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Rift-related regional metamorphism of passive margins is usually difficult to observe on the surface, mainly due to its strong metamorphic overprint during the subsequent orogenic processes that cause its exposure. However, recognition of such a pre-orogenic evolution is achievable by careful characterization of the polyphase tectono-metamorphic record of the orogenic upper plate. A multidisciplinary approach, involving metamorphic petrology, P-T modelling, structural geology and in situ U-Pb monazite geochronology using laser-ablation split-stream inductively coupled plasma mass spectrometry, was applied to unravel the polyphase tectono-metamorphic record of metapelites at the western margin of the Teplá-Barrandian domain in the Bohemian Massif. The study resulted in discovery of three tectono-metamorphic events. The oldest event M1 is L P- H T regional metamorphism with a geothermal gradient between 30 and 50 °C km−1, peak temperatures up to 650 °C and of Cambro-Ordovician age ( c. 485 Ma). The M1 event was followed by M2-D2, which is characterized by a Barrovian sequence of minerals from biotite to kyanite and a geothermal gradient of 20-25 °C km−1. D2-M2 is associated with a vertical fabric S2 and was dated as Devonian ( c. 375 Ma). Finally, the vertical fabric S2 was overprinted by a D3-M3 event that formed sillimanite to chlorite bearing gently inclined fabric S3 also of Devonian age. The high geothermal gradient of the M1 event can be explained as the result of an extensional, rift-related tectonic setting. In addition, restoration of the deep architecture and polarity of the extended domain before the Devonian history - together with the supracrustal sedimentary and magmatic record - lead us to propose a model for formation of an Ordovician passive continental margin. The subsequent Devonian evolution is interpreted as horizontal shortening of the passive margin at the beginning of Variscan convergence, followed by detachment-accommodated exhumation of lower-crustal rocks. Both Devonian shortening and detachment occurred in the upper plate of a Devonian subduction zone. The tectonic evolution presented in this article modifies previous models of the tectonic history of the western margin of the Teplá-Barrandian domain, and also put constraints on the evolution of the southern margin of the Rheic ocean from the passive margin formation to the early phases of Variscan orogeny. [ABSTRACT FROM AUTHOR]

A structural and geochronological Ar/Ar study was performed in kilometre-scale middle and lower crustal lens-shaped domains dominated by a preserved subvertical foliation, surrounded by horizontally foliated migmatites. These domains occur within the Moldanubian nappe overlying the Brunia microcontinent at the eastern margin of the European Variscides. Three main deformation phases were recognized: subvertical S2 fabric trending NW-SE in lower crustal rocks and NE-SW in mid-crustal rocks. It is reworked by HT/MT horizontal fabric S3 along margins of crustal domains and in surrounding migmatites. S3 bears a prolate NE lineation parallel to the S2-S3 intersection in the lower crustal domain. In the middle crustal units, L3 is weak, connected to oblate strain and trends NE-SW parallel to the S2-S3 intersection. D4 non-coaxial shear deformation is mainly localized at the boundary between the Moldanubian nappe and Brunia and bears strong top to the NNE shear criteria. In order to constrain kinematics of the D3 deformation, strain modelling was performed to show that the Moldanubian hot nappe was frontally thrust over the Brunia indentor. The renewed D4 tangential movement only heterogeneously reactivates the horizontal S3. This evolution is recorded in Ar/Ar amphibole cooling ages, which show two statistically significant Carboniferous peaks at ~342 and 332 Ma, which are also reflected by published detrital muscovite Ar/Ar ages in the adjacent foreland basin. This geochronological record is correlated with progressive erosion of the topographically elevated upper crustal part of the Moldanubian nappe during D3 frontal thrusting, followed by greenschist facies D4 transpressive reactivation and subsequent erosion of high-grade parts of the nappe. [ABSTRACT FROM AUTHOR]

Ordovician metasedimentary rocks are the oldest and most extensive sedimentary sequence in the Chinese Altai. They experienced two major episodes of deformation (D1 and D2) resulting in the formation of juxtaposed Barrovian-type and migmatite domains. D1 is characterized by a penetrative sub-horizontal fabric (S1), and D2 is marked by upright folds (F2) with NW- SE-trending axial planes in shallow crustal levels and by sub-vertical transposition foliations (S2) in the high-grade cores of large-scale F2 antiforms. In the Barrovian-type domain, successive growth of biotite, garnet and staurolite is observed in the S1 fabric. Kyanite included in garnet and plagioclase in the migmatite domain is interpreted to have formed also in S1. In the biotite and garnet zones, the spaced S2 cleavage is marked by biotite and muscovite, and in the staurolite and kyanite zones, the penetrative S2 fabric is characterized by sillimanite, locally with late cordierite. Phase equilibria modelling indicates that the S1 fabric was associated with an increase in pressure and temperature under Barrovian-type conditions in both domains. The S2 fabric was related to decompression, in which rocks in the biotite and garnet zones well preserve the peak assemblage, and the higher grade rocks in the staurolite and kyanite zones re-equilibrated to different degrees under high-temperature/low-pressure ( H T/ L P) conditions. The D1 metamorphic history is attributed to the progressive burial related to Early-Middle Palaeozoic crustal thickening and the metamorphism associated with D2 is interpreted to result from exhumation by vertical extrusion. The extrusion of hot rocks was contemporaneous with the formation of gneiss domes accompanied by the intrusion of juvenile magmas at middle crustal levels during the Middle Palaeozoic. Consequently, there is a genetic link between the Barrovian-type and migmatite domains related to continuous transition of the Barrovian-type fabric into the H T/ L P one during development of domal structures in the southern Altai orogenic belt. This study has a broad impact on the understanding of the thermo-mechanical behaviour of accretionary orogenic systems worldwide. The lower crustal flow and doming of hot crust, so far reported only in continental collisional settings, seems to be also an integral mechanism responsible for both horizontal and vertical redistribution of accreted material prior to continental collision. [ABSTRACT FROM AUTHOR]

One of the biggest challenge for acoustic emission (AE) signal classification on real constructions is transfer from laboratory measurement on specimens to full scale. Detected AE responses are (among other factors) strongly influenced by propagation of waves in material and transfer function of sensor used. Propagation of elastic stress waves in plate of AISI 304 stainless steel was investigated in this work. Two types of wave excitation were used: broad band HSU-Nielsen source and artificial narrow band source via Vallen VS150-M transducer. AE responses were detected with use of 3 different AE transducers to take into account the effect of sensor transfer function on detected response. Attenuation curves were constructed from extracted amplitudes and digitalized signal was recorded for subsequent advanced analysis. Description of detected wave modes and separation of reflected waves was successfully done with use of combination of voltage-time dependency, wavelet transform (WT) and dispersion curves. Effect of wave propagation and transfer function of a sensor on signal maximum amplitude was discussed.

Urolithiasis is a frequent and in many cases serious disease. Proper analysis of kidney stone composition is crucial for appropriate treatment and prevention of disease recurrence. In this work, scanning electron microscopy (SEM) coupled with energy-dispersive spectroscopy was applied for a study of 30 samples covering the most common types of human kidney stones. The results are analyzed and evaluated in terms of applicability of the method for both routine kidney stone analysis as well as collecting of specific data. The method provides complex information about studied samples including morphology of the stones and of the present crystals or their aggregates. It also brings information on elemental composition of the phases. After application of standardization, quantitative microanalysis with detection limits of 400 ppm (Mg, P, S, Cl, K, Ca), 500 ppm (Na) and 1200 ppm (F) was obtained. Compositional mapping with EDS shows the elemental distribution within a sample. This study demonstrated that information on morphology and chemistry acquired by these methods was highly reliable for identification of phases, even when present in small amounts. It provided information on kidney stone structure, relationships between phases, major and minor element content, and variations in chemical composition related to the growth of the stones. SEM represents a powerful tool in urinary stone analysis, since a single facility can produce a wide spectrum of information. It can be suggested as a basic method used for routine urinary stone identification, whilst bringing additional detailed information that cannot be obtained by other methods.

High concentrations of airborne asbestos in the ambient air are still a serious problem of air quality in numerous localities around the world. Since 2002, elevated concentrations of asbestos minerals of unknown origin have been detected in the ambient air of Pilsen, Czech Republic. To determine the asbestos fibre sources in this urban air, a systematic study was conducted. First, 14 bulk dust samples were collected in Pilsen at nine localities, and 6 bulk samples of construction aggregates for gravel production were collected in a quarry in the Pilsen-Litice district. The quarry is the largest quarry in the Pilsen region and the closest quarry to the built-up urban area. X-ray diffraction of the asbestos minerals revealed that monoclinic amphibole (MA, namely actinolite based on subsequent SEM-EDX analysis) in the bulk samples accounted for < 1-33% of the mass and that the highest values were found in the bulk dust samples from the railway platform of the Pilsen main railway station. Simultaneously, 24-h samples of airborne particulate matter (PM) at three localities in Pilsen were collected. Actinolite was identified in 40% of the PM samples. The relationship between the meteorology and presence of actinolite in the 24 PM 10 samples was not proven, probably due to the long sampling integration time. Therefore, highly time-and-size-resolved PM sampling was performed. Second, sampling of size-segregated aerosols and measurements of the wind speed (WS), wind direction (WD), precipitation (P) and hourly PM 10 , PM 2.5 and PM 1 were conducted in a suburban locality near the quarry in two monthly highly time-resolved periods (30, 60, 120 min). Three/eight PM size fractions were sampled by a Davis Rotating-drum Uniform-size-cut Monitor (3/8DRUM) and analysed for the presences of asbestos fibres by scanning electron microscopy with energy dispersive x-ray spectroscopy (SEM-EDX). Asbestos fibre detection in highly time-resolved PM samples and current WD and WS determination allows the apportionment directionality of asbestos fibre sources. The number of critical actinolite asbestos fibres (length ≥ 5 μm and width < 3 μm, 3:1) increased with the PM 1-10 /PM 10 and PM 2.5-10 /PM 10 ratios, WS > 2 m s -1 and precipitation < 1 mm. Additionally, the number of critical actinolite asbestos fibres was not related to a specific WD. Therefore, we conclude that the sources of airborne critical actinolite asbestos fibres in Pilsen's urban area are omnipresent. Frequent use of construction aggregates and gravel from the metamorphic spilite quarries in the Pilsen region and in many localities around the urban area is a plausible explanation for the omnipresence of the critical actinolite asbestos fibres concentration in Pilsen's ambient air. Mitigation strategies to reduce the concentrations of critical actinolite asbestos fibres must be developed. Continuous monitoring and performing SEM-EDX analysis of highly time-and-size-resolved PM samples, correlated with fast changing WS and WD, seems to be a strong tool for efficiently controlling the mitigation strategies of critical actinolite asbestos fibres.

Increasing amounts of impurities (especially As) in Cu ores have aggravated the problem of flue dust generation in recent years. As an example from a smelter processing As-rich Cu ores, we characterized a flue dust particularly rich in As (>50 wt%) to understand its mineralogy and pH-dependent leaching behavior, with special emphasis on binding, release and solubility controls of inorganic contaminants (As, Bi, Cd, Cu, Pb, Sb, Zn). Whereas arsenolite (As 2 O 3 ) was the major host for As and Sb, other contaminants were bound in sulfides, arsenates, alloys and slag-like particles. The EU regulatory leaching test (EN 12457-2) indicated that leached As, Cd, Sb and Zn significantly exceeded the limit values for landfills accepting hazardous waste. The pH-dependent leaching test (CEN/TS 14997) revealed that As, Sb and Pb exhibited the greatest leaching at pH 11-12, whereas Cd, Cu and Zn were leached most under acidic condition (pH 3) and Bi leaching was pH-independent. Mineralogical investigation of leached residue coupled with geochemical modeling confirmed that newly formed Ca, Pb and Ca-Pb arsenates (mimetite, Pb 5 (AsO 4 ) 3 Cl) partly control the release of As and other contaminants under circumneutral and alkaline conditions and will be of key importance for the fate of smelter-derived contamination in soils or when stabilization technology is employed., (Copyright © 2017 Elsevier Ltd. All rights reserved.)