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2. Calcium trifluoroacetate as an efficient catalyst for ring-opening of epoxides by amines under solvent-free conditions.

Author

Outouch R, Rauchdi M, Boualy B, El Firdoussi L, Roucoux A, and Ali MA

Subjects
Catalysis, Stereoisomerism, Substrate Specificity, Amines chemistry, Calcium chemistry, Epoxy Compounds chemistry, Trifluoroacetic Acid chemistry
Abstract

Ca(CF3CO2)2 efficiently catalyzed the selective ring-opening of epoxides by amines leading to the synthesis of β-aminoalcohols. The reaction works well with various aromatic and aliphatic amines under solvent-free conditions. Corresponding β-aminoalcohols were obtained in excellent yields with high regioselectivity. The catalyst was easily prepared by reaction of CaH2 in trifluoroacetic acid.

Published
2014

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