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1. GEMAS: Chemical weathering of silicate parent materials revealed by agricultural soil of Europe

Author

Albanese, S., Andersson, M., Baritz, R., Batista, M.J., Bel-lan, A., Cicchella, D., De Vivo, B., De Vos, W., Dinelli, E., Ďuriš, M., Dusza-Dobek, A., Eklund, M., Ernstsen, V., Filzmoser, P., Flem, B., Flight, D.M.A., Forrester, S., Fuchs, M., Fügedi, U., Gilucis, A., Gosar, M., Gregorauskiene, V., De Groot, W., Gulan, A., Halamić, J., Haslinger, E., Hayoz, P., Hoffmann, R., Hoogewerff, J., Hrvatovic, H., Husnjak, S., Janik, L., Jordan, G., Kaminari, M., Kirby, J., Kivisilla, J., Klos, V., Krone, F., Kwećko, P., Kuti, L., Lima, A., Locutura, J., Lucivjansky, D.P., Mann, A., Mackovych, D., Matschullat, J., McLaughlin, M., Malyuk, B.I., Maquil, R., Meuli, R.G., Mol, G., O'Connor, P., Oorts, R.K., Ottesen, R.T., Pasieczna, A., Petersell, W., Pfleiderer, S., Poňavič, M., Pramuka, S., Prazeres, C., Rauch, U., Radusinović, S., Salpeteur, I., Scanlon, R., Schedl, A., Scheib, A.J., Schoeters, I., Šefčik, P., Sellersjö, E., Skopljak, F., Slaninka, I., Šorša, A., Srvkota, R., Stafilov, T., Tarvainen, T., Trendavilov, V., Valera, P., Verougstraete, V., Vidojević, D., Zissimos, A., Zomeni, Z., Négrel, Philippe, Ladenberger, Anna, Reimann, Clemens, Demetriades, Alecos, Birke, Manfred, and Sadeghi, Martiya

Published
2023
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2. GEMAS: Geochemical distribution of Mg in agricultural soil of Europe

Author

Albanese, S., Andersson, M., Baritz, R., Batista, M.J., Bel-lan, A., Cicchella, D., De Vivo, B., De Vos, W., Dinelli, E., Ďuriš, M., Dusza-Dobek, A., Eklund, M., Ernstsen, V., Filzmoser, P., Flem, B., Flight, D.M.A., Forrester, S., Fuchs, M., Fügedi, U., Gilucis, A., Gosar, M., Gregorauskiene, V., De Groot, W., Gulan, A., Halamić, J., Haslinger, E., Hayoz, P., Hoffmann, R., Hoogewerff, J., Hrvatovic, H., Husnjak, S., Janik, L., Jordan, G., Kaminari, M., Kirby, J., Kivisilla, J., Klos, V., Krone, F., Kwećko, P., Kuti, L., Lima, A., Locutura, J., Lucivjansky, D.P., Mann, A., Mackovych, D., Matschullat, J., McLaughlin, M., Malyuk, B.I., Maquil, R., Meuli, R.G., Mol, G., O'Connor, P., Oorts, R.K., Ottesen, R.T., Pasieczna, A., Petersell, W., Pfleiderer, S., Poňavič, M., Pramuka, S., Prazeres, C., Rauch, U., Radusinović, S., Salpeteur, I., Scanlon, R., Schedl, A., Scheib, A.J., Schoeters, I., Šefčik, P., Sellersjö, E., Skopljak, F., Slaninka, I., Šorša, A., Srvkota, R., Stafilov, T., Tarvainen, T., Trendavilov, V., Valera, P., Verougstraete, V., Vidojević, D., Zissimos, A., Zomeni, Z., Négrel, Philippe, Ladenberger, Anna, Reimann, Clemens, Birke, Manfred, Demetriades, Alecos, and Sadeghi, Martiya

Published
2021
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3. Use of GEMAS data for risk assessment of cadmium in European agricultural and grazing land soil under the REACH Regulation

Author

Birke, M., Reimann, C., Oorts, K., Uwe, R., Alecos, D., Dinelli, E., Ladenberger, A., Halamić, J., Mateja, G., Jähne Klingberg, F., Andersson, M., Baritz, R., Batista, M. J., Bel Ian, A., Cicchella, D., De Vos, W., Duris, M., Dusza Dobek, A., Eggen, O. A., Eklund, M., Ernsten, V., Filzmoser, P., Flight, D. M. A., Forrester, S., Fügedi, U., Gilcucis, A., Gregorauskiene, V., De Groot, W., Gulan, A., Haslinger, E., Hayoz, P., Hoogewerff, J., Hrvatovic, H., Husnjak, S., Janik, L., Jordan, G., Kaminari, M., Kirby, J., Klos, V., Kwecko, P., Kuti, L., Locutura, J., Lucivjansky, P., Mann, A., Mackovych, D., Mclaughlin, M., Malyuk, B. I., Maquil, R., Meuli, R. G., Mol, G., Negrel, P., ’Connor, P. O, Ottesen, R. T., Pasnieczna, A., Petersell, V., Pfleiderer, S., Ponavi c, M., Prazeres, C., Radusinovic, S., Salpeteur, I., Scanlon, R., Schedl, A., Scheib, A., Schoeters, I., Sefcik, P., Sellersjo, E., Slaninka, I., Soriano Disla, J. M., Sorsa, A., Svrkota, R., Stafilov, T., Tarvainen, T., Tendavilov, V., Valera, P., Verougstraete, V., Vidojevic, D., Zomeni, Z., Zissimos, A., ALBANESE, STEFANO, DE VIVO, BENEDETTO, LIMA, ANNAMARIA, Birke, M., Reimann, C., Oorts, K., Uwe, R., Alecos, D., Dinelli, E., Ladenberger, A., Halamić, J., Mateja, G., Jähne Klingberg, F., Albanese, Stefano, Andersson, M., Baritz, R., Batista, M. J., Bel Ian, A., Cicchella, D., DE VIVO, Benedetto, De Vos, W., Duris, M., Dusza Dobek, A., Eggen, O. A., Eklund, M., Ernsten, V., Filzmoser, P., Flight, D. M. A., Forrester, S., Fügedi, U., Gilcucis, A., Gregorauskiene, V., De Groot, W., Gulan, A., Haslinger, E., Hayoz, P., Hoogewerff, J., Hrvatovic, H., Husnjak, S., Janik, L., Jordan, G., Kaminari, M., Kirby, J., Klos, V., Kwecko, P., Kuti, L., Lima, Annamaria, Locutura, J., Lucivjansky, P., Mann, A., Mackovych, D., Mclaughlin, M., Malyuk, B. I., Maquil, R., Meuli, R. G., Mol, G., Negrel, P., ’Connor, P. O, Ottesen, R. T., Pasnieczna, A., Petersell, V., Pfleiderer, S., Ponavi c, M., Prazeres, C., Radusinovic, S., Salpeteur, I., Scanlon, R., Schedl, A., Scheib, A., Schoeters, I., Sefcik, P., Sellersjo, E., Slaninka, I., Soriano Disla, J. M., Sorsa, A., Svrkota, R., Stafilov, T., Tarvainen, T., Tendavilov, V., Valera, P., Verougstraete, V., Vidojevic, D., Zomeni, Z., Zissimos, A., Birke, Manfred, Reimann, Clemen, Oorts, Koen, Rauch, Uwe, Demetriades, Aleco, Dinelli, Enrico, Ladenberger, Anna, Halamić, Josip, Gosar, Mateja, and Jähne-Klingberg, Fabian

Subjects
Pollution, agricultural soil, grazing land soil, risk assessment, REACH, cadmium, Soil test, media_common.quotation_subject, chemistry.chemical_element, 010501 environmental sciences, 010502 geochemistry & geophysics, Agricultural soil, 01 natural sciences, Ecology and Environment, Geochemistry and Petrology, Grazing, Environmental Chemistry, Risk assessment, 0105 earth and related environmental sciences, media_common, Hydrology, Cadmium, business.industry, Forestry, Expert group, Chemistry, chemistry, Agriculture, Soil water, Earth Sciences, business, Grazing land soil
Abstract

Over 4000 soil samples were collected for the “Geochemical Mapping of Agricultural and Grazing Land Soil of Europe” (GEMAS) project carried out by the EuroGeoSurveys Geochemistry Expert Group. Cadmium concentrations are reported for the

Published
2016
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4. Identification of the co-existence of low total organic carbon contents and low pH values in agricultural soil in north-central Europe using hot spot analysis based on GEMAS project data

Author

Xu, Haofan, Demetriades, Alecos, Reimann, Clemens, Jimenez, Juan J., Filser, Juliane, Zhang, Chaosheng, Albanese, S., Andersson, M., Baritz, R., Batista, M. J., Bel-lan, A., Birke, M., Cicchella, D., De Vivo, B., De Vos, W., Dinelli, E., Duris, M., Dusza-Dobek, A., Eklund, M., Ernstsen, V, Filzmoser, P., Flem, B., Flight, D. M. A., Forrester, S., Fuchs, M., Fugedi, U., Gilucis, A., Gosar, M., Gregorauskiene, V, De Groot, W., Gulan, A., Halamic, J., Haslinger, E., Hayoz, P., Hoffmann, R., Hoogewerff, J., Hrvatovic, H., Husnjak, S., Janik, L., Jordan, G., Kirby, J., Klos, V, Krone, F., Kwecko, P., Kuti, L., Ladenberger, A., Lima, A., Locutura, J., Lucivjansky, P., Mann, A., Mackovych, D., McLaughlin, M., Malyuk, B., I, Maquil, R., Matschullat, J., Meuli, R. G., Mol, G., Negrel, P., O'Connor, P., Oorts, K., Pasieczna, A., Petersell, V, Pfleiderer, S., Ponavic, M., Prazeres, C., Rauch, U., Radusinovic, S., Sadeghi, M., Salpeteur, I, Scanlon, R., Schedl, A., Scheib, A., Schoeters, I, Sellersjo, E., Slaninka, I, Soriano-Disla, J. M., Sorsa, A., Svrkota, R., Stafilov, T., Tarvainen, T., Trendavilov, V, Valera, P., Verougstraete, V., Vidojevi, D., Zissimos, A., Zomeni, Z., Xu H., Demetriades A., Reimann C., Jimenez J.J., Filser J., Zhang C., GEMAS Project Team: Albanese S., Andersson M., Baritz R., Batista M.J., Bel-lan A., Birke M., Cicchella D., De Vivo B., De Vos W., Dinelli E., Ďuriš M., Dusza-Dobek A., Eklund M., Ernstsen V., Filzmoser P., Flem B., Flight D.M.A., Forrester S., Fuchs M., Fügedi U., Gilucis A., Gosar M., Gregorauskiene V., De Groot W., Gulan A., Halamić J., Haslinger E., Hayoz P., Hoffmann R., Hoogewerff J., Hrvatovic H., Husnjak S., Janik L., Jordan G., Kirby J., Klos V., Krone F., Kwecko P., Kuti L., Ladenberger A., Lima A., Locutura J., Lucivjansky P., Mann A., Mackovych D., McLaughlin M., Malyuk B.I., Maquil R., Matschullat J., Meuli R.G., Mol G., Négrel P., O'Connor P., Oorts K., Pasieczna A., Petersell V., Pfleiderer S., Poňavič M., Prazeres C., Rauch U., Radusinović S., Sadeghi M., Salpeteur I., Scanlon R., Schedl A., Scheib A., Schoeters I., Sellersjö E., Slaninka I., Soriano-Disla J.M., Šorša A., Svrkota R., Stafilov T., Tarvainen T., Trendavilov V., Valera P., Verougstraete V., Vidojević D., Zissimos A., Zomeni Z., Haofan, Xu, Alecos, Demetriade, Clemens, Reimann, Juan J, Jiménez, Juliane, Filser, Chaosheng, Zhang, Albanese, S., Andersson, M., Baritz, R., Batista, M. J., Bel-lan, A., Birke, M., Cicchella, D., De Vivo, B., De Vos, W., Dinelli, E., Ďuriš, M., Dusza-Dobek, A., Eklund, M., Ernstsen, V., Filzmoser, P., Flem, B., Flight, D. M. A., Forrester, S., Fuchs, M., Fügedi, U., Gilucis, A., Gosar, M., Gregorauskiene, V., De Groot, W., Gulan, A., Halamić, J., Haslinger, E., Hayoz, P., Hoffmann, R., Hoogewerff, J., Hrvatovic, H., Husnjak, S., Janik, L., Jordan, G., Kirby, J., Klos, V., Krone, F., Kwecko, P., Kuti, L., Ladenberger, A., Lima, A., Locutura, J., Lucivjansky, P., Mann, A., Mackovych, D., Mclaughlin, M., Malyuk, B. I., Maquil, R., Matschullat, J., Meuli, R. G., Mol, G., Négrel, P., O'Connor, P., Oorts, K., Pasieczna, A., Petersell, V., Pfleiderer, S., Poňavič, M., Prazeres, C., Rauch, U., Radusinović, S., Sadeghi, M., Salpeteur, I., Scanlon, R., Schedl, A., Scheib, A., Schoeters, I., Sellersjö, E., Slaninka, I., Soriano-Disla, J. M., Šorša, A., Svrkota, R., Stafilov, T., Tarvainen, T., Trendavilov, V., Valera, P., Verougstraete, V., Vidojević, D., Zissimos, A., and Zomeni, Z.

Subjects
Pollution, Environmental Engineering, 010504 meteorology & atmospheric sciences, Hot spot analysis, Hot spot analysi, media_common.quotation_subject, Hot spot (veterinary medicine), 010501 environmental sciences, 01 natural sciences, GEMAS, chemistry.chemical_compound, Environmental Chemistry, European agricultural soil, TOC, pH, Waste Management and Disposal, 0105 earth and related environmental sciences, media_common, Total organic carbon, North central, business.industry, chemistry, Agriculture, Environmental chemistry, Carbon dioxide, Spatial ecology, Environmental science, Soil fertility, business
Abstract

Total organic carbon (TOC) contents in agricultural soil are presently receiving increased attention, not only because of their relationship to soil fertility, but also due to the sequestration of organic carbon in soil to reduce carbon dioxide emissions. In this research, the spatial patterns of TOC and its relationship with pH at the European scale were studied using hot spot analysis based on the agricultural soil results of the Geochemical Mapping of Agricultural Soil (GEMAS) project. The hot and cold spot maps revealed the overall spatial patterns showing a negative correlation between TOC contents and pH values in European agricultural soil. High TOC contents accompanying low pH values in the north-eastern part of Europe (e.g., Fennoscandia), and low TOC with high pH values in the southern part (e.g., Spain. Italy, Balkan countries). A special feature of co-existence of comparatively low TOC contents and low pH values in north-central Europe was also identified on hot and cold spot analysis maps. It has been found that these patterns are strongly related to the high concentration of SiO2 (quartz) in the coarse-textured glacial sediments in north-central Europe. The hot spot analysis was effective, therefore, in highlighting the spatial patterns of TOC in European agricultural soil and helpful to identify hidden patterns. (C) 2019 Elsevier B.V. All rights reserved.

Published
2019
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5. Bioavailable 87Sr/86Sr in European soils:A baseline for provenancing studies

Author

Hoogewerff, Jurian A., Reimann, Clemens, Ueckermann, Enriette, Frei, Robert, Frei, Karin M., van Aswegen, Thalita, Stirling, Claudine, Reid, Malcolm, Clayton, Aaron, Ladenberger, Anna, Albanese, S., Andersson, M., Baritz, R., Batista, M. J., Bel-Ian, A., Birke, M., Cicchella, D., Demetriades, A., De Vivo, B., De Vos, W., Dinelli, E., Duris, M., Dusza-Dobek, A., Eggen, O. A., Eklund, M., Ernstsen, V., Filzmoser, P., Flight, D. M. A., Forrester, S., Fuchs, M., Fugedi, U., Gilucis, A., Gregorauskiene, V, De Groot, W., Gulan, A., Halamic, J., Haslinger, E., Hayoz, P., Hoffmann, R., Hrvatovic, H., Husnjak, S., Janik, L., Jordan, G., Kaminari, M., Kirby, J., Kivisilla, J., Klos, V, Krone, F., Kwecko, F., Kuti, L., Lima, A., Locutura, J., Lucivjansky, D. P., Mann, A., Mackovych, D., Matschullat, J., McLaughlin, M., Malyuk, B., I, Maquil, R., Meuli, R. G., Mol, G., Negrel, P., Connor, O., Oorts, R. K., Ottesen, R. T., Pasieczna, A., Petersell, W., Ponavic, M., Pramuka, S., Prazeres, C., Rauch, U., Radusinovic, S., Reimann, C., Sadeghi, M., Salpeteur, I, Scanlon, R., Schedl, A., Scheib, A. J., Schoeters, I, Sefcik, P., Sellersjo, E., Skopijak, F., Slaninka, I, Soriano-Disla, J. M., Sorsa, A., Srvkota, R., Stafilov, T., Tarvainen, T., Trendavilov, V, Valera, P., Verougstraete, V., Vidojevic, D., Zissimos, A., Zomeni, Z., Hoogewerff, Jurian A., Reimann, Clemens, Ueckermann, Enriette, Frei, Robert, Frei, Karin M., van Aswegen, Thalita, Stirling, Claudine, Reid, Malcolm, Clayton, Aaron, Ladenberger, Anna, Albanese, S., Andersson, M., Baritz, R., Batista, M. J., Bel-Ian, A., Birke, M., Cicchella, D., Demetriades, A., De Vivo, B., De Vos, W., Dinelli, E., Duris, M., Dusza-Dobek, A., Eggen, O. A., Eklund, M., Ernstsen, V., Filzmoser, P., Flight, D. M. A., Forrester, S., Fuchs, M., Fugedi, U., Gilucis, A., Gregorauskiene, V, De Groot, W., Gulan, A., Halamic, J., Haslinger, E., Hayoz, P., Hoffmann, R., Hrvatovic, H., Husnjak, S., Janik, L., Jordan, G., Kaminari, M., Kirby, J., Kivisilla, J., Klos, V, Krone, F., Kwecko, F., Kuti, L., Lima, A., Locutura, J., Lucivjansky, D. P., Mann, A., Mackovych, D., Matschullat, J., McLaughlin, M., Malyuk, B., I, Maquil, R., Meuli, R. G., Mol, G., Negrel, P., Connor, O., Oorts, R. K., Ottesen, R. T., Pasieczna, A., Petersell, W., Ponavic, M., Pramuka, S., Prazeres, C., Rauch, U., Radusinovic, S., Reimann, C., Sadeghi, M., Salpeteur, I, Scanlon, R., Schedl, A., Scheib, A. J., Schoeters, I, Sefcik, P., Sellersjo, E., Skopijak, F., Slaninka, I, Soriano-Disla, J. M., Sorsa, A., Srvkota, R., Stafilov, T., Tarvainen, T., Trendavilov, V, Valera, P., Verougstraete, V., Vidojevic, D., Zissimos, A., and Zomeni, Z.

Published
2019

6. GEMAS: PREDICTION OF SOLID-SOLUTION PHASE PARTITIONING COEFFICIENTS (K-d) FOR OXOANIONS AND BORIC ACID IN SOILS USING MID-INFRARED DIFFUSE REFLECTANCE SPECTROSCOPY

Author

Janik, L. J., Forrester, S. T., Soriano Disla, J. M., Kirby, J. K., Mclaughlin, M. J., Reimann, C., ALBANESE, STEFANO, Andersson, M., Baritz, R., Batista, M. J., Bel lan, A., Birke, M., Cicchella, D., Demetriades, A., DE VIVO, BENEDETTO, De Vos, W., Dinelli, E., duriš, M., Dusza Dobek, A., Eggen, O. A., Eklund, M., Ernstsen, V., Filzmoser, P., Flight, D. M. A., Fuchs, M., Fügedi, U., Gilucis, A., Gosar, M., Gregorauskiene, V., De Groot, W., Gulan, A., Halamic, J., Haslinger, E., Hayoz, P., Hoffmann, R., Hoogewerff, J., Hrvatovic, H., Husnjak, S., Jordan, G., Kaminari, M., Klos, V., Krone, F., Kwecko, P., Kuti, L., Ladenberger, A., LIMA, ANNAMARIA, Locutura, J., Lucivjansky, P., Mann, A., Mackovych, D., Malyuk, B. I., Maquil, R., Meuli, R. G., Mol, G., Negrel, P., O’Connor, P., Oorts, K., Ottesen, R. T., Pasieczna, A., Petersell, W., Pfleiderer, S., Ponnavic, M., Prazeres, C., Rauch, U., Radusinovic, S., Sadeghi, M., Salpeteur, I., Scanlon, R., Schedl, A., Scheib, A. J., Schoeters, I., Sellersj€o, E., Slaninka, I., Šorša, A., Srvkota, R., Stafilov, T., Tarvainen, T., Trendavilov, V., Valera, P., Verougstraete, V., Vidojevic, D., Zomeni, Z., Janik, L. J., Forrester, S. T., Soriano Disla, J. M., Kirby, J. K., Mclaughlin, M. J., Reimann, C., Albanese, Stefano, Andersson, M., Baritz, R., Batista, M. J., Bel lan, A., Birke, M., Cicchella, D., Demetriades, A., DE VIVO, Benedetto, De Vos, W., Dinelli, E., duriš, M., Dusza Dobek, A., Eggen, O. A., Eklund, M., Ernstsen, V., Filzmoser, P., Flight, D. M. A., Fuchs, M., Fügedi, U., Gilucis, A., Gosar, M., Gregorauskiene, V., De Groot, W., Gulan, A., Halamic, J., Haslinger, E., Hayoz, P., Hoffmann, R., Hoogewerff, J., Hrvatovic, H., Husnjak, S., Jordan, G., Kaminari, M., Klos, V., Krone, F., Kwecko, P., Kuti, L., Ladenberger, A., Lima, Annamaria, Locutura, J., Lucivjansky, P., Mann, A., Mackovych, D., Malyuk, B. I., Maquil, R., Meuli, R. G., Mol, G., Negrel, P., O’Connor, P., Oorts, K., Ottesen, R. T., Pasieczna, A., Petersell, W., Pfleiderer, S., Ponnavic, M., Prazeres, C., Rauch, U., Radusinovic, S., Sadeghi, M., Salpeteur, I., Scanlon, R., Schedl, A., Scheib, A. J., Schoeters, I., Sellersj€o, E., Slaninka, I., Šorša, A., Srvkota, R., Stafilov, T., Tarvainen, T., Trendavilov, V., Valera, P., Verougstraete, V., Vidojevic, D., and Zomeni, Z.

Subjects
Anions, Soil, Solid-solution partitioning coefficients (K-d), Metal, metalloid, Anions Metal/metalloid Solid-solution partitioning coefficients (Kd) Mid-infrared spectroscopy Partial least squares regression Soil, Mid-infrared spectroscopy, Partial least squares regression
Abstract

The authors' aim was to develop rapid and inexpensive regression models for the prediction of partitioning coefficients (K-d), defined as the ratio of the total or surface-bound metal/metalloid concentration of the solid phase to the total concentration in the solution phase. Values of K-d were measured for boric acid (B[OH](3)(0)) and selected added soluble oxoanions: molybdate (MoO42-), antimonate (Sb[OH](6-)), selenate (SeO42-), tellurate (TeO42-) and vanadate (VO43-). Models were developed using approximately 500 spectrally representative soils of the Geochemical Mapping of Agricultural Soils of Europe (GEMAS) program. These calibration soils represented the major properties of the entire 4813 soils of the GEMAS project. Multiple linear regression (MLR) from soil properties, partial least-squares regression (PLSR) using mid-infrared diffuse reflectance Fourier-transformed (DRIFT) spectra, and models using DRIFT spectra plus analytical pH values (DRIFT+pH), were compared with predicted log Kd+1 values. Apart from selenate (R-2=0.43), the DRIFT+pH calibrations resulted in marginally better models to predict log Kd+1 values (R-2=0.62-0.79), compared with those from PSLR-DRIFT (R-2=0.61-0.72) and MLR (R-2=0.54-0.79). The DRIFT+pH calibrations were applied to the prediction of log Kd+1 values in the remaining 4313 soils. An example map of predicted log Kd+1 values for added soluble MoO42- in soils across Europe is presented. The DRIFT+pH PLSR models provided a rapid and inexpensive tool to assess the risk of mobility and potential availability of boric acid and selected oxoanions in European soils. For these models to be used in the prediction of log Kd+1 values in soils globally, additional research will be needed to determine if soil variability is accounted on the calibration. Environ Toxicol Chem 2014;9999:1-12. (c) 2014 SETAC

Published
2015
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7. Geochemical fingerprinting and source discrimination of agricultural soils at continental scale

Author

Négrel, P., Sadeghi, M., Ladenberger, A., Reimann, C., Birke, M., Albanese, S., Andersson, M., Baritz, R., Batista, M. J., Bel lan, A., Cicchella, D., Demetriades, A., De Vivo, B., De Vos, W., Duriš, M., Dusza Dobek, A., Eggen, O. A., Eklund, M., Ernstsen, V., Filzmoser, P., Flight, D. M. A., Forrester, S., Fuchs, M., Fügedi, U., Gilucis, A., Gosar, M., Gregorauskiene, V., De Groot, W., Gulan, A., Halamic, J., Haslinger, E., Hayoz, P., Hoffmann, R., Hoogewerff, J., Hrvatovic, H., Husnjak, S., Janik, L., Jordan, G., Kaminari, M., Kirby, J., Kivisilla, J., Klos, V., Krone, F., Kwecko, P., Kuti, L., Lima, A., Locutura, J., Lucivjansky, D. P., Mann, A., Mackovych, D., Mclaughlin, M., Malyuk, B. I., Maquil, R., Meuli, R. G., Mol, G., O'Connor, P., Oorts, R. K., Ottesen, R. T., Pasieczna, A., Petersell, W., Pfleiderer, S., Ponavic, M., Pramuka, S., Prazeres, C., Rauch, U., Radusinovic, S., Salpeteur, I., Scanlon, R., Schedl, A., Scheib, A. J., Schoeters, I., Šefcik, P., Sellersjö, E., Skopljak, F., Slaninka, I., Šorša, A., Srvkota, R., Stafilov, T., Tarvainen, T., Trendavilov, V., Valera, P., Verougstraete, V., Vidojevic, D., Zissimos, A., Z. , Zomeni, DINELLI, ENRICO, Négrel, P., Sadeghi, M., Ladenberger, A., Reimann, C., Birke, M., Albanese, S., Andersson, M., Baritz, R., Batista, M.J., Bel-lan, A., Cicchella, D., Demetriades, A., De Vivo, B., De Vos, W., Dinelli, E., Duriš, M., Dusza-Dobek, A., Eggen, O.A., Eklund, M., Ernstsen, V., Filzmoser, P., Flight, D.M.A., Forrester, S., Fuchs, M., Fügedi, U., Gilucis, A., Gosar, M., Gregorauskiene, V., De Groot, W., Gulan, A., Halamic, J., Haslinger, E., Hayoz, P., Hoffmann, R., Hoogewerff, J., Hrvatovic, H., Husnjak, S., Janik, L., Jordan, G., Kaminari, M., Kirby, J., Kivisilla, J., Klos, V., Krone, F., Kwecko, P., Kuti, L., Lima, A., Locutura, J., Lucivjansky, D.P., Mann, A., Mackovych, D., Mclaughlin, M., Malyuk, B.I., Maquil, R., Meuli, R.G., Mol, G., O'Connor, P., Oorts, R.K., Ottesen, R.T., Pasieczna, A., Petersell, W., Pfleiderer, S., Ponavic, M., Pramuka, S., Prazeres, C., Rauch, U., Radusinovic, S., Salpeteur, I., Scanlon, R., Schedl, A., Scheib, A.J., Schoeters, I., Šefcik, P., Sellersjö, E., Skopljak, F., Slaninka, I., Šorša, A., Srvkota, R., Stafilov, T., Tarvainen, T., Trendavilov, V., Valera, P., Verougstraete, V., Vidojevic, D., Zissimos, A., Z., Zomeni., Bureau de Recherches Géologiques et Minières (BRGM) (BRGM), Geological Survey of Sweden, sgu, Geological Survey of Norway (NGU), Geological Survey of Norway, and Federal Institute for Geosciences and Natural Resources (BGR)

Subjects
Soil map, genetic structures, Soil test, Weathering, Parent material, Mineralogy, Sediment, Geology, 15. Life on land, Soil type, Agricultural soil, Upper continental crust UCC, Geochemistry, Geochemistry and Petrology, [SDU.STU.GC]Sciences of the Universe [physics]/Earth Sciences/Geochemistry, Soil water, Chemical composition
Abstract

International audience; 2108 agricultural soil samples (Ap-horizon, 0–20 cm) were collected in Europe (33 countries, area 5.6 million km2) as part of the recently completed GEMAS (GEochemical Mapping of Agricultural and grazing land Soil) soil mapping project. GEMAS soil data have been used to provide a general view of element origin and mobility with a main focus on source parent material (and source rocks) at the continental scale, either by reference to average crustal abundances or to normalized patterns of element mobility during weathering processes. The survey area covers a large territory with diverse types of soil parent materials, with distinct geological history and a wide range of climate zones, and landscapes.To normalize the chemical composition of European agricultural soil, mean values and standard deviation of the selected elements have been compared to model compositions of the upper continental crust (UCC) and mean European river suspended sediment. Some elements are enriched relative to the UCC (Al, P, Pb, Zr,) whereas others, such as Mg, Na and Sr are depleted. The concept of the UCC extended normalization pattern has been applied to selected elements. The mean values of Rb, K, Y, Ti, Al, Si, Zr, Ce and Fe are very similar to the values from the UCC model, even when standard deviations indicate slight enrichment or depletion. Zirconium has the best fit to the UCC model using both mean value and standard deviation. Lead and Cr are enriched in European soil when compared to the UCC model, but their standard deviation values span a large, particularly towards very low values, which can be interpreted as a lithological effect.GEMAS soil data have been normalized to Al and Na, taking into account the main lithologies of the UCC, in order to discriminate provenance sources. Additionally, sodium normalization highlights variations related to the soluble and insoluble behavior of some elements (e.g., K, Rb versus Ti, Al, Si, V, Y, Zr, Ba, and La, respectively), their reactivity (e.g, Fe, Mn, Zn) and association with carbonates (e.g., Ca and Sr). Maps of Europe showing the spatial distribution of normalized compositions and element ratios reveal difficulties with the use of classical element ratios because of the large lithological differences in compositions of soil parent material. The ratio maps and color composite images extracted from the GEMAS data can help to discriminate the main lithologies in Europe at the regional scale but need to be used with caution due to the complexity of superimposed processes responsible for the soil chemical composition.

Published
2015
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8. GEMAS : Indium in agricultural and grazing land soil of Europe - Its source and geochemical distribution patterns

Author

Ladenberger, Anna, Demetriades, Alecos, Reimann, Clemens, Birke, Manfred, Sadeghi, Martiya, Uhlbäck, Jo, Andersson, Madelen, Jonsson, Erik, Albanese, S., Baritz, R., Batista, M. J., Bel-lan, A., Cicchella, D., De Vivo, B., De Vos, W., Dinelli, E., uri?, M., Dusza-Dobek, A., Eggen, O. A., Eklund, M., Ernstsen, V., Filzmoser, P., Flight, D. M A, Forrester, S., Fuchs, M., Fügedi, U., Gilucis, A., Gosar, M., Gregorauskiene, V., De Groot, W., Gulan, A., Halamic, J., Haslinger, E., Hayoz, P., Hoffmann, R., Hoogewerff, J., Hrvatovic, H., Husnjak, S., Janik, L., Jordan, G., Kaminari, M., Kirby, J., Klos, V., Krone, F., Kwecko, P., Kuti, L., Lima, A., Locutura, J., Lucivjansky, P., Mann, A., Mackovych, D., McLaughlin, M., Malyuk, B. I., Maquil, R., Meuli, R. G., Mol, G., Négrel, P., O'Connor, P., Oorts, K., Ottesen, R. T., Pasieczna, A., Petersell, V., Pfleiderer, S., Ponavic, M., Prazeres, C., Rauch, U., Radusinovic, S., Salpeteur, I., Scanlon, R., Schedl, A., Scheib, A., Schoeters, I., Sellersjö, E., Slaninka, I., Soriano-Disla, J. M., or?a, A., Svrkota, R., Stafilov, T., Tarvainen, T., Trendavilov, V., Valera, P., Verougstraete, V., Vidojevic, D., Zomeni, Z., Ladenberger, A., Demetriades, A., Reimann, C., Birke, M., Sadeghi, M., Uhlbäck, J., Andersson, M., Jonsson, E., Albanese, S., Baritz, R., Batista, M.J., Bel-lan, A., Cicchella, D., De Vivo, B., De Vos, W., Dinelli, E., Ďuriš, M., Dusza-Dobek, A., Eggen, O.A., Eklund, M., Ernstsen, V., Filzmoser, P., Flight, D.M.A., Forrester, S., Fuchs, M., Fügedi, U., Gilucis, A., Gosar, M., Gregorauskiene, V., De Groot, W., Gulan, A., Halamic, J., Haslinger, E., Hayoz, P., Hoffmann, R., Hoogewerff, J., Hrvatovic, H., Husnjak, S., Janik, L., Jordan, G., Kaminari, M., Kirby, J., Klos, V., Krone, F., Kwecko, P., Kuti, L., Lima, A., Locutura, J., Lucivjansky, P., Mann, A., Mackovych, D., Mclaughlin, M., Malyuk, B.I., Maquil, R., Meuli, R.G., Mol, G., Négrel, P., O'Connor, P., Oorts, K., Ottesen, R.T., Pasieczna, A., Petersell, V., Pfleiderer, S., Ponavic, M., Prazeres, C., Rauch, U., Radusinovic, S., Salpeteur, I., Scanlon, R., Schedl, A., Scheib, A., Schoeters, I., Sellersjö, E., Slaninka, I., Soriano-Disla, J.M., Šorša, A., Svrkota, R., Stafilov, T., Tarvainen, T., Trendavilov, V., Valera, P., Verougstraete, V., Vidojevic, D., Zomeni, Z., Uhlback, J., Albanese, Stefano, Batista, M. J., Bel lan, A., DE VIVO, Benedetto, Dusza Dobek, A., Eggen, O. A., Falconi, M., Flight, D. M. A., Halami ć, J., Lima, Annamaria, Malyuk, B. I., Meuli, R. G., Ottesen, R. T., Pfleiderer, S., Poňavič, M., Radusinović, S., Soriano Disla, J. M., Stafilov, T., and Vidojević, D.

Subjects
Mediterranean climate, Hydrology, geography, geography.geographical_feature_category, Land use, Lithology, Iindium, Geochemistry, Agricultural soil, Grazing land soil, Continental-scale, Europe, Weathering, Soil science, Spatial distribution, Karst, Indium, Soil series, Geochemistry and Petrology, Grazing, Economic Geology, Geology
Abstract

Indium is a very rare element, which is usually not reported in geochemical data sets. It is classified as a critical metal, with important applications in the electronics industry, especially in the production of solar panels and liquid-crystal displays (LCDs).Over 4000 samples of agricultural and grazing land soil have been collected for the "Geochemical Mapping of Agricultural and Grazing Land Soil of Europe" (GEMAS) project, carried out by the EuroGeoSurveys Geochemistry Expert Group. Indium concentrations in soil have been analysed using aqua regia extraction followed by ICP-MS. Median values of In for both land use types are nearly identical, 0.0176. mg/kg for agricultural soil and 0.0177. mg/kg for grazing land soil.The spatial distribution patterns of In in European soil are mainly controlled by geology and the presence of Zn and Sn mineralisation. The preference of In to accumulate in the fine-grained fraction of soil with high clay content dominates the major anomaly patterns on the geochemical maps. In the Mediterranean region, secondary In enrichment is visible in karst areas. A notable feature of the In spatial distribution is the large difference between northern and southern Europe, with median values of 0.012 and 0.021. mg. In/kg, respectively, suggesting that, in addition to lithology, weathering and climate are important factors influencing In soil enrichment over time. © 2015 Elsevier B.V.

Published
2015
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9. Geochemical evidence of aeolian deposits in European soils

Author

Scheib A.J., Birke M., Dinelli E., Albanese S., Andersson M., Baritz R., Batista M.J., Bel-lan A., Cicchella D., Demetriades A., De Vivo B., De Vos W., DuriS M., Dusza-Dobek A., Eggen O.A., Eklund M., Ernstsen V., Filzmoser P., Flight D.M.A., Forrester S., Fuchs M., Fugedi U., Gilucis A., Gosar M., Gregorauskiene V., De Groot W., Gulan A., Halamic J., Haslinger E., Hayoz P., Hoffmann R., Hoogewerff J., Hrvatovic H., Husnjak S., Janik L., Jordan G., Kaminari M., Kirby J., Kivisilla J., Klos V., Krone F., Kwecko P., Kuti L., Ladenberger A., Lima A., Locutura J., Lucivjansky D.P., Mann A., Mackovych D., McLaughlin M., Malyuk B.I., Maquil R., Meuli R.G., Mol G., Negrel P., O'Connor P., Oorts R.K., Ottesen R.T., Pasieczna A., Petersell W., Pfleiderer S., Pon aviC M., Pramuka S., Prazeres C., Rauch U., Radusinovic S., Reimann C., Salpeteur I., Sadeghi M., Scanlon R., Schedl A., Schoeters I., SefCik P., Sellersjo E., Skopljak F., Slaninka I., Sor Sa A., Srvkota R., Stafilov T., Tarvainen T., Trendavilov V., Valera P., Verougstraete V., Vidojevic D., Zomeni Z., Scheib, A. J., Birke, M., Dinelli, E, Albanese, Stefano, Andersson, M., Baritz, R., Batista, M. J., BEL LAN, A., Cicchella, D., Demetriades, A., DE VIVO, Benedetto, DE VOS, W., Duris, M., DUSZA DOBEK, A., Eggen, O. A., Eklund, M., Ernstsen, V., Filzmoser, P., Flight, D. M. A., Forrester, S., Fuchs, M., Fugedi, U., Gilucis, A., Gosar, M., Gregorauskiene, V., DE GROOT, W., Gulan, A., Halamic, J., Haslinger, E., Hayoz, P., Hoffmann, R., Hoogewerff, J., Hrvatovic, H., Husnjak, S., Janik, L., Jordan, G., Kaminari, M., Kirby, J., Kivisilla, J., Klos, V., Krone, F., Kwecko, P., Kuti, L., Ladenberger, A., Lima, Annamaria, Locutura, J., Lucivjansky, P., Mann, A., Mackovych, D., Maclughlin, M., Malyuk, B. I., Maquil, R., Meuli, R. G., Mol, G., Négrel, P., O’Connor, P., Oorts, K., Rottesen, R. T., Pasieczna, A., Petersell, V., Pfleiderer, S., Poňavič, M., Pramuka, S., Prazeres, C., Rauch, U., Radusinovic, C., Reimann, C., Salpeteur, I., Sadeghi, M., Scanlon, A., Schedl, A., Schoeters, I., Sefcik, P., Sellersjö, E., Skopljak, F., Slaninka, I., Šorša, A., Srvkota, R., Stafilov, T., Tarvainen, T., Trendavilov, V., Valera, P., Verougstraete, V., Vidojevic, D., and Zomeni, Z.

Subjects
aeolian deposit, genetic structures, soil
Abstract

Hafnium (Hf) and zirconium (Zr) concentrations measured in over 4100 agricultural soil samples from Europe were assessed with the focus on their relationship to the distribution of aeolian deposits, such as loess and coversands. Comparison of extractable (aqua regia; ICP-MS) and total (XRFS) concentrations shows that only 1.0 to 1.7% of the total Hf and Zr is chemically extractable because of the resistant nature of their host minerals. Resistate minerals, such as zircon, are commonly found in the predominantly silty fraction of loess deposits. In this study a statistical analysis of total Hf and Zr soil data from areas with and without loess was carried out to derive threshold values of 10 mg kg−1 (Hf) and 318 mg kg−1 (Zr). These values were subsequently applied across the project area in an attempt to indicate the presence of aeolian deposits. The spatial distribution of abovethreshold concentrations suggests a more extensive and coherent loess belt across central and eastern Europe, providing additional evidence of loess across Brittany, Aquitaine and near the Vosges mountains in France as well as in the basins of central and northern Spain. Above-threshold concentrations were also detected in loess regardless of its thickness, emphasising the importance of the abundance of zircon in the upper part of the soil profile rather than the actual thickness of the deposit. Soil data however, failed to indicate various loess facies within most of the Pannonian Basin, suggesting that this approach only works where deposits contain a sufficient amount of zircon. This may also explain why the extensive coversands across northern Germany and Poland were largely undetected. This study demonstrates that continental-scale soil geochemical data can help identify and map the distribution of zircon-rich loess and coversand, and subsequently enhance and improve current knowledge of the extent of these deposits.

Published
2014
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10. GEMAS: Geochemical distribution of Mg in agricultural soil of Europe

Author

M. Fuchs, P. Kwecko, P. Hayoz, Jörg Matschullat, B. I. Malyuk, Anna Ladenberger, B. De Vivo, Stjepan Husnjak, Rainer Baritz, V. Verougstraete, S. Pfleiderer, E. Haslinger, P. O'Connor, V. Gregorauskiene, Andreas M. Zissimos, L. Janik, Philippe Négrel, M. Eklund, V. Ernstsen, Alecos Demetriades, V. Trendavilov, A. Dusza-Dobek, Jurian Hoogewerff, Clemens Reimann, Martiya Sadeghi, W. De Groot, G. Mol, R. Maquil, E. Sellersjö, A. Bel-lan, Enrico Dinelli, Belinda Flem, M. Kaminari, W. Petersell, Andreas Scheib, Annamaria Lima, Anna Pasieczna, R. Hoffmann, M. Andersson, Paolo Valera, R. Scanlon, V. Klos, I. Slaninka, M. Duris, S. Forrester, S. Pramuka, D. Mackovych, S. Radusinović, U. Fugedi, C. Prazeres, A. Gulan, W. De Vos, A. Mann, Ajka Šorša, Jason K. Kirby, F. Krone, Z. Zomeni, J. Kivisilla, G. Jordan, Manfred Birke, L. Kuti, Rolf Tore Ottesen, Dee Flight, H. Hrvatovic, R. Srvkota, P. Sefcik, I. Salpeteur, Josip Halamić, Peter Filzmoser, D. P. Lucivjansky, Trajče Stafilov, F. Skopljak, M. Ponavic, Mateja Gosar, Stefano Albanese, R. G. Meuli, D. Vidojević, Maria João Batista, R. K. Oorts, A. Schedl, Domenico Cicchella, Timo Tarvainen, J. Locutura, A. Gilucis, I. Schoeters, U. Rauch, Mike J. McLaughlin, Bureau de Recherches Géologiques et Minières (BRGM) (BRGM), Geological Survey of Norway (NGU), Bundesanstalt für Geowissenschaften und Rohstoffe (BGR), Negrel, P., Ladenberger, A., Reimann, C., Birke, M., Demetriades, A., Sadeghi, M., Albanese, S., Andersson, M., Baritz, R., Batista, M. J., Bel-lan, A., Cicchella, D., De Vivo, B., De Vos, W., Dinelli, E., Duris, M., Dusza-Dobek, A., Eklund, M., Ernstsen, V., Filzmoser, P., Flem, B., Flight, D. M. A., Forrester, S., Fuchs, M., Fugedi, U., Gilucis, A., Gosar, M., Gregorauskiene, V., De Groot, W., Gulan, A., Halamic, J., Haslinger, E., Hayoz, P., Hoffmann, R., Hoogewerff, J., Hrvatovic, H., Husnjak, S., Janik, L., Jordan, G., Kaminari, M., Kirby, J., Kivisilla, J., Klos, V., Krone, F., Kwecko, P., Kuti, L., Lima, A., Locutura, J., Lucivjansky, D. P., Mann, A., Mackovych, D., Matschullat, J., Mclaughlin, M., Malyuk, B. I., Maquil, R., Meuli, R. G., Mol, G., O'Connor, P., Oorts, R. K., Ottesen, R. T., Pasieczna, A., Petersell, W., Pfleiderer, S., Ponavic, M., Pramuka, S., Prazeres, C., Rauch, U., Radusinovic, S., Salpeteur, I., Scanlon, R., Schedl, A., Scheib, A. J., Schoeters, I., Sefcik, P., Sellersjo, E., Skopljak, F., Slaninka, I., Sorsa, A., Srvkota, R., Stafilov, T., Tarvainen, T., Trendavilov, V., Valera, P., Verougstraete, V., Vidojevic, D., Zissimos, A., Zomeni, Z., Negrel P., Ladenberger A., Reimann C., Birke M., Demetriades A., Sadeghi M., Albanese S., Andersson M., Baritz R., Batista M.J., Bel-lan A., Cicchella D., De Vivo B., De Vos W., Dinelli E., Duris M., Dusza-Dobek A., Eklund M., Ernstsen V., Filzmoser P., Flem B., Flight D.M.A., Forrester S., Fuchs M., Fugedi U., Gilucis A., Gosar M., Gregorauskiene V., De Groot W., Gulan A., Halamic J., Haslinger E., Hayoz P., Hoffmann R., Hoogewerff J., Hrvatovic H., Husnjak S., Janik L., Jordan G., Kaminari M., Kirby J., Kivisilla J., Klos V., Krone F., Kwecko P., Kuti L., Lima A., Locutura J., Lucivjansky D.P., Mann A., Mackovych D., Matschullat J., McLaughlin M., Malyuk B.I., Maquil R., Meuli R.G., Mol G., O'Connor P., Oorts R.K., Ottesen R.T., Pasieczna A., Petersell W., Pfleiderer S., Ponavic M., Pramuka S., Prazeres C., Rauch U., Radusinovic S., Salpeteur I., Scanlon R., Schedl A., Scheib A.J., Schoeters I., Sefcik P., Sellersjo E., Skopljak F., Slaninka I., Sorsa A., Srvkota R., Stafilov T., Tarvainen T., Trendavilov V., Valera P., Verougstraete V., Vidojevic D., Zissimos A., and Zomeni Z.

Subjects
Mediterranean climate, Lithology, Earth science, Weathering, Parent materials, Mineralogy, Total concentration, Partial extraction, 010501 environmental sciences, 010502 geochemistry & geophysics, 01 natural sciences, chemistry.chemical_compound, Geochemistry and Petrology, Aqua regia, 0105 earth and related environmental sciences, 2. Zero hunger, geography, geography.geographical_feature_category, Land use, Bedrock, 15. Life on land, Karst, Soil quality, Parent material, chemistry, [SDU]Sciences of the Universe [physics], Environmental science, Economic Geology
Abstract

Agricultural soil (Ap-horizon, 0–20 cm) samples were collected from 33 European countries as part of the GEMAS (GEochemical Mapping of Agricultural and grazing land Soil) soil-mapping project. The Mg data derived from total concentrations (XRF) and two acid digestion methods, aqua regia (AR) and Mobile Metal Ion (MMI®), were used to provide an overview of its spatial distribution in soil at the continental-scale. Magnesium is one of the most abundant elements in the Earth's crust and essential nutrient for plants and animals and its presence in soil is, therefore, important for soil quality evaluation. In this study, the geochemical behaviour of Mg in European agricultural soil was investigated in relation to a variety of soil parent materials, climatic zones, and landscapes. The chemical composition of soil reflects mostly the primary mineralogy of the source bedrock, and the superimposed effects of pre- and post-depositional chemical weathering, controlled by element mobility and formation of secondary phases such as clays. Low Mg concentrations in agricultural soil occur in regions with quartz-rich glacial sediments (Poland, Baltic States, N. Germany), and in soil developed on quartz-rich sandstone parent materials (e.g., central Sweden). High Mg concentrations occur in soil developed over mafic lithologies such as ophiolite belts and in carbonate-rich regions, including karst areas. The maximum extent of the last glaciation is well defined by a Mg concentration break, which is marked by low Mg concentrations in Fennoscandia and north-central Europe, and high Mg concentrations in Mediterranean region. Lithology of parent materials seems to play a key role in the Mg nutritional status of agricultural soil at the European scale. Influence from agricultural practice and use of fertilisers appears to be subordinate. Comparison of the continental-scale spatial distribution of Mg in agricultural soil by using the results from three analytical methods (XRF, AR and MMI®) provides complementary information about Mg mobility and its residence time in soil. Thus, allowing evaluation of soil weathering grade and impact of land use exploitation.

Published
2021
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11. GEMAS: Geochemical background and mineral potential of emerging tech-critical elements in Europe revealed from low-sampling density geochemical mapping

Author

M. Fuchs, P. Kwecko, E. Haslinger, P. O'Connor, R. G. Meuli, F. Skopljak, P. Hayoz, Z. Zomeni, P. Sefcik, W. De Groot, G. Mol, U. Rauch, M. Andersson, Trajče Stafilov, R. Srvkota, V. Klos, S. Pfleiderer, D. Vidojević, Paolo Valera, Josip Halamić, Stefano Albanese, R. Hoffmann, F. Krone, Belinda Flem, Anna Pasieczna, A. Gilucis, Alecos Demetriades, Peter Filzmoser, Annamaria Lima, I. Slaninka, D. P. Lucivjansky, S. Forrester, R. K. Oorts, D. Mackovych, M. Eklund, V. Gregorauskiene, Mateja Gosar, V. Verougstraete, L. Janik, Timo Tarvainen, S. Radusinović, U. Fugedi, M. Poňavič, Anna Ladenberger, W. De Vos, I. Schoeters, Jurian Hoogewerff, Clemens Reimann, M. Ďuriš, Philippe Négrel, E. Sellersjö, Martiya Sadeghi, W. Petersell, O. A. Eggen, Andreas Scheib, R. Maquil, A. Schedl, Jörg Matschullat, B. I. Malyuk, Domenico Cicchella, A. Mann, Ajka Šorša, J. Kivisilla, Manfred Birke, L. Kuti, Enrico Dinelli, R. Scanlon, C. Prazeres, Andreas M. Zissimos, V. Trendavilov, A. Bel-lan, Dee Flight, A. Dusza-Dobek, H. Hrvatovic, I. Salpeteur, Jason K. Kirby, S. Pramuka, Mike J. McLaughlin, M. Kaminari, Rolf Tore Ottesen, J. Locutura, A. Gulan, V. Ernstsen, G. Jordan, Maria João Batista, B. De Vivo, Stjepan Husnjak, Rainer Baritz, Bureau de Recherches Géologiques et Minières (BRGM) (BRGM), Geological Survey of Sweden, sgu, Geological Survey of Norway (NGU), Geological Survey of Norway, Federal Institute for Geosciences and Natural Resources (BGR), Institute of Geology and Mineral Exploration (IGME), IGME, Negrel, P., Ladenberger, A., Reimann, C., Birke, M., Demetriades, A., Sadeghi, M., Albanese, S., Andersson, M., Baritz, R., Batista, M. J., Flem, B., Bel-lan, A., Cicchella, D., De Vivo, B., De Vos, W., Dinelli, E., Duris, M., Dusza-Dobek, A., Eggen, O. A., Eklund, M., Ernstsen, V., Filzmoser, P., Flight, D. M. A., Forrester, S., Fuchs, M., Fugedi, U., Gilucis, A., Gosar, M., Gregorauskiene, V., De Groot, W., Gulan, A., Halamic, J., Haslinger, E., Hayoz, P., Hoffmann, R., Hoogewerff, J., Hrvatovic, H., Husnjak, S., Janik, L., Jordan, G., Kaminari, M., Kirby, J., Kivisilla, J., Klos, V., Krone, F., Kwecko, P., Kuti, L., Lima, A., Locutura, J., Lucivjansky, D. P., Mann, A., Mackovych, D., Matschullat, J., Mclaughlin, M., Malyuk, B. I., Maquil, R., Meuli, R. G., Mol, G., O'Connor, P., Oorts, R. K., Ottesen, R. T., Pasieczna, A., Petersell, W., Pfleiderer, S., Ponavic, M., Pramuka, S., Prazeres, C., Rauch, U., Radusinovic, S., Salpeteur, I., Scanlon, R., Schedl, A., Scheib, A. J., Schoeters, I., Sefcik, P., Sellersjo, E., Skopljak, F., Slaninka, I., Sorsa, A., Srvkota, R., Stafilov, T., Tarvainen, T., Trendavilov, V., Valera, P., Verougstraete, V., Vidojevic, D., Zissimos, A., Zomeni, Z., Negrel P., Ladenberger A., Reimann C., Birke M., Demetriades A., Sadeghi M., Albanese S., Andersson M., Baritz R., Batista M.J., Flem B., Bel-lan A., Cicchella D., De Vivo B., De Vos W., Dinelli E., Duris M., Dusza-Dobek A., Eggen O.A., Eklund M., Ernstsen V., Filzmoser P., Flight D.M.A., Forrester S., Fuchs M., Fugedi U., Gilucis A., Gosar M., Gregorauskiene V., De Groot W., Gulan A., Halamic J., Haslinger E., Hayoz P., Hoffmann R., Hoogewerff J., Hrvatovic H., Husnjak S., Janik L., Jordan G., Kaminari M., Kirby J., Kivisilla J., Klos V., Krone F., Kwecko P., Kuti L., Lima A., Locutura J., Lucivjansky D.P., Mann A., Mackovych D., Matschullat J., McLaughlin M., Malyuk B.I., Maquil R., Meuli R.G., Mol G., O'Connor P., Oorts R.K., Ottesen R.T., Pasieczna A., Petersell W., Pfleiderer S., Ponavic M., Pramuka S., Prazeres C., Rauch U., Radusinovic S., Salpeteur I., Scanlon R., Schedl A., Scheib A.J., Schoeters I., Sefcik P., Sellersjo E., Skopljak F., Slaninka I., Sorsa A., Srvkota R., Stafilov T., Tarvainen T., Trendavilov V., Valera P., Verougstraete V., Vidojevic D., Zissimos A., and Zomeni Z.

Subjects
Antimony, Soil test, Weathering, Earth science, Sorting (sediment), Lithium, 010501 environmental sciences, 010502 geochemistry & geophysics, Spatial distribution, Agricultural soil, 01 natural sciences, Tungsten, Geochemistry and Petrology, Environmental Chemistry, ComputingMilieux_MISCELLANEOUS, 0105 earth and related environmental sciences, geography, geography.geographical_feature_category, Bedrock, 15. Life on land, Platinum group, Pollution, Weathering, Geochemistry, Critical elements, Geochemistry, [SDU]Sciences of the Universe [physics], 13. Climate action, [SDE]Environmental Sciences, Leaching (pedology), Spatial ecology, Environmental science, Critical element
Abstract

The demand for ‘high-tech’ element resources (e.g., rare earth elements, lithium, platinum group elements) has increased with their continued consumption in developed countries and the emergence of developing economies. To provide a sound knowledge base for future generations, it is necessary to identify the spatial distribution of critical elements at a broad-scale, and to delineate areas for follow-up surveys. Subsequently, this knowledge can be used to study possible environmental consequences of the increased use of these resources. In this paper, three critical industrial elements (Sb, W, Li) from low-sampling density geochemical mapping at the continental-scale are presented. The geochemical distribution and spatial patterns have been obtained from agricultural soil samples (Ap-horizon, 0–20 cm; N = 2108 samples) collected at a density of 1 site per 2500 km2 and analysed by ICP-MS after a hot aqua regia digestion as part of the GEMAS (GEochemical Mapping of Agricultural and grazing land Soil) soil-mapping project in 33 European countries. Most of the geochemical maps show exclusively natural background element concentrations with minor, or without, anthropogenic influence. The maximum extent of the last glaciation is marked as a discrete element concentration break, and a distinct difference occurs in element concentration levels between the soil of northern and southern Europe, most likely an effect of soil genesis, age and weathering. The Sb, W and Li concentrations in soil provide a general overview of element spatial distribution in relation to complexity of the underlying bedrock and element mobility in the surface environment at the continental-scale. The chemical composition of agricultural soil represents largely the primary mineralogy of the source bedrock, the effects of pre- and post-depositional chemical weathering, formation of secondary products, such as clays, and element mobility, either by leaching or mineral sorting. Observed geochemical patterns of Li, W and Sb can be often linked with known mineralisation as recorded in the ProMine Mineral Database, where elements in question occur either as main or secondary resources. Anthropogenic impact has only been identified locally, predominantly in the vicinity of large urban agglomerations. Unexplained high element concentrations may potentially indicate new sources for high-tech elements and should be investigated at a more detailed scale.

Published
2019
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12. U-Th signatures of agricultural soil at the European continental scale (GEMAS): Distribution, weathering patterns and processes controlling their concentrations

Author

S. Forrester, D. Mackovych, H. Hrvatovic, Ignace Salpeteur, Enrico Dinelli, F. Krone, M. Poňavič, M. Kaminari, Rolf Tore Ottesen, V. Verougstraete, W. De Groot, G. Mol, M. Fuchs, P. Kwecko, L. Janik, Walter De Vos, M. Eklund, Maria João Batista, Annamaria Lima, José M. Soriano-Disla, Alecos Demetriades, V. Gregorauskiene, B. I. Malyuk, Anna Ladenberger, Mike J. McLaughlin, R. G. Meuli, A. Mann, R. Srvkota, Ajka Šorša, U. Rauch, S. Pfleiderer, Manfred Birke, L. Kuti, V. Petersell, M. Ďuriš, Philippe Négrel, P. Hayoz, Martiya Sadeghi, A. Dusza-Dobek, R. Scanlon, D. Vidojević, R. Hoffmann, C. Prazeres, I. Schoeters, Stefano Albanese, Jurian Hoogewerff, J. Locutura, Benedetto De Vivo, Jason K. Kirby, Anna Pasieczna, R. Maquil, A. Schedl, A. Gulan, Stjepan Husnjak, Domenico Cicchella, Rainer Baritz, S. Radusinović, U. Fugedi, M. Andersson, Timo Tarvainen, Paolo Valera, Koen Oorts, G. Jordan, Clemens Reimann, E. Sellersjö, I. Slaninka, O. A. Eggen, Andreas Scheib, Trajče Stafilov, E. Haslinger, P. O'Connor, P. Lucivjansky, Z. Zomeni, V. Klos, Peter Filzmoser, Mateja Gosar, V. Ernstsen, A. Gilucis, V. Trendavilov, A. Bel-lan, Josip Halamić, Dee Flight, Bureau de Recherches Géologiques et Minières (BRGM) (BRGM), Geological Survey of Norway (NGU), Geological Survey of Norway, Geological Survey of Sweden, sgu, Federal Institute for Geosciences and Natural Resources (BGR), Geological Survey of Finland, Finnish Meteorological Institute (FMI), Bundesanstalt für Geowissenschaften und Rohstoffe (BGR), Institut Gilbert-Laustriat : Biomolécules, Biotechnologie, Innovation Thérapeutique, Université Louis Pasteur - Strasbourg I-Centre National de la Recherche Scientifique (CNRS), Université de Nice Sophia-Antipolis (UNSA), Négrel, Philippe, De Vivo, Benedetto, Reimann, Clemen, Ladenberger, Anna, Cicchella, Domenico, Albanese, Stefano, Birke, Manfred, De Vos, Walter, Dinelli, Enrico, Lima, Annamaria, O'Connor, Patrick J., Salpeteur, Ignace, Tarvainen, Timo, Andersson, M., Baritz, R., Batista, M.J., Bel-lan, A., Demetriades, A., Ďuriš, M., Dusza-Dobek, A., Eggen, O.A., Eklund, M., Ernstsen, V., Filzmoser, P., Flight, D.M.A., Forrester, S., Fuchs, M., Fügedi, U., Gilucis, A., Gosar, M., Gregorauskiene, V., De Groot, W., Gulan, A., Halamić, J., Haslinger, E., Hayoz, P., Hoffmann, R., Hoogewerff, J., Hrvatovic, H., Husnjak, S., Janik, L., Jordan, G., Kaminari, M., Kirby, J., Klos, V., Krone, F., Kwecko, P., Kuti, L., Locutura, J., Lucivjansky, P., Mann, A., Mackovych, D., McLaughlin, M., Malyuk, B.I., Maquil, R., Meuli, R.G., Mol, G., Oorts, K., Ottesen, R.T., Pasieczna, A., Petersell, V., Pfleiderer, S., Poňavič, M., Prazeres, C., Rauch, U., Radusinović, S., Sadeghi, M., Scanlon, R., Schedl, A., Scheib, A., Schoeters, I., Sellersjö, E., Slaninka, I., Soriano-Disla, J.M., Šorša, A., Srvkota, R., Stafilov, T., Trendavilov, V., Valera, P., Verougstraete, V., Vidojević, D., Zomeni, Z., Negrel, P., De Vivo, B., Reimann, C., Ladenberger, A., Cicchella, D., Albanese, S., Birke, M., De Vos, W., Dinelli, E., Lima, A., O'Connor, P. J., Salpeteur, I., Tarvainen, T., Batista, M. J., Duris, M., Eggen, O. A., Flight, D. M. A., Fugedi, U., Halamic, J., Mclaughlin, M., Malyuk, B. I., Meuli, R. G., Ottesen, R. T., Ponavic, M., Radusinovic, S., Sellersjo, E., Soriano-Disla, J. M., Sorsa, A., and Vidojevic, D.

Subjects
Environmental Engineering, Lithology, Weathering, Geochemistry, 010501 environmental sciences, 010502 geochemistry & geophysics, 01 natural sciences, Agricultural soil, chemistry.chemical_compound, Aqua regia, Environmental Chemistry, Organic matter, Waste Management and Disposal, ComputingMilieux_MISCELLANEOUS, 0105 earth and related environmental sciences, 2. Zero hunger, chemistry.chemical_classification, geography, geography.geographical_feature_category, Bedrock, Thorium, 15. Life on land, Pollution, chemistry, [SDU]Sciences of the Universe [physics], Soil water, [SDE]Environmental Sciences, Environmental science, Uranium, Mafic, agricultural soil, weathering, geochemistry, uranium, thorium, Calcareous
Abstract

Agricultural soil (Ap-horizon, 0–20 cm) samples were collected in Europe (33 countries, 5.6 million km2) as part of the GEMAS (GEochemical Mapping of Agricultural and grazing land Soil) soil-mapping project. The GEMAS survey area includes diverse groups of soil parent materials with varying geological history, a wide range of climate zones, and landscapes. The soil data have been used to provide a general view of U and Th mobility at the continental scale, using aqua regia and MMI® extractions. The U-Th distribution pattern is closely related to the compositional variation of the geological bedrock on which the soil is developed and human impact on the environment has not concealed these genuine geochemical features. Results from both extraction methods (aqua regia and MMI®) used in this study support this general picture. Ternary plots of several soil parameters have been used to evaluate chemical weathering trends. In the aqua regia extraction, some relative Th enrichment-U loss is related to the influence of alkaline and schist bedrocks, due to weathering processes. Whereas U enrichment-Th loss characterizes soils developed on alkaline and mafic bedrock end-members on one hand and calcareous rock, with a concomitant Sc depletion (used as proxy for mafic lithologies), on the other hand. This reflects weathering processes sensu latu, and their role in U retention in related soils. Contrary to that, the large U enrichment relative to Th in the MMI® extraction and the absence of end-member parent material influence explaining the enrichment indicates that lithology is not the cause of such enrichment. Comparison of U and Th to the soil geological parent material evidenced i) higher capability of U to be weathered in soils and higher resistance of Th to weathering processes and its enrichment in soils; and, ii) the MMI® extraction results show a greater affinity of U than Th for the bearing phases like clays and organic matter. The comparison of geological units with U anomalies in agricultural soil at the country scale (France) enables better understanding of U sources in the surficial environment and can be a useful tool in risk assessments.

Published
2018
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13. GEMAS: establishing geochemical background and threshold for 53 chemical elements in European agricultural soil

Author

Clemens Reimann, S. Radusinović, U. Fugedi, E. Sellersjö, W. De Vos, I. Schoeters, V. Verougstraete, O. A. Eggen, D. Vidojević, Enrico Dinelli, U. Rauch, Rolf Tore Ottesen, Andreas M. Zissimos, G. Jordan, Andreas Scheib, V. Tendavilov, Anna Ladenberger, José M. Soriano-Disla, Timo Tarvainen, Karl Fabian, Jurian Hoogewerff, R. Maquil, A. Dusza-Dobek, Koen Oorts, Annamaria Lima, P. Hayoz, W. De Groot, G. Mol, L. Janik, Josip Halamić, Jörg Matschullat, B. I. Malyuk, Z. Zomeni, A. Schedl, S. Pfleiderer, Alecos Demetriades, A. Pasnieczna, P. Kwecko, R. Svrkota, Domenico Cicchella, V. Gregorauskiene, R. G. Meuli, M. Poňavič, Maria João Batista, R. Scanlon, A. Gilucis, M. Eklund, Mike J. McLaughlin, M. Ďuriš, Philippe Négrel, Patrice de Caritat, Jason K. Kirby, Stefano Albanese, Martiya Sadeghi, C. Prazeres, M. Kaminari, M. Anderson, Trajče Stafilov, Dee Flight, A. Mann, Ajka Šorša, Mateja Gosar, Paolo Valera, P. Lucivjansky, Manfred Birke, L. Kuti, V. Petersell, Fabian Jähne-Klingberg, E. Haslinger, P. O'Connor, V. Klos, V. Ernsten, A. Bel-Ian, I. Slaninka, Peter Filzmoser, B. De Vivo, Stjepan Husnjak, Rainer Baritz, H. Hrvatovic, I. Salpeteur, J. Locutura, S. Forrester, D. Mackovych, A. Gulan, P. Sefcik, Geological Survey of Norway (NGU), Geological Survey of Norway, Federal Institute for Geosciences and Natural Resources (BGR), Institute of Statistics and Mathematical Methods in Economics, Institute of Geology and Mineral Exploration (IGME), IGME, Bureau de Recherches Géologiques et Minières (BRGM) (BRGM), Université Catholique de Louvain = Catholic University of Louvain (UCL), Bundesanstalt für Geowissenschaften und Rohstoffe (BGR), Departimento di Scienze della Terra [Napoli], Università degli studi di Napoli Federico II, Dipartimento di Scienze Biologiche, Geologiche e Ambientali (BiGeA), Alma Mater Studiorum Università di Bologna [Bologna] (UNIBO), Institut Gilbert-Laustriat : Biomolécules, Biotechnologie, Innovation Thérapeutique, Université Louis Pasteur - Strasbourg I-Centre National de la Recherche Scientifique (CNRS), Université de Nice Sophia-Antipolis (UNSA), Geological Survey of Sweden, sgu, Centre de résonance magnétique biologique et médicale (CRMBM), Aix Marseille Université (AMU)-Assistance Publique - Hôpitaux de Marseille (APHM)-Centre National de la Recherche Scientifique (CNRS), Reimann, Clemen, Fabian, Karl, Birke, Manfred, Filzmoser, Peter, Demetriades, Aleco, Négrel, Philippe, Oorts, Koen, Matschullat, Jörg, de Caritat, Patrice, Albanese, S., Anderson, M., Baritz, R., Batista, M.J., Bel-Ian, A., Cicchella, D., De Vivo, B., De Vos, W., Dinelli, E., Ďuriš, M., Dusza-Dobek, A., Eggen, O.A., Eklund, M., Ernsten, V., Flight, D.M.A., Forrester, S., Fügedi, U., Gilucis, A., Gosar, M., Gregorauskiene, V., De Groot, W., Gulan, A., Halamić, J., Haslinger, E., Hayoz, P., Hoogewerff, J., Hrvatovic, H., Husnjak, S., Jähne-Klingberg, F., Janik, L., Jordan, G., Kaminari, M., Kirby, J., Klos, V., Kwećko, P., Kuti, L., Ladenberger, A., Lima, A., Locutura, J., Lucivjansky, P., Mann, A., Mackovych, D., McLaughlin, M., Malyuk, B.I., Maquil, R., Meuli, R.G., Mol, G., O'Connor, P., Ottesen, R.T., Pasnieczna, A., Petersell, V., Pfleiderer, S., Poňavič, M., Prazeres, C., Radusinović, S., Rauch, U., Salpeteur, I., Scanlon, R., Schedl, A., Scheib, A., Schoeters, I., Šefčik, P., Sellersjö, E., Slaninka, I., Soriano-Disla, J.M., Šorša, A., Svrkota, R., Stafilov, T., Tarvainen, T., Tendavilov, V., Valera, P., Verougstraete, V., Vidojević, D., Zissimos, A., Zomeni, Z., Sadeghi, M., Reimann, C., Fabian, K., Birke, M., Filzmoser, P., Demetriades, A., Negrel, P., Oorts, K., Matschullat, J., de Caritat, P., Batista, M. J., Duris, M., Eggen, O. A., Flight, D. M. A., Fugedi, U., Halamic, J., Jahne-Klingberg, F., Kwecko, P., Mclaughlin, M., Malyuk, B. I., Meuli, R. G., Ottesen, R. T., Ponavic, M., Radusinovic, S., Sefcik, P., Sellersjo, E., Soriano-Disla, J. M., Sorsa, A., and Vidojevic, D.

Subjects
Soil test, Geochemical threshold, 010501 environmental sciences, Spatial distribution, 01 natural sciences, Agricultural soil, Ecology and Environment, chemistry.chemical_compound, Geochemistry and Petrology, Environmental Chemistry, Aqua regia, Continental scale, ComputingMilieux_MISCELLANEOUS, 0105 earth and related environmental sciences, Hydrology, business.industry, 04 agricultural and veterinary sciences, 15. Life on land, Contamination, Pollution, Europe, Chemistry, chemistry, Agriculture and Soil Science, 13. Climate action, Agriculture, [SDU]Sciences of the Universe [physics], Environmental chemistry, Smelting, [SDE]Environmental Sciences, 040103 agronomy & agriculture, Earth Sciences, 0401 agriculture, forestry, and fisheries, Environmental science, business, Background variation
Abstract

The GEMAS (geochemical mapping of agricultural soil) project collected 2108 Ap horizon soil samples from regularly ploughed fields in 33 European countries, covering 5.6 million km(2). The

Published
2018
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14. GEMAS: Cobalt, Cr, Cu and Ni distribution in agricultural and grazing land soil of Europe

Author

ALBANESE, STEFANO, LIMA, ANNAMARIA, DE VIVO, BENEDETTO, Sadeghi, M., Cicchella, D., Dinelli, E., Valera, P., Falconi, M., Demetriades, A., Andersson, M., Baritz, R., Batista, M. J., Bel lan, A., Birke, M., De Vos, W., Ďuriš, M., Dusza Dobek, A., Eggen, O. A., Eklund, M., Ernstsen, V., Filzmoser, P., Flight, D. M. A., Forrester, S., Fuchs, M., Fügedi, U., Gilucis, A., Gosar, M., Gregorauskiene, V., De Groot, W., Gulan, A., Halamić, J., Haslinger, E., Hayoz, P., Hoffmann, R., Hoogewerff, J., Hrvatovic, H., Husnjak, S., Janik, L., Jordan, G., Kaminari, M., Kirby, J., Klos, V., Krone, F., Kwecko, P., Kuti, L., Ladenberger, A., Locutura, J., Lucivjansky, P., Mann, A., Mackovych, D., Mclaughlin, M., Malyuk, B. I., Maquil, R., Meuli, R. G., Mol, G., Négrel, P., O'Connor, P., Oorts, K., Ottesen, R. T., Pasieczna, A., Petersell, V., Pfleiderer, S., Poňavič, M., Prazeres, C., Rauch, U., Radusinović, S., Reimann, C., Salpeteur, I., Scanlon, R., Schedl, A., Scheib, A., Schoeters, I., Sellersjö, E., Slaninka, I., Soriano Disla, J. M., Šorša, A., Svrkota, R., Stafilov, T., Tarvainen, T., Trendavilov, V., Verougstraete, V., Vidojević, D., Zomeni, Z., Albanese, Stefano, Sadeghi, M., Lima, Annamaria, Cicchella, D., Dinelli, E., Valera, P., Falconi, M., Demetriades, A., DE VIVO, Benedetto, Andersson, M., Baritz, R., Batista, M. J., Bel lan, A., Birke, M., De Vos, W., Ďuriš, M., Dusza Dobek, A., Eggen, O. A., Eklund, M., Ernstsen, V., Filzmoser, P., Flight, D. M. A., Forrester, S., Fuchs, M., Fügedi, U., Gilucis, A., Gosar, M., Gregorauskiene, V., De Groot, W., Gulan, A., Halamić, J., Haslinger, E., Hayoz, P., Hoffmann, R., Hoogewerff, J., Hrvatovic, H., Husnjak, S., Janik, L., Jordan, G., Kaminari, M., Kirby, J., Klos, V., Krone, F., Kwecko, P., Kuti, L., Ladenberger, A., Locutura, J., Lucivjansky, P., Mann, A., Mackovych, D., Mclaughlin, M., Malyuk, B. I., Maquil, R., Meuli, R. G., Mol, G., Négrel, P., O'Connor, P., Oorts, K., Ottesen, R. T., Pasieczna, A., Petersell, V., Pfleiderer, S., Poňavič, M., Prazeres, C., Rauch, U., Radusinović, S., Reimann, C., Salpeteur, I., Scanlon, R., Schedl, A., Scheib, A., Schoeters, I., Sellersjö, E., Slaninka, I., Soriano Disla, J. M., Šorša, A., Svrkota, R., Stafilov, T., Tarvainen, T., Trendavilov, V., Verougstraete, V., Vidojević, D., Zomeni, Z., Albanese, S., Lima, A., De Vivo, B., Batista, M.J., Bel-lan, A., Duris, M., Dusza-Dobek, A., Eggen, O.A., Flight, D.M.A., Fugedi, U., Halamic, J., Malyuk, B.I., Meuli, R.G., Negrel, P., Ottesen, R.T., Ponavic, M., Radusinovic, S., Sellersjo, E., Soriano-Disla, J.M., Sorsa, A., and Vidojevic, D.

Subjects
Mediterranean climate, Soil test, Metal, Mafic-ultramafic rocks, Soil guidelines, Earth science, European soil, Mineralogy, cobalt, crom, distribution, Ni, Cu, Ophiolite, Metals, Geochemistry and Petrology, Ultramafic rock, Grazing, Geochemical mapping, Economic Geology, Glacial period, Mafic, European soil Mafic–ultramafic rocks Metals Geochemical mapping Soil guidelines, Scale (map), Geology, Mafic-ultramafic rock
Abstract

In the framework of the GEMAS project, 2211 samples of agricultural soil (Ap, 0-20cm, regularly ploughed fields), and 2118 samples from land under permanent grass cover (Gr, 0-10cm, grazing land soil) were collected across almost the whole European continent, at a density of 1 sample site/2500km2, in accordance with a common sampling protocol.Among many other elements, the concentrations of Co, Cr, Cu and Ni in European soil were determined by ICP-MS after a hot aqua extraction, and WD-XRFS analytical methods, and their spatial distribution patterns generated by means of a GIS software.The presence of mafic and ultramafic rocks, ophiolite complexes and mineralisation, is widespread across the European continent, and seems to explain most of the variability of the elements studied in this paper. A large belt, north of the last glaciation maximum limit, is generally dominated by lower concentrations compared with central European and Mediterranean areas and to some areas in Northern Europe where higher Co, Cr, Cu and Ni values also occur.The application of the guideline value set for Cu and Ni by the EU Directive 86/278/EEC to the Ap soil samples of the GEMAS data set highlighted that at the continental scale the use of a unique reference interval is a tool of limited effectiveness; the lithological variation, occurring across a whole continent, generates changes in the geochemistry of soil, which cannot be accommodated by using a single reference interval even if it is very wide. The GEMAS data set should form the sound basis to set at the European scale the geochemical background reference intervals, at least, for regions sharing common lithological settings and a common geological history. •Geochemistry of Co, Cr, Cu and Ni•Mineral deposits in Europe with Co, Cr, Cu and Ni•Distribution of Co, Cr, Cu and Ni in European agricultural and grazing land soil•Comparison of aqua regia extractable and total element concentrations in soil•Comparison of Cu and Ni concentrations with European guideline values. © 2015 Elsevier B.V.

Published
2015
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15. GEMAS: Source, distribution patterns and geochemical behaviour of Ge in agricultural and grazing land soils at European continental scale

Author

Négrel, Philippe, Ladenberger, Anna, Reimann, Clemens, Birke, Manfred, Sadeghi, Martiya, The GEMAS Project Team: S. Albanese, M. Andersson, R. Baritz, M. J. Batista, A. Bel lan, D. Cicchella, A. Demetriades, B. De Vivo, W. De Vos, M. Duris, A. Dusza Dobek, O. A. Eggen, M. Eklund, V. Ernstsen, P. Filzmoser, D. M. A. Flight, S. Forrester, M. Fuchs, U. Fügedi, A. Gilucis, M. Gosar, V. Gregorauskiene, W. De Groot, A. Gulan, J. Halamic, E. Haslinger, P. Hayoz, R. Hoffmann, J. Hoogewerff, H. Hrvatovic, S. Husnjak, L. Janik, G. Jordan, M. Kaminari, J. Kirby, J. Kivisilla, V. Klos, F. Krone, P. Kwecko, L. Kuti, A. Lima, J. Locutura, D. P. Lucivjansky, A. Mann, D. Mackovych, M. McLaughlin, B. I. Malyuk, R. Maquil, R. G. Meuli, G. Mol, P. O'Connor, R. K. Oorts, R. T. Ottesen, A. Pasieczna, W. Petersell, S. Pfleiderer, M. Ponavic, S. Pramuka, C. Prazeres, U. Rauch, S. Radusinovic, I. Salpeteur, R. Scanlon, A. Schedl, A. J. Scheib, I. Schoeters, P. Sefcik, E. Sellersjo, F. Skopljak, I. Slaninka, A. Sorsa, R. Srvkota, T. Stafilov, T. Tarvainen, V. Trendavilov, P. Valera, V. Verougstraete, D. Vidojevic, A. Zissimos, Z. Zomeni, DINELLI, ENRICO, Negrel, P., Ladenberger, A., Reimann, C., Birke, M., Sadeghi, M., Albanese, Stefano, Andersson, M., Baritz, R., Batista, M. J., BEL LAN, A., Cicchella, D., Demetriades, A., DE VIVO, Benedetto, DE VOS, W., Dinelli, E., Duris, M., DUSZA DOBEK, A., Eggen, O. A., Eklund, M., Ernstsen, V., Filzmoser, P., Flight, D. M. A., Forrester, S., Fuchs, Fügedi, U., Gilucis, A., Gosar, M., Gregorauskiene, V., DE GROOT, W., Gulan, A., Halamic, J., Haslinger, E., Hayoz, P., Hoffmann, R., Hoogewerff, J., Hrvatovic, H., Husnjak, S., Janik, L., Jordan, G., Kaminari, M., Kirby, J., Kivisilla, J., Klos, V., Krone, F., Kwecko, P., Kuti, L., Lima, Annamaria, Locutura, J., Lucivjansky, D. P., Mann, A., Mackovych, D., Mclaughlin, M., Malyuk, B. I., Maquil, R., Meuli, R. G., Mol, G., O'Connor, P., Oorts, R. K., Ottesen, R. T., Pasieczna, A., Petersell, W., Pfleiderer, S., Ponavic, M., Pramuka, S., Prazeres, C., Rauch, U., Radusinovic, S., Salpeteur, I., Scanlon, R., Schedl, A., Scheib, A. J., Schoeters, I., Sefcik, P., Sellersjo, E., Skopljak, F., Slaninka, I., Sorsa, A., Srvkota, R., Stafilov, T., Tarvainen, T., Trendavilov, V., Valera, P., Verougstraete, V., Vidojevic, D., Zissimos, A., Zomeni, Z., Bureau de Recherches Géologiques et Minières (BRGM) (BRGM), Geological Survey of Sweden, sgu, Geological Survey of Norway (NGU), Geological Survey of Norway, Federal Institute for Geosciences and Natural Resources (BGR), Négrel, Philippe, Ladenberger, Anna, Reimann, Clemen, Birke, Manfred, Sadeghi, Martiya, The GEMAS Project Team: S. Albanese, M. Andersson, R. Baritz, M.J. Batista, A. Bel-lan, D. Cicchella, A. Demetriade, B. De Vivo, W. De Vo, Dinelli Enrico, M. Duri, A. Dusza-Dobek, O.A. Eggen, M. Eklund, V. Ernstsen, P. Filzmoser, D.M.A. Flight, S. Forrester, M. Fuch, U. Fügedi, A. Giluci, M. Gosar, V. Gregorauskiene, W. De Groot, A. Gulan, J. Halamic, E. Haslinger, P. Hayoz, R. Hoffmann, J. Hoogewerff, H. Hrvatovic, S. Husnjak, L. Janik, G. Jordan, M. Kaminari, J. Kirby, J. Kivisilla, V. Klo, F. Krone, P. Kwecko, L. Kuti, A. Lima, J. Locutura, D. P. Lucivjansky, A. Mann, D. Mackovych, M. McLaughlin, B.I. Malyuk, R. Maquil, R.G. Meuli, G. Mol, P. O'Connor, R. K. Oort, R.T. Ottesen, A. Pasieczna, W. Petersell, S. Pfleiderer, M. Ponavic, S. Pramuka, C. Prazere, U. Rauch, S. Radusinovic, I. Salpeteur, R. Scanlon, A. Schedl, A.J. Scheib, I. Schoeter, P. Sefcik, E Sellersjo, F. Skopljak, I. Slaninka, A. Sorsa, R. Srvkota, T. Stafilov, T. Tarvainen, V. Trendavilov, P. Valera, V. Verougstraete, D. Vidojevic, A. Zissimo, and Z. Zomeni

Subjects
Regosol, Soil production function, Weathering, Soil science, 010501 environmental sciences, 010502 geochemistry & geophysics, Agricultural soil, 01 natural sciences, Soil survey, Soil series, Geochemistry and Petrology, [SDU.STU.GC]Sciences of the Universe [physics]/Earth Sciences/Geochemistry, Environmental Chemistry, 0105 earth and related environmental sciences, Soil map, Germanium, Geochemistry, Pedalfer, 15. Life on land, Pollution, Chemistry, Pedogenesis, Agriculture and Soil Science, 13. Climate action, Soil water, Earth Sciences, Geology
Abstract

International audience; Agricultural soil (Ap-horizon, 0–20 cm) and grazing land soil (Gr-horizon, 0–10 cm) samples were collected from a large part of Europe (33 countries, 5.6 million km2) as part of the GEMAS (GEochemical Mapping of Agricultural and grazing land Soil) soil mapping project. GEMAS soil data have been used to provide a general view of element mobility and source rocks at the continental scale, either by reference to average crustal abundances or to normalized patterns of element mobility during weathering processes. The survey area includes a diverse group of soil parent materials with varying geological history, a wide range of climate zones, and landscapes.The concentrations of Ge in European soil were determined by ICP-MS after an aqua extraction, and their spatial distribution patterns generated by means of a GIS software.The median values of Ge and its spatial distribution in Ap and Gr soils are almost the same (0.037 vs. 0.034 mg/kg, respectively). The majority of Ge anomalies is related to the type of soil parent material, namely lithology of the bedrock and minor influence of soil parameters such as pH, TOC and clay content. Metallogenic belts with sulphide mineralisation provide the primary source of Ge in soil in several regions in Europe, e.g. in Scandinavia, Germany, France, Spain and Balkan countries.Comparison with total Ge concentrations obtained from the Baltic Soil Survey shows that aqua regia is a very selective method with rather low-efficiency and cannot provide a complete explanation for Ge geochemical behaviour in soil. Additionally, large differences in Ge distribution are to be expected when different soil depth horizons are analysed.

Published
2016
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16. The GEMAS periodic table of mineralisation and mineral deposits in Europe

Author

ALBANESE, STEFANO, DE VIVO, BENEDETTO, LIMA, ANNAMARIA, DEMETRIADES, A., REIMANN, C., BIRKE, M., ALBANESE, S., ANDERSSON, M., BARITZ, R., BATISTA, M. J., BEL-LAN, A., CICCHELLA, D., DE VIVO, B., DE VOS, W., DINELLI, E., DURIŠ, M., DUSZA-DOBEK, A., EGGEN, O. A., EKLUND, M., ERNSTSEN,V., FILZMOSER,P., FLIGHT,D. M. A., FORRESTER, S., FUCHS, M., FÜGEDI, U., GILUCIS, A., GOSAR, M., GREGORAUSKIENE, V., DE GROOT, W., GULAN, A., HALAMIC, J., HASLINGER, E., HAYOZ, P., HOFFMANN, R., HOOGEWERFF, J., HRVATOVIC, H., HUSNJAK, S., JANIK,L., JORDAN, G., KAMINARI,M., KIRBY, J., KLOS, V., KRONE, F., KWECKO, P., KUTI, L., LADENBERGER, A., LIMA, A., LOCUTURA, J., LUCIVJANSKY, P., MANN, A., MACKOVYCH, D., MCLAUGHLIN, M., MALYUK, B. I., MAQUIL, R., MEULI, R. G., MOL, G., NÉGREL, P., O'CONNOR, P., OORTS, K., OTTESEN, R. T., PASIECZNA, A., PETERSELL, V., PFLEIDERER,S., PONAVIC, M., PRAZERES, C., RAUCH, U., RADUSINOVIC, S., SALPETEUR, I., SADEGHI, M., SCANLON, R., SCHEDL, A., SCHEIB, A., SCHOETERS, I., SELLERSJÖ, E., SLANINKA, I., SORIANO-DISLA, J. M., ŠORŠA, A., SVRKOTA, R., STAFILOV, T., TARVAINEN, T., TRENDAVILOV, V., VALERA, P., VEROUGSTRAETE, V., VIDOJEVIC, D., ZOMENI, Z., Association Applied Geochemistry, Albanese, Stefano, DE VIVO, Benedetto, and Lima, Annamaria

Published
2015

17. The GEMAS periodic table of agricultural soil in Europe

Author

ALBANESE, STEFANO, DE VIVO, BENEDETTO, LIMA, ANNAMARIA, REIMANN C., BIRKE M., FABIAN K., DEMETRIADES A., ALBANESE S., ANDERSSON M., BARITZ R., BATISTA M. J., BEL-LAN A., CICCHELLA D., DE VIVO B., DE VOS W., DINELLI E., DURIŠ M., DUSZA-DOBEK A., EGGEN O. A., EKLUND M., ERNSTSEN V., FILZMOSER P., FLIGHT D. M. A., FORRESTER S., FUCHS M., FÜGEDI U., GILUCIS A., GOSAR M., GREGORAUSKIENE V., DE GROOT W., GULAN A., HALAMIC J., HASLINGER E., HAYOZ P., HOFFMANN R., HOOGEWERFF J., HRVATOVIC H., HUSNJAK S., JANIK L., JORDAN G., KAMINARI M., KIRBY J., KLOS V., KRONE F., KWECKO P., KUTI L., LADENBERGER A., LIMA A., LOCUTURA J., LUCIVJANSKY P., MANN A., MACKOVYCH D., MCLAUGHLIN M., MALYUK B. I., MAQUIL R., MEULI R. G., MOL G., NÉGREL P., O'CONNOR P., OORTS K., OTTESEN R. T., PASIECZNA A., PETERSELL V., PFLEIDERER S., PONAVIC M., PRAZERES C., RAUCH U., RADUSINOVIC S., SALPETEUR I., SADEGHI M., SCANLON R., SCHEDL A., SCHEIB A., SCHOETERS I., SELLERSJÖ E., SLANINKA I., SORIANO-DISLA J. M., ŠORŠA A., SVRKOTA R., STAFILOV T., TARVAINEN T., TRENDAVILOV V., VALERA P., VEROUGSTRAETE V., VIDOJEVIC D., ZOMENI Z., Albanese, Stefano, DE VIVO, Benedetto, and Lima, Annamaria

Published
2015

18. GEMAS: Spatial distribution of the pH of European agricultural and grazing land soils

Author

Fabian C., Reimann C., Fabian K., Birke M., Baritz R., Haslinger E., Albanese S., Andersson M., Batista M. J., Bel lan A., Cicchella D., Demetriades A., De Vivo B., De Vos W., Duriš M., Dusza Dobek A., Eggen O. A., Eklund M., Ernstsen V., Filzmoser P., Flight D. M. A., Forrester S., Fuchs M., Fügedi U., Gilucis A., Gosar M., Gregorauskiene V., De Groot W., Gulan A., Halamić J., Hayoz P., Hoffmann R., Hoogewerff J., Hrvatovic H., Husnjak S., Janik L., Jordan G., Kaminari M., Kirby J., Kivisilla J., Klos V., Krone F., Kwećko P., Kuti L., Ladenberger A., Lima A., Locutura J., Lucivjansky D. P., Mann A., Mackovych D., McLaughlin M., Malyuk B. I., Maquil R., Meuli R. G., Mol G., Negrel P., O'Connor P., Oorts R. K., Ottesen R. T., Pasieczna A., Petersel, W., Pfleiderer S., Poňavič M., Pramuka S., Prazeres C., Rauch U., Radusinović S., Salpeteur I., Scanlon R., Schedl A., Scheib A. J., Schoeters I., Šefčik P., Sellersjö E., Skopljak F., Slaninka I., Šorša A., Srvkota R., Stafilov T., Tarvainen T., Trendavilov V., Valera P., Verougstraete V., Vidojević D., Zissimos A., Zomeni Z., DINELLI, ENRICO, Fabian C., Reimann C., Fabian K., Birke M., Baritz R., Haslinger E., Albanese S., Andersson M., Batista M.J., Bel-lan A., Cicchella D., Demetriades A., De Vivo B., De Vos W., Dinelli E., Duriš M., Dusza-Dobek A., Eggen O.A., Eklund M., Ernstsen V., Filzmoser P., Flight D.M.A., Forrester S., Fuchs M., Fügedi U., Gilucis A., Gosar M., Gregorauskiene V., De Groot W., Gulan A., Halamić J., Hayoz P., Hoffmann R., Hoogewerff J., Hrvatovic H., Husnjak S., Janik L., Jordan G., Kaminari M., Kirby J., Kivisilla J., Klos V., Krone F., Kwećko P., Kuti L., Ladenberger A., Lima A., Locutura J., Lucivjansky D.P., Mann A., Mackovych D., McLaughlin M., Malyuk B.I., Maquil R., Meuli R.G., Mol G., Negrel P., O'Connor P., Oorts R.K., Ottesen R.T., Pasieczna A., Petersel, W., Pfleiderer S., Poňavič M., Pramuka S., Prazeres C., Rauch U., Radusinović S., Salpeteur I., Scanlon R., Schedl A., Scheib A.J., Schoeters I., Šefčik P., Sellersjö E., Skopljak F., Slaninka I., Šorša A., Srvkota R., Stafilov T., Tarvainen T., Trendavilov V., Valera P., Verougstraete V., Vidojević D., Zissimos A., Zomeni Z., Fabian, C., Reimann, C., Fabian, K., Birke, M., Baritz, R., Haslinger, E., Albanese, Stefano, Andersson, M., Batista, M. J., BEL LAN, A., Cicchella, D., Demetriades, D., DE VIVO, Benedetto, DE VOS, W., Dinelli, E., Duriš, M., DUSZA DOBEK, A., Eggen, O. A., Eklund, M., Ernstsen, V., Filzmoser, P., Flight, D. M. A., Forrester, S., Fuchs, M., Fugedi, U., Gilucis, A., Gosar, M., Gregorauskiene, V., DE GROOT, W., Gulan, A., Halamic, J., Hayoz, P., Hoffmann, R., Hoogewerff, J., Hrvatovic, H., Husnjak, S., Janik, L., Jordan, G., Kaminari, M., Kirby, J., Kivisilla, J., Klos, V., Krone, F., Kwecko, P., Kuti, L., Ladenberger, A., Lima, Annamaria, Locutura, J., Lucivjansky, D. P., Mann, A., Mackovych, D., Mclaughlin, M., Malyuk, B. I., Maquil, R., Meuli, R. G., Mol, G., Negrel, P., O’Connor, P., Oorts, R. K., Ottesen, R. T., Pasieczna, A., Petersell, W., Pfleiderer, S., Ponavic, M., Pramuka, S., Prazeres, C., Rauch, U., Radusinovic, S., Salpeteur, I., Scanlon, R., Schedl, A., Scheib, A. J., Schoeters, I., Šefcik, P., Sellersjo, E., Skopljak, F., Slaninka, I., Šorša, A., Srvkota, R., Stafilov, T., Tarvainen, T., Trendavilov, V., Valera, P., Verougstraete, V., Vidojevic, D., Zissimos, A., and Zomeni, Z.

Subjects
Hydrology, Soil test, Spatial distribution, Pollution, Agricultural soil, Grazing soil, GEMAS, chemistry.chemical_compound, soil pH, GEochemical Mapping, chemistry, Geochemistry and Petrology, Soil pH, Soil water, Grazing, Environmental Chemistry, Carbonate, Environmental science, Precipitation, Glacial period, grazing land soil, pH value, Grazing land soil, geochemistry
Abstract

During 2008 the GEochemical Mapping of Agricultural Soils (GEMAS) project collected 2108 agricultural (ploughed soil, Ap horizon, 0–20 cm) and 2023 grazing land soil samples (Gr, 0–10 cm) evenly spread over 33 European countries and covering an area of 5.6 million km2. The pH of all samples was determined by one single laboratory applying a 0.01 M CaCl2 extraction, and following a strict quality-control procedure. The resulting pH-value distributions for European Ap and Gr soil are both bimodal. Broad acidic modes, with pH between 4 and 6, and sharp alkaline modes, with pH between 7 and 8 due to the Ca2+ buffer system, are clearly separated. The European median pH is 5.8 for the GEMAS Ap soil samples and 5.5 for the GEMAS Gr soil samples. According to the pH distribution maps, Europe is separated into two main zones: northern Europe with generally lower pH values (Ap: 5.2, Gr: 4.8), dominated by acidic soils occurring in Fennoscandia, and southern Europe with higher pH values (Ap: 6.3, Gr: 5.9), dominated by carbonate rich soils. The separation line coincides with the southern border of the sediments of the last glaciation. The dominant factors controlling pH at the European scale are thus geology (crystalline bedrock) in combination with climate (temperature and precipitation). The GEMAS pH maps mainly reflect the natural site conditions on the European scale, whilst anthropogenic impact is hardly detectable. The GEMAS results provide a unique set of homogenous and spatially representative soil pH data for the continent. The data set defines a dependable continental-scale background, and offers the possibility to calibrate studies on more detailed scales.

Published
2014

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