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One-third of Mars' surface has shallow-buried H$_2$O, but it is currently too cold for use by life. Proposals to warm Mars using greenhouse gases require a large mass of ingredients that are rare on Mars' surface. However, we show here that artificial aerosols made from materials that are readily available at Mars-for example, conductive nanorods that are ~9 $\mu$m long-could warm Mars >5 $\times$ 10$^3$ times more effectively than the best gases. Such nanoparticles forward-scatter sunlight and efficiently block upwelling thermal infrared. Similar to the natural dust of Mars, they are swept high into Mars' atmosphere, allowing delivery from the near-surface. For a particle lifetime of 10 years, two climate models indicate that sustained release at 30 liters/sec would globally warm Mars by $\gtrsim$30 K and start to melt the ice. Therefore, if nanoparticles can be made at scale on (or delivered to) Mars, then the barrier to warming of Mars appears to not be as high as previously thought.

Energy balance models (EBMs), alongside radiative-convective climate models (RCMs) and global climate models (GCMs), are useful tools for simulating planetary climates. Historically, planetary and exoplanetary EBMs have solely been 1D latitudinally-dependent models with no longitudinal dependence, until the study of Okuya et al., which focused on simulating synchronously-rotating planets. Following the work of Okuya et al., I have designed the first 2D EBM (PlaHab) that can simulate N2-CO2-H2O-H2 atmospheres of both rapidly-rotating and synchronously-rotating planets, including Mars, Earth, and exoplanets located within their circumstellar habitable zones. PlaHab includes physics for both water and CO2 condensation. Regional topography can be incorporated. Here, I have specifically applied PlaHab to investigate present Earth, early Mars, TRAPPIST-1e and Proxima Centauri b, representing examples of habitable (and potentially habitable) worlds in our solar system and beyond. I compare my EBM results against those of other 1D and 3D models, including those of the recent Trappist-1 Habitable Atmosphere (THAI) comparison project. Overall, EBM results are consistent with those of other 1D and 3D models although inconsistencies among all models continue to be related to the treatment of clouds and other known differences between EBMs and GCMs, including heat transport parameterizations. Although two-dimensional EBMs are a relatively new entry in the study of planetary/exoplanetary climates, their ease-of-use, speed, flexibility, wide applicability, and greater complexity (relative to 1D models), may indicate an ideal combination for the modeling of planetary and exoplanetary atmospheres alike., Comment: Accepted into The Planetary Science Journal (35 pages, 12 Figures, 4 Tables)

Energy balance models (EBMs) are one- or two-dimensional climate models that can provide insight into planetary atmospheres, particularly with regard to habitability. Because EBMs are far less computationally intensive than three-dimensional general circulation models (GCMs), they can be run over large, uncertain parameter spaces and can be used to explore long-period phenomena like carbon and Milankovitch cycles. Because horizontal dimensions are incorporated in EBMs, they can explore processes that are beyond the reach of one-dimensional radiative-convective models (RCMs). EBMs are, however, dependent on parameterizations and tunings to account for physical processes that are neglected. Thus, EBMs rely on observations and results from GCMs and RCMs. Different EBMs have included a wide range of parameterizations (for albedo, radiation, and heat diffusion) and additional physics, such as carbon cycling and ice sheets. This CUISINES exoplanet model intercomparison project (exoMIP) will compare various EBMs across a set of numerical experiments. The set of experiments will include Earth-like planets at different obliquities, parameter sweeps across obliquity, and variations in instellation and CO$_2$ abundance to produce hysteresis diagrams. We expect a range of different results due to the choices made in the various codes, highlighting which results are robust across models and which are dependent on parameterizations or other modeling choices. Additionally, it will allow developers to identify model defects and determine which parameterizations are most useful or relevant to the problem of interest. Ultimately, this exoMIP will allow us to improve the consistency between EBMs and accelerate the process of discovering habitable exoplanets., Comment: 19 pages, 5 figures, accepted for publication at Planetary Science Journal

Habitability has been generally defined as the capability of an environment to support life. Ecologists have been using Habitat Suitability Models (HSMs) for more than four decades to study the habitability of Earth from local to global scales. Astrobiologists have been proposing different habitability models for some time, with little integration and consistency among them, being different in function to those used by ecologists. Habitability models are not only used to determine if environments are habitable or not, but they also are used to characterize what key factors are responsible for the gradual transition from low to high habitability states. Here we review and compare some of the different models used by ecologists and astrobiologists and suggest how they could be integrated into new habitability standards. Such standards will help to improve the comparison and characterization of potentially habitable environments, prioritize target selections, and study correlations between habitability and biosignatures. Habitability models are the foundation of planetary habitability science and the synergy between ecologists and astrobiologists is necessary to expand our understanding of the habitability of Earth, the Solar System, and extrasolar planets., Comment: Published in Astrobiology, 21(8). arXiv admin note: substantial text overlap with arXiv:2007.05491

The habitable zone is the region around a star where standing bodies of liquid water can be stable on a planetary surface. Its width is often assumed to be dictated by the efficiency of the carbonate-silicate cycle, which has maintained habitable surface conditions on our planet for billions of years. This cycle may be inhibited by surface condensation of significant amounts of $CO_{\mathrm{2}}$ ice, which is likely to occur on distant planets containing high enough levels of atmospheric $CO_{\mathrm{2}}$. Such a process could permanently trap $CO_{\mathrm{2}}$ ice within the planet, threatening its long-term habitability. Recent work has modeled this scenario for initially cold and icy planetary bodies orbiting the Sun. Here, we use an advanced energy balance model to consider both initially warm and cold rapidly-rotating planets orbiting F - K stars. We show that the range of orbital distances where significant surface $CO_{\mathrm{2}}$ ice condensation occurs is significantly reduced for warm start planets. Star type does not affect this conclusion, although surface $CO_{\mathrm{2}}$ ice condenses over a larger fraction of the habitable zone around hotter stars. The warm start simulations are thus consistent with 1-D model predictions, suggesting that the classical habitable zone limits in those earlier models are still valid. We also find that the cold start simulations exhibit trends that are consistent with those of previous work for the Sun although we now extend the analysis to other star types., Comment: 11 pages, 6 figures; accepted for publication in MNRAS

Habitability has been generally defined as the capability of an environment to support life. Ecologists have been using Habitat Suitability Models (HSMs) for more than four decades to study the habitability of Earth from local to global scales. Astrobiologists have been proposing different habitability models for some time, with little integration and consistency between them and different in function to those used by ecologists. In this white paper, we suggest a mass-energy habitability model as an example of how to adapt and expand the models used by ecologists to the astrobiology field. We propose to implement these models into a NASA Habitability Standard (NHS) to standardize the habitability objectives of planetary missions. These standards will help to compare and characterize potentially habitable environments, prioritize target selections, and study correlations between habitability and biosignatures. Habitability models are the foundation of planetary habitability science. The synergy between the methods used by ecologists and astrobiologists will help to integrate and expand our understanding of the habitability of Earth, the Solar System, and exoplanets., Comment: White Paper for the Planetary Science and Astrobiology Decadal Survey 2023-2032

The habitable zone is the main tool that mission architectures utilize to select potentially habitable planets for follow up spectroscopic observation. Given its importance, the precise size and location of the habitable zone remains a hot topic, as many studies, using a hierarchy of models, have assessed various factors including: atmospheric composition, time, and planetary mass. However, little work has assessed how the habitable zone changes with variations in background nitrogen pressure, which is directly connected to the habitability and life bearing potential of planets. Here, I use an advanced energy balance model with clouds to show that our solar system habitable zone is about 0.9 to 1.7 AU, assuming a 5 bar nitrogen background pressure and a maximum 100 percent cloud cover at the inner edge. This width is about 20 percent wider than the conservative habitable zone estimate. Similar extensions are calculated for A to M stars. I also show that cooling clouds and hazes and high background pressures can decrease the runaway greenhouse threshold temperature to approximately 300 K (or less) for planets orbiting any star type. This is because the associated increase in planetary albedo enables stable climates closer to the star, where rapid destabilization can be triggered from a lower mean surface temperature. Enhanced longwave emission for planets with very high stratospheric temperatures also permits stable climates at smaller orbital distances. The model predicts a runaway greenhouse above approximately 330 K for planets orbiting the Sun, which is consistent with previous work. However, moist greenhouses only occur for planets orbiting A-stars., Comment: Published in The Monthly Notices of the Royal Astronomical Society (27 pages, 7 figures)

The debate over the early Martian climate is among the most intriguing in planetary science. Although the geologic evidence generally supports a warmer and wetter climate, climate models have had difficulty simulating such a scenario, leading some to suggest that the observed fluvial geology (e.g. valley networks, modified landscapes) on the Martian surface, could have formed in a cold climate instead. However, as we have originally predicted using a single-column radiative-convective climate model [Ramirez et al. 2014a], warming from CO2-H2 collision-induced absorption (CIA) on a volcanically active early Mars could have raised mean surface temperatures above the freezing point, with later calculations showing that this is achievable with hydrogen concentrations as low as ~1%. Nevertheless, these predictions should be tested against more complex models. Here, we use an advanced energy balance model that includes a northern lowlands ocean to show that mean surface temperatures near or slightly above the freezing point of water were necessary to carve the valley networks. Our scenario is consistent with a relatively large ocean as has been suggested. Valley network distributions would have been global prior to subsequent removal processes. At lower mean surface temperatures and smaller ocean sizes, precipitation and surface erosion efficiency diminish. The warm period may have been ~< 10 million years, perhaps suggesting that episodic warming mechanisms were not needed. Atmospheric collapse and permanently glaciated conditions occur once surface ice coverage exceeds a threshold depending on CIA assumptions. Our results support an early warm and semi-arid climate consistent with many geologic observations., Comment: Published in JGR:Planets (61 pages, 12 Figures, 2 Tables; Supp Info: 7 pages, 5 figures)

We are now on a clear trajectory for improvements in exoplanet observations that will revolutionize our ability to characterize their atmospheric structure, composition, and circulation, from gas giants to rocky planets. However, exoplanet atmospheric models capable of interpreting the upcoming observations are often limited by insufficiencies in the laboratory and theoretical data that serve as critical inputs to atmospheric physical and chemical tools. Here we provide an up-to-date and condensed description of areas where laboratory and/or ab initio investigations could fill critical gaps in our ability to model exoplanet atmospheric opacities, clouds, and chemistry, building off a larger 2016 white paper, and endorsed by the NAS Exoplanet Science Strategy report. Now is the ideal time for progress in these areas, but this progress requires better access to, understanding of, and training in the production of spectroscopic data as well as a better insight into chemical reaction kinetics both thermal and radiation-induced at a broad range of temperatures. Given that most published efforts have emphasized relatively Earth-like conditions, we can expect significant and enlightening discoveries as emphasis moves to the exotic atmospheres of exoplanets., Comment: Submitted as an Astro2020 Science White Paper

As we begin to discover rocky planets in the habitable zone of nearby stars with missions like TESS and CHEOPS, we will need quick advancements on instrumentation and observational techniques that will enable us to answer key science questions, such as What are the atmospheric characteristics of habitable zone rocky planets? How common are Earth-like biosignatures in rocky planets?} How similar or dissimilar are those planets to Earth? Over the next decade we expect to have discovered several Earth-analog candidates, but we will not have the tools to study the atmospheres of all of them in detail. Ground-based ELTs can identify biosignatures in the spectra of these candidate exo-Earths and understand how the planets' atmospheres compare to the Earth at different epochs. Transit spectroscopy, high-resolution spectroscopy, and reflected-light direct imaging on ELTs can identify multiple biosignatures for habitable zone, rocky planets around M stars at optical to near-infrared wavelengths. Thermal infrared direct imaging can detect habitable zone, rocky planets around AFGK stars, identifying ozone and motivating reflected-light follow-up observations with NASA missions like HabEx/LUVOIR. Therefore, we recommend that the Astro2020 Decadal Survey Committee support: (1) the search for Earth-like biosignatures on rocky planets around nearby stars as a key science case; (2) the construction over the next decade of ground-based Extremely Large Telecopes (ELTs), which will provide the large aperture and spatial resolution necessary to start revealing the atmospheres of Earth-analogues around nearby stars; (3) the development of instrumentation that optimizes the detection of biosignatures; and (4) the generation of accurate line lists for potential biosignature gases, which are needed as model templates to detect those molecules., Comment: 9 pages, 3 figures. Science White Paper submitted to the Astro2020 Decadal Survey

Provided that sufficient resources are deployed, we can look forward to an extraordinary future in which we will characterize potentially habitable planets. Until now, we have had to base interpretations of observations on habitability hypotheses that have remained untested. To test these theories observationally, we propose a statistical comparative planetology approach to questions of planetary habitability. The key objective of this approach will be to make quick and cheap measurements of critical planetary characteristics on a large sample of exoplanets, exploiting statistical marginalization to answer broad habitability questions. This relaxes the requirement of obtaining multiple types of data for a given planet, as it allows us to test a given hypothesis from only one type of measurement using the power of an ensemble. This approach contrasts with a "systems science" approach, where a few planets would be extensively studied with many types of measurements. A systems science approach is associated with a number of difficulties which may limit overall scientific return, including: the limited spectral coverage and noise of instruments, the diversity of exoplanets, and the extensive list of potential false negatives and false positives. A statistical approach could also be complementary to a systems science framework by providing context to interpret extensive measurements on planets of particular interest. We strongly recommend future missions with a focus on exoplanet characterization, and with the capability to study large numbers of planets in a homogenous way, rather than exclusively small, intense studies directed at a small sample of planets., Comment: White paper submitted in response to the solicitation of feedback for the "2020 Decadal Survey" by the National Academy of Sciences

The habitable zone (HZ) is the region around a star(s) where standing bodies of water could exist on the surface of a rocky planet. The classical HZ definition makes a number of assumptions common to the Earth, including assuming that the most important greenhouse gases for habitable planets are CO2 and H2O, habitable planets orbit main-sequence stars, and that the carbonate-silicate cycle is a universal process on potentially habitable planets. Here, we discuss these and other predictions for the habitable zone and the observations that are needed to test them. We also, for the first time, argue why A-stars may be interesting HZ prospects. Instead of relying on unverified extrapolations from our Earth, we argue that future habitability studies require first principles approaches where temporal, spatial, physical, chemical, and biological systems are dynamically coupled. We also suggest that next-generation missions are only the beginning of a much more data-filled era in the not-too-distant future, when possibly hundreds to thousands of HZ planets will yield the statistical data we need to go beyond just finding habitable zone planets to actually determining which ones are most likely to exhibit life., Comment: White paper submitted to the NAS Astro 2020 decadal survey(5 pages, 1 figure + cover page, 13 co-authors + 10 co-signers). First author name added to description. In this arxiv version, one more co-signer was added after the NAS version was submitted. Link: http://surveygizmoresponseuploads.s3.amazonaws.com/fileuploads/623127/4458621/64-2dc3fcc201a3075e3da6233f1a91c668_RamirezRamsesM.pdf

The climate of early Mars remains a topic of intense debate. Ancient terrains preserve landscapes consistent with stream channels, lake basins, and possibly even oceans, and thus the presence of liquid water flowing on the Martian surface 4 billion years ago. However, despite the geological evidence, determining how long climatic conditions supporting liquid water lasted remains uncertain. Climate models have struggled to generate sufficiently warm surface conditions given the faint young Sun - even assuming a denser early atmosphere. A warm climate could have potentially been sustained by supplementing atmospheric CO2 and H2O warming with either secondary greenhouse gases or clouds. Alternatively, the Martian climate could have been predominantly cold and icy, with transient warming episodes triggered by meteoritic impacts, volcanic eruptions, methane bursts, or limit cycles. Here, we argue that a warm and semi-arid climate capable of producing rain is most consistent with the geological and climatological evidence., Comment: 26 pages, 4 figures, 2 boxes (published in Nature Geoscience)

Ongoing and future space missions aim to identify potentially habitable planets in our Solar System and beyond. Planetary habitability is determined not only by a planet's current stellar insolation and atmospheric properties, but also by the evolutionary history of its climate. It has been suggested that icy planets and moons become habitable after their initial ice shield melts as their host stars brighten. Here we show from global climate model simulations that a habitable state is not achieved in the climatic evolution of those icy planets and moons that possess an inactive carbonate-silicate cycle and low concentrations of greenhouse gases. Examples for such planetary bodies are the icy moons Europa and Enceladus, and certain icy exoplanets orbiting G and F stars. We find that the stellar fluxes that are required to overcome a planet's initial snowball state are so large that they lead to significant water loss and preclude a habitable planet. Specifically, they exceed the moist greenhouse limit, at which water vapour accumulates at high altitudes where it can readily escape, or the runaway greenhouse limit, at which the strength of the greenhouse increases until the oceans boil away. We suggest that some icy planetary bodies may transition directly to a moist or runaway greenhouse without passing through a habitable Earth-like state., Comment: 31 pages, 4 figures, 2 supplementary tables, and 9 supplementary figures

The habitable zone (HZ) is the circular region around a star(s) where standing bodies of water could exist on the surface of a rocky planet. Space missions employ the HZ to select promising targets for follow-up habitability assessment. The classical HZ definition assumes that the most important greenhouse gases for habitable planets orbiting main-sequence stars are CO2 and H2O. Although the classical HZ is an effective navigational tool, recent HZ formulations demonstrate that it cannot thoroughly capture the diversity of habitable exoplanets. Here, I review the planetary and stellar processes considered in both classical and newer HZ formulations. Supplementing the classical HZ with additional considerations from these newer formulations improves our capability to filter out worlds that are unlikely to host life. Such improved HZ tools will be necessary for current and upcoming missions aiming to detect and characterize potentially habitable exoplanets., Comment: Published in Geosciences. Invited review for the "Planetary Evolution and Search for Life on Habitable Planets" Special Issue (58 pages, 15 Figures, 1 Table). Fixed a typo in Table 1 and updated acknowledgements (was not fixed in v2). http://www.mdpi.com/2076-3263/8/8/280/htm

The habitable zone (HZ) is the circumstellar region where standing bodies of liquid water could exist on the surface of a rocky planet. Conventional definitions assume that CO2 and H2O are the only greenhouse gases. The outer edge of this classical N2-CO2-H2O HZ extends out to nearly 1.7 AU in our solar system, beyond which condensation and scattering by CO2 outstrip its greenhouse capacity. We use a single column radiative-convective climate model to assess the greenhouse effect of CH4 (10 to about 100,000 ppm) on the classical habitable zone (N2-CO2-H2O) for main-sequence stars with stellar temperatures between 2,600 to 10,000 K (about A3 to M8). Assuming N2-CO2-H2O atmospheres, previous studies have shown that cooler stars more effectively heat terrestrial planets. However, we find that the addition of CH4 produces net greenhouse warming (tens of degrees) in planets orbiting stars hotter than a mid-K (about 4500K), whereas a prominent anti-greenhouse effect is noted for planets around cooler stars. We show that 10% CH4 can increase the width of the classical HZ of the hottest stars (TEFF = 10,000 K) by over 20%. In contrast, the CH4 anti-greenhouse can shrink the HZ for the coolest stars (TEFF = 2,600 K) by a similar percentage. We find that dense CO2-CH4 atmospheres near the outer edge of hotter stars may suggest inhabitance, highlighting the importance of including secondary greenhouse gases in alternative definitions of the HZ. We parameterize the limits of this N2-CO2-H2O-CH4 habitable zone and discuss implications in the search for extraterrestrial life., Comment: Published in The Astrophysical Journal (8 Figures, 2 Tables, 25 pages) http://iopscience.iop.org/article/10.3847/1538-4357/aab8fa

Traditional definitions of the habitable zone assume that habitable planets contain a carbonate-silicate cycle that regulates CO2 between the atmosphere, surface, and the interior. Such theories have been used to cast doubt on the habitability of ocean worlds. However, Levi et al (2017) have recently proposed a mechanism by which CO2 is mobilized between the atmosphere and the interior of an ocean world. At high enough CO2 pressures, sea ice can become enriched in CO2 clathrates and sink after a threshold density is achieved. The presence of subpolar sea ice is of great importance for habitability in ocean worlds. It may moderate the climate and is fundamental in current theories of life formation in diluted environments. Here, we model the Levi et al. mechanism and use latitudinally-dependent non-grey energy balance and single-column radiative-convective climate models and find that this mechanism may be sustained on ocean worlds that rotate at least 3 times faster than the Earth. We calculate the circumstellar region in which this cycle may operate for G-M-stars (Teff = 2,600 to 5,800 K), extending from about 1.23 to 1.65, 0.69 to 0.954, 0.38 to 0.528 AU, 0.219 to 0.308 AU, 0.146 to 0.206 AU, and 0.0428 to 0.0617 AU for G2, K2, M0, M3, M5, and M8 stars, respectively. However, unless planets are very young and not tidally locked, our mechanism would be unlikely to apply to stars cooler than a ~M3. We predict C/O ratios for our atmospheres (about 0.5) that can be verified by the JWST mission., Comment: Published in the Monthly Notices of the Royal Astronomical Society (31 pages, 7 Figures, 1 Table) https://doi.org/10.1093/mnras/sty761

This is a white paper in response to the National Academy of Sciences "Exoplanet Science Strategy" call. We summarize recent advances in theoretical habitability studies and argue that such studies will remain important for guiding and interpreting observations. Interactions between 1-D and 3-D climate modelers will be necessary to resolve recent discrepancies in model results and improve habitability studies. Observational capabilities will also need improvement. Although basic observations can be performed with present capabilities, technological advances will be necessary to improve climate models to the level needed for planetary habitability studies., Comment: This is a white paper submitted to the National Academies 2018 "Exoplanet Science Strategy" call(6 pages total, including cover page). Corrected references section in this version. http://sites.nationalacademies.org/SSB/CurrentProjects/SSB_180659

In this Research Note, I use my single-column climate model to explicitly show that the moist greenhouse surface temperature threshold is sensitive to stratospheric temperature. I argue that this explains most of the discrepancy between 1-D and recent 3-D computations of the moist greenhouse threshold for M-star planets given that calculated stratospheric (and upper atmospheric) temperatures are higher than what are usually assumed in 1-D calculations. I suggest that collaborations between the two sets of modelers would lead to greater understanding of the moist greenhouse threshold. I also discuss implications for habitability if high stratospheric temperatures are a common feature on M-star planets near the inner edge., Comment: Published in the Research Notes of the AAS (4 pages, 1 figure)

The climate of early Mars has been hotly debated for decades. Although most investigators believe that the geology indicates the presence of surface water, disagreement has persisted regarding how warm and wet the surface must have been and how long such conditions may have existed. Although the geologic evidence is most easily explained by a persistently warm climate, the perceived difficulty that climate models have in generating warm surface conditions has seeded various models that assume a cold and glaciated early Mars punctuated by transient warming episodes. However, I use a single-column radiative-convective climate model to show that it is relatively more straightforward to satisfy warm and relatively unglaciated early Mars conditions, requiring only about 1 percent H2 and 3 bar CO2 or about 20 percent H2 and 0.55 bar CO2. In contrast, the reflectivity of surface ice greatly increases the difficulty to transiently warm an initially frozen surface. Surface pressure thresholds required for warm conditions increase about 10 to 60 percent for transient warming models, depending on ice cover fraction. No warm solution is possible for ice cover fractions exceeding 40, 70, and 85 percent for mixed snow and ice and 25, 35, and 49 percent for fresher snow and ice at H2 concentrations of 3, 10, and 20 percent, respectively. If high temperatures (298 to 323 K) were required to produce the observed surface clay amounts on a transiently warm early Mars (Bishop et al), I show that such temperatures would have required surface pressures that exceed available paleopressure constraints for nearly all H2 concentrations considered (1 to 20 percent). I then argue that a warm and semi-arid climate remains the simplest and most logical solution to Mars paleoclimate., Comment: Accepted in Icarus (36 pages, 12 figures)

The classical habitable zone is the circular region around a star in which liquid water could exist on the surface of a rocky planet. The outer edge of the traditional N2-CO2-H2O habitable zone (HZ) extends out to nearly 1.7 AU in our Solar System, beyond which condensation and scattering by CO2 outstrips its greenhouse capacity. Here, we show that volcanic outgassing of atmospheric H2 on a planet near the outer edge can extend the habitable zone out to ~2.4 AU in our solar system. This wider volcanic hydrogen habitable zone (N2-CO2-H2O-H2) can be sustained as long as volcanic H2 output offsets its escape from the top of the atmosphere. We use a single-column radiative-convective climate model to compute the HZ limits of this volcanic hydrogen habitable zone for hydrogen concentrations between 1% and 50%, assuming diffusion-limited atmospheric escape. At a hydrogen concentration of 50%, the effective stellar flux required to support the outer edge decreases by ~35% to 60% for M to A stars. The corresponding orbital distances increase by ~30% to 60%. The inner edge of this HZ only moves out by ~0.1 to 4% relative to the classical HZ because H2 warming is reduced in dense H2O atmospheres. The atmospheric scale heights of such volcanic H2 atmospheres near the outer edge of the HZ also increase, facilitating remote detection of atmospheric signatures., Comment: 13 pages, 3 figures, 2 tables (published in The Astrophysical Journal Letters)

The presence of the ancient valley networks on Mars indicates that the climate at 3.8 Ga was warm enough to allow substantial liquid water to flow on the martian surface for extended periods of time. However, the mechanism for producing this warming continues to be debated. One hypothesis is that Mars could have been kept warm by global cirrus cloud decks in a CO2-H2O atmosphere containing at least 0.25 bar of CO2 (Urata and Toon, 2013). Initial warming from some other process, e.g., impacts, would be required to make this model work. Those results were generated using the CAM 3-D global climate model. Here, we use a single-column radiative-convective climate model to further investigate the cirrus cloud warming hypothesis. Our calculations indicate that cirrus cloud decks could have produced global mean surface temperatures above freezing, but only if cirrus cloud cover approaches ~75 - 100% and if other cloud properties (e.g., height, optical depth, particle size) are chosen favorably. However, at more realistic cirrus cloud fractions, or if cloud parameters are not optimal, cirrus clouds do not provide the necessary warming, suggesting that other greenhouse mechanisms are needed., Comment: Accepted for publication in Icarus (33 pages, 12 figures, 8 Tables)

Once a star leaves the main sequence and becomes a red giant, its Habitable Zone (HZ) moves outward, promoting detectable habitable conditions at larger orbital distances. We use a one-dimensional radiative-convective climate and stellar evolutionary models to calculate post-MS HZ distances for a grid of stars from 3,700K to 10,000K (~M1 to A5 stellar types) for different stellar metallicities. The post-MS HZ limits are comparable to the distances of known directly imaged planets. We model the stellar as well as planetary atmospheric mass loss during the Red Giant Branch (RGB) and Asymptotic Giant Branch (AGB) phases for super-Moons to super-Earths. A planet can stay between 200 million years up to 9 Gyr in the post-MS HZ for our hottest and coldest grid stars, respectively, assuming solar metallicity. These numbers increase for increased stellar metallicity. Total atmospheric erosion only occurs for planets in close-in orbits. The post-MS HZ orbital distances are within detection capabilities of direct imaging techniques., Comment: Published in The Astrophysical Journal (28 pages, 7 figures, 8 tables)

A recent study by Ramirez et al. (2014) demonstrated that an atmosphere with 1.3-4 bar of CO2 and H2O, in addition to 5-20% H2, could have raised the mean annual and global surface temperature of early Mars above the freezing point of water. Such warm temperatures appear necessary to generate the rainfall (or snowfall) amounts required to carve the ancient martian valleys. Here, we use our best estimates for early martian outgassing rates, along with a 1-D photochemical model, to assess the conversion efficiency of CO, CH4, and H2S to CO2, SO2, and H2. Our outgassing estimates assume that Mars was actively recycling volatiles between its crust and interior, as Earth does today. H2 production from serpentinization and deposition of banded iron-formations is also considered. Under these assumptions, maintaining an H2 concentration of ~1-2% by volume is achievable, but reaching 5% H2 requires additional H2 sources or a slowing of the hydrogen escape rate below the diffusion limit. If the early martian atmosphere was indeed H2-rich, we might be able to see evidence of this in the rock record. The hypothesis proposed here is consistent with new data from the Curiosity Rover, which show evidence for a long-lived lake in Gale Crater near Mt. Sharp. It is also consistent with measured oxygen fugacities of martian meteorites, which show evidence for progressive mantle oxidation over time., Comment: 23 pages, 9 figures, published Icarus

We calculate the pre-main-sequence HZ for stars of spectral classes F to M. The spatial distribution of liquid water and its change during the pre-main-sequence phase of protoplanetary systems is important in understanding how planets become habitable. Such worlds are interesting targets for future missions because the coolest stars could provide habitable conditions for up to 2.5 billion years post-accretion. Moreover, for a given star type, planetary systems are more easily resolved because of higher pre-main-sequence stellar luminosities, resulting in larger planet to star separation for cool stars than is the case for the traditional main-sequence (MS) habitable zone (HZ). We use 1D radiative-convective climate and stellar evolutionary models to calculate pre-main-sequence HZ distances for F1 to M8 stellar types. We also show that accreting planets that are later located in the traditional MS HZ orbiting stars cooler than a K5 (including the full range of M-stars) receive stellar fluxes that exceed the runaway greenhouse threshold, and thus may lose substantial amounts of water initially delivered to them. We predict that M-star planets need to initially accrete more water than Earth did or, alternatively, have additional water delivered later during the long pre-main-sequence phase to remain habitable. Our findings are also consistent with recent claims that Venus lost its water during accretion., Comment: Accepted into "The Astrophysical Journal Letters" on Nov. 5, 2014 (appearing in Vol. 798, Issue 1, January 2015)

The presence of valleys on ancient terrains of Mars suggest that liquid water flowed on the martian surface 3.8 billion years ago or before. The above-freezing temperatures required to explain valley formation could have been transient, in response to frequent large meteorite impacts on early Mars, or they could have been caused by long-lived greenhouse warming. Climate models that consider only the greenhouse gases carbon dioxide and water vapor have been unable to recreate warm surface conditions, given the lower solar luminosity at that time. Here we use a one-dimensional climate model to demonstrate that an atmosphere containing 1.3-4 bar of CO2 and water vapor, along with 5 to 20 percent H2, could have raised the mean surface temperature of early Mars above the freezing point of water. Vigorous volcanic outgassing from a highly reduced early martian mantle is expected to provide sufficient atmospheric H2 and CO2, the latter from the photochemical oxidation of outgassed CH4 and CO, to form a CO2-H2 greenhouse. Such a dense early martian atmosphere is consistent with independent estimates of surface pressure based on cratering data., Comment: 48 pages, 12 figures, and 4 tables. The official Nature Geoscience version is found here: http://www.nature.com/ngeo/journal/v7/n1/full/ngeo2000.html

The ongoing discoveries of extrasolar planets are unveiling a wide range of terrestrial mass (size) planets around their host stars. In this letter, we present estimates of habitable zones (HZs) around stars with stellar effective temperatures in the range 2600 K - 7200 K, for planetary masses between 0.1 ME and 5 ME. Assuming H2O (inner HZ) and CO2 (outer HZ) dominated atmospheres, and scaling the background N2 atmospheric pressure with the radius of the planet, our results indicate that larger planets have wider HZs than do smaller ones. Specifically, with the assumption that smaller planets will have less dense atmospheres, the inner edge of the HZ (runaway greenhouse limit) moves outward (~10% lower than Earth flux) for low mass planets due to larger greenhouse effect arising from the increased H2O column depth. For larger planets, the H2O column depth is smaller, and higher temperatures are needed before water vapor completely dominates the outgoing longwave radiation. Hence the inner edge moves inward (7% higher than Earth's flux). The outer HZ changes little due to the competing effects of the greenhouse effect and an increase in albedo. New, 3-D climate model results from other groups are also summarized, and we argue that further, independent studies are needed to verify their predictions. Combined with our previous work, the results presented here provide refined estimates of HZs around main-sequence stars and provide a step towards a more comprehensive analysis of HZs., Comment: In press, Astrophysical Journal Letters. Author affiliation updated. References added. Analytical expression to calculate updated Habitable Zones is provided. An online Habitable Zone calculator, and a FORTRAN code with coefficient data to calculate updated HZs, is available at: http://www3.geosc.psu.edu/~ruk15/planets/

The habitable zone (HZ) around a star is typically defined as the region where a rocky planet can maintain liquid water on its surface. That definition is appropriate, because this allows for the possibility that carbon-based, photosynthetic life exists on the planet in sufficient abundance to modify the planet's atmosphere in a way that might be remotely detected. Exactly what conditions are needed, however, to maintain liquid water remains a topic for debate. Historically, modelers have restricted themselves to water-rich planets with CO2 and H2O as the only important greenhouse gases. More recently, some researchers have suggested broadening the definition to include arid, 'Dune' planets on the inner edge and planets with captured H2 atmospheres on the outer edge, thereby greatly increasing the HZ width. Such planets could exist, but we demonstrate that an inner edge limit of 0.59 AU or less is physically unrealistic. We further argue that conservative HZ definitions should be used for designing future space-based telescopes, but that optimistic definitions may be useful in interpreting the data from such missions. In terms of effective solar flux, Seff, the recently recalculated HZ boundaries are: recent Venus-1.78, runaway greenhouse-1.04, moist greenhouse-1.01, maximum greenhouse-0.35, early Mars-0.32. Based on a combination of different HZ definitions, the frequency of potentially Earth-like planets around late-K and M stars observed by Kepler is in the range of 0.4-0.5., Comment: Typo in the third author name corrected. To be published in Proceedings of the National Academy of Sciences (PNAS) special issue on Exoplanets. Article + Supplementary Information available at http://www.pnas.org/content/early/2013/11/20/1309107110.full.pdf+html?with-ds=yes

This paper has been withdrawn by the author in favor of a private review., Comment: This paper has been withdrawn by the author in favor of a private review

Identifying terrestrial planets in the habitable zones (HZs) of other stars is one of the primary goals of ongoing radial velocity and transit exoplanet surveys and proposed future space missions. Most current estimates of the boundaries of the HZ are based on 1-D, cloud-free, climate model calculations by Kasting et al.(1993). The inner edge of the HZ in Kasting et al.(1993) model was determined by loss of water, and the outer edge was determined by the maximum greenhouse provided by a CO2 atmosphere. A conservative estimate for the width of the HZ from this model in our Solar system is 0.95-1.67 AU. Here, an updated 1-D radiative-convective, cloud-free climate model is used to obtain new estimates for HZ widths around F, G, K and M stars. New H2O and CO2 absorption coefficients, derived from the HITRAN 2008 and HITEMP 2010 line-by-line databases, are important improvements to the climate model. According to the new model, the water loss (inner HZ) and maximum greenhouse (outer HZ) limits for our Solar System are at 0.99 AU and 1.70 AU, respectively, suggesting that the present Earth lies near the inner edge. Additional calculations are performed for stars with effective temperatures between 2600 K and 7200 K, and the results are presented in parametric form, making them easy to apply to actual stars. The new model indicates that, near the inner edge of the HZ, there is no clear distinction between runaway greenhouse and water loss limits for stars with T_{eff} ~< 5000 K which has implications for ongoing planet searches around K and M stars. To assess the potential habitability of extrasolar terrestrial planets, we propose using stellar flux incident on a planet rather than equilibrium temperature. Our model does not include the radiative effects of clouds; thus, the actual HZ boundaries may extend further in both directions than the estimates just given., Comment: (updated version) Accepted to Astrophysical Journal. Additional references added. Typo in Water Rayleigh scattering expression corrected. An online habitable zone calculator (and a FORTRAN code) is available at the first author's website or at http://depts.washington.edu/naivpl/content/hz-calculator