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ABSTRACT: A series of field-based multi-physics observations were conducted as part of the Brine Availability Test in Salt (BATS) underground at the Waste Isolation Pilot Plant (WIPP), near Carlsbad, NM. Observations were made of brine production, temperature, electrical resistivity, acoustic emissions (AE), and gas/liquid tracer migration through salt around twin heated/unheated borehole arrays. Here, we present AE results from thermal cycling experiments performed May - July 2021, during which the heater was pulsed several times followed by two longer heated periods. Sixteen AE sensors were installed in three parallel observational boreholes surrounding the central heated borehole. Observed AE demonstrate that heating and cooling cycles significantly impact salt behavior. AE rates increased during heating and increased further upon cooling. Average energy and frequency bandwidth also increased during heating and cooling of salt. Similar behavior was observed for each heating/cooling cycle, suggesting that temperature-enhanced salt healing may have eliminated any threshold loading associated with the onset of AE (i.e., the Kaiser effect). Locations of AE events remained centralized around the borehole. These results show that AE provide valuable information about the thermal behavior of salt, particularly that cooling of salt results in the highest AE behavior. 1. INTRODUCTION The Waste Isolation Pilot Plant (WIPP) outside of Carlsbad, NM is the nation’s only active geologic repository for nuclear waste. Currently, WIPP is licensed to dispose of transuranic radioactive waste from defense activities. The US Department of Energy Office of Nuclear Energy’s (DOE-NE) Spent Fuel and Waste Science and Technology program is pursuing generic research into multiple possible disposal media (i.e., salt, argillite, and crystalline rocks) for heat-generating waste from spent nuclear fuel. The DOE Office of Environmental Management (DOE-EM) that manages the WIPP site provides access to the WIPP underground DOE-NE work that is testing the behavior of the generic bedded salt under conditions relevant to spent fuel and high-level waste disposal.

Declining sea ice in the Arctic Ocean is exposing its coasts to more frequent and intense forms of wave energy and storm surge. As a result, erosion rates along some stretches of coastline in the A...

The success of geological carbon storage (GCS) depends on the sealing properties of caprocks, typically mudrocks, and their laminated variety – shales. In this study, we examined mineralogical changes in carbonate-rich Mancos Shale and corresponding changes in micro-mechanical properties following the reaction with carbon dioxide (CO2). Mineralogical changes of Mancos Shale depended on the pressure of CO2 during its exposure to the CO2-brine mixtures for up to 8 weeks. Dedolomitization was observed in the reactors pressurized with 100 psi of CO2, combined with the precipitation of gypsum. In the reactor pressurized with 2500 psi of CO2, the complete dissolution of calcite, partial dissolution of dolomite, and precipitation of magnesite and anhydrite were observed. Localized mechanical weakening was observed only for dolomite-muscovite-illite-rich laminae following whole shale puck alteration at 2500 psi of CO2, and a decrease of up to 50 ± 20% in scratch toughness was observed. The quartz-calcite-rich laminae did not exhibit a measurable difference in scratch toughness before and after reaction in CO2-rich brine. The predicted changes in mineralogy, porosity, density, and hardness of Mancos Shale are limited, according to the geochemical models describing alteration of shale by CO2-rich brine lasting for 5000 years. This study illustrates a coupled and localized chemical-mechanical response of caprock to the injection of CO2.

Calcite (CaCO3) is one of the most abundant minerals in the Earth’s crust, and it is susceptible to subcritical chemically-driven fracturing. Understanding chemical processes at individual fracture tips, and how they control the development of fractures and fracture networks in the subsurface, is critical for carbon and nuclear waste storage, resource extraction, and predicting earthquakes. Chemical processes controlling subcritical fracture in calcite are poorly understood. We demonstrate a novel approach to quantify the coupled chemical-mechanical effects on subcritical fracture. The calcite surface was indented using a Vickers-geometry indenter tip, which resulted in repeatable micron-scale fractures propagating from the indent. Individual indented samples were submerged in an array of aqueous fluids and an optical microscope was used to track the fracture growth in situ. The fracture propagation rate varied from 1.6 × 10−8 m s−1 to 2.4 × 10−10 m s−1. The rate depended on the type of aqueous ligand present, and did not correlate with the measured dissolution rate of calcite or trends in zeta-potential. We postulate that chemical complexation at the fracture tip in calcite controls the growth of subcritical fracture. Previous studies indirectly pointed to the zeta-potential being the most critical factor, while our work indicates that variation in the zeta-potential has a secondary effect.