27 results on '"Raymond G. Merrill"'
Search Results
2. Crewed Mars Mission Mode Options for Nuclear Electric/Chemical Hybrid Transportation Systems
- Author
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Raymond G. Merrill, Andrew C. McCrea, Min Qu, Akshay Prasad, Katherine T. McBrayer, and Patrick Chai
- Subjects
business.industry ,Mode (statistics) ,Environmental science ,Mars Exploration Program ,Aerospace engineering ,business - Published
- 2021
3. Integrated Trajectory, Habitat, and Logistics Analysis and Trade Study for Human Mars Missions
- Author
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Emily Judd, Patrick Chai, Christopher A. Jones, Nicole Piontek, Jason Cho, Raymond G. Merrill, Jordan Klovstad, Andrew Owens, Chel Stromgren, and William Cirillo
- Subjects
Habitat ,Computer science ,business.industry ,Environmental resource management ,Trajectory ,Exploration of Mars ,business - Published
- 2020
4. Enabling Global Lunar Access for Human Landing Systems Staged at Earth-Moon L2 Southern Near Rectilinear Halo and Butterfly Orbits
- Author
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Zachary D. May, Min Qu, and Raymond G. Merrill
- Subjects
Butterfly ,Earth (chemistry) ,Halo ,Geology ,Astrobiology - Published
- 2020
5. Hybrid Transportation System Integrated Trajectory Design and Optimization for Mars Landing Site Accessibility
- Author
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Raymond G. Merrill, Kaila G. Pfrang, Min Qu, and Patrick Chai
- Subjects
Spacecraft ,Closure (computer programming) ,business.industry ,Computer science ,Trajectory ,Mars landing ,Crew ,Systems engineering ,Mars Exploration Program ,Plan (drawing) ,Trajectory optimization ,business - Abstract
NASA’s Mars Study Capability Team continues the agency’s efforts to study and refine the nation’s plan to field a sustainable human Mars campaign. One of the primary open issues left unanswered during previous analysis cycles was the uncertainty of the impact to the vehicle performance requirement to deliver crew and cargo to the same landing site across multiple mission opportunities. The Mars Study Capability Team has recently developed an integrated trajectory optimization and system closure model to solve the complex interplanetary trajectory optimization using both low-thrust and high-thrust maneuvers. This paper demonstrates the capability of this new integrated trajectory design and optimization method as it applies to the landing site accessibility problem for the Hybrid transportation architecture. The results showed that the current vehicle is capable of reaching up to +20 degree latitude and down to -20 degree latitude in every mission opportunity from 2033 to 2052. However, reaching latitudes beyond +/- 20 required more propellant than the spacecraft is currently designed to carry for many of the mission opportunities.
- Published
- 2019
6. Asteroid Redirect Mission concept: A bold approach for utilizing space resources
- Author
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Daniel D. Mazanek, Robert P. Mueller, John R. Brophy, and Raymond G. Merrill
- Subjects
Ion thruster ,Computer science ,Asteroid ,Paradigm shift ,Systems engineering ,Aerospace Engineering ,In situ resource utilization ,Space (commercial competition) ,Natural resource ,Space exploration ,Space Age - Abstract
The utilization of natural resources from asteroids is an idea that is older than the Space Age. The technologies are now available to transform this endeavor from an idea into reality. The Asteroid Redirect Mission (ARM) is a mission concept which includes the goal of robotically returning a small Near-Earth Asteroid (NEA) or a multi-ton boulder from a large NEA to cislunar space in the mid-2020s using an advanced Solar Electric Propulsion (SEP) vehicle and currently available technologies. The paradigm shift enabled by the ARM concept would allow in-situ resource utilization (ISRU) to be used at the human mission departure location (i.e., cislunar space) versus exclusively at the deep-space mission destination. This approach drastically reduces the barriers associated with utilizing ISRU for human deep-space missions. The successful testing of ISRU techniques and associated equipment could enable large-scale commercial ISRU operations to become a reality and enable a future space-based economy utilizing processed asteroidal materials. This paper provides an overview of the ARM concept and discusses the mission objectives, key technologies, and capabilities associated with the mission, as well as how the ARM and associated operations would benefit humanity׳s quest for the exploration and settlement of space.
- Published
- 2015
7. Integrated Optimization of Mars Hybrid Solar-Electric/Chemical Propulsion Trajectories
- Author
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Patrick Chai, Raymond G. Merrill, Min Qu, and Haijun Shen
- Subjects
Martian ,Spacecraft ,business.industry ,Computer science ,Frame (networking) ,ComputerApplications_COMPUTERSINOTHERSYSTEMS ,Trajectory optimization ,Mars Exploration Program ,Aerospace engineering ,Propulsion ,Architecture ,business ,Sizing - Abstract
NASA’s Human Exploration and Operation Mission Directorate is developing a reusable hybrid transportation architecture in which both chemical and solar-electric propulsion systems are used to deliver crew and cargo to the Martian sphere of influence. By combining chemical and solar-electric propulsions into a single spacecraft and applying each where it is the most effective, the hybrid architecture enables a series of Mars trajectories that are more fuel efficient than an all chemical propulsion architecture without significant increase to trip time. Solving the complex problem of low-thrust trajectory optimization coupled with the vehicle sizing requires development of an integrated trajectory analysis frame- work. Previous studies have utilized a more segmented optimization framework due to the limitation of the tools available. A new integrated optimization framework was recently developed to address the deficiencies of the previous methods that enables higher fidelity analysis to be performed and increases the efficiency of large design space explorations.
- Published
- 2018
8. Sensitivity Analysis of Hybrid Propulsion Transportation System for Human Mars Expeditions
- Author
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Ryan T. Joyce, Min Qu, Patrick Chai, Raymond G. Merrill, and Paul D. Kessler
- Subjects
020301 aerospace & aeronautics ,Engineering ,Ion thruster ,Spacecraft propulsion ,Payload ,business.industry ,In-space propulsion technologies ,02 engineering and technology ,Mars Exploration Program ,Propulsion ,01 natural sciences ,0203 mechanical engineering ,Electrically powered spacecraft propulsion ,Marine propulsion ,0103 physical sciences ,Aerospace engineering ,business ,010303 astronomy & astrophysics - Abstract
The National Aeronautics and Space Administration continues to develop and refine various transportation options to successfully field a human Mars campaign. One of these transportation options is the Hybrid Transportation System which utilizes both solar electric propulsion and chemical propulsion. The Hybrid propulsion system utilizes chemical propulsion to perform high thrust maneuvers, where the delta-V is most optimal when ap- plied to save time and to leverage the Oberth effect. It then utilizes solar electric propulsion to augment the chemical burns throughout the interplanetary trajectory. This eliminates the need for the development of two separate vehicles for crew and cargo missions. Previous studies considered single point designs of the architecture, with fixed payload mass and propulsion system performance parameters. As the architecture matures, it is inevitable that the payload mass and the performance of the propulsion system will change. It is desirable to understand how these changes will impact the in-space transportation system's mass and power requirements. This study presents an in-depth sensitivity analysis of the Hybrid crew transportation system to payload mass growth and solar electric propulsion performance. This analysis is used to identify the breakpoints of the current architecture and to inform future architecture and campaign design decisions.
- Published
- 2017
9. Cis-Lunar Reusable In-Space Transportation Architecture for the Evolvable Mars Campaign
- Author
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Eric S. McVay, Christopher A. Jones, and Raymond G. Merrill
- Subjects
Propellant ,020301 aerospace & aeronautics ,Engineering ,Spacecraft propulsion ,business.industry ,Payload ,Liquid rocket propellants ,02 engineering and technology ,Mars Exploration Program ,Propulsion ,Exploration of Mars ,01 natural sciences ,Space exploration ,0203 mechanical engineering ,0103 physical sciences ,Aerospace engineering ,business ,010303 astronomy & astrophysics - Abstract
Human exploration missions to Mars or other destinations in the solar system require large quantities of propellant to enable the transportation of required elements from Earth's sphere of influence to Mars. Current and proposed launch vehicles are incapable of launching all of the requisite mass on a single vehicle; hence, multiple launches and in-space aggregation are required to perform a Mars mission. This study examines the potential of reusable chemical propulsion stages based in cis-lunar space to meet the transportation objectives of the Evolvable Mars Campaign and identifies cis-lunar propellant supply requirements. These stages could be supplied with fuel and oxidizer delivered to cis-lunar space, either launched from Earth or other inner solar system sources such as the Moon or near Earth asteroids. The effects of uncertainty in the model parameters are evaluated through sensitivity analysis of key parameters including the liquid propellant combination, inert mass fraction of the vehicle, change in velocity margin, and change in payload masses. The outcomes of this research include a description of the transportation elements, the architecture that they enable, and an option for a campaign that meets the objectives of the Evolvable Mars Campaign. This provides a more complete understanding of the propellant requirements, as a function of time, that must be delivered to cis-lunar space. Over the selected sensitivity ranges for the current payload and schedule requirements of the 2016 point of departure of the Evolvable Mars Campaign destination systems, the resulting propellant delivery quantities are between 34 and 61 tonnes per year of hydrogen and oxygen propellant, or between 53 and 76 tonnes per year of methane and oxygen propellant, or between 74 and 92 tonnes per year of hypergolic propellant. These estimates can guide future propellant manufacture and/or delivery architectural analysis.
- Published
- 2016
10. Mars Sphere of Influence Maneuvers for NASA’s Evolvable Mars Campaign
- Author
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Patrick Chai, Min Qu, David R. Komar, and Raymond G. Merrill
- Subjects
Sphere of influence (astrodynamics) ,Mars landing ,Mars Exploration Program ,Exploration of Mars ,Geology ,Astrobiology - Published
- 2016
11. Mars Hybrid Propulsion System Trajectory Analysis, Part II: Cargo Missions
- Author
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Patrick Chai, Raymond G. Merrill, and Min Qu
- Published
- 2015
12. Mars Hybrid Propulsion System Trajectory Analysis, Part I: Crew Missions
- Author
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Min Qu, Raymond G. Merrill, and Patrick Chai
- Subjects
Martian ,Engineering ,Spacecraft propulsion ,business.industry ,Payload ,Human spaceflight ,In-space propulsion technologies ,Mars Exploration Program ,Aerospace engineering ,Propulsion ,business ,Exploration of Mars - Abstract
NASAs Human spaceflight Architecture Team team is developing a reusable hybrid transportation architecture in which both chemical and electric propulsion systems are used to send crew and cargo to Mars destinations such as Phobos, Deimos, the surface of Mars, and other orbits around Mars. By combining chemical and electrical propulsion into a single spaceship and applying each where it is more effective, the hybrid architecture enables a series of Mars trajectories that are more fuel-efficient than an all chemical architecture without significant increases in flight times. This paper shows the feasibility of the hybrid transportation architecture to pre-deploy cargo to Mars and Phobos in support of the Evolvable Mars Campaign crew missions. The analysis shows that the hybrid propulsion stage is able to deliver all of the current manifested payload to Phobos and Mars through the first three crew missions. The conjunction class trajectory also allows the hybrid propulsion stage to return to Earth in a timely fashion so it can be reused for additional cargo deployment. The 1,100 days total trip time allows the hybrid propulsion stage to deliver cargo to Mars every other Earth-Mars transit opportunity. For the first two Mars surface mission in the Evolvable Mars Campaign, the short trip time allows the hybrid propulsion stage to be reused for three round-trip journeys to Mars, which matches the hybrid propulsion stage’s designed lifetime for three round-trip crew missions to the Martian sphere of influence.
- Published
- 2015
13. An Integrated Hybrid Transportation Architecture for Human Mars Expeditions
- Author
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Raymond G. Merrill, Patrick Chai, Christopher A. Jones, D.R. Komar, and Min Qu
- Subjects
Engineering ,Electrically powered spacecraft propulsion ,Conceptual design ,business.industry ,Human spaceflight ,In-space propulsion technologies ,ComputerApplications_COMPUTERSINOTHERSYSTEMS ,Mars Exploration Program ,Aerospace engineering ,Propulsion ,Architecture ,business ,Critical path method - Abstract
NASA's Human Spaceflight Architecture Team is developing a reusable hybrid transportation architecture that uses both chemical and electric propulsion systems on the same vehicle to send crew and cargo to Mars destinations such as Phobos, Deimos, the surface of Mars, and other orbits around Mars. By applying chemical and electrical propulsion where each is most effective, the hybrid architecture enables a series of Mars trajectories that are more fuel-efficient than an all chemical architecture without significant increases in flight times. This paper presents an integrated Hybrid in-space transportation architecture for piloted missions and delivery of cargo. A concept for a Mars campaign including orbital and Mars surface missions is described in detail including a system concept of operations and conceptual design. Specific constraints, margin, and pinch points are identified for the architecture and opportunities for critical path commercial and international collaboration are discussed.
- Published
- 2015
14. Viability of a Reusable In-Space Transportation System
- Author
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Brian Nufer, John G. Martin, Sharon A. Jefferies, Roger A. Lepsch, Carey M. McCleskey, David R. Komar, David D. North, and Raymond G. Merrill
- Subjects
Engineering ,Spacecraft ,business.industry ,In-space propulsion technologies ,ComputerApplications_COMPUTERSINOTHERSYSTEMS ,Mars Exploration Program ,Parking orbit ,Reuse ,Concept of operations ,Systems engineering ,Aerospace engineering ,Space Transportation System ,business ,Reusability - Abstract
The National Aeronautics and Space Administration (NASA) is currently developing options for an Evolvable Mars Campaign (EMC) that expands human presence from Low Earth Orbit (LEO) into the solar system and to the surface of Mars. The Hybrid in-space transportation architecture is one option being investigated within the EMC. The architecture enables return of the entire in-space propulsion stage and habitat to cis-lunar space after a round trip to Mars. This concept of operations opens the door for a fully reusable Mars transportation system from cis-lunar space to a Mars parking orbit and back. This paper explores the reuse of in-space transportation systems, with a focus on the propulsion systems. It begins by examining why reusability should be pursued and defines reusability in space-flight context. A range of functions and enablers associated with preparing a system for reuse are identified and a vision for reusability is proposed that can be advanced and implemented as new capabilities are developed. Following this, past reusable spacecraft and servicing capabilities, as well as those currently in development are discussed. Using the Hybrid transportation architecture as an example, an assessment of the degree of reusability that can be incorporated into the architecture with current capabilities is provided and areas for development are identified that will enable greater levels of reuse in the future. Implications and implementation challenges specific to the architecture are also presented.
- Published
- 2015
15. Mars, Phobos, and Deimos Sample Return Enabled by ARRM Alternative Trade Study Spacecraft
- Author
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Matthew A. Vavrina, Jacob A. Englander, Bo J. Naasz, Raymond G. Merrill, and Min Qu
- Subjects
Physics ,Moons of Mars ,Near-Earth object ,Ion thruster ,Spacecraft ,business.industry ,Asteroid ,Mars Exploration Program ,business ,Geocentric orbit ,Spacecraft design ,Astrobiology - Abstract
The Asteroid Robotic Redirect Mission (ARRM) has been the topic of many mission design studies since 2011. The reference ARRM spacecraft uses a powerful solar electric propulsion (SEP) system and a bag device to capture a small asteroid from an Earth-like orbit and redirect it to a distant retrograde orbit (DRO) around the moon. The ARRM Option B spacecraft uses the same propulsion system and multi-Degree of Freedom (DoF) manipulators device to retrieve a very large sample (thousands of kilograms) from a 100+ meter diameter farther-away Near Earth Asteroid (NEA). This study will demonstrate that the ARRM Option B spacecraft design can also be used to return samples from Mars and its moons - either by acquiring a large rock from the surface of Phobos or Deimos, and or by rendezvousing with a sample-return spacecraft launched from the surface of Mars.
- Published
- 2014
16. Asteroid Redirect Robotic Mission: Robotic Boulder Capture Option Overview
- Author
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Kevin Earle, Scott P. Belbin, Raymond G. Merrill, Bo J. Naasz, Paul Abell, David M. Reeves, and Daniel D. Mazanek
- Subjects
Planetary body ,Ion thruster ,business.industry ,Flight management system ,Robotics ,In situ resource utilization ,Geography ,Systems analysis ,Asteroid capture ,Aeronautics ,Asteroid ,Systems engineering ,Artificial intelligence ,business - Abstract
The National Aeronautics and Space Administration (NASA) is currently studying an option for the Asteroid Redirect Robotic Mission (ARRM) that would capture a multi-ton boulder (typically 2-4 meters in size) from the surface of a large (is approximately 100+ meter) Near-Earth Asteroid (NEA) and return it to cislunar space for subsequent human and robotic exploration. This alternative mission approach, designated the Robotic Boulder Capture Option (Option B), has been investigated to determine the mission feasibility and identify potential differences from the initial ARRM concept of capturing an entire small NEA (4-10 meters in size), which has been designated the Small Asteroid Capture Option (Option A). Compared to the initial ARRM concept, Option B allows for centimeter-level characterization over an entire large NEA, the certainty of target NEA composition type, the ability to select the boulder that is captured, numerous opportunities for mission enhancements to support science objectives, additional experience operating at a low-gravity planetary body including extended surface contact, and the ability to demonstrate future planetary defense strategies on a hazardous-size NEA. Option B can leverage precursor missions and existing Agency capabilities to help ensure mission success by targeting wellcharacterized asteroids and can accommodate uncertain programmatic schedules by tailoring the return mass.
- Published
- 2014
17. Interplanetary Trajectory Design for the Asteroid Robotic Redirect Mission Alternate Approach Trade Study
- Author
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Min Qu, Christopher A. Jones, Jacob A. Englander, Matthew A. Vavrina, and Raymond G. Merrill
- Subjects
Physics ,Near-Earth object ,Asteroid capture ,Spacecraft ,Ion thruster ,Asteroid ,business.industry ,Robotics ,Artificial intelligence ,Trajectory optimization ,Aerospace engineering ,business ,Target acquisition - Abstract
This paper presents mission performance analysis methods and results for the Asteroid Robotic Redirect Mission (ARRM) option to capture a free standing boulder on the surface of a 100 m or larger NEA. It details the optimization and design of heliocentric low-thrust trajectories to asteroid targets for the ARRM solar electric propulsion spacecraft. Extensive searches were conducted to determine asteroid targets with large pick-up mass potential and potential observation opportunities. Interplanetary trajectory approximations were developed in method based tools for Itokawa, Bennu, 1999 JU3, and 2008 EV5 and were validated by end-to-end integrated trajectories.
- Published
- 2014
18. Boulder Capture System Design Options for the Asteroid Robotic Redirect Mission Alternate Approach Trade Study
- Author
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Scott P. Belbin and Raymond G. Merrill
- Subjects
Near-Earth object ,business.industry ,Process (computing) ,Robotics ,Escape velocity ,System configuration ,Asteroid capture ,Geography ,Asteroid ,Systems design ,Artificial intelligence ,Aerospace engineering ,business ,Simulation - Abstract
This paper presents a boulder acquisition and asteroid surface interaction electromechanical concept developed for the Asteroid Robotic Redirect Mission (ARRM) option to capture a free standing boulder on the surface of a 100 m or larger Near Earth Asteroid (NEA). It details the down select process and ranking of potential boulder capture methods, the evolution of a simple yet elegant articulating spaceframe, and ongoing risk reduction and concept refinement efforts. The capture system configuration leverages the spaceframe, heritage manipulators, and a new microspine technology to enable the ARRM boulder capture. While at the NEA it enables attenuation of terminal descent velocity, ascent to escape velocity, boulder collection and restraint. After departure from the NEA it enables, robotic inspection, sample caching, and crew Extra Vehicular Activities (EVA).
- Published
- 2014
19. Evaluation of Candidate Procedures for the Preparation of Audit Materials for Analysis of Semivolatile Organic Compounds
- Author
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Raymond G. Merrill, Robert F. Martz, Joan T. Bursey, Curtis M. Morris, James F. McGaughey, and Jack C. Suggs
- Subjects
Complete data ,Assurance qualite ,Waste management ,business.industry ,Hold time ,Health, Toxicology and Mutagenesis ,Operating procedures ,Transferability ,Public Health, Environmental and Occupational Health ,Soil Science ,Audit ,Pollution ,Analytical Chemistry ,Environmental chemistry ,Environmental Chemistry ,Environmental science ,business ,Waste Management and Disposal ,Quality assurance ,Water Science and Technology - Abstract
Audit materials for the SemiVOST method (SW-846 Sampling Method 0010 and Analytical Method 8270) and Standard Operating Procedures for preparation of these audit materials have been developed and are now available from the U.S. Environmental Protection Agency (EPA). The audit materials consist of spiked XAD-2® sorbent. Two procedures were considered: gaseous spiking and liquid spiking. Standard Operating Procedures (SOPs) were prepared based on experience in preparing and analyzing the audit materials. An interlaboratory study involving three laboratories was planned to evaluate the ruggedness and transferability of the standard operating procedures. The initial interlaboratory study was unsuccessful in obtaining a complete data set: however it did demonstrate that a two-week hold time before sorbent extraction did not decrease recoveries of the spiked semivolatile organic compounds. The SOPs were revised after the first interlaboratory study, and a second study involved four laboratories. Three laboratories prepared the audit materials according to the SOPs and all four laboratories analyzed the spiked samples. The complete set of analytical data was statistically evaluated to judge the effectiveness of the SOPs in preparing the audit materials. EPA procedures for preparing audit standards had not been available previously.
- Published
- 1998
20. An initial comparison of selected Earth departure options for solar electric propulsion missions
- Author
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Min Qu, Nathan Strange, Jon Chrone, Raymond G. Merrill, David R. Komar, and Damon Landau
- Subjects
Physics ,Earth's orbit ,Electrically powered spacecraft propulsion ,Ion thruster ,business.industry ,Rendezvous ,In-space propulsion technologies ,Propulsion ,Aerospace engineering ,Interplanetary spaceflight ,business ,Space exploration - Abstract
Earth departure options such as the location for deployment, aggregation, and crew rendezvous as well as the type of propulsion leveraged for each mission phase effect overall mission performance metrics such as number of critical maneuvers, mass of propellant to achieve departure, and initial mass required in low Earth orbit. This paper identifies and compares a subset of tactical options for deployment, crew rendezvous, and Earth departure that leverage electric propulsion and hybrid chemical electric propulsion with a goal of improving system efficiency. Departure maneuver specific limitations and penalties are then identified for missions to specific targets for human interplanetary missions providing a better understanding of the impact of decisions related to aggregation and rendezvous locations as well as Earth departure maneuvers on overall system performance.
- Published
- 2012
21. 300-kW Solar Electric Propulsion System Configuration for Human Exploration of Near-Earth Asteroids
- Author
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John R. Brophy, Thomas W. Kerslake, R. Gershman, Raymond G. Merrill, Damon Landau, and Nathan Strange
- Subjects
Cost reduction ,Propellant ,Engineering ,Near-Earth object ,Ion thruster ,Conceptual design ,business.industry ,Asteroid ,Photovoltaic system ,Electrical engineering ,Aerospace engineering ,business ,Space exploration - Abstract
The use of Solar Electric Propulsion (SEP) can provide significant benefits for the human exploration of near-Earth asteroids. These benefits include substantial cost savings - represented by a significant reduction in the mass required to be lifted to low Earth orbit - and increased mission flexibility. To achieve these benefits, system power levels of 100's of kW are necessary along with the capability to store and process tens of thousands of kilograms of xenon propellant. The paper presents a conceptual design of a 300-kW SEP vehicle, with the capability to store nearly 40,000 kg of xenon, to support human missions to near-Earth asteroids.
- Published
- 2011
22. Characterization of indoor and outdoor air associated with residences using woodstoves: A pilot study
- Author
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Raymond G. Merrill, V. Ross Highsmith, and Roy B. Zweidinger
- Subjects
chemistry.chemical_classification ,lcsh:GE1-350 ,Air exchange ,Vapor phase ,Environmental engineering ,Particulates ,Organic compound ,Additional research ,Dilution ,Sampling system ,chemistry ,Environmental science ,Volatile organic compound ,lcsh:Environmental sciences ,General Environmental Science - Abstract
Particulate, semivolatile organic compound (SVOC), volatile organic compound (VOC), and aldehyde samples were simultaneously collected during two nighttime 12-hour sampling periods at three Raleigh, NC, residences with operating woodstoves during February 1985. Particulate and SVOC samples were also collected from the woodstoves by using the Woodstove Dilution Sampling System. Extensive inorganic and organic analyses were conducted. Mutagenic activity on the particle samples was determined by using the forward mutation assay to 8-azaguanine resistance in Salmonella typhimurium . CO and air exchange rates were measured in each residence. Indoor fine particle mass was significantly lower than the corresponding outdoor fine particle mass in the three homes monitored. Vapor-phase extractable organic mass was approximately six times the corresponding particle-bound extractable organic mass, suggesting the need for additional research in the collection and characterization of indoor air vapor phase organic components. VOC distribution was uniform from outdoors to indoors and did not change with increased outdoor woodstove emissions. Increased napthalene concentrations were observed at one residence identified as having a leaking woodstove. Aldehyde concentrations indoors were higher than the corresponding outdoor samples. The distribution of indoor aldehydes differed from that of outdoor aldehydes which suggest that the building materials, furnishings, and individual homeowner activities impact more significantly on the indoor concentrations than woodsmoke or automotive emissions.
- Published
- 1988
23. Stack sampling for organic emissions
- Author
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Larry D. Johnson and Raymond G. Merrill
- Subjects
Stack (abstract data type) ,Computer science ,business.industry ,Health, Toxicology and Mutagenesis ,Major stationary source ,Environmental Chemistry ,Sampling (statistics) ,Nanotechnology ,Process engineering ,business ,Pollution ,Field (computer science) - Abstract
Along with increased activity in source sampling for organics, there have been many improvements in the methods of acquiring samples. Much has been learned about how best to proceed, and a number of potentially serious pitfalls have been discovered, characterized, and circumvented. Unfortunately, communication of all of this new technology has not always been effective. This paper reviews some of the more important fundamental principles involved in stack sampling for organics, briefly describes and discusses recently developed equipment, and points out a few of the more serious pitfalls to be avoided. Extensive references are provided, many of which are often overlooked by newcomers to the field. The conclusion is reached that it is possible to consistently obtain high‐quality samples of organic materials from stationary source stacks, even though knowledge and caution are necessary.
- Published
- 1983
24. Screening methods for the identification of organic emissions from indoor air pollution sources
- Author
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Leonard H. Nelms, Raymond G. Merrill, Robert F. Martz, and Raymond S. Steiber
- Subjects
Chromatography ,Chemistry ,business.industry ,Exhaust gas ,Sampling (statistics) ,Mass spectrometry ,Pollution ,Indoor air quality ,Gas chromatography ,Gas chromatography–mass spectrometry ,Process engineering ,business ,Air quality index ,Screening procedures - Abstract
Development of on-line gas Chromatographic screening procedures is necessary to permit subsequent evaluation of materials in test chamber studies. This screening uses techniques such as static vapor-phase sampling by ‘headspace’ methods, and a dynamic method similar to the ‘purge-and-trap’ procedures used for determination of volatile organic compounds in water samples. These are methods of sampling that simulate the chamber conditions on a small scale, while allowing emissions to be collected and analyzed. The evaluation is done to select gas Chromatographic columns and develop operating conditions that will permit the rapid and reliable separation of chemical compounds generated during testing. The Chromatographic procedure is used in the qualitative identification of chemical compounds by gas chromatography/mass spectrometry. After identification of the compounds or, alternatively, their chemical classes, representative members are selected as calibration standards for the actual emission testing program. The standards selected are adequate to allow, in most cases, either quantitative or semi-quantitative calculation of the amount of each material present in the chamber exhaust gas. The use of response curves for the chemical classes allows subsequent recalculation of the amounts for each compound.
- Published
- 1987
25. Wood Smoke Impacted Air: Mutagenicity and Chemical Analysis of Ambient Air in a Residential Area of Juneau, Alaska
- Author
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Joellen Lewtas, Randall R Watts, Raymond G. Merrill, Ronald J. Drago, Ron Williams, and Erica Perry
- Subjects
Quality Control ,Air Pollutants ,Atmospheric Science ,Environmental Engineering ,Chemistry ,General Engineering ,Wood smoke ,In Vitro Techniques ,Particulates ,Wood ,Pollution ,Rats ,Ambient air ,Ames test ,Smoke ,Environmental chemistry ,Animals ,General Earth and Planetary Sciences ,Particle ,Particle size ,Energy source ,Air quality index ,Alaska ,Mutagens ,General Environmental Science - Abstract
An ambient air sampling program was conducted in a wood smoke impacted residential area of Juneau, Alaska during the winter of 1985-86. This study was undertaken to determine the bacterial mutagenicity (Ames test) and chemical characteristics of respirable particulate matter collected in this area. Fine particle (0-2.5 {mu}m) concentrations for the sampling period of November 16th to January 7th ranged from 1.19 to 209.8 {mu}g/m{sup 3}. Bioassay samples from ambient air fine particle concentration periods of 25.6 to 209.8 {mu}g/m{sup 3} showed indirect acting mutagenicity of 6.64 to 77.8 rev/m{sup 3} with a mutagenicity/particle concentration correlation coefficient of 0.89. The indirect acting mutagenic potency values ranged from 0.29 to 1.44 rev/{mu}g of extracted organics and averaged 0.73 {plus minus} 0.26. Correlations between fine particle concentration, indirect acting mutagenicity and PAH concentrations were observed for most periods throughout the study. A comparison of ambient air samples collected from wood smoke impacted residential areas in Raleigh, NC; Albuquerque, NM; and Juneau, AK showed that the relationship between ambient air mutagenicity and fine particle concentration was similar for each location.
- Published
- 1988
26. Source Assessment Sampling System (SASS) Versus Dilution Tunnel Sampling
- Author
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Raymond G. Merrill, Joellen Lewtas, and Robert E. Hall
- Subjects
Sampling system ,Environmental engineering ,Environmental science ,Sampling (statistics) ,Inorganic materials ,Sass ,Particulates ,Combustion ,computer ,Dilution ,computer.programming_language - Abstract
Two sampling methods have received increased attention recently because of their ability to collect particulate and organic emissions from combustion sources (Huisingh et al., 1978; Lewtas, in press). One method of sampling, represented by the Source Assessment Sampling System (SASS), is designed to collect and size-classify particulate and to collect nonparticulate organic and inorganic materials at source conditions. The second method, represented by various types of dilution tunnel, is designed to collect total particulate and particulate-bound organic material at conditions which approximate ambient environment.
- Published
- 1983
27. Human missions to phobos and deimos using combined chemical and solar electric propulsion
- Author
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John R. Brophy, Richard R. Hofer, Nathan Strange, Raymond G. Merrill, Damon Landau, and Bret G. Drake
- Subjects
Physics ,Moons of Mars ,Ion thruster ,Astrobiology
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