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JWST has begun its scientific mission, which includes the atmospheric characterization of transiting exoplanets. Some of the first exoplanets to be observed by JWST have equilibrium temperatures below 1000 K, which is a regime where photochemical hazes are expected to form. The optical properties of these hazes, which controls how they interact with light, are critical for interpreting exoplanet observations, but relevant data are not available. Here we measure the optical properties of organic haze analogues generated in water-rich exoplanet atmosphere experiments. We report optical constants (0.4 to 28.6 micron) of organic hazes for current and future observational and modeling efforts covering the entire wavelength range of JWST instrumentation and a large part of Hubble. We use these optical constants to generate hazy model atmospheric spectra. The synthetic spectra show that differences in haze optical constants have a detectable effect on the spectra, impacting our interpretation of exoplanet observations. This study emphasizes the need to investigate the optical properties of hazes formed in different exoplanet atmospheres, and establishes a practical procedure to determine such properties., Comment: 4 figures, 1 Table, Paper under review in Nature Astronomy

Chemistry in Titan's N2-CH4 atmosphere produces complex organic aerosols. The chemical processes and the resulting organic compounds are still far from understood, although extensive observations, laboratory, and theoretical simulations have greatly improved physical and chemical constraints on Titan's atmosphere. Here, we conduct a series of Titan atmosphere simulation experiments with N2-CH4 gas mixtures and investigate the effect of initial CH4 ratio, pressure, and flow rate on the production rates and composition of the gas and solid products at a Titan relevant temperature (100 K) for the first time. We find that the production rate of the gas and solid products increases with increasing CH4 ratio. The nitrogen-containing species have much higher yield than hydrocarbons in the gas products, and the N-to-C ratio of the solid products appears to be the highest compared to previous plasma simulations with the same CH4 ratio. The greater degree of nitrogen incorporation in the low temperature simulation experiments suggests temperature may play an important role in nitrogen incorporation in Titan's cold atmosphere. We also find that H2 is the dominant gas product and serves as an indicator of the production rate of new organic molecules in the experiment, and that CH2NH may greatly contribute to the incorporation of both carbon and nitrogen into the solid particles. The pressure and flow rate affect the amount of time of the gas mixture exposed to the energy source and therefore impact the N2-CH4 chemistry initiated by the plasma discharge, emphasizing the influence of the energy flux in Titan atmospheric chemistry., Comment: Accepted in ACS Earth and Space Chemistry, 6 figures

Triton is the largest moon of the Neptune system and possesses a thin nitrogen atmosphere with trace amounts of carbon monoxide and methane, making it of similar composition to that of the dwarf planet Pluto. Like Pluto and Saturn's moon Titan, Triton has a haze layer thought to be composed of organics formed through photochemistry. Here, we perform atmospheric chamber experiments of 0.5% carbon monoxide and 0.2% methane in molecular nitrogen at 90 K and 1 mbar to generate Triton haze analogues. We then characterize the physical and chemical properties of these particles. We measure their production rate, their bulk composition with combustion analysis, their molecular composition with very high resolution mass spectrometry, and their transmission and reflectance from the optical to the near-infrared (0.4 to 5 microns) with Fourier Transform Infrared (FTIR) spectroscopy. We compare these properties to existing measurements of Triton's tenuous atmosphere and its surface, as well as contextualize these results in view of all the small, hazy nitrogen-rich worlds of our solar system. We find that carbon monoxide present at greater mixing ratios than methane in the atmosphere can lead to significantly oxygen- and nitrogen-rich haze materials. These Triton haze analogues have clear observable signatures in their near-infrared spectra, which may help us differentiate the mechanisms behind haze formation processes across diverse solar system bodies., Comment: 48 pages (but only 26 actual article pages!), 11 figures, 4 tables; accepted for publication in JGR: Planets

Titan's thick atmosphere is primarily composed of nitrogen and methane. Complex chemistry happening in Titan's atmosphere produces optically thick organic hazes. These hazes play significant roles in Titan's atmosphere and on its surface, and their optical properties are crucial for understanding many processes happening on Titan. Due to the lack of such information, the optical constants of laboratory prepared Titan haze analogues are essential inputs for atmospheric modeling and data analysis of remote sensing observations of Titan. Here, we perform laboratory simulations in a Titan relevant environment, analyze the resulting Titan haze analogues using vacuum Fourier transform infrared spectroscopy, and calculate the optical constants from the measured transmittance and reflectance spectra. We provide a reliable set of optical constants of Titan haze analogue in the wavelength range from 0.4 to 3.5 micron and will extend to 28.5 micron in the near future, which can both be used for analyzing existing and future observational data of Titan. This study establishes a feasible method to determine optical constants of haze analogues of (exo)planetary bodies., Comment: 22 pages, 5 figures, accepted for publication in The Planetary Science Journal

Knudsen flow is easily simulated with a Monte Carlo method. In this study we develop a Visual Basic for Excel (VBA) code to simulate the molecular beam from a vaporizing solid. The system at NASA Glenn uses the restricted collimation method of Chatillon and colleagues, which consists of two apertures between the effusion cell and the ionizer. The diameter of the first aperture is smaller than the diameter of the effusion cell orifice, so the ionizer effectively only sees inside the effusion cell. The code is able to calculate the transmission coefficient through the cell orifice, through the cell orifice and the first aperture, and through the cell orifice and first and second aperatures. Calculated transmission coefficients through the cell orifice are compared to tabulated values to validate the code. Then transmission coefficients are calculated through the cell orifice and both apertures to the ionizer. This allows the geometry (aperture spacing and diameters) of the sampling system the sampling system to be optimized. Calculated transmission factors are also compared to literature values calculated via an analytic method.