1. Secondary Grain Boundary Dislocations Alter Segregation Energy Spectra
- Author
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Chen, Xinren, Gonçalves, William, Hu, Yi, Gao, Yipeng, Harrison, Patrick, Das, Saurabh Mohan, Dehm, Gerhard, Gault, Baptiste, Ludwig, Wolfgang, Rauch, Edgar, Zhou, Xuyang, and Raabe, Dierk
- Subjects
Condensed Matter - Materials Science - Abstract
Grain boundaries (GBs) trigger structure-specific chemical segregation of solute atoms. According to the three-dimensional (3D) topology of grains, GBs - although defined as planar defects - cannot be free of curvature. This implies formation of topologically-necessary arrays of secondary GB dislocations. We report here that these pattern-forming secondary GB dislocations can have an additional and, in some cases, even a much stronger effect on GB segregation than defect-free GBs. Using nanoscale correlative tomography combining crystallography and chemical analysis, we quantified the relationship between secondary GB dislocations and their segregation energy spectra for a model Fe-W alloy. This discovery unlocks new design opportunities for advanced materials, leveraging the additional degrees of freedom provided by topologically-necessary secondary GB dislocations to modulate segregation.
- Published
- 2024