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Synthetic plastic is a material that is difficult to decompose in the environment and causes serious problems in long term such as an increase in the volume of waste. To reduce plastic waste, biodegradable composite (biocomposite) is expected to overcome this problem. Natural cellulose fiber can be used as a filler in biopolymer matrix based biocomposite. This study aims to determine the tensile properties, fracture morphology, and biodegradation rate of biocomposite from Polyvinyl Alcohol (PVA) and sugarcane bagasse fiber. The test of biocomposite samples was carried out with a tensile test, scanning electron microscopy (SEM), and soil burial test. The results show that the highest tensile strength and modulus elasticity was in PVA pure film for 2.15 MPa and 3.468 MPa, respectively. The addition of cellulose fiber from sugarcane bagasse in the PVA matrix does not have a strengthening effect on the tensile strength of the biocomposite. This is due to the presence of porosity, agglomeration, and poor bonding between the matrix and fiber according to the SEM observation. The biodegradation rate showed that all biocomposite samples were degraded in the soil and had weight loss above 40% after 15 days of burial in the soil.

Owing to the increasing global pollution due to the use of conventional plastic materials, biodegradable films and sheets have been given prominent importance owing to their efficiency in replacing traditional plastic materials. In the recent times, due to globalization and industrialization, the minimization of the use of synthetic petroleum-based materials has been in practice by the global community, and increase in the use of natural materials like biomass waste in place of traditional materials promoting the green and sustainable technology development. Such production of alternative biomaterials development from the lignocellulosic fiber-reinforced composite films and laminates has been seriously investigated by engineers, technologists, and materialists owing to their sustainability, renewability, low toxicity, and abundantly available. Banana is one among the largely consumed tropical crop globally which is due to the quantity of cultivation and the availability of calorific values in the fruit. It is also a fruit which is potentially rich in starch content with more than 65 % of starch. This banana starch can be considered as a potential material for the manufacturing of coating material, edible sheet, food preservation and packaging owing to its innocuous, less cost, and biodegradability. The application of banana starch is dictated by the functional, structural and physicochemical properties of the developed material. But an unmodified native banana starch may not be characterized with all the necessary properties for any customized application. In order to widen the application band of the banana starch, it has to be modified by using enzymes, chemical, and physical methods. This review comprehensively deals with the extraction and synthesis of banana starch from various sources, their modification, properties of the banana starch and its characterization. Some aspects regarding the hybridization of the banana starch with nanoparticles has also been given.

In the past few decades, there has been increased interest in the use of natural fibers as reinforcement in bioplastic polymer composites because it is biodegradable. This is a result of the drawbacks of biodegradable polymer-based materials, which are brittle, intractable, and poorly water-sensitive. Natural fibers are chosen because they may be obtained organically, can be collected safely, and can be less expensive. In this work, cinnamon essential oil (CEO)/sugar palm nanocellulose/starch biopolymer composites were casted to investigate the morphological, water barrier and biodegradable properties. From the research, it shows water absorption increased regarding the plasticizer concentration. Besides, water vapor permeability (WVP) and solubility of the different concentration plasticizer used in the biopolymer shows an increasing trend due to high water content. All films degrade completely after the 12th day indicating the biodegradability of the film. Furthermore, seal strength for the lower concentrations of plasticizer shows the higher strength, while GS4.5 cannot be sealed due to high water contents. The images show the compatible films with slightly yellowish and transparent films. The variation of plasticizers did not affect the antibacterial activity of CEO inside the film forming solution. Overall, cinnamon essential oil (CEO)/sugar palm nanocellulose/starch biopolymer composites are good potential to enhance their suitability for food packaging applications.

The growing consciousness about global environmental concerns, particularly landfills, in conjunction with the rapid use of petroleum-based plastics, is a key factor behind the use of natural and biodegradable polymers in short-life applications like food packaging, container, and tray. Sugar palm stem is a biomass that has proven the potential to produce biodegradable polymers such as sugar palm starch. Nevertheless, their applications were limited due to their low tensile strength and excessive hydrophilicity. Plasticization using polyols, reinforcement with sugar palm fiber, cellulose, microcrystalline cellulose, or nanocellulose, blending with thermoplastic polymer, and addition of essential oils has been used to maximize the functional qualities of the starch biopolymer. As the content of plasticizers grew, the glass transition temperature and water absorption ability decreased. Furthermore, the addition of sugar palm nanocellulose to sugar palm starch improves the performances of sugar palm starch-based films as a packaging material. Addition of essential oil contributes to antibacterial properties and slightly improved tensile strength of the film. A comprehensive understanding on the interaction of starch-based biodegradable polymer and nanocellulose constituents for enhancing the physico-chemical properties of starch-based films is prerequisite for researchers in the design of industrial products with enhanced functional attributes. To address the knowledge gap, more studies including the reinforcement of new types of biodegradable polymer and nanocellulose derived from natural sources should be conducted in order to continually populate the database for research purposes.

Nanocellulose is a product of cellulose, a sustainable and plentiful resource. It’s distinctive nanoscale structure makes it a versatile, green and interesting material for a variety of applications. This article describes in detail the biosources of nanocellulose, the types and characteristics of nanocellulose, and the techniques used to produce nanocellulose fibers. The mechanical properties and morphologies of nanocellulose fibers are addressed in depth, along with their prospective applications in sectors, including paper packaging, building materials, composites, biomedicine, energy storage and filtration. In addition, the current state of nanocellulose research, including the opportunities in the field, as well as the future prospects of nanocellulose as a viable and sustainable material for a vast array of applications, are discussed.

Araucaria Araucana starch is a raw material with proven potential in obtaining biodegradable polymers. Plasticization improves the flexibility characteristics of starch-based films, however, they still tend to have low tensile strength and high hydrophilicity. The addition of nanocellulose is a technique to improve these characteristics. In this paper, the effects of adding different sources and concentrations of nanocellulose (NC) on the properties of thermoplastic Araucaria Araucana films are addressed. One can highlight, the main effects are the increase of tensile strength and transparency of the films along with the reduction of water vapor permeability and water solubility. Further studies involving the reinforcement of Araucaria Araucana starch and nanocellulose should be conducted to overcome the lack of information.

The title of this research is "Intercourse Conducted by Siblings (Persuasion) in Criminal Perspectives" based on normative juridical research through legislation and conceptual approaches. Then do a search and analysis to answer the legal issues faced and draw conclusions in the end. Intercourse with siblings (incest) is rife in social life. This is due to several factors, both internally and externally. This action does not yet have concrete qualifications related to criminal acts and there is no formulation in material criminal law, either in the Criminal Code or special laws. The incest has negative impacts both biologically and sociologically, so it is necessary to conduct a study of the Qualifications of Sexual Relationships with Siblings (with blood) that have implications for criminal acts and criminal liability for perpetrators of crimes related to incest as legal issues faced. The results of this study are in the form of qualifications for incestuous relations on the basis of the legal conception of incestuous relations and criminal liability based on several legal rules (laws). Keywords: Intercourse; Siblings; Incest; Criminal Acts. AbstrakJudul penelitian ini “Persetubuhan dengan Kekerasan yang dilakukan dengan Saudara Sekandung (Sedarah) dalam Kualifikasi Tindak Pidana” yang berlandaskan penelitian yuridis normatif melalui pendekatan perundang-undangan dan pendekatan konseptual. Kemudian dilakukan penelusuran dan analisis untuk menjawab isu hukum yang dihadapi dan menarik kesimpulan pada akhirnya. Persetubuhan dengan saudara sekandung (incest) marak terjadi dalam kehidupan bermasyarakat. Hal ini dikarenakan beberapa faktor, baik secara internal maupun eksternal. Tindakan ini belum memiliki kualifikasi yang konkret terkait dengan tindak pidana dan belum adanya perumusan dalam hukum pidana materiil, baik dalam KUHP maupun undang-undang khusus. Incest notabenenya memiliki dampak-dampak negatif secara biologis maupun sosiologis, sehingga perlu dilakukan penelitian terhadap Kualifikasi Hubungan Seksual Dengan Saudara Sekandung (Sedarah) yang Berimplikasi Tindak Pidana dan Pertanggungjawaban Pidana Terhadap Pelaku Tindak Pidana Terkait Incest sebagai isu hukum yang dihadapi. Hasil dari penelitian ini berupa kualifikasi tindak pidana hubungan incest atas dasar konsepsi hukum hubungan incest serta pertanggungjawaban pidananya berdasarkan beberapa aturan hukum (undang-undang). Kata Kunci: Persetubuhan; Saudara Kandung; Inses; Tindak Pidana.

Bio-based materials must be studied to replace polymers from petrochemical sources in packaging applications. However, using polymers from petrochemical sources has caused consumer and environmental concerns. Therefore, synthetic and non-synthetic materials that can be used for packaging applications, scale-up methods, industrial uses, sustainability assessments, and end-of-life alternatives will all be included in this study. Synthetic polymers, e.g., polylactic acid (PLA), polyethylene furanoate (PEF), polybutylene succinate (PBS), and non-synthetic polymers, including waxes, lipids, proteins, starch, cellulose, and polyhydrodialkanoate (PHAs), are some of the bio-based compounds that will be covered in this work. Besides that, more attention is paid to surface modification techniques and coatings, multilayers, biocomposites, and additives used to modify material characteristics, particularly gas and moisture barriers and biodegradability. In sum, this research offers a comprehensive analysis of bio-based packaging materials, including processing, and an assessment of sustainability and available alternatives.

The efficacy of wood dust fibre treatment on the property of wood dust reinforced recycled polypropylene composite (r-WoPPC) filament was investigated. The wood dust fibre was treated using alkali, silane, and NaOH-silane. The treated wood fibre was incorporated with r-PP using a twin-screw extruder to produce filament. The silane treatment on wood dust fibre enhances interfacial bonding between wood fibre and recycled PP; hence, a filament has the highest wire pull strength, which is 35.2% higher compared to untreated and alkaline-treated wood dust filament. It is because silanol in silane forms a siloxane bond that acts as a coupling agent that improves interfacial bonding between wood dust fibre and recycled PP. The SEM micrograph of the fracture structure reveals that treated silane has strong interfacial bonding between wood dust fibre and recycled PP, having minimal void, gap, and good fibre adhesion. The water absorption test results indicate that filament with treated wood dust absorbs less water than filament with untreated wood because the treatment minimizes the gap between wood fibres and recycled PP. The FTIR analysis identified the presence of silane on the wood dust surface for silane-treated wood dust. The DSC studies suggest that the temperature range 167–170 °C be used in the extrusion machine to produce r-WoPPC filament. As a result, r-WoPPc filaments containing silane-treated wood dust have better mechanical properties and have a greater potential for usage in FDM applications.

Biocomposite materials are essential for environmental protection, as they have the ability of substituting synthetic plastic with natural materials. This work investigated how different plasticizers (Glycerol (G), Fructose (F), Sorbitol (S), and Urea (U)) affect the morphological, mechanical, thermal, and physical characteristics of films made of wheat starch at various concentrations (0%, 15%, 25%, and 35%). Plasticizers were added to improve the flexibility and homogeneity of the wheat starch-based bioplastic. Control film exhibited high tensile strength (38.7 MPa) with low elongation (1.9%). However, films plasticized with 35% sorbitol showed the highest elongation, which was 60.7% at break. At 35% of all plasticizers, fructose showed the highest tensile strength, with 7.6 MPa. The addition of different plasticizers shows improvement in water resistance; films plasticized with glycerol had the lowest water absorption at 35% fructose (187.4%) and also showed coherent surfaces. Glycerol, sorbitol, and urea films showed a higher mass loss compared to fructose films. Fructose showed the highest performance after the analysis of the results, with low water absorption, water content, and mass loss and with high mechanical performance at 35% of fructose. SEM images show that the addition of fructose and glycerol improves the surface homogenate, while sorbitol and urea have a less compact structure with large pores.

The rapid use of petroleum resources coupled with increased awareness of global environmental problems associated with the use of petroleum-based plastics is a major driving force in the acceptance of natural fibers and biopolymers as green materials. Because of their environmentally friendly and sustainable nature, natural fibers and biopolymers have gained significant attention from scientists and industries. Cassava (

The development of environmentally benign silicone composites from sugar palm fibre and silicone rubber was carried out in this study. The mechanical, physical, and morphological properties of the composites with sugar palm (SP) filler contents ranging from 0% to 16% by weight (wt%) were investigated. Based on the uniaxial tensile tests, it was found that the increment in filler content led to higher stiffness. Via dynamic mechanical analysis (DMA), the viscoelastic properties of the silicone biocomposite showed that the storage modulus and loss modulus increased with the increment in filler content. The physical properties also revealed that the density and moisture absorption rate increased as the filler content increased. Inversely, the swelling effect of the highest filler content (16 wt%) revealed that its swelling ratio possessed the lowest rate as compared to the lower filler addition and pure silicone rubber. The morphological analysis via scanning electron microscopy (SEM) showed that the sugar palm filler was evenly dispersed and no agglomeration could be seen. Thus, it can be concluded that the addition of sugar palm filler enhanced the stiffness property of silicone rubber. These new findings could contribute positively to the employment of natural fibres as reinforcements for greener biocomposite materials.

Materials that exhibit highly nonlinear behaviour are intricate to study. This is due to their physical properties, as they possess a very large deformation. Silicone rubber is among the materials that can be classified as possessing such characteristics, despite their being soft and frequently applied in medical applications. Due to their low mechanical properties, however, it is believed that a filler addition could enhance them. This study, therefore, aims to investigate the effect of the addition of bamboo cellulosic filler to silicone rubber in terms of its compressive properties in order to quantify its material constants using the hyperelastic theory, specifically the Neo-Hookean and Mooney–Rivlin models. The specimens’ compressive properties were also compared between specimens immersed in seawater and those not immersed in seawater. The findings showed that the compressive properties, stiffness, and compressive strength of the bamboo cellulosic fibre reinforced the silicone rubber biocomposites, improved with higher bamboo filler addition. Specimens immersed in seawater showed that they can withstand a compressive load of up to 83.16 kPa in comparison to specimens not immersed in seawater (up to 79.8 kPa). Using the hyperelastic constitutive models, the Mooney–Rivlin model displayed the most accurate performance curve fit with the experimental compression data with an R2 of up to 0.9999. The material constant values also revealed that the specimens immersed in seawater improved in stiffness property, as the C1 material constant values are higher than for the specimens not immersed in seawater. From these findings, this study has shown that bamboo cellulosic filler added into silicone rubber enhances the material’s compressive properties and that the rubber further improves with immersion in seawater. Thus, these findings contribute significantly towards knowledge of bamboo cellulosic fibre–reinforced silicone rubber biocomposite materials.

Concrete is a composite material that is commonly used in the construction industry. It will certainly be exposed to fires of varying intensities when used in buildings and industries. The major goal of this article was to look into the influence of mineral additions such as foundry sand and marble dust on the residual characteristics of concrete. To examine the behavior of residual characteristics of concrete after fire exposure, marble dust was substituted for cement and fine sand was substituted for foundry sand in varying amounts ranging from 0% to 20%. It aided in the better disposal of waste material so that it might be used as an addition. The purpose of the experiment was to see how increased temperatures affected residual properties of concrete, including flexural strength, compressive strength, tensile strength, static as well as dynamic elastic modulus, water absorption, mass loss, and ultrasonic pulse velocity. At temperatures of 200 °C, 400 °C, 600 °C, 800 °C, and 1000 °C, the typical fire exposure behavior of concrete was investigated. The effects of two cooling techniques, annealing and quenching, on the residual properties of concrete after exposure to high temperatures were investigated in this study. Replacement of up to 10% of the cement with marble dust and fine sand with foundry sand when concrete is exposed to temperatures up to 400 °C does not influence the behavior of concrete. At temperatures above 400 °C, however, the breakdown of concrete, which includes marble dust and foundry sand, causes a rapid deterioration in the residual properties of concrete, primarily for replacement of more than 10%.

Ever since the introduction of 3D printing, industries have seen an exponential growth in production and efficiency. Three-dimensional printing is the process of additive manufacturing (AM) in which the conventional method of material removal is challenged. Layer-on-layer deposition is the basic principle of the AM. Additive manufacturing technologies are used to create 3D-printed objects. An object is built in an additive technique by laying down successive layers of material until the object is complete. Each of these layers can be viewed as a cross-section of the item that has been lightly cut. When compared to traditional production methods, 3D printing allows the creation of complicated shapes with less material. In conventional methods, the materials go through several damages due to the tool–workpiece contact creating friction between them and the dissipated heat that damages the material. Overcoming the conventional method of machining with the help of 3D printing is a new advancement in the industries. The process involves using non-conventional methods for the machining of the parts. This research was oriented towards the chemical vapor jet drilling of the acrylonitrile–butadiene–styrene (ABS) materials. ABS materials are highly machinable and can be recycled for further usage. This paper focused on the usage of acetone as the chemical for drilling. The surface roughness and circularity of the drilled hole was taken into account for this research paper. We set up a manual experiment to run tests and get results. A vapor jet machine was designed with acetone as the core for the vapor. Various analyses were also formulated and conducted during experimentations. Surface roughness analysis provided the insight of roughness after the machining with the help of acetone vapor jet spray. SEM and micro-image parameters were also considered for more clear and advanced reports. In this research paper, DSC and FTIR analysis were performed to understand changes in the internal structure and the material properties of the ABS. Moreover, the research aimed to investigate the effect of various inputs processing parameters such as pressure, flow rate, and stand-off distance on the surface roughness and circularity of ABS workpiece material. The Taguchi L9 orthogonal array design was utilized to conduct tests by chemical vapor jet drilling using acetone and to evaluate the performance of the set-up while reducing the influence of interfering factors in order to provide reliable surface finish and circularity results. The results and conclusion of the research paper aimed to determine the most suitable parameters for the non-conventional acetone vapor jet drilling of the ABS material. The theoretical calculations predicted 1.64432 and 0.3289080 values of surface roughness and circularity, respectively. On the other hand, the experimental values were recorded as 1.598 for surface roughness and 0.322 for circularity. Therefore, a negligible error of 0.046 for surface roughness and 0.0031 for circularity, respectively, was noted which validate the statistical equations and the consistency of the combined vapor jet drilling process.

The present study investigates the preference index of natural fibers such as sisal, coir, and rice straw fibers in stone matrix asphalt mixtures (SMA), using waste marble as filler. Waste marble was used as the filler in asphalt mixtures and was crushed by abrasion machine and sieved according to SMA filler requirements. The SEM topography and EDS analysis of sisal, coir, and rice straw fibers were also carried out. The Marshall test was conducted, which is the most acceptable, cost-effective, and widely adopted method to estimate the optimum bitumen and to examine several Marshall Measures, such as flow value, voids filled with bitumen (VFB), stability, voids in mineral aggregate (VMA), and air voids (VA). Furthermore, tests were performed on the specimen with the optimum amount of bitumen, different percentages of fibers, and waste marble as filler to calculate drain down, moister sensitivity, and Marshall Stability. Multi-criteria decision-making (MCDM) techniques were implemented to obtain subjective and objective weights, which were further used to compute the values of the preference index of natural fiber contents. The outcomes revealed favorable results for the usage of marble dust as filler in Stone Matrix Asphalt (SMA). In addition, the preference index upshots are inclined toward the usage of rice straw over coir followed by sisal fiber. It was observed that the value of the preference index in rice straw at 0.3 varied from 0.918, 0.925, and 0.931 in rice straw using equal, objective, and subjective weights, respectively. The maximum drain down value observed is 0.335 based on ASTM-D 6390 and IRC-SP-79 are against 0.3 percent natural fiber. Moreover, as per the prescribed limit of MoRTH, because of the thin film around aggregates, moisture susceptibility characteristics, i.e., better resistance to moisture, were enhanced by more than 80%.

Oil palm nanocellulose has been demonstrated to display a wide range of unique properties for many fields. They are suitable for biomedical applications and have been used in this domain for decades. The current variety of nanocellulose fibers allows the development of new nanocomposites. This work fabricated oil palm nanocellulose with variations of fiber loading (1, 2, 3, 4, and 5 wt%) and thermoplastic polyurethane (TPU) polymer matrix by using a mechanical stirring followed by hot pressing methods. The physical characters of nanocellulose oil palm reinforced TPU nanocomposites, such as water absorption, thickness swelling, and density were characterized. The fiber loading of oil palm nanocellulose content at 5 wt% shows the highest water uptake, thickness swelling, and the lowest density properties of oil palm nanocellulose reinforced TPU nanocomposites.

Advances in Sustainable Nanocomposites is a newly opened Special Issue of Sustainability, that aims to publish original and review papers on the new scientific development of sustainable nanocomposite materials that are accelerated by zero-carbon policy goals [...]

The production of prompt D-0, D+, and D*(+) mesons was measured at midrapidity (vertical bar y vertical bar < 0.5) in Pb-Pb collisions at the centre-of-mass energy per nucleon-nucleon pair root S-NN = 5.02 TeV with the ALICE detector at the LHC. The D mesons were reconstructed via their hadronic decay channels and their production yields were measured in central (0-10%) and semicentral (30-50%) collisions. The measurement was performed up to a transverse momentum (p(T)) of 36 or 50 GeV/c depending on the D meson species and the centrality interval. For the first time in Pb-Pb collisions at the LHC, the yield of D-0 mesons was measured down to p(T) = 0, which allowed a model-independent determination of the p(T)-integrated yield per unit of rapidity (dN/dy). A maximum suppression by a factor 5 and 2.5 was observed with the nuclear modification factor (R-AA) of prompt D mesons at p(T) = 6-8 GeV/c for the 0-10% and 30-50% centrality classes, respectively. The D-meson R-AA is compared with that of charged pions, charged hadrons, and J/psi mesons as well as with theoretical predictions. The analysis of the agreement between the measured R-AA, elliptic (v(2)) and triangular (v(3)) flow, and the model predictions allowed us to constrain the charm spatial diffusion coefficient D-s. Furthermore the comparison of R-AA and v(2) with different implementations of the same models provides an important insight into the role of radiative energy loss as well as charm quark recombination in the hadronisation mechanisms.

This research is driven by stringent environmental legislation requiring the consumption and use of environmentally friendly materials. In this context, this paper is concerned with the development and characterization of thermoplastic arrowroot starch (TPAS) based biocomposite films by incorporating arrowroot fiber (AF) (0-10%) into a glycerol plasticized matrix by using the solution casting method. Developed TPAS/AF composite films were investigated, such as physical, morphological (FESEM), tensile, and tear strength characteristics. The tensile and tear strengths of TPAS/AF composites were increased significantly from 4.77 to 15.22 MPa and 0.87 to 1.28 MPa, respectively, as compared to the control TPAS films, which were 2.42 MPa and 0.83 MPa, respectively, while elongation was significantly decreased from 25.57 to 6.21% compared to control TPAS film, which was 46.62%. The findings revealed that after the fiber was reinforced, the mechanical properties were enhanced, and the optimum filler content was 10%. Regardless of fiber loadings, the results of water absorption testing revealed that the composite films immersed in seawater and rainwater absorbed more water than distilled water. Overall, the results of this research focus on providing information on biopolymer composite film and revealing the great potential it has for the food packaging industry.