Search

Dust is a key component of the geological and climatic systems of Earth and Mars. On Mars, dust is ubiquitous. It coats rocks and soils, and, in the atmosphere, it interacts strongly with solar and thermal radiation. Yet, key questions remain about the genesis and fate of martian dust, as well as its sources, composition, and properties. We collected wind-blown dust from basaltic plains in SW Iceland at Skjaldbreiðauhraun that represent a geologic Mars-analog environment. Icelandic dust differs from the typical continental sources (e.g. Sahara, Asia) because of its basaltic volcanogenic origin, which is similar to Mars. Dust collection took place in July of 2019 as a complementary project to the SAND-E: Semi-Autonomous Navigation for Detrital Environments project. Here we report preliminary analyses of this Mars-analog dust material, with the goal of understanding the processes that control the physico-chemical proper-ties of the different grain-size fractions.

Sediments and sedimentary rocks preserve a rich history of environment and climate. Identifying these signals requires an understanding of the physical and chemical processes that have affected sedimentary deposits [1]. Such processes include sorting and rounding during transport and chemical alteration through weathering and diagenesis. Although these processes have long been studied in quartz-dominated sedimentary systems [2], a lack of studies of basaltic sedimentary systems limits our interpretations of the environment and climate where mafic source rocks dominate, such as on Mars [3,4]. As part of the SAND-E: Semi-Autonomous Navigation for Detrital Environments project [5], which uses robotic operations to examine physical and chemical changes to sediments in basaltic glacio-fluvialaeolian environments, this research studies changes in sorting and rounding of fluvial-aeolian sediments along a glacier-proximal-to-glacier-distal transect in the outwash-plain of the Ϸόrisjökull glacier in SW Iceland (Fig. 1)

NASA’s Mars Science Laboratory Curiosity rover has been exploring Vera Rubin ridge (VRR), part of the Murray formation in Gale crater, Mars, between sol 1809 and 2302. Evidence for Fe-oxides and phyllosilicates in mineralogical and geochemical data for this region was returned by Curiosity [1-5]. We applied thermochemical modeling to con-strain the formation conditions of the phyllosilicate-hematite assemblage identified on and below VRR. Average alteration compositions for the Murray formation on and below VRR were derived using CheMin and APXS data. These compositions were reacted with Gale Portage Water (GPW) between 25–100 °C and for 10% and 50% Fe3+/Fetot of the host rock [6]. Here we summarize models run at 50 °C and 10% Fe3+/Fetot for alteration compositions derived from Murray host rock compositions.

Siderite (FeCO3) has been detected in Gale Crater for the first time by the Mars Science Laboratory (MSL) Curiosity and is seen in multiple samples in the Glen Torridon (GT) region. The identification of siderite is based on evolved gas analysis (EGA) data from the Sample Analysis at Mars (SAM) instrument and X-ray diffraction (XRD) data from the Chemistry and Mineralogy (CheMin) instrument. Curiosity descended off of the Vera Rubin ridge (VRR) into the Glen Torridon region on Sol 2300. Glen Torridon is of particular interest because a strong clay mineral signature had been detected by orbital instruments [1]. To date, four drilled samples have been collected at two different drill locations: Kilmarie and Aberlady from adjacent blocks at the base of the south side of VRR in the Jura member and Glen Etive 1 and 2 on the same block in the Knockfarril member.

The martian surface has a primarily basaltic composition and is dominated by sedimentary deposits. Ancient layered sedimentary rocks have been identified across the planet from orbit, have been studied in situ by the Mars Exploration Rovers and the Mars Science Laboratory rover, and will be studied by the Mars 2020 rover. These ancient sedimentary rocks were deposited in fluvial, lacustrine, and eolian environments during a warmer and wetter era on Mars. It is important to study the composition of sediments in Mars analog environments to characterize how minerals in basaltic sedimentary systems are sorted and/or aqueously altered. This information can help us better interpret sedimentary processes from similar deposits on Mars and derive information about the igneous source rocks. Sediment sorting has been studied extensively on Earth, but not typically in basaltic environments. Previous work has addressed sorting of basaltic sediments through experimental techniques and in modern eolian basaltic systems and aqueous alteration in subglacial and proglacial environments. We add to this body of research by studying sediment sorting and aqueous alteration in a glacio-fluvio-eolian basaltic system in southwest Iceland.

ChemCam is an active remote sensing instrument suite that has operated successfully on MSL since landing Aug. 6th, 2012. It uses laser pulses to remove dust and to analyze rocks up to 7 m away. Laser-induced breakdown spectroscopy (LIBS) obtains emission spectra of materials ablated from the samples in electronically excited states. The intensities of the emission lines scale with the abundances of the related element. ChemCam is sensitive to most major rock-forming elements as well as to a set of minor and trace elements such as F, Cl, Li, P, Sr, Ba, and Rb. The measured chemical composition can then be used to infer the mineralogical composition of the ablated material. Here, we report a summary of inferred apatite detections along the MSL traverse at Gale Crater. We present the geologic settings of these findings and derive some interpretations about the formation conditions of apatite in time and space.

Liquid water was abundant on early Mars, but whether the climate was warm and wet or cold and icy with punctuated periods of melting is still poorly understood. Modern climate models for Mars tend to predict a colder, icier early climate than previously imagined. In addition, ice and glaciation have been major geologic agents throughout the later Hesperian and Amazonian eras. One process that can act in such climates is repeated freezing and thawing of water on the surface and in the subsurface, and is significant because it can occur anywhere with an active layer and could have persisted for a time after liquid water was no longer stable on Mars’ surface. As freeze-thaw is the dominant mechanical weathering process in most glacial/periglacial terrains, it was likely a significant geomorphologic driver at local to regional scales during past climates, and would potentially have been most active when day-average surface temperatures exceeded 0 °C for part of the year. Indeed, freeze-thaw involving liquid water in the Amazonian is evidenced by abundant geomorphic features including polygonal ground and solifluction lobes requiring seasonal thawing. In addition to physical modification, freezing can drive solutions towards supersaturation and force dissolved solutes out as precipitates. In Mars-like terrains, dissolved solutes are typically dominated by silica. In polar regions on Earth, freeze-thaw cycles have been shown to promote deposition of silica, and freeze-thaw experiments on synthetic solutions found stable amorphous silica that built up over multiple cycles. Freeze-thaw may therefore be an important but overlooked chemical weathering process on Mars. However, our ability to assess its impact on alteration of martian terrains is majorly limited by the current lack of understanding of the alteration phases produced (and formation rates) under controlled freeze-thaw weathering of Mars-relevant materials. To address this knowledge gap, we report results from (1) freeze-thaw weathering products found at a glacial Mars analog site at the Three Sisters, Oregon, and (2) new controlled freeze-thaw experiments on basaltic material.

The Mars Science Laboratory (MSL) Curiosity rover explored Vera Rubin ridge (VRR) in Gale crater, Mars, for almost 500 sols (Mars days) between arriving at the ridge on sol 1809 of the mission in September 2017 and leaving it on sol 2302 upon entering the Glen Torridon area south of the ridge. VRR is a topographic ridge on the central mound, Aeolis Mons (Mt. Sharp), in Gale crater that displays a strong hematite spectral signature from orbit. In-situ observations on the ridge led to the recognition that the ridge-forming rocks belong to the Murray formation, the lowermost exposed stratigraphic unit of the Mt. Sharp group, that was first encountered at the Pahrump Hills location. Including VRR rocks, the Murray formation, interpreted to be primarily deposited in an ancient lacustrine environment in Gale crater, is more than 300 m thick. VRR itself is composed of two stratigraphic members within the Murray formation, the Pettegrove Point member overlain by the Jura member. The Pettegrove Point member overlies the Blunts Point member of the Murray formation. Areas of gray coloration are observed in the Jura member predominantly, but also in the Pettegrove Point member. Generally, gray areas are found in local topographic depressions, but contacts between red and gray rocks crosscut stratigraphy. Additionally, cm-scale dark concretions with very high iron-content are commonly observed in gray rocks, typically surrounded by a lighttoned zone that is conversely depleted in iron. A key goal for the VRR campaign was to characterize geochemical variations in the ridge-forming rocks to investigate the role of primary and diagenetic controls on the geochemistry and morphology of VRR. Here, we present observations by the ChemCam instrument on VRR and compare these to the full Murray formation chemostratigraphy. This work was recently submitted to a special issue of JGRPlanets that detail the full VRR campaign.

Iceland’s basaltic volcanic rocks and glacial, fluvial, and aeolian landscapes resemble those studied on Mars, which makes it an ideal location to study the evolution of basaltic landscapes, the weathering and alteration of basaltic sediments in cold and wet environments, and the generation of a basaltic sedimentary record. The SAND-E: Semi-Autonomous Navigation for Detrital Environments project examines physical and chemical changes in sediments transported through basaltic fluvial and aeolian environments, and tests operational scenarios, which include a drone and a robotic rover instrumented with autonomous terrain analysis software. As part of the SAND-E project, we examined a glacial outwash plain at Skjaldbreiðauhraun, in SW Iceland. This study uses micro X-ray fluorescence (μXRF) to examine the chemical and physical properties of unconsolidated sediment-size fractions from 710 μm to < 63 μm along a downstream transect from a glacial sourced watershed. μXRF is ideally suited for this task because it maps elemental distributions at sub-grain scales thereby allowing a direct correlation between grainsize, grain shape, and chemistry. It is also a good analog technique for the Mars 2020 mission equipped with the PIXL (Planetary Instrument for X-ray Lithochemistry) that will be deployed at Jezero Crater, Mars.

Unmanned aerial systems (UAS) and automated terrain analysis for science and navigation are new technologies for planetary exploration. The Mars Helicopter will fly with the Mars2020 rover, the Dragonfly quadcopter will explore Titan, and Soil Properties and Object Classification (SPOC) software will be used for path planning and navigation on the Mars2020 rover. Using an Argo J5 rover instrumented with stereo cameras and Autonomous Soil Assessment System (ASAS) software, and an off the shelf quadcopter, SAND-E tested the use of automated terrain analysis and UAS data for science operations in a Mars-analog environment in Iceland during July of 2019. Scientifically, we sought to determine changes in the physical and chemical properties of sediments along a glacial-fluvial-aeolian transport pathway. Operationally, we tested rover mission-like scenarios that included UAS images and classified terrain images. Here, we present the initial results for both the operations and science elements of the study. Site Selection: A goal of SAND-E is examine sorting and alteration of sediments in fluvial and aeolian environments in both mineral-dominated and glass-dominated basaltic settings. During the first year of the project we focused on a mineral-dominated environment. Selection of the location was based on prior publications that indicated our selected region had a greater abundance of crystalline sediments than other areas fluvial-aeolian settings in Iceland. Other criteria included the presence of both fluvial and aeolian landforms along a transport pathway such that the sediments in transport could be linked to their source rocks. We chose the Skjaldbreidauhraun glacial outwash plain, which sits at the base of Thórisjökull glacier. The site is 30 km north of Thingvellir National Park and ~2 hours from Reykjavik. The outwash plain is fed by two small catchments that drain from the base of the glacier and cut through hyaloclastite and shield volcano bedrock. The drainage progresses from steep alluvial fans near the glacier into a low-sloping fluvial braidplain that becomes confined by the Skjaldbreidur shield volcano and creates a shallow canyon cut into lava bedrock. The fluvial system was a typical braided alluvial environment composed pebble- and cobble-bedded longitudinal bars and sandy channel beds. The river remained active and fluctuated in response to diurnal runoff cycles near the glacier before disappearing into the sandy substrate downstream. The high concentration of suspended sediment in the river was evident by the cloudy water and the silt and clay-sized sediments that draped the channel beds after abandonment and created playas in the lowest sloping areas of the catchment. The entire fluvial system was affected by the winds generated by frontal systems and katabatic flows descending the glacier. This resulted in the formation of aeolian lag deposits and a wind-deflation plain where the fluvial system was not active. Wind ripples and drifts formed in abandoned fluvial channels from aeolian reworking of the sand-sized fluvial sediments. The silt- and clay-sized sediments found in fluvial channels, bar tops, and playas generated dust plumes during high wind events. Our operation sought to capture the variability in this system by sampling from the range of fluvial and aeolian features 6.3 km (proximal), 11.3 km (medial), and 14.4 km (distal) along the river from its origin at the base of glacier.

The Mars Science Laboratory (MSL) rover, Curiosity, has been traversing across fluvial, lacustrine, and eolian sedimentary rocks since it touched down in 2012. The CheMin X-ray diffractometer (XRD) on board Curiosity has revealed smectite clay minerals in most fluvio-lacustrine samples and abundant X-ray amorphous materials in all samples analyzed to date. For example, mudstones from the Sheepbed member at the base of the stratigraphic section and the lower part of the Murray formation contain on average ~7 to 20 wt% smectite and ~30 to 46 wt% X-ray amorphous abundances. On Earth, smectite and secondary X-ray amorphous materials are juvenile weathering products that are generated in sedimentary environments and ultimately record the interaction between primary igneous minerals and the hydrosphere, atmosphere, and biosphere. For this study, we investigated glacio-fluvio-eolian sediments generated in basaltic terrains as terrestrial analogs for the mudstones from Gale Crater, Mars. This work focuses on the clay sized sediments (<2 μm) from these deposits as this grain size hosts the most mineralogically and geochemically altered detritus in sedimentary environments. The goal of investigating basaltic sedimentation is to create a terrestrial reference frame that sheds light on the paleoclimate and paleoaqueous conditions responsible for shaping the ancient sedimentary environments of Mars (e.g., Gale Crater and Jezero Crater).

Gale crater was selected as the landing site for the Mars Science Laboratory Curiosity rover because of orbital evidence for a variety of secondary minerals in the lower slopes of Aeolis Mons (aka Mount Sharp) that indicate changes in aqueous conditions over time. Distinct units demonstrate orbital spectral signatures of hematite, phyllosilicate (smectite), and sulfate minerals, which suggest that ancient aqueous environments in Gale crater varied in oxidation potential, pH, and water activity. Vera Rubin ridge (VRR) is the first of these units identified from orbit to have been studied by Curiosity. Orbital near-infrared data from VRR show a strong band at 860 nm indicative of hematite. Before Curiosity arrived at VRR, the hypotheses to explain the formation of hematite included (1) precipitation at a redox interface where aqueous Fe2+ was oxidized to Fe3+, and (2) acidic alteration of olivine in oxic fluids. Studying the composition and sedimentology of the rocks on VRR allow us to test and refine these hypotheses and flesh out the depositional and diagenetic history of the ridge. Here, we focus on the mineralogical results of four rock powders drilled from and immediately below VRR as determined by CheMin.

Analyses of X-ray diffraction (XRD) patterns taken by the CheMin instrument on the Curiosity Rover in Gale crater have documented the presence of clay minerals interpreted as smectites and a suite of amorphous to short-range order materials termed X-ray amorphous materials. These X-ray amorphous materials are commonly ironrich and aluminum poor and likely some of them are weathering products rather than primary glasses due to the presence of volatiles. Outstanding questions remain regarding the chemical composition and mineral structure of these X-ray amorphous materials and the smectites present at Gale crater and what they indicate about environmental conditions during their formation. To gain a better understanding of the mineral transitions that occur within ferromagnesian parent materials, we have investigated the development of secondary clay minerals and shortrange order materials in two soil chronosequences with varying climates developing on ultramafic bedrock. Field Sites: We investigated soil weathering within two field locations, the Klamath Mountains of Northern California, and the Tablelands of Newfoundland, Canada. Both sites possess age dated or correlated recently deglaciated soils and undated but substantially older soils. In the Klamath mountains the Trinity Ultramafic Body was deglaciated roughly 15,000 years bp while in the Tablelands a moraine was dated to about 17,600 years bp. The Klamath Mountains feature a seasonally wet and dry climate while the Tablelands are wet year-round with saturated soil conditions observed during sampling and standing water observed within 3 of 4 soil pit sampling locations.

The data from the MErcury Surface, Space ENvironment, GEochemistry, and Ranging (MESSENGER) spacecraft have revealed several surprising characteristics about the surface of Mercury, leading to its classification as a geochemical endmember among the terrestrial planets. Some of these features include elevated abundances of up to 3 wt% S, C enrichment as high as 4 wt% over the local mean in low reflectance materials (LRM), Na up to 5 wt% at high northern latitudes, and Fe abundances typically lower than 2 wt% [e.g., 1–4]. The S and Fe concentrations have been used to infer that Mercury’s igneous history evolved under highly reduced oxygen fugacity conditions between 2.6 and 7.3 log10 units below the iron-wüstite buffer [e.g., 5], which is more reducing than any other terrestrial planet in the solar system [e.g., 6]. This highly reduced nature has important consequences for the differentiation and thermal/magmatic evolution of Mercury. While the immense amount of data collected by MESSENGER revealed Mercury as a geochemical endmember, this new knowledge gained raised additional questions that necessitate continued exploration of the planet. Fortunately, BepiColombo launched in October of 2018, and this joint ESA/JAXA dual-orbiter spacecraft is the most ambitious effort yet attempted to explore Mercury [e.g., 7]. Looking beyond BepiColombo, there are major aspects of Mercury’s geochemical character and evolution for which significant knowledge gaps can be dramatically improved with data acquired from the planet’s surface via in situ landed science.

One objective of rover missions is exploring the geological context of the surroundings. Over the years, igneous petrology and sedimentology have been disconnected, the first investigating magmatic processes and volcanic activities, and the second seeking environmental conditions in the past and assessing the habitability of the planet. Although different, one is related to the other: igneous rocks are altered and broken down, leading to the formation of sedimentary rocks, which can in turn be used to back out the nature of their magmatic source. The Curiosity rover that landed in the 3.7 Gyr old impact crater Gale is traveling through sedimentary rocks. About fifty float rocks have been observed, and several of them with ambiguous texture and composition have been classified as igneous or sedimentary depending on studies such as Jake_M. The composition of several unambiguous igneous rocks has been analyzed [4- 6] but their heterogeneity at a larger instrumental (measurement size < 2 cm) scale prevents the measurement of a bulk composition as performed on Earth. An original approach avoiding these two last issues is to consider igneous mineral chemistry analyzed within igneous and sedimentary rocks to assess magmatic processes that could have formed them. Most Curiosity data are used to explore ancient environmental conditions, and a significant number of compositional analyses are under-explored for constraining magmatic activities. We will present how we can make use of sedimentary data for investigating igneous processes in the vicinity of Gale crater. Geological Context: We focus on the first 750 martian days, corresponding to measurements in a coherent lacustrine sedimentary unit called Bradbury, because all sedimentary rocks were sourced from the same watershed and appear to have a consistent source with minimal alteration [2-3]. Igneous detrital minerals including feldspar and pyroxene, are observed in sedimentary rocks. Monte Carlo models showed that minimal cation loss is observed based on the composition of all Bradbury rocks, implying negligible weathering [3]. Although clay minerals are detected in few rocks [7], chemical compositions of rocks can be explained by a mixture of primary igneous minerals [3]. Variation of composition within Bradbury rocks can be explained by mineral sorting and one distinct source component. While a common magmatic source is suggested, Bradbury sediments likely come from several volcanic eruptions from a single magmatic chamber [9- 10]. The occurrence of alkali minerals like sanidine and K-rich rocks throughout Bradbury supports the presence of a potassic component, likely trachytic, while plagioclase and a mafic composition suggest a basaltic component [8-9]. Instruments: Mineral chemistry can be estimated by three instruments onboard Curiosity. The CheMin instrument enables detection of mineral assemblages using X-ray diffraction (XRD). Using Rietveld refinement, each mineral is identified according to their 1D XRD pattern [11]. Note that distinction between pyroxene minerals is challenging with the CheMin instrument due to overlapping peaks on XRD patterns and low angular resolution of the instrument [12]. Then, using least square regression and optimization algorithms based on unit-cell parameters, mineral chemistry has been estimated by [11]. Plagioclase composition has been estimated using the NaAlSi3O8- CaAl2Si2O8 system and alkali feldspar is based on the NaAlSi3O8-KAlSi3O8 system (stars in Fig.1). Two mudstone samples (John Klein and Cumberland) and one sandstone sample (Windjana) were analyzed by CheMin at Yellowknife Bay and Kimberley, respectively. Figure 1. Ternary diagrams of feldspars (top) and pyroxene (bottom) quadrilateral. Stars correspond to CheMin composition and the gray patches to ChemCam composition. The colored dots are the composition of feldspar and pyroxene that crystallized during fractional crystallization at FMQ+1 of a melt extracted at distinct melting degree during the adiabatic ascent of a primitive mantle composition, without any water (left panels) and with 0.5 wt.% of water (right panels) at distinct pressure. The ChemCam instrument enables the analysis of the chemical compositions of rocks at hundreds of micrometer scale (350-550 μm) using laser induced breakdown spectroscopy (LIBS), which may provide the composition of minerals when they are larger than the beam spot (>550 μm) [13]. Within >5000 LIBS points, we performed a typical stoichiometric filtering allowing us to distinguish 56 feldspar and 10 pyroxene mineral compositions (grey patches in Fig. 1). Finally, the Alpha Particle X-ray Spectrometer (APXS) analyzes the composition of rocks with a 1.6 cm diameter spot size. Monte Carlo mass balance modeling allowed [3] to decipher a feldspar range varying between An30 and An40 (Fig. 1). Discussion: Although there could be a more complex history and other ways to form the whole compositional range of igneous minerals analyzed within the Bradbury formation, we are presenting here simple magmatic pathways commonly occurring on Earth using the thermodynamical softwares pMELTS and rhyoliteMELTS [14]. The objective is to find reasonable igneous processes that produce minerals that parallel the compositions of feldspar and pyroxene analyzed by the Curiosity rover. As commonly observed for mid-ocean ridge basalts, the adiabatic ascent of a primitive mantle composition [15] partially melting at 2 GPa has been modeled, followed by the extraction of a liquid at distinct degrees of partial melting, which undergoes fractional crystallization at an oxygen fugacity +1 log unit above the fayalite-magnetite-quartz (FMQ) buffer within the crust (0.02-0.4 GPa) with H2O = 0- 0.5 wt. %. These latter conditions correspond to those recorded within igneous clasts from the Noachian martian breccia NWA 7034 and paired and within Gale igneous rocks (colored dots in Fig. 1) [16-17]. To check the reliability of these 2-step models, we also tested fractional crystallization at similar conditions (FMQ+1; P=0.02-0.4 GPa; H2O = 0-0.5 wt. %) of starting compositions corresponding to that of magmas with distinct melting degrees obtained from isobaric experiments at 2 GPa [18]. Mineral compositions obtained from both models are similar. As shown on Fig. 1, the whole range of observed feldspar compositions cannot be reproduced by fractionation of one magma only. Indeed, while alkali feldspar and Na-plagioclase likely crystallized from fractional crystallization of a low-degree melt (here <15%), plagioclase and pyroxene can only be formed by fractional crystallization of a higher degree melt (here >19%). The corresponding liquid descent lines are broadly in agreement with compositions estimated by ChemCam corresponding to float igneous rocks (Fig. 2) [4-6]. Figure 2. Silica versus alkali content. Lines show the liquid lines of descent from magmas with distinct degrees of melting. Gray patches represents the composition of Gale igneous rocks [4-6]. Trachytic to rhyolitic magmas crystallize alkali feldspar, and andesite to dacite magmas likely form plagioclase. Therefore, at least two starting magmas at distinct melting degrees, which could easily come from a single mantle source, are necessary to explain the whole compositional range of feldspar and pyroxene analyzed within Bradbury rocks. Conclusion: Because rocks from the Bradbury formation are likely originating from the same magmatic source with minimal weathering as supported by several studies using different approaches, igneous mineral chemistry analyzed by CheMin and ChemCam allows us to back out reasonable magmatic pathways that could have crystallized them. Fractional crystallization of at least two starting magmas originating from distinct melting degrees of a single mantle source can explain the whole range of feldspar and pyroxene composition. Both alkaline and sub-alkaline liquids can be produced, with compositions corresponding to those of the igneous rocks analyzed by ChemCam within the Bradbury formation, highlighting the complexity of Mars magmatism.

One of the most exciting endeavors in modern space exploration is extended human exploration of the Moon and Mars. We have entered a new phase in the human venture where we seek to expand our "...presence deeper into space and to the Moon for sustainable long-term exploration and utilization". With this endeavor come new challenges. Among them is the requirement for In Situ Resource Utilization (ISRU) methods to supplement or replace materials transported from Earth. The energy required to leave Earth's gravity well is immense, as is well illustrated by the nearly 3000 metric ton Saturn V required to deliver a payload of less than 50 metric tons to the Moon during the Apollo era. Much of this mass is propellant. Launch vehicles from Earth into space are generally 85 to 95% propellant (oxidizer + fuel) by mass. Potential ascent vehicles from Mars would also need to be approximately 80% propellant by mass to return to Earth. ISRU of fuel reactants could exchange delivered fuel mass directly for payload mass on the order of several metric tons. Devices like MOXIE are being designed to address the oxidizer component. However, 40% of the propellant mass in an ascent vehicle is the fuel reactant, and ISRU of this component has not been addressed for Mars or the Moon. Toward addressing this need, we have begun to develop and optimize methods to generate and recover fuel components, including H2, from Lunar and Martian relevant materials as potential in situ resources for future extended human missions. Hydrogen is an ideal resource to target. Not only can H2 be used directly as part of a propellant, it can also be used as a component in other fuels, such as methane. It is useful agriculturally for fixing nitrogen and can be oxidized to produce heat and water.

Mariner 10 provided our first closeup reconnaissance of Mercury during its three flybys in 1974 and 1975. MESSENGER’s 2011–2015 orbital investigation enabled numerous discoveries, several of which led to substantial or complete changes in our fundamental understanding of the planet. Among these were the unanticipated, widespread presence of volatile elements (e.g., Na, K, S); a surface with extremely low Fe abundance whose darkening agent is likely C; a previously unknown landform—hollows— that may form by volatile sublimation from within rocks exposed to the harsh conditions on the surface; a history of expansive effusive and explosive volcanism; substantial radial contraction of the planet from interior cooling; offset of the dipole moment of the internal magnetic field northward from the geographic equator by ~20% of the planet’s radius; crustal magnetization, attributed at least in part to an ancient field; unexpected seasonal variability and relationships among exospheric species and processes; and the presence in permanently shadowed polar terrain of water ice and other volatile materials, likely to include complex organic compounds. Mercury’s highly chemically reduced and unexpectedly volatile-rich composition is unique among the terrestrial planets and was not predicted by earlier hypotheses for the planet’s origin. As an end-member of terrestrial planet formation, Mercury holds unique clues about the original distribution of elements in the earliest stages of the Solar System and how planets (and exoplanets) form and evolve in close proximity to their host stars. The BepiColombo mission promises to expand our knowledge of this planet and to shed light on some of the mysteries revealed by the MESSENGER mission. However, several fundamental science questions raised by MESSENGER’s pioneering exploration of Mercury can only be answered with in situ measurements from the planet’s surface.

Clay minerals are common in ancient terrains on Mars and their presence at the surface alludes to aqueous processes in the Noachian to Early Hesperian (>3.5 Ga). Gale crater was selected as Curiosity’s landing site largely because of the identification of clay mineral rich strata from orbit. On Earth, the types of clay minerals (i.e., smectites) identified in Gale crater are typically juvenile weathering products that ultimately record the interaction between primary igneous minerals with the hydrosphere, atmosphere, and biosphere. Trioctahedral and dioctahedral smectite were identified by Curiosity in units stratigraphically below the Clay Mineral-Bearing Unit (CBU) identified from orbit. Compositional and sedimentological data suggest the smectite formed via authigenesis in a lake environment and may have been altered during early diagenesis. The CBU is stratigraphically equivalent to a hematite-rich unit to the north and stratigraphically underlies sulfate-rich units to the south, suggesting a dynamic environment and evolving history of water in the ancient Gale crater lake. Targeting these clay mineral rich areas on Mars with rover missions provides an opportunity to explore the aqueous and sedimentary history of the planet.

Liquid water was abundant on early Mars, but whether the climate was warm and wet or cold and icy with punctuated periods of melting is still poorly understood. Modern climate models for Mars tend to predict a colder, icier early climate than previously imagined [e.g., 1]. However, any model for the early climate on Mars must be reconciled with the chemical record. We currently do not understand how alteration mineralogy formed in snow and ice dominated conditions compares to that of warmer climates, and it is unclear whether cold climate weathering could form all or any of the aqueous alteration phases expressed on early martian surfaces [2]. To help resolve this knowledge gap, we synthesize results from glacial Mars analog sites at the Three Sisters, Oregon and mafic regions of the Antarctic ice sheet, and compare them to the surface mineralogy of Mars. These sites provide the opportunity to investigate weathering in environments analogous to glacial environments on Mars throughout geologic time, including snowpacks or smaller wet-based or polythermal glaciers [3, 4] as well as the proposed extensive ice sheets of the late Noachian icy highlands model

The Mars Science Laboratory Curiosity rover landed in Gale crater in August 2012 to investigate early Hesperian-aged sedimentary rocks on the lower slopes of Aeolis Mons (i.e., Mount Sharp) that show variations in phyllosilicates, hematite, and sulfates from orbital reflectance spectroscopy, suggesting changes in ancient aqueous environments. During the Eighth International Conference on Mars in July 2014, Curiosity was still traversing the Bradbury group on the plains of Gale crater (Aeolis Palus) and had only analyzed four samples in its internal laboratories. Soon after Mars 8, Curiosity began its investigation of Mount Sharp and has since driven through ~350 m of vertical stratigraphy, the majority of which is part of the Murray formation. The Murray fm is comprised primarily of laminated mudstone with occasional sandstone and heterolithic facies and represents a long-lived fluvio-lacustrine environment. Curiosity has analyzed 13 drilled rock samples from the Murray formation and 4 from the ancient eolian Stimson fm with the Chemistry and Mineralogy (CheMin) instrument. Here, we discuss the mineralogy of all fluvio-lacustrine samples analyzed to date and what these results tell us about sources of the sediments, aqueous environments, and habitability of ancient Gale crater.

Sedimentary rocks are historical archives of planetary surface processes; their grains, textures, and chemistry integrate the effects of source terrains, paleoclimatic conditions, weathering and transport processes, authigenic mineral precipitation, and diagenesis, which records groundwater chemistry through time. “Source to Sink” basin analysis seeks to constrain the influence of each of these different signals through sedimentary and geochemical analyses. Here, we use Mars Science Laboratory (MSL) Curiosity rover images and geochemical and mineralogical data from a traverse across a portion of the Murray formation—the lowermost unit exposed in the Gale crater central mound—to begin to constrain the aspects of the source to sink system that formed this Martian mudstone between 3.7 and 3.2 Ga.

If Mars has been assumed to be mostly basaltic for a long time, a series of recent discoveries have challenged this simplistic view. Orbital data indicated feldspar-rich rocks in Noachian terrains, likely supporting ancient evolved magmatism. The first indurated regolithic martian meteorite breccia NWA 7034, dated at 4.43 Gyr, contain several leucocratic felsic clasts identified as monzonitic and trachyandesitic, containing feldspars including K-spars and Na-rich plagioclases, pyroxenes, ilmenites and apatites. These clasts have been interpreted as the result of crystallization of a large impact pond. The Mars Science Laboratory rover (Curiosity), travelling within sedimentary bedrock on the floor of the Gale impact crater, discovered feldspar cumulates and a trachyandesite suggesting fractional crystallization of a basaltic melt. In addition, in the Bradbury group of fluvio-deltaic rocks (observed during the 1st 750 sols), sedimentary rocks are mostly comprised of secondary phases and detrital igneous minerals like feldspar, and pyroxene that are thought to come from Noachian-aged magmatic sources, although no definite origin and igneous processes have been inferred.

The Mars Science Laboratory Curiosity rover arrived at Mars in August 2012 with a primary goal of characterizing the habitability of ancient and modern environments. Curiosity landed in Gale crater to study a sequence of ~3.5 Ga old sedimentary rocks that, based on orbital visible/near-infrared reflectance spectra, contain secondary minerals that suggest deposition and/or alteration in liquid water. The sedimentary sequence that comprises the lower slopes of Mount Sharp within Gale crater may preserve a dramatic shift on early Mars from a relatively warm and wet climate to a cold and dry climate based on a transition from smectite-bearing strata to sulfate-bearing strata. The rover is equipped with cameras and geochemical and mineralogical instruments to examine the sedimentology and identify compositional changes within the stratigraphy. These observations provide information about variations in depositional and diagenetic environments over time. The Chemistry and Mineralogy (CheMin) instrument is one of two internal laboratories on Curiosity and includes a transmission X-ray diffractometer (XRD) and X-ray fluorescence (XRF) spectrometer with a Co-K source. CheMin measures loose sediment samples scooped from the surface and drilled rock powders. The XRD provides quantitative mineralogy of scooped and drilled samples to a detection limit of ~1 wt.%. Curiosity has traversed >20 km since landing and has primarily been exploring the site of a predominantly ancient lake environment fed by groundwater and streams emanating from the crater rim. Results from CheMin demonstrate an incredible diversity in the mineralogy of fluvio-lacustrine rocks that signify variations in source rock composition, sediment transport mechanisms, and depositional and diagenetic fluid chemistry. Abundant trioctahedral smectite and magnetite at the base of the section may have formed from low-salinity pore waters with a circumneutral pH within lake sediments. A transition to dioctahedral smectite, hematite, and Ca-sulfate going up section suggests a change to more saline and oxidative aqueous conditions within the lake waters themselves and/or within diagenetic fluids. The primary minerals detected in fluvio-lacustrine samples by CheMin also suggest diversity in the igneous source regions for the sediments, where abundant pyroxene and plagioclase in most samples suggest a basaltic protolith, but sanidine and pyroxene in one sample may have been sourced from a potassic trachyte, and tridymite and sanidine in another sample may have been transported from a rhyolitic source. Crystal chemistry of major phases in each sample have been calculated from refined unit-cell parameters, providing further constraints on aqueous alteration processes and igneous protoliths for the sediments. Perhaps one of the biggest mysteries revealed by the CheMin instrument is the high abundance of X-ray amorphous materials (15 to 73 wt.%) in all samples measured to date. X-ray amorphous materials were detected by CheMin based on the observation of broad humps in XRD patterns. How these materials formed, their composition, and why they persist near the martian surface remain a topic of debate. The sedimentology and composition of the rocks analyzed by Curiosity demonstrate that habitable environments persisted intermittently on the surface or in the subsurface of Gale crater for perhaps more than a billion years.

The Mars Curiosity rover has traversed nearly 20 km and gained over 350 meters in elevation since landing in Gale crater in August 2012. Through 2250 sols of surface operations, Curiosity has spent approximately 60% of its time investigating the Murray formation, a unit of layered sediments. The occurrence of sulfur compounds in the Murray formation has been established by imaging of light-toned veins by MastCam and MAHLI, chemical compositions measured by the Alpha Particle X-ray Spectrometer (APXS) and ChemCam, crystalline phase identifications by the CheMin X-ray diffractometer, and evolved gas analyses from the Sample Analysis at Mars (SAM) instrument.

Over the last decade, various datasets have shown evidence for unexpected Noachian felsic materials at the surface of Mars. The Martian meteorite NWA 7034, also well-known as Black Beauty, has been identified as a regolith breccia containing mafic clasts along with remarkable felsic igneous clasts dated at 4.43 Gyr and classified as monzonitic [1-2]. In addition, the Curiosity rover has been analyzing felsic materials within Gale crater since its landing in 2012 [3-4]. The X-ray diffractometer (XRD) in the CheMin instrument and the laser induced breakdown spectrometer (LIBS) ChemCam onboard Curiosity identified plagioclase and K-spar along with augite and pigeonite [3-5]. In sedimentary rocks, those minerals are detrital, coming from a magmatic source of Noachian age that was sufficiently evolved to form K-spar [1,6]. Several igneous materials analyzed by Chem- Cam have been classified as part of the alkaline trend including Harrison, a trachy-andesite [7].

Since the beginning of the Mars Science Laboratory (MSL) mission, Vera Rubin Ridge (VRR) has been a location of interest to the MSL science team because of its apparent erosional resistance and strong near-IR (~860 nm) absorption feature seen from orbit in the Mars Reconnaissance Orbiter mission's Compact Reconnaissance Imaging Spectrometer for Mars (CRISM) data. The strong CRISM absorption feature along VRR was hypothesized to be primarily associated with an increased abundance of crystal-line hematite compared to lower Mt. Sharp units. How-ever, surface multispectral and mineralogic data, from the Mastcam and CheMin instruments onboard the Curiosity rover, suggest hematite is not the only mineral contributing to the near-IR absorption feature measured in VRR or the reason for its relative hardness.

The Mars Science Laboratory (MSL) Curiosity rover has spent the last two years investigating a prominent resistant ridge, informally named the Vera Rubin Ridge (VRR), at the base of Mount Sharp (Aeolis Mons). The ridge has been a high priority science target for the MSL mission since landing in Gale crater more than 6 years ago because of the detection of a strong hematite spectral signature, and its distinct topography. Examining the chemistry of the ridge can aid in determining the relationship to other rocks analyzed during the rover traverse, specifically the Murray formation (fm) encountered below the ridge. We can also determine compositional trends with elevation and/or laterally within the ridge, and whether spectral properties observed on the ridge, both from orbit and in situ, correspond with changes in chemistry. The composition of the ridge, combined with mineralogy of drilled samples, can help to elucidate bigger picture questions regarding depositional environment, possible changing lake water chemistry and diagenetic/alteration history.

The Murray formation is predominantly composed of lacustrine mudstone that forms the basal layer of Aeolis Mons (informally Mt. Sharp) in Gale Crater, Mars. The Murray formation has distinct iron and sulfur mineralogical variation within its stratigraphy detectable by the Chemistry Mineralogy (Che-Min) instrument consisting of magnetite/hematite in the lower Murray and higher hematite, CaSO4, and smectite content in the upper Murray. The objectives of this work were to evaluate the Sample Analysis at Mars Evolved Gas Analyzer (SAM-EGA) data to 1) Determine what SAM-EGA-detectable phases correlate or do not correlate with the Murray mineralogical composition detected by CheMin and 2) Utilize CheMin/SAM results to propose possible formation scenarios for the observed Murray mudstone mineralogy.

The Mars Science Laboratory Curiosity’s Chemistry and Mineralogy (CheMin) instrument performed X-ray diffraction (XRD) analysis of Gale Crater drill sample Windjana and found 21 wt.% nearly pure potassium feldspar in the disordered structural state of high-sanidine. The source of sanidine in Windjana is not clear – it could be detrital igneous, hydrothermal, or authigenic, with each possible source representing widely different implications for the sedimentary history of Gale Crater and igneous evolution of sediment sources. Here, we try to constrain the origin of the Windjana sanidine by determining unit-cell (UC) parameters and compositions of sanidines from a range of environments on Earth.

Mars has a sedimentary history that spans billions of years. Orbital images have allowed for the identification of vast regional sedimentary deposits that can be traced over 100s of kilometers and are 100s of meters thick including localized alluvial, deltaic, and lacustrine deposits. Detections of secondary minerals in these deposits from orbital spectroscopy suggest the aqueous history of early Mars varied as a function of space and time. Orbital observations, however, provide a simplified and incomplete picture of Mars’ sedimentary history because measurements for inferring sediment transport and deposition, such as lithology, grain size, and internal structures, and measurements for inferring sediment source and aqueous alteration, such as outcrop-scale mineralogic and geochemical composition and diagenetic features, cannot be identified from orbit. Rover observations have significantly enhanced our view of ancient and modern sedimentary environments on Mars, resulting in detailed reconstructions of paleo-environments and habitability.

The Sample Analysis at Mars (SAM) instrument suite on the Mars Science Laboratory (MSL) rover has been essential in understanding volatile-bearing phases in Gale Crater materials. SAM’s evolved gas analysis mass spectrometry (EGA-MS) has detected H2O, CO2, O2, H2, SO2, H2S, HCl, NO, and other trace gases, including organic fragments, in many samples. The identity and evolution temperature of evolved gases can support CheMin instrument mineral detection and place constraints on trace volatile-bearing phases or phases difficult to characterize with X-ray diffraction (e.g., amorphous phases). For the past ~500 sols, MSL has been exploring the Vera Rubin Ridge (VRR), which exhibits a striking hematite signature in orbital remote sensing data, in order to understand the depositional and diagenetic history recorded in the rocks and how it relates to the underlying Murray Formation. Four rock samples were drilled, one from the Blunts Point Member (Duluth, DU), one from the Pettegrrove Point Member (Stoer, ST), and two from the Jura Member. The Jura Member displays differences in color, summarized as grey and red, and a key goal was to constrain the cause of this color difference and the associated implications for depositional or post-depositional conditions. To investigate, a grey (Highfield, HF) and a red (Rock Hall, RH) Jura sample were drilled. Here we will give an overview of results from SAM EGA-MS analyses of VRR materials, with some comparisons to analyses of samples of the underlying Murray.

Volcanic surfaces are common and varied throughout the terrestrial planets. Remote spectroscopy is often the only method for determining surface chemistry and mineralogy of such provinces, and is thus critical for understanding petrologic processes and constraining planetary interior evolution and chemistry. Natural volcanic systems exhibit variability in magmatic chemical evolution, crystallinity, oxidation, and eruption-related alteration (e.g. hydrothermal). The extent to which spectroscopy can identify these characteristics alongside each other is thus a key question for interpreting volcanic processes from orbit. While the effects of each of these on visible/near infrared (VNIR) and thermal infrared (TIR) spectra of igneous rocks has been studied separately to varying degrees, their combined spectral effects (and interpretability of such spectra) are understudied.

Vera Rubin Ridge (VRR) in Gale Crater, Mars, is a ~200 m wide ~6.5 km long northeast- southwest resistant geomorphological feature on the northern slopes of Aeolis Mons (Mt. Sharp). Analysis of Compact Reconnaissance Imaging Spectrometer for Mars (CRISM) orbital data showed that VRR has strong hematite spectral signatures. Hematite was confirmed in-situ at VRR with the Curiosity rover and has been shown to be present throughout the Mur- ray formation. VRR is stratigraphically continu-ous with the underlying Murray formation. Previous thermochemical modelling showed how hematite at VRR could have formed as the result of open-system weathering at high water/rock ratios. Here we use thermochemical modelling to investigate possible reaction pathways for the hematite-clay- bearing assemblage observed at VRR, starting from an identified least-altered (minimum clay content) Murray composition, and a Mars basal brine.

Abundant evidence for liquid water exists at Gale crater, Mars. However, the characteristics of past water remain an area of active research. The first exposures of the Murray formation in Gale crater, Mars (Fig. 1) were studied with four samples analyzed using CheMin: Buckskin, Telegraph Peak, Mojave, and Confidence Hills. Analyses indicate differences in mineralogy and chemistry between the samples which have been attributed to changes in pH and oxidation state of depositional and diagenetic environments. Recent work also suggests that hydrothermal fluids may have been present based on the presence of Se, Zn, Pb, and other elements.

Characterizing the structure and composition of phyllosilicates is important for interpreting the aqueous history of Mars and identifying potential habitable environments. Smectites and chlorites are the most dominant clay types on Mars, and there is evidence of the presence of smectite/chlorite intergrades. Smectite has been detected at Gale Crater, Mars, via orbital observations and in-situ measurements, in abundances up to approximately 25 weight percentage of bulk rock. John Klein (JK) and Cumberland (CB) were analyzed by the Chemistry and Mineralogy (CheMin) and Samples Analysis at Mars (SAM) evolved gas analysis experiment (EGA) instruments, onboard Mars Science Laboratory (MSL), Curiosity, to distinguish clay mineralogy. John Klein has a collapsed 2:1 smectite with a d-spacing of 10 Angstroms, whereas Cumberland smectite did not fully collapse and has a d-spacing of approximately 13.2 Angstroms. It has been suggested that partial chloritization or ‘pillaring’ could be responsible for the expanded Cumberland smectite because pillaring inhibits the collapse of smectites down to 10 Angstrom, even under the desiccating conditions on the martian surface. Clay minerals have been detected in ancient fluvio-lacustrine rocks throughout Curiosity’s traverse and catalog the changes of the lake water chemistry and diagenetic conditions at Gale Crater, Mars. Investigating clay minerals is important for identifying them on the Martian surface, in particular as Curiosity proceeds into the upcoming Clay-bearing Unit.

The NASA Curiosity rover has encountered both ancient and modern dune deposits within Gale crater. The modern dunes are actively migrating across the surface within the Bagnold Dune field of which Curiosity conducted analysis campaigns at two different localities. Variations in mafic-felsic mineral abundances between these two sites have been related to the aeolian mineral sorting regime for basaltic environments identified on the Earth which become preferentially enriched in olivine relative to plagioclase feldspar with increasing distance from the source. This aeolian mineral sorting regime for basaltic minerals has also been inferred for Mars from orbital data. The aim of this study is to investigate whether this aeolian mafic-felsic mineral sorting trend has left a geochemical signature in the ancient dune deposits preserved within the Stimson formation. The Stimson formation unconformably overlies the Murray formation and consists of thickly laminated, cross-bedded sandstone. Stimson outcrops have a variable thickness up to 5 meters covering a total area of 17 square kilometers. A dry, aeolian origin was determined for this sandstone due to the high sphericity and roundness of the grains, uniform bimodal grain size distribution (250-710 microns), and 1-meter-thick cross-beds. Identifying the geochemical signature of mineral sorting can provide insights about the paleo-net sediment transport direction of the dunes and prevailing wind direction at the time of deposition.

The Mars Science Laboratory Curiosity rover landed in Gale crater in August 2012 to characterize modern and ancient surface environments. Curiosity executed a two-phase campaign to study the morphology, activity, physical properties, and chemical and mineralogical composition of the Bagnold Dune Field, an active eolian dune field on the lower slopes of Aeolis Mons (Mount Sharp). Detectable aspects of dune sand mineralogy have been examined from orbit with the visible/short-wave infrared spectrometer CRISMand the thermal-infrared spectrometers THEMIS and TES. CRISM data demonstrate variations in plagioclase, pyroxene, and olivine abundances across the dune field. Curiosity analyzed sediments from two locations in the dune field to evaluate the causes of the mineralogical differences observed from orbit. The Gobabeb sample was collected from Namib Dune, a barchanoidal dune on the upwind margin of the dune field, and the Ogunquit Beach sample was collected from the Mount Desert Island sand patch located downwind from Namib. These samples were sieved to <150 μm and delivered to the CheMin X-ray diffraction instrument for quantitative mineralogical analysis. CRISM-derived mineralogy of the Namib Dune and Mount Desert Island and CheMin-derived mineralogy of the Gobabeb and Ogunquit Beach samples can be used in a value-added manner to interpret grain segregation at the bedform to dune-field scale and evaluate contributions from local sediment sources. Models of CRISM data demonstrate that Mount Desert Island is more enriched in olivine and less enriched in plagioclase than Namib dune, suggesting that fine-grained mafic sediments are preferentially mobilized downwind. Curiosity data indicate olivine also forms a coarse lag on the lee sides of barchanoidal dunes. Minor abundances of hematite, quartz, and anhydrite and small differences in the crystal chemistry of plagioclase and pyroxene derived from CheMin data suggest that sediments from the underlying lacustrine rocks also contribute to the Bagnold sands.

The surface of Mars exhibits strong evidence for a widespread and long-lived cryosphere. Observations of the surface have identified phases produced by water-rock interactions, but the contribution of glaciers to the observed alteration mineralogy is unclear. To characterize the chemical alteration expected on an icy early Mars, we collected water and rock samples from terrestrial glaciated volcanics. We related geochemical measurements of meltwater to the mineralogy and chemistry of proglacial rock coatings. In these terrains, water is dominated by dissolved silica relative to other dissolved cations, particularly at mafic sites. Rock coatings associated with glacial striations on mafic boulders include a silica-rich component, indicating that silica precipitation is occurring in the subglacial environment. We propose that glacial alteration of volcanic bedrock is dominated by a combination of high rates of silica dissolution and precipitation of opaline silica. On Mars, cryosphere-driven chemical weathering could be the origin of observed silica-enriched phases.

Gale crater contains two fine-grained mudstone sedimentary units: The Sheepbed mudstone member, and the Murray formation mud-stones. These mudstones formed as part of an ancient fluviolacustrine system. The NASA Curiosity rover has analysed these mudstone units using the Chemistry and Camera (ChemCam), Alpha Particle X-ray Spectrometer (APXS) and Chemistry and Mineralogy (CheMin) onboard instrument suites. Subsequent mineralogical analyses have uncovered a wide geochemical and mineralogical diversity across and within these two mudstone formations. This study aims to determine the principal cause (alteration or source region) of this geochemical variation through a statistical analysis of the ChemCam dataset up to sol 1482, including the lower to middle Murray formation.

Final Document is attached. Introduction: The Mars Science Laboratory Curi-osity rover landed in Gale crater in August 2012 to search for habitable enironments preserved in the rocks and sediments on the lower slopes of Aeolis Mons (i.e., Mount Sharp). Along the traverse, Curiosity encountered an active aeolian sand sheet, informally known as the Bagnold dune field. Orbital CRISM vis/near-IR data suggest that there are varying abun-dances of olivine and pyroxene across the dune field, where the barchan dunes on the edge of the dune field have stronger olivine signatures than the linear dunes.