Search

Old landfill leachate is normally rich in colloidal particles, has low organic compound, poor biodegradability and hard to be biologically treated. The suspended particles are generally dispersed, negatively charged and do not settle by gravity due to their instability and repulsion. This paper aimed to evaluate the effectiveness of SnCl4 as a positively charged coagulant in treating concentrated colour and suspended solids (SS) from an old leachate sampled at one of the local landfills in Malaysia (Alor Pongsu Landfill Site, Keria Perak), which may also represent other landfills with similar property. The mechanism and the effect of pH, zeta potential (ZP) and particle size of colloids on the reduction of the pollutants were evaluated through standard coagulation and flocculation experiment with ZP measurement. The standard jar test was examined at a pre-determined SnCl4 dosage and varied from pH 3 to pH 12. The raw leachate was found negatively charged throughout pH 3 to pH 12. Adding a positively charged SnCl4 increased the leachate surface charge to close to the point of zero charges (IEP) at pH 8 with −0.4 mV. Generally, as the pH value increase from acidic to basic condition, the raw leachate becomes more negatively charged as at higher pH values It was also found that the pH of the solution correlated with the size of the particles, where 221.3 d.nm was recorded from pH 4 to pH 11 and improved to the largest size 660 d.nm at pH 3. The highest colour and SS performance were observed at optimum pH 8 with reductions of 98.9% and 100%, respectively The reduction of repulsive forces at this pH promoted the collision of particles and thus made the aggregation possible. ZP measurement in is important as it provides an early estimation of the effective pH for the optimum coagulation and flocculation process of landfill leachate contributed by the colloidal particles. [ABSTRACT FROM AUTHOR]

This review of literature published in 2015 focuses on waste related to chemical and allied products. The topics cover the waste management, physicochemical treatment, aerobic granular, aerobic waste treatment, anaerobic granular, anaerobic waste treatment, chemical waste, chemical wastewater, fertilizer waste, fertilizer wastewater, pesticide wastewater, pharmaceutical wastewater, ozonation. cosmetics waste, groundwater remediation, nutrient removal, nitrification denitrification, membrane biological reactor and pesticide waste. [ABSTRACT FROM AUTHOR]

Landfill leachate is a highly polluted and generated from water infiltration through solid waste produced domestically and industrially. In this study, a coagulation–flocculation process using a combination of Polyaluminium chloride (PACl) as a coagulant and Dimocarpus longan seed powder (LSP) as coagulant aid was used in treating landfill leachate. LSP has been tested as the main coagulant and as coagulant aid with PACl. As the main coagulant, the optimum dosage and pH for PACl were 5 g/L and 6, respectively, with removal efficiencies of 67.44%, 99.47%, and 98% for COD, SS, and color, respectively. For LSP as the main coagulant, results show that LSP is not effective where the removal efficiencies obtained for COD, SS, and color were 39.40%, 22.20%, and 28.30%, respectively, with the optimum dosage of 2 g/L and pH 4. The maximum removal efficiencies of COD, SS, and color were 69.19%, 99.50%, and 98.80%, respectively, when LSP was used as coagulant aid with PACl. Results show that using LSP as coagulant aid was found to be more effective in the removal of COD, SS, and color with less PACl dosage. The PACl dosage was decreased from 5 to 2.75 g/L when LSP was used as a coagulant aid. Cost estimation for using PACl alone and using LSP as the coagulant aid showed a reduction in the cost of approximately 40% of the cost of using PACl alone. Overall, this study confirmed the efficiency of LSP to be used as a natural coagulant aid in leachate treatment. [ABSTRACT FROM AUTHOR]

This study was conducted to evaluate the effect of the toxicity levels of the coagulation and flocculation process on raw and treated leachate using acute toxicity tests. Tin tetrachloride (SnCl 4 ) and the Jatropha curcas (JC) seed were used as coagulant and coagulant aid to remove concentrated suspended solids, SS (534 mg/L), color (19,297 Pt-Co), and chemical oxygen demand (COD) (4188 mg/L) in a stabilized landfill leachate. The toxicity effects on local red tilapia fish (Oreochromis niloticus) were investigated, which involved three main steps, namely, acclimatization, range-finding test, and short-term definitive test. The presence of JC seed (0.9 g/L) as a flocculant reduced the dosage of SnCl 4 from 11.1 to 8.5 g/L and exhibited good removals of 99.78%, 98.53%, and 74.29%, respectively, for SS, color, and COD. The toxicity test indicated that only five fish died in the first 12 h for the treated sample compared with seven deaths for untreated leachate. In 96 h, a total of 42 and 31 mortality rates were noted for the raw and treated leachate samples, respectively. The treated sample could reduce the toxicity effects to the tested tilapia fish and is safe to be discharged at appropriate dilution concentrations. PRACTITIONER POINTS: Coagulation-flocculation by Tin (IV) chloride and Jatropha Curcas (JC) was investigated. Almost complete reduction of SS was obtained at 8.5 g/L of SnCl4 and 0.9 g/L of JC as flocculant. The toxicity effect was evaluated using red tilapia (Oreochromis niloticus) fish as the indicator. Treated leachate was considered acceptable as the number of dead fish was lower than the untreated leachate., (© 2021 Water Environment Federation.)