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We study the morphological distribution of galaxies in some nearby clusters, using the Sloan Digital Sky Survey – Data Release 9 (SDSS-DR9). The segregation between early-type galaxies and late-type ones is investigated in g – r / u – g color space, using the color cut u – r = 2.22. The results are compared with those obtained using a color cut that changes with magnitude. They are found to be consistent, particularly for late-type galaxies. The results obtained by the fixed color-cut criterion are also found to be consistent with those obtained by the inverse concentration index parameter, especially for early-type galaxies. Comparable results are obtained for the stacked sample, whose morphologies, given by the fixed color-cut criterion are compared with the visual morphologies provided by the Galaxy Zoo project. A good degree of consistency is seen, which becomes more evident for late-type galaxies.

Proton-conducting solid polymer blend electrolytes based on methylcellulose-polyvinyl alcohol:ammonium nitrate (MC-PVA:NH4NO3) were prepared by the solution cast technique. The structural and electrical properties of the samples were examined by X-ray diffraction (XRD), Fourier transform infrared (FTIR), and electrical impedance (EI) spectroscopy. The shifting and change in the intensity of FTIR bands of the electrolyte samples confirm the complex formation between the MC-PVA polymer blend and the NH4NO3 added salt. The observed broadening in the XRD pattern of the doped samples reveals the increase of the amorphous fraction of polymer electrolyte samples. The increase in electrical conductivity of polymer electrolyte samples with increasing salt concentration attributed to the formation of charge-transfer complexes, and to increase in the amorphous domains. A maximum ionic conductivity of about 7.39 × 10−5 S cm−1 was achieved at room temperature for the sample incorporating 20 wt% of NH4NO3. The DC conductivity of the present polymer system exhibits Arrhenius-type dependence with temperature. The decrease in the values of activation energies with increasing salt concentration indicates the ease mobility of ions. The decrease in dielectric constant with increasing frequency was observed at all temperatures. Optical properties such as absorption edge, optical band gap, and tail of localized state were estimated for polymer blend and their electrolyte films. It was found that the optical band gap values shifted towards lower photon energy from 6.06 to 4.75 eV by altering the NH4NO3 salt content. [ABSTRACT FROM AUTHOR]

In this paper, the sample preparation of polymer nanocomposites based on methyl cellulose (MC) with small optical bandgaps has been discussed. Copper monosulfide (CuS) nanoparticles have been synthesized from the sodium sulphide (Na2S) and copper chloride (CuCl2) salts. Distinguishable localized surface resonance plasmon (LSRP) absorption peaks for CuS nanoparticles within the 680–1090 nm scanned wavelength range were observed for the samples. An absorption edge (Ed) was found to be widely shifted to a lower photon energy region. A linear relationship between the refractive index of the samples and the CuS fraction was utilized to describe the distribution of the particle. The optical bandgap of MC was reduced from 6.2 to 2.3 eV upon the incorporation of 0.08 M of CuS nanoparticles. The optical dielectric loss, as an alternative method, was used successfully to estimate the optical bandgap. Moreover, the electronic transition type was identified by using Tauc’s extrapolation method. The plots of the optical dielectric constant and energy bandgap as a function of the CuS concentration were utilized to examine the validity of the Penn model. For the nanocomposite samples, the Urbach energy was found to be increased, which can be evidence for a large possible number of bands-to-tail and tail-to-tail transitions. However, from the X-ray diffraction (XRD) analysis, it was also found that the synthesized CuS nanoparticles disrupted the crystallinity phase of the MC polymer. Finally, fourier transform infrared (FTIR) spectroscopy for the samples was also performed. Significant decreases of transmittance intensity as well as band shifting in the FTIR spectra were observed for the doped samples. [ABSTRACT FROM AUTHOR]

The polymer composite films of Poly(methyl methacrylate) (PMMA) doped with different wt% of Silicon powder (Si) were prepared using solution casting technique, to investigate the effect of Si content on the optical characterization of PMMA matrix. It is found that the fundamental optical absorption edge of PMMA is shifting toward lower energy with the increase of the Si content, resulting the decreases in the optical band gap of PMMA monotonously. The optical constants of PMMA:Si composite, such as the optical absorption coefficient, refractive index, extinction coefficient and complex dielectric constant, are greater than those of pure PMMA. The energy dispersion parameters of PMMA:Si composite versus Si wt% have been determined and explained using Wemple-DiDomenico single oscillator model. The linear relationship between the static refractive index and Si volume fraction reveal the well-dispersed Si powder in the PMMA host polymer matrix. The SEM micrographs also revealed the uniform dispersion of Si powder in PMMA matrix. The observed improve in the optical properties of PMMA:Si films denote that this composite could be used in UV-blocking contact lenses and optoelectronic devices. [ABSTRACT FROM AUTHOR]

In this paper composite materials, based on polymer blends of polyvinyl alcohol (PVA): polyvinyl pyrrolidone (PVP) with small optical band gap, has been studied. Silver sulfide (Ag 2 S) semiconductor particles have been synthesized in PVA:PVP blend host polymer, using in situ method. X-ray diffraction (XRD) analyses and Fourier transform infrared (FTIR) spectroscopy for the composite samples were carried out. From the XRD pattern, distinguishable crystalline peaks caused by the Ag 2 S semiconductor particles were observed. From the result of FTIR spectroscopy, the intensity of the FTIR bands were shifted and increased, revealing the occurrence of interactions between the PVA:PVP blend system and Ag 2 S particles. The composite samples were found to exhibit absorption spectra that cover UV–visible to near infrared regions. The absorption edge was found to be 5 eV for pure PVA:PVP system and shifted to 1.15 eV for incorporated PVA:PVP with 3 M of Ag 2 S. The refractive index was also evaluated for the samples and observed to be increased from 1.15 to 1.52 as doping increased to the highest. A linear relationship between the refractive index and the filler fraction has been reported. Theoretical discussion of optical dielectric loss, which is a crucial parameter for the band gap estimation, was given. The achieved results reveal that spectra of the optical dielectric loss (ɛ i ) can be used to study the band gap structure and Tauc's model can be important in determining the types of electronic transition. The optical band gap was found to decrease from 5.2 eV for the pure PVA:PVP to 1.1 eV for doped PVA:PVP with 3 M of Ag 2 S. Such reduction can be associated with the increase of optical dielectric constant. Finally, the correlation between optical dielectric constant and density of states was discussed. [ABSTRACT FROM AUTHOR]

In this paper, the sample preparation of polymer nanocomposites based on methyl cellulose (MC) with small optical bandgaps has been discussed. Copper monosulfide (CuS) nanoparticles have been synthesized from the sodium sulphide (Na₂S) and copper chloride (CuCl₂) salts. Distinguishable localized surface resonance plasmon (LSRP) absorption peaks for CuS nanoparticles within the 680⁻1090 nm scanned wavelength range were observed for the samples. An absorption edge ( E d ) was found to be widely shifted to a lower photon energy region. A linear relationship between the refractive index of the samples and the CuS fraction was utilized to describe the distribution of the particle. The optical bandgap of MC was reduced from 6.2 to 2.3 eV upon the incorporation of 0.08 M of CuS nanoparticles. The optical dielectric loss, as an alternative method, was used successfully to estimate the optical bandgap. Moreover, the electronic transition type was identified by using Tauc's extrapolation method. The plots of the optical dielectric constant and energy bandgap as a function of the CuS concentration were utilized to examine the validity of the Penn model. For the nanocomposite samples, the Urbach energy was found to be increased, which can be evidence for a large possible number of bands-to-tail and tail-to-tail transitions. However, from the X-ray diffraction (XRD) analysis, it was also found that the synthesized CuS nanoparticles disrupted the crystallinity phase of the MC polymer. Finally, fourier transform infrared (FTIR) spectroscopy for the samples was also performed. Significant decreases of transmittance intensity as well as band shifting in the FTIR spectra were observed for the doped samples., Competing Interests: The authors declare no conflict of interest