxide, General Materials Science, Surface charge, Electrical and Electronic Engineering, Molten salt, 0210 nano-technology
Abstract

International audience; Inorganic molten salts are known as fluxes for the synthesis of novel bulk inorganic compounds and of mesostructures and nanostructures with crystal habits different from those observed in more conventional solvents. However, they have not demonstrated the ability to provide mesostructures and nanostructures of complex metal oxides that are currently unreported at the mesoscale and nanoscale. In this report, we show the first occurrence of Sr4Mn3O10 at the mesoscale, as platelets synthesized in molten strontium hydroxide at 600 °C with basal faces of few hundreds of nanometers and thicknesses ranging from 20 to 100 nm. We address carefully the atom-scale structure by transmission electron microscopy, including electron energy loss spectroscopy and electron tomography. We then propose that the final morphology is driven by the surface charge of each facet through surface energy. The reactivity of these platelets is then addressed, highlighting cation leaching when in contact with acidic water, which results in crystalline–amorphous core–shell platelets that are active electrocatalysts towards the oxygen reduction reaction.

Published
2018
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11. Experimental Descriptors for the Synthesis of Multicationic Nickel Perovskite Nanoparticles for Oxygen Reduction

Author

Francisco Gonell, David Portehault, Vincent Vivier, Christel Laberty-Robert, Carlos M. Sánchez-Sánchez, Novel Advanced Nano-Objects (LCMCP-NANO), Matériaux Hybrides et Nanomatériaux (LCMCP-MHN), Laboratoire de Chimie de la Matière Condensée de Paris (LCMCP), Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Laboratoire de Chimie de la Matière Condensée de Paris (LCMCP), Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS), Laboratoire Interfaces et Systèmes Electrochimiques (LISE), Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS), and Reactive Materials for Electrochemical Systems (LCMCP-RMES )

Subjects
Materials science, Synthesis methods, Nanoparticle, chemistry.chemical_element, nickel oxide, 02 engineering and technology, 010402 general chemistry, 01 natural sciences, Nanomaterials, Oxygen reduction reaction, General Materials Science, perovskite, Perovskite (structure), oxygen reduction reaction, Nickel oxide, molten salts, [CHIM.MATE]Chemical Sciences/Material chemistry, 021001 nanoscience & nanotechnology, Oxygen reduction, 0104 chemical sciences, Nickel, chemistry, Chemical engineering, layered materials, synthesis mechanism, 0210 nano-technology
Abstract

International audience; In many liquid-phase synthesis methods developed to produce nanomaterials, the key parameters governing the selective synthesis of solids and compounds are clearly identified, e.g. heat treatment profile, precursors solubility, pH, etc. Most of these well-understood approaches rely on relatively low temperature processes, below 400 °C, where conventional solvents are still stable. Interestingly, thermally stable inorganic molten salts enable to widen the temperature range for liquid-phase syntheses. They provide access to other families of crystalline solids requiring higher temperatures, as multicationic oxides. Nonetheless, the mechanisms that govern solid state formation and phase selection when different compounds compete are poorly understood. Herein, we report how experimental parameters, such as temperature, time, reaction medium composition and solvent oxo-basicity, enable to drive the synthesis mechanisms in molten salts towards nanoscaled multicationic oxides. We especially enlighten the phase-selective synthesis of pseudo-cubic perovskite LaNiO3 and layered Ruddlesden-Popper phases La2NiO4 and LaSrNiO4 at the nanoscale, by suggesting that the oxidation state of the metallic precursor plays a key role in the reaction pathway. This allows designing electrocatalysts for oxygen reduction reaction.

Published
2020
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12. Morphological and Structural Evolution of Co3O4 Nanoparticles Revealed by in Situ Electrochemical Transmission Electron Microscopy during Electrocatalytic Water Oxidation

Author

Nathaly Ortiz Peña, Christel Laberty-Robert, David Portehault, Sophie Carenco, Ovidiu Ersen, Clément Sanchez, Dris Ihiawakrim, Benedikt Lassalle-Kaiser, Madeleine Han, Institut de Physique et Chimie des Matériaux de Strasbourg (IPCMS), Université de Strasbourg (UNISTRA)-Centre National de la Recherche Scientifique (CNRS)-Matériaux et nanosciences d'Alsace (FMNGE), Institut de Chimie du CNRS (INC)-Université de Strasbourg (UNISTRA)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Institut National de la Santé et de la Recherche Médicale (INSERM)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université de Strasbourg (UNISTRA)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Institut National de la Santé et de la Recherche Médicale (INSERM)-Centre National de la Recherche Scientifique (CNRS)-Réseau nanophotonique et optique, Centre National de la Recherche Scientifique (CNRS)-Université de Strasbourg (UNISTRA)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Centre National de la Recherche Scientifique (CNRS)-Université de Strasbourg (UNISTRA), Novel Advanced Nano-Objects (LCMCP-NANO), Matériaux Hybrides et Nanomatériaux (LCMCP-MHN), Laboratoire de Chimie de la Matière Condensée de Paris (LCMCP), Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Laboratoire de Chimie de la Matière Condensée de Paris (LCMCP), Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS), Synchrotron SOLEIL (SSOLEIL), Centre National de la Recherche Scientifique (CNRS), Chaire Chimie des matériaux hybrides, Reactive Materials for Electrochemical Systems (LCMCP-RMES ), Agence Nationale de la Recherche ANR, ANR-16-CE05-0011,InSiChem,Etude ' in-situ ' et multiéchelle d'électrocatalyseurs pour la conversion d'énergie(2016), Université de Strasbourg (UNISTRA)-Matériaux et nanosciences d'Alsace (FMNGE), and Institut de Chimie du CNRS (INC)-Université de Strasbourg (UNISTRA)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Institut National de la Santé et de la Recherche Médicale (INSERM)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université de Strasbourg (UNISTRA)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Institut National de la Santé et de la Recherche Médicale (INSERM)-Centre National de la Recherche Scientifique (CNRS)-Centre National de la Recherche Scientifique (CNRS)-Réseau nanophotonique et optique

Subjects
In situ, Materials science, General Engineering, Oxygen evolution, General Physics and Astronomy, Nanoparticle, 02 engineering and technology, [CHIM.MATE]Chemical Sciences/Material chemistry, 010402 general chemistry, 021001 nanoscience & nanotechnology, Electrochemistry, Electrocatalyst, 01 natural sciences, 7. Clean energy, Structural evolution, 0104 chemical sciences, Chemical engineering, Transmission electron microscopy, [CHIM.ANAL]Chemical Sciences/Analytical chemistry, General Materials Science, 0210 nano-technology, Cobalt oxide, ComputingMilieux_MISCELLANEOUS
Abstract

Unveiling the mechanism of electrocatalytic processes is fundamental for the search of more efficient and stable electrode materials for clean energy conversion devices. Although several in situ te...

Published
2019
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