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This paper introduces a memory-reduction third-order compact gas-kinetic scheme (CGKS) for solving compressible Euler and Navier-Stokes equations on 3D unstructured meshes. The scheme utilizes a time-evolution gas distribution function to provide a time-evolution solution at cell interfaces, enabling the implementation of Hermite WENO techniques for high-order reconstruction. However, the HWENO method needs to store a coefficients matrix for the quadratic polynomial to achieve third-order accuracy, resulting in high memory usage. A novel reconstruction method, built upon HWENO reconstruction, has been designed to enhance computational efficiency and reduce memory usage compared to the original CGKS. The simple idea is that the first-order and second-order terms of the quadratic polynomials are determined in a two-step way. In the first step, the second-order terms are obtained from the reconstruction of a linear polynomial of the first-order derivatives by only using the cell-averaged slopes, since the second-order derivatives are nothing but the "derivatives of derivatives". Subsequently, the first-order terms left can be determined by the linear reconstruction only using cell-averaged values. Thus, we successfully split one quadratic least-square regression into several linear least-square regressions, which are commonly used in a second-order finite volume code. Since only a small matrix inversion is needed in a 3-D linear least-square regression, the computational cost for the new reconstruction is dramatically reduced and the storage of the reconstruction-coefficient matrix is no longer necessary. The proposed new reconstruction technique can reduce the overall computational cost by about 20 to 30 percent. The challenging large-scale unsteady numerical simulation is performed, which demonstrates that the current improvement brings the CGKS to a new level for industrial applications., Comment: arXiv admin note: substantial text overlap with arXiv:2402.02075

Under ambient conditions, we directly observed NaCl crystals experimentally in the rGO membranes soaked in the salt solution with concentration below and far below the saturated concentration. Moreover, in most probability, the NaCl crystals show stoichiometries behavior. We attribute this unexpected crystallization to the cation-{\pi} interactions between the ions and the aromatic rings of the rGO., Comment: 5pages, 2 figures

Because they may provide ultrathin, high-flux, and energy-efficient membranes for precise ionic and molecular sieving in aqueous solution, GO membranes (partially oxidized, stacked sheets of graphene) have shown great potential in water desalination and purification, gas and ion separation, biosensors, proton conductors, lithium-based batteries and super-capacitors. Unlike carbon nanotube (CNT) membranes, in which the nanotube pores have fixed sizes, the pores of GO membranes - the interlayer spacing between GO sheets - are of variable size. This presents a challenge for using GO membranes for filtration. Despite the great efforts to tune and fix the interlayer spacing, it remains difficult both to reduce the interlayer spacing sufficiently to exclude small ions while keeping this separation constant against the tendency of GO membranes to swell when immersed in aqueous solution, which greatly affects the applications of GO membranes. Here, we demonstrate experimentally that highly efficient and selective ion rejection by GO membranes can be readily achieved by controlling the interlayer spacing of GO membranes using cations (K+, Na+, Ca2+, Li+ and Mg2+) themselves. The interspacing can be controlled with precision as small as 1 A, and GO membranes controlled by one kind of cation can exclude other cations with a larger hydrated volume, which can only be accommodated with a larger interlayer spacing. First-principles calculations reveal that the strong noncovalent cation-pi interactions between hydrated cations in solution and aromatic ring structures in GO are the cause of this unexpected behavior. These findings open up new avenues for using GO membranes for water desalination and purification, lithium-based batteries and super-capacitors, molecular sieves for separating ions or molecules, and many other applications., Comment: 11 pages, 4 figures