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In order to express the energy flow, motion flow, and control flow in wireless rechargeable sensor networks accurately and intuitively, and to maximize the charging benefit of MVs (mobile vehicles), a type of MTS-HACO (Mobile Transition Sequence Hybrid Ant Colony Optimization) is proposed. Firstly, node places are grouped according to the firing time of node's energy consumption transition to ensure that in each time slot, MV places only enable charging transitions for the node places with lower remaining lifetimes. Then, the FSOMCT (Firing Sequence Optimization of Mobile Charging Transition) problem is formulated under the constraints of MV places capacity, travelling arc weight, charging arc weight, and so on. The elite strategy and the Max–Min Ant Colony system are further introduced to improve the ant colony algorithm, while the improved FWA (fireworks algorithm) optimizes the path constructed by each ant. Finally, the optimal mobile charging transition firing sequence and charging times are obtained, ensuring that MVs have sufficient energy to return to the base station. Simulation results indicate that, compared with the periodic algorithm and the PE-FWA algorithm, the proposed method can improve charging benefit by approximately 48.7% and 26.3%, respectively. [ABSTRACT FROM AUTHOR]

Semi‐hydrogenation of alkynes to industrially important alkenes is earnestly desirable in the fine chemical industry but energetically unfavorable. Herein, it is reported that mesoporous palladium (meso‐Pd) catalyst changes the hydrogenation pathways in ethanol with ammonium borane as the hydrogen source, realizing the high catalytic selectivity of ≈99% in semi‐hydrogenation of alkynes. Mechanism studies reveal that the active polar hydrogen can be produced and reserved well in the electron‐rich mesoporous channels of meso‐Pd catalyst, resulting in a transfer hydrogenation pathway, which selectively semi‐hydrogenates alkynes into alkenes without over‐hydrogenating alkenes into alkanes. Moreover, it is demonstrated that the polar hydrogen engineering of meso‐Pd catalyst is highly efficient in various alkyne semi‐hydrogenation and chemoselective hydrogenation reactions. The results thus establish metal catalyst mesostructuring as an alternative route for engineering polar hydrogen in the transfer hydrogenation reactions, thus realizing the high catalytic selectivity in various selective catalysis. [ABSTRACT FROM AUTHOR]

We report a general concurrent template strategy for precise synthesis of mesoporous Pt-/Pd-based intermetallic nanoparticles with desired morphology and ordered mesostructure. The concurrent template not only supplies a mesoporous metal seed for re-crystallization growth of atomically ordered intermetallic phases with unique atomic stoichiometry but also provides a nanoconfinement environment for nanocasting synthesis of mesoporous nanoparticles with ordered mesostructure and rhombic dodecahedral morphology under elevated temperature. Using the selective hydrogenation of 3-nitrophenylacetylene as a proof-of-concept catalytic reaction, mesoporous intermetallic PtSn nanoparticles exhibited remarkably controllable intermetallic phase-dependent catalytic selectivity and excellent catalytic stability. This work provides a very powerful strategy for precise preparation of ordered mesoporous intermetallic nanocrystals for application in selective catalysis and fuel cell electrocatalysis., (© 2022 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH.)

We reported mesoporosity engineering as a general strategy to promote semihydrogenation selectivity of palladium (Pd)-based nanobundles catalysts. The best mesoporous PdP displayed full conversion, remarkable activity, excellent selectivity, and high stability in semihydrogenation of 1-phenyl-1-propyne, all of which are remarkably better than commercial Lindlar catalysts. Mechanistic investigations ascribed high semihydrogenation selectivity to the continuous crystalline framework and penetrated mesoporous channel of catalysts that weakened the adsorption and interaction capacity of alkenes and thus inhibited over-hydrogenation of alkenes to industrially unfavorable alkanes. Density functional theory calculations further demonstrated that convex crystalline mesoporosity of nanobundles catalysts electronically optimized the coordination environment of Pd active sites and energetically changed hydrogenation trends, resulting in a superior semihydrogenation selectivity to targeted alkenes., (© 2021 Wiley-VCH GmbH.)