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The pulp and paper industry has significant sustainability implications and necessarily requires a careful consideration of direct and lower-tier suppliers for effective sustainable supply chain management. This paper utilized an extensive literature review and semi-structured interviews of experts in the Chinese pulp and paper industry to unearth the factors that highly influence multi-tier supply chain sustainability. A Technological-Organizational-Environmental (TOE) and Human-Organizational-Technological (HOT-fit) based theoretical framework was employed to classify the identified factors. Then, an Analytical Hierarchy Process (AHP) based methodology was applied to determine the relative importance of the factors. A comparison analysis of the relative importance of the factors as determined by the experts in the focal companies, Tier-1 suppliers and Tier-2 suppliers of the Chinese pulp and paper industry is presented. The results show that institutional and technological factors are most critical to actualizing multi-tier supply chain sustainability. Thus, the study outcomes present relevant theoretical and practical implications for the managers and practitioners in the pulp and paper industry on how to facilitate multi-tier supply chain sustainability for increased competitiveness. Furthermore, this study provides guidelines for other industries as well and sets the stage for subsequent theorization and exploration of multi-tier supply chain sustainability for expected performance gains. [ABSTRACT FROM AUTHOR]

This study focuses on the elimination of residual dyes from industrial wastewater using talc as an adsorbent. Talc is an easily available, ecological, and inexpensive adsorbent. The adsorption process was tested on two model dye samples (Ecozol Blue LR Liquid and Cartasol Yellow 3GF Direct Yellow 132), and two samples of real wastewater from the pulp and paper industry (PM and TP). Kinetic studies revealed that the adsorption of Ecozol Blue LR Liquid followed pseudo-second-order kinetics, while the other tested samples followed pseudo-first-order kinetics. Langmuir, Freundlich, and Dubinin-Radushkevich adsorption isotherm models were also evaluated. The Langmuir isotherm model best fitted the experimental data for the adsorption of model dye solutions and wastewater sample TP onto talc. For wastewater sample PM, the Dubinin-Radushkevich isotherm model provided the best fit to the experimental data. The results of the adsorption isotherms indicated that the adsorption of all tested systems was favorable and primarily involved physical adsorption. The adsorption efficiency for the model solutions exceeded 90 %. For real wastewater samples, the monitored adsorption efficiency in the COD pollution indicator was less efficient, ranging from 43 to 51 %. The lower efficiency of COD may have resulted from the adsorption of residual dyes with lower specific COD values before the adsorption of other organics.

Cellulose and paper produce significant waste such as ash, activated sludge, and sludge from the pulp and paper industry. Depending on the raw material, legislation, and subprocesses, these sludges contain around 30–50% organic matter, mainly composed of less than 0.02 mm cellulose fibers and hemicellulose and lignin. This work used sludge from the pulp and paper industry as a substrate for manufacturing mycelium-based biomaterials using the white rot fungus Trametes versicolor. Chemical and surface analyses revealed the formation of new materials. Acoustic impedance analyses revealed that these materials have a noise reduction coefficient and sound absorption average comparable to extruded polystyrene and polyurethane. In addition, the material's thermal conductivity was near that of sheep wool. Therefore, the biomaterials fabricated using sludge and Trametes versicolor have the potential to be a game-changer in the industry as promising thermoacoustic insulators. [ABSTRACT FROM AUTHOR]

Objectives. This study aimed to investigate 12-month and 7-day prevalence of musculoskeletal symptoms among workers of the pulp and paper industry, and assess the contribution of age, gender, body mass index (BMI) and physical activity (PA). Methods. The sample comprised 904 workers. Musculoskeletal symptoms were assessed using the Nordic musculoskeletal questionnaire. χ2 tests assessed the association between musculoskeletal symptoms and age/gender/BMI/PA, and multivariate logistic regression models predicted the 12-month occurrence of symptoms in the five most prevalent regions. Results. The five most affected body regions were the lower back, shoulders, neck, knees and wrists/hands. Older workers presented more symptoms in all body regions, except dorsal; female gender was associated with neck symptoms (p = 0.001); overweight was associated with a higher prevalence of lower back (p = 0.01), knee (p = 0.017) and ankle/foot (p = 0.037) symptoms; and a moderate PA level was associated with thigh/hip symptoms (p = 0.006). Age was a significant predictor in all five most affected regions; gender was a significant predictor for shoulders, neck and wrists/hands; and BMI was a significant predictor for lower back symptoms. Conclusion. The 12-month and 7-day prevalence of musculoskeletal symptoms among workers of the pulp and paper industry is higher in the lower back, shoulders, neck, knees and wrists/hands. [ABSTRACT FROM AUTHOR]

The complex mixture of pollutants found in industrial effluents creates a significant environmental challenge. Enzymatic treatment offers a promising alternative to traditional physiochemical techniques. With an emphasis on laccase enzymes, this review examines the potential of both free and immobilized biocatalysts for the treatment of industrial wastewater, especially from pulp and paper mills. Laccase has become one of the most popular options for bioremediation because of its broad substrate specificity and capacity to break down different kinds of organic pollutants. The different methods of laccase immobilization, including adsorption, encapsulation and cross-linking are examined, exploring their advantages and limitations. The benefits of immobilization for enzyme stability, reusability and operational efficiency in wastewater treatment processes are further discussed. By comparing the advantages and limitations of free and immobilized biocatalysts, this review aims to provide valuable insights for the development of efficient and sustainable enzymatic strategies for industrial wastewater treatment. Furthermore, this paper offers future possibilities for using biocatalyst in pulp and paper waste treatment. [ABSTRACT FROM AUTHOR]

The chemical oxygen demand (COD) emissions from the pulp and paper industry in China have declined continuously since the tighter COD discharge standards were implemented in 2008. Using firm-level data from 2003 to 2013, we investigate how China's pulp and paper firms would respond to the tighter COD discharge standards with a difference-in-differences design. We find that the tighter COD discharge standards have significant causal effects to induce the pulp and paper firms to reduce their COD emissions primarily through adopting cleaner production. However, the effectiveness of the tighter COD discharge standards depends on monitoring and enforcement activities as well as other regulations accompanying with the tighter COD discharge standards, all of which have become strengthened since China's 11th Five-Year-Plan (FYP, 2006–2010). While strengthened environmental regulations since the 11th FYP are from the top leadership of the Chinese government in order to deal with the increasing environmental degradation, the underlying driving force of the strengthened environmental regulations is from the household demand for better environmental quality as income increases. This study enriches literature not only on firms' responses to environmental regulations in developing countries but also on environmental regulations and technology adoption as well as environmental enforcement and compliance. [ABSTRACT FROM AUTHOR]

Pulp and paper mill effluents represent a significant environmental concern due to the presence of various toxic organic and inorganic pollutants, posing risks even at low concentrations. With the paper production process consuming approximately 200 tons of water per ton of paper and generating effluents containing over 250 different chemicals, effective treatment methods are essential to mitigate the environmental impact of the pulp and paper (PP) industry. This study presents a comprehensive evaluation of the efficacy of heterogeneous and homogeneous photocatalytic treatments for PP industry-derived effluents, targeting reductions in major pollutant concentrations below environmental standards. A thorough review of the literature on pollutant removal from PP effluents using photocatalytic treatment, particularly employing UV/TiO2 and UV/ZnO photocatalysts, reveals significant removal rates. Doped photocatalysts have shown enhanced performance, achieving removal percentages of 98 % for BOD and COD, and 99 % for color and lignin. Additionally, Fenton and photo-Fenton treatment techniques have demonstrated high removal efficiencies for BOD, COD, color, and lignin.

The objective of this study was to assess, through simulation, conductivity variations in pulp and paper circuits when recycling waste water treatment plant (WWTP) effluent with a view to reducing fresh water use in a tissue mill. WWTP effluent was recycled in the process for different uses. A PS2000 digital model coupled with the PHREEQC chemical simulation engine was used to identify and quantify the main sources of conductivity: caustic soda, sodium bisulphite and acetate production through anaerobic microbial activity. Recycling WWTP effluent enables fresh water uptake to be reduced by 50% when used for pulp dilution or white water, by 81% when used in paper machine showers, and up to 96% for all uses combined. As fresh water use decreases, circuit closure increases along with, consequently, COD and conductivity. COD build-up can be controlled by best available techniques application. Recycling WWTP effluent has a strong impact on conductivity. However, the impact of high conductivity levels on additives performance is limited in the case of the mill studied. Acetate concentration could be controlled by better agitation of tanks or the introduction of air by pumps. Furthermore, limiting acetate production can reduce the need for caustic soda to control the pH. HIGHLIGHTS Modelling conductivity in pulp and paper mills.; Reuse in pulp and paper mills.; Reduction of fresh water consumption.; Anticipating discharge quality.; Reduction of chemicals uses.;

Background: The pulp and paper industry (P&PI) is undergoing significant disruption driven by global megatrends that necessitate advanced tools for predicting future behavior and adapting strategies accordingly. Methods: This work utilizes a multi-criteria framework to quantify the effects of digitalization, changes in social behavior, and sustainability as three major megatrends transforming the P&PI industry, with a specific focus on hygiene tissue products. Thus, the research combines a comprehensive literature review, insights from a Delphi study, and topic modeling to qualitatively and quantitatively assess the present and future impacts of these global megatrends. Results: The findings suggest an urgent need to identify alternative raw materials to prevent potential supply chain disruptions. Moreover, due to shifts in social behavior, it becomes critical for businesses to substantiate their sustainability claims with hard data to avoid the risk of a "greenwashing" perception among consumers. Conclusions: This study provides decision support for strategic planning by highlighting actionable insights, quantitative predictions, and trend analysis, alongside the examination of consumer and market trends. It aims to incorporate diverse stakeholder perspectives and criteria into decision-making processes, thereby enriching the strategic planning and sustainability efforts within the P&PI industry. [ABSTRACT FROM AUTHOR]

Substantial R &D efforts are currently directed towards the development of combined heat and power (CHP) systems that automatically and seamlessly connect to the power grid. In this paper we develop a real options model to assess the impact that the operational flexibility characterizing such systems will have on the optimal timing and capacity associated with investments in CHP plants. We take the viewpoint of a manufacturer operating in an energy-intensive industry who contemplates investing in CHP. We discuss and compare investments in two types of CHP systems: a standard one that is operationally rigid and a technologically advanced one that is operationally flexible. The interaction between temporal and operational flexibility under uncertainty and irreversibility is central to our analysis. We show that operational flexibility guarantees earlier investment but has an ambiguous effect in terms of capacity. In particular, when operational flexibility is very valuable the potential investor is opting for investing in a plant with larger productive capacity. The potential investor chooses a smaller CHP unit if otherwise. A numerical exercise calibrated using data from the Italian pulp and paper and electricity industries complements our theoretical analysis. [ABSTRACT FROM AUTHOR]

This study focuses on the elimination of residual dyes from industrial wastewater using talc as an adsorbent. Talc is an easily available, ecological, and inexpensive adsorbent. The adsorption process was tested on two model dye samples (Ecozol Blue LR Liquid and Cartasol Yellow 3GF Direct Yellow 132), and two samples of real wastewater from the pulp and paper industry (PM and TP). Kinetic studies revealed that the adsorption of Ecozol Blue LR Liquid followed pseudo-second-order kinetics, while the other tested samples followed pseudo-first-order kinetics. Langmuir, Freundlich, and Dubinin-Radushkevich adsorption isotherm models were also evaluated. The Langmuir isotherm model best fitted the experimental data for the adsorption of model dye solutions and wastewater sample TP onto talc. For wastewater sample PM, the Dubinin-Radushkevich isotherm model provided the best fit to the experimental data. The results of the adsorption isotherms indicated that the adsorption of all tested systems was favorable and primarily involved physical adsorption. The adsorption efficiency for the model solutions exceeded 90 %. For real wastewater samples, the monitored adsorption efficiency in the COD pollution indicator was less efficient, ranging from 43 to 51 %. The lower efficiency of COD may have resulted from the adsorption of residual dyes with lower specific COD values before the adsorption of other organics. [ABSTRACT FROM AUTHOR]

The pulp and paper industry is critical to global industrial and economic development. Recently, India's pulp and paper industries have been facing severe competitive challenges. The challenges have impaired the environmental performance and resulted in the closure of several operations. Assessment and prediction of the performance of the Indian pulp and paper industry using various parameters is a critical task for researchers. This study proposes a framework for performance assessment and prediction based on Data Envelopment Analysis (DEA), Artificial Neural Networks, and Deep Learning (DL) to assist industry administration and decision-making. We presented a case study based on eight industries to demonstrate the methodology's applicability. This study analyses and predicts industry performance based on sample data observations over 30 years. The result suggests the DEA-DL-based efficiency prediction has an overall MSE of 0.08 compared with the actual efficiency. Furthermore, the efficiency rankings are compared between the three techniques. The results suggest that the integrated DEA-DL method is primarily accurate in most scenarios with the actual values. The findings of this study provide a comprehensive analysis of environmental performance for policymakers. [ABSTRACT FROM AUTHOR]

Developing land use strategies to optimize carbon sinks and improve carbon footprints involves proposing efficient nature-based solutions that industries and businesses can implement while considering financial and legislative constraints. The pulp and paper industry is associated with significant greenhouse gas (GHG) emissions, primarily due to the substantial carbon dioxide (CO2) footprint of its mills. Also, some forestry operations contribute to the release of carbon to the atmosphere in the form of CO2 and methane (CH4). Conversely, this industry could potentially be a significant ally in the fight against climate change by favoring forestry practices that reduce carbon emissions and increase its sequestration, namely, by adding value to industrial by-products (e.g., biosolids) instead of treating them as wastes and landfilling them. Notably, the pulp and paper industry has been seeking alternative uses of its by-products, such as fertilizers to maximize tree growth. In this paper, we identify opportunities and challenges that exist for the pulp and paper industry in regard to recycling industrial by-products to: 1) lower GHG emissions directly at the mill and 2) improve its GHG budget by increasing carbon sequestration in forests and plantations. We illustrate our analyses by describing a case study of a pulp and paper mill in southern Quebec, Canada, that uses its biosolids and other by-products as fertilizers. This case study highlights that this strategy could not only contribute to the reduction of GHGs but could also create added value and improve economic returns of forest operations.

To ensure development sustainability, the linear economic approach is being transformed into a cyclical model. For the pulp and paper industry (PPI), which occupies a significant place in the Russian economy, the shift of circular principles to the field of bioeconomics is becoming more important. This requires the development of basic biotechnological approaches implemented in closed cycles (biorefining). The aim of this study was to develop the biotechnological foundations of the circular economic system of the pulp and paper industry. To achieve the goal, the factors for the implementation of the circular mechanism in the pulp and paper industry were established. The composition of pulp and paper waste was systematized, taking into account the places of their occurrence; the directions and forms of the biorefining of pulp and paper secondary renewable resources were determined; and the principal possibility of obtaining bioethanol, based on the whole complex of sugars from cellulose production wastes, is shown. A wide range of general scientific methods was involved (analysis, synthesis, classification, modeling, etc.). Statistical methods were used to process experimental results in the field of pulp and paper waste bioconversion. The biotechnologies involved included methods of destruction, detoxification, and conversion of useful resources into secondary raw materials and final products. From the standpoint of the environmental approach, there are serious efficiency imbalances in the pulp and paper industry, which justify the implementation of circular mechanisms for organizing economic systems. The overall efficiency is ensured by the use of renewable resources and obtaining environmental effects. Algorithms and parameters of green biotechnological regulations for pulp and paper industry waste recycling provide the possibility of microbiological production of a complex of products: biocomposites, bioplastics, medical products, fertilizers, feed additives, vitamin supplements, and bioenergy resources. A strategy for the efficient biochemical processing of pulp and paper waste into green ethanol was determined. The possibility of increasing the efficiency of alcoholic fermentation using various biocatalysts was experimentally confirmed. The technological features of this method, associated with the need for microaerobic fermentation modes, were determined. [ABSTRACT FROM AUTHOR]

The relationship between environmental regulation and firm productivity has been widely debated but inconsistencies in findings across different studies. Using detailed firm-level micro-data from 2000 to 2007, this paper employs difference-in-difference combined with matching based on entropy balancing method to explore the effect of environmental regulation on firm total factor productivity (TFP) in pulp and paper industry in China. Our main findings are as following: Firstly, stricter environmental regulation, as represented by the Wastewater Discharge Standards for Pulp and Paper Industry in Shandong province, increases firm TFP significantly. Moreover, the coefficients of interest are robust to multiple robustness checks. Secondly, dynamic effects estimates reveal that when faced with this phase-in environmental regulation, firms take the foreseeably increasing strictness into account from the very beginning and prefer to take one-step adjustment to reach full compliance. Thirdly, potential mechanism analysis finds that the positive effect mainly comes from the improvement of resource allocation efficiency within firms. Fourthly, the heterogeneity test indicates that the effect of environmental regulation on firm TFP is heterogeneous across firms with different sizes, ages, ownerships, capital intensity, and export status. Finally, this paper provides convincing and insightful evidence that environmental regulation has the potential to achieve the dual goals of environmental sustainability and economic growth and is thus of broader significance for understanding the enforcement of environmental regulation in developing countries. [ABSTRACT FROM AUTHOR]

Background: The pulp and paper industry (P&PI) is undergoing significant disruption driven by global megatrends that necessitate advanced tools for predicting future behavior and adapting strategies accordingly. Methods: This work utilizes a multi-criteria framework to quantify the effects of digitalization, changes in social behavior, and sustainability as three major megatrends transforming the P&PI industry, with a specific focus on hygiene tissue products. Thus, the research combines a comprehensive literature review, insights from a Delphi study, and topic modeling to qualitatively and quantitatively assess the present and future impacts of these global megatrends. Results: The findings suggest an urgent need to identify alternative raw materials to prevent potential supply chain disruptions. Moreover, due to shifts in social behavior, it becomes critical for businesses to substantiate their sustainability claims with hard data to avoid the risk of a “greenwashing” perception among consumers. Conclusions: This study provides decision support for strategic planning by highlighting actionable insights, quantitative predictions, and trend analysis, alongside the examination of consumer and market trends. It aims to incorporate diverse stakeholder perspectives and criteria into decision-making processes, thereby enriching the strategic planning and sustainability efforts within the P&PI industry.

This study reviews the mass transfer with a focus on the challenges, benefits, processing and prospects in the pulp and paper industry with a scope limited to Kraft pulping which is the dominant pulping process worldwide. The mass transfer usually occurs in various processes that deal with reactions, separation, and heat transfer. All these aforementioned processes occur in the production of pulp and paper from their raw materials. The application of mass transfer to these processes is of great importance in setting target yields, and specifications and improving efficiency. The major processes where mass transfer principles are applied are drying, chemical washing, pulp digestion and pulp bleaching respectively. Understanding the requirements and targets of each of these processes in combination with the mass transfer principles helps in the development of models and design of equipment that operate based on the developed models in meeting the required targets. Studies have indicated that mass and energy balances cannot be done independently in meeting the required targets and equipment design. The drying and stripping of lignocellulosic components of the feed-in paper manufacture constitute a large part of the challenges faced by the industry. Drying techniques have been considered to be inefficient, and lignocellulosic by-products are known to contain toxic components. Green chemistry production processes and newer drying techniques were indicated as possible solutions. It is expected that researchers and investors would find this article useful.

Production planning and scheduling in the pulp and paper industry can be very challenging. In most cases, practitioners address the production planning process manually, which is time-consuming and sub-optimal. This study deals with production planning encountered in a pulp mill company involving different wood species, parallel heterogeneous lines, inventory limits, sequence-independent setup times and preventive maintenance. To tackle the problem, an efficient mixed-integer formulation is proposed that optimizes when, where and how much to produce of different wood species and schedules preventive maintenance to minimize the total setup times. Several computational experiments are conducted to solve a case study in a pulp mill company in Chile. The results show the capability of the model to support the decision-making process in the pulp and paper industry, providing an efficient tool for practitioners to solve the problem in a reasonable amount of time. [ABSTRACT FROM AUTHOR]

The current disposal of biosludge generated in wastewater treatment has high costs and causes environmental problems, anaerobic digestion (AD) of solid waste is a promising alternative. Thermal hydrolysis (TH) is an accepted technology to enhance anaerobic biodegradability of sewage sludge, but this technology has not been developed to be used with biological sludge from industrial wastewater treatment. In this work, the improvements to the AD of biological sludge from cellulose industry when thermal pretreatment is carried out were experimentally determined. The experimental conditions for TH were 140 °C and 165 °C for 45 minutes. Batch tests were carried out to quantify methane production evaluated as biomethane potential (BMP), anaerobic biodegradability according to volatile solids (VS) consumption and kinetic adjustments. An innovative kinetic model based on the serial mechanism of fast and slow biodegradation fractions was tested for untreated waste, and parallel mechanism was also evaluated. Increases in BMP and biodegradability values according to VS consumption were determined with increasing TH temperature. The results of 241 NmL CH4 gVS substrate−1 for BMP and 65% biodegradability are reported for the 165 °C treatment. AD rate increased for the TH waste compared to the untreated biosludge. Improvements of up to 159% for BMP and 260% for biodegradability according to VS consumption were quantified for TH biosludge compared to untreated biosludge. [ABSTRACT FROM AUTHOR]

The article deals with the problem of calculating the volume calendar plan of a paper mill. The presented mathematical model and methods make it possible to schedule paper production orders between several paper machines (PM) to even their loading, devise cutting plans for each winder and arrange the order of their implementation. When forming cutting plans, orders are grouped in accordance with such parameters as grammage, roll diameter, core diameter, product type and number of layers. Deadlines and volumes in customer orders are taken into account. The cutting plans for each winder account for the allowable roll width limits and the maximum number of knives. To find the optimal schedule, a combination of the following criteria is used: minimal trim loss, minimal changes to the knives' setup and smooth transitions by product grades. Solution algorithms are presented that use a combination of the simplex method, the column generation, the branch and bound methods, the greedy algorithm and the local search procedure. We tested the solution approach on real production data from a paper mill in European Russia and obtained the production sequence that better matches deadlines in customer orders compared to the plan devised manually by production planners. [ABSTRACT FROM AUTHOR]

Laccases are multicopper-containing enzymes that have the ability to oxidize a wide variety of substrates with a single electron transfer reaction. These are environmentally benign versatile biocatalysts that have gained great interest in the biotechnological community since they utilize molecular oxygen as the last electron acceptor and only produce water as a byproduct. This family of enzymes has been widely used in a broad variety of applications, ranging from food additives and beverage processing to biological diagnostics and even as crosslinking agents in the furniture construction and manufacture of biofuels. Considering the benefits of enzyme immobilization, there has been a dramatic increase in applying immobilized laccases in recent years. Despite the impressive biotechnological promise, the use of laccases in the real world is still constrained by cost–benefit analysis, particularly in terms of practically large-scale production. The enzyme industry is booming research on laccase production, and use neglects to include the economic impact of the operations. Because of their ability to metabolize complex xenobiotics, they are also useful biocatalysts in enzymatic bioremediation processes, such as wastewater treatment. This study discusses the most important and recent breakthroughs in the biocatalytic attributes, sources, and exploitation of laccases in biotechnology for a sustainable industry. [ABSTRACT FROM AUTHOR]

The forest industry is a significant emitter of CO2 and thus it needs to transform toward​ a more sustainable operation in order to contribute to tackling climate change. This paper looks at the progress, tools, possibilities, and barriers of Finnish and Swedish forest industries in achieving deep decarbonization. Finland and Sweden have set ambitious national targets to reach net negative greenhouse gas emissions. The role of the forest industry in reaching national targets in these countries remains unclear even if significant fossil CO2 emission reduction and efficiency improvement has occurred. If the forest industries in these countries fulfill their planned future visions, their contribution to meeting the targets will be substantial. This study identified the largest CO2 emitting sectors in the forest industry. They are for both countries, arranged by size, transport including non-road mobile machinery, on-site energy production, fossil fuel use in processes (lime kilns and dryers), and purchased electricity. Viable decarbonization measures exist for key fossil CO2 emissions sources, but several technical, economic, and political barriers are hindering their implementation. Fuel switching from fossil energy sources to bio-based alternatives is the main tool in the decarbonization of the forest sector in both countries, but also electrification of e.g. transport, provides emission reduction opportunities. The forest industry has a high and sustainable potential to become carbon-negative by investing in bioenergy with carbon capture and storage (BECCS) but achieving net-zero emissions might not be realistic without changes in policies and suitable incentives.

Xylooligosaccharides (XOS) are oligomers with recognized and important prebiotic properties, whose consumption is associated with several health benefits, including a positive impact on the immune system. In this work, XOS were produced through a green process of enzymatic hydrolysis performed directly on an intermediate product from a pulp and paper industry, Eucalyptus bleached kraft pulp. Focusing on an industrial, sustainable and more economical application, two goals were defined and validated: (i) no pretreatment of the substrate and (ii) the replacement of the commonly used buffer solution as reaction medium for only water. The influence of the most relevant operating conditions on the production of XOS as well as the respective yields obtained were very similar when using either buffer or water as the reaction medium. For the use of water, although the solution pH decreases during the enzymatic reaction, this change did not affect the production of XOS. For the optimized conditions, 80 °C and 100 U/g pulp, a maximum yield of 31.4 ± 2.6% per total xylan in the pulp was obtained, resulting in more than 50 kg of XOS per ton of pulp. The correspondent hydrolysate was mainly composed by xylobiose (66%) and xylotriose (29%), oligomers with the highest prebiotic effect. [ABSTRACT FROM AUTHOR]

Bioenergy with CO2 capture and storage (BECCS) is a promising negative emission technology (NET). When using sustainably produced biomass as fuel, BECCS allows the production of power and heat with negative CO2 emissions. The main technical challenges hindering the deployment of BECCS technologies include energy penalties associated with the capture process. This work evaluates the performance of an advanced CO2 capture technology, chemical looping with oxygen uncoupling (CLOU), replacing a conventional fluidized bed boiler in the power boiler role in a large, modern integrated pulp and paper mill. Results from a MATLAB/Simulink reactor model were incorporated in a plant and integration model developed in a commercial process simulation software to quantify the performance of the CLOU-integrated cogeneration plant. The results show that in this specific application, the typically already low efficiency penalty of CLOU-based carbon capture and storage (CCS) systems could be eliminated entirely, and actually even a very small efficiency gain could be obtained. The highly efficient operation is possible due to the high moisture and hydrogen contents of the biomass and the separation of combustion products and excess air streams in the CLOU process; this provides an opportunity to recover a significant amount of heat by flue gas condensation at a higher temperature level than what is possible in a conventional boiler. Together with abundant low-temperature heat sinks available at the pulp and paper application allows freeing a considerable amount of low-pressure steam for expansion in the condensing turbine. The resulting increase in gross generator output proved enough to not only match, but very slightly exceed the approximately 18 MW parasitic load introduced by the CLOU system in comparison to the conventional boiler. [ABSTRACT FROM AUTHOR]

The relevance. The waste of Baikal Pulp and Paper Mill causes a real danger of a social and environmental disaster for Lake Baikal and the entire Southern Baikal region, therefore, the problem of developing integrated solutions for dumping the accumulation of lignin-containing waste is especially acute. One of the promising areas for processing this type of waste is the use of natural processes, for example, freezing in winter, temperature detection or self-overgrowth of the occurrence of natural succession. The main aim of the research is to develop an environmentally friendly technology for processing colloidal lignin-containing waste from the pulp and paper industry. Methods: pilot tests at the Solzan industrial site of Baikal Pulp and Paper Mill for freezing lignin-containing wastes and obtaining soils from them by mixing with additives; performing quantitative chemical analysis using the methods of atomic absorption and atomic emission spectrometry, high performance liquid chromatography, toxicological analysis. Results. Pilot tests have shown that after freezing, the colloidal structure of lignin-containing sediments is destroyed with a decrease in volume up to 40 %, humidity up to 60 %, and also with a decrease in toxicity – from the third (moderately hazardous) to the fourth (low hazardous) and fifth class (practically non-hazardous) of hazard of the waste depending on its composition. After freezing, the resulting sludge with the introduction of various additives (CHP ash, sewage treatment plant sludge) can be used as soil ground and fertilizers for reclamation of disturbed lands and crops. Thus, an environmentally friendly technology was developed for processing waste from the pulp and paper industry to obtain soil ground, which is low-energy and does not contain expensive imported equipment.

The pulp and paper industry (PPI) has several opportunities to contribute to meeting prevailing climate targets. It can cut its own CO2 emissions, which currently account for 2% of global industrial fossil CO2 emissions, and it has an opportunity to produce renewable energy, fuels, and materials for other sectors. The purpose of this study is to improve understanding of the decarbonization prospects of the PPI. The study provides insights on the magnitude of needed annual renewal rates for several possible net-zero target years of industrial fossil CO2 emissions in the PPI and discusses decarbonization opportunities, namely, energy and material efficiency improvement, fuel switching, electrification, renewable energy production, carbon capture, and new products. The effects of climate policies on the decarbonization opportunities are critically evaluated to provide an overview of the current and future business environment of the European PPI. The focus is on Europe, but other regions are analyzed briefly to widen the view. The analysis shows that there are no major technical barriers to the fossil-free operation of the PPI, but the sector renovates slowly, and many new opportunities are not implemented on a large scale due to immature technology, poor economic feasibility, or unclear political environment. [ABSTRACT FROM AUTHOR]

Pulp and paper wastewater sludges are waste streams produced in major quantities across the world. The recycling of these organic sludges, for example to soil amendments, is desired in the circular economy but carries the risk of potential pollutants to be also introduced into the environment. Pulp and paper wastewater sludges have been scarcely studied matrices in the microplastic research due to their complex composition. In this study, we optimized an extraction process for microplastics from pulp and paper wastewater sludges, and quantified and characterized microplastics down to 20 μm in primary sludge and biosludge generated at the wastewater treatment plant of a multi-product pulp and paper mill in Finland. The occurrence of microplastics was high in primary sludge, 900–1600 microplastics g−1 dry weight, while the maximum number of detected microplastics in biosludge samples remained at 210 g−1 dry weight. Biosludge samples suffered from larger amounts of remaining solids after the extraction process, thus compromising the detection of smaller microplastics (<100 μm) and increasing the uncertainty related to the interpretation of the results. The most prevalent microplastic shape in all samples was fragment, and the most recurring polymer types were polyethylene and polypropylene, while a polystyrene-based copolymer represented approximately 10% of identified microplastics in primary sludge. The present study advances the development of microplastic analysis of the challenging pulp and paper wastewater sludges and brings novel information to the progressing discussion of their circulation potential. [Display omitted] • Varying consistency of pulp and paper sludges challenges microplastics extraction. • Primary sludge shows higher microplastic occurrence than biosludge. • Prevalent microplastic types in both sludges are PE and PP fragments. • Microplastic analysis from pulp and paper sludges requires further attention. [ABSTRACT FROM AUTHOR]

To ensure development sustainability, the linear economic approach is being transformed into a cyclical model. For the pulp and paper industry (PPI), which occupies a significant place in the Russian economy, the shift of circular principles to the field of bioeconomics is becoming more important. This requires the development of basic biotechnological approaches implemented in closed cycles (biorefining). The aim of this study was to develop the biotechnological foundations of the circular economic system of the pulp and paper industry. To achieve the goal, the factors for the implementation of the circular mechanism in the pulp and paper industry were established. The composition of pulp and paper waste was systematized, taking into account the places of their occurrence; the directions and forms of the biorefining of pulp and paper secondary renewable resources were determined; and the principal possibility of obtaining bioethanol, based on the whole complex of sugars from cellulose production wastes, is shown. A wide range of general scientific methods was involved (analysis, synthesis, classification, modeling, etc.). Statistical methods were used to process experimental results in the field of pulp and paper waste bioconversion. The biotechnologies involved included methods of destruction, detoxification, and conversion of useful resources into secondary raw materials and final products. From the standpoint of the environmental approach, there are serious efficiency imbalances in the pulp and paper industry, which justify the implementation of circular mechanisms for organizing economic systems. The overall efficiency is ensured by the use of renewable resources and obtaining environmental effects. Algorithms and parameters of green biotechnological regulations for pulp and paper industry waste recycling provide the possibility of microbiological production of a complex of products: biocomposites, bioplastics, medical products, fertilizers, feed additives, vitamin supplements, and bioenergy resources. A strategy for the efficient biochemical processing of pulp and paper waste into green ethanol was determined. The possibility of increasing the efficiency of alcoholic fermentation using various biocatalysts was experimentally confirmed. The technological features of this method, associated with the need for microaerobic fermentation modes, were determined.

The pulp and paper industry is a power-intensive technology so great attention to reducing its own energy consumption and declining the waste of available energy should be devoted. In the current investigation, the energy-exergy approach of a pulp and paper company integrated with a chemical recovery of black liquor (BL) and soda is studied actually for one year. The chemical BL recovery system that has the primary benefits to avoid environmental pollution by burning organic waste and recycling the soda is also comprehensively investigated. Natural gas (NG) and BL are utilized in power boiler (PB) and recovery boiler (RB), respectively. Moreover, in the present implementation, the chemical reactions of NG and BL are presented. The obtained results show that the percentages of energy losses in the condenser, RB, evaporators, and PB are 49.16, 19.28, 14.22, and 3.96%, respectively. The average values of exergy destruction percentages in RB and PB around the year are 41.63 and 33.5%, respectively. The maximum system overall exergy efficiency is 32.09% at an environment temperature of 290 K, whereas the energy efficiency of the system is 53.7%.

Anodizing is commonly used for corrosion protection of aluminum and its alloys in the construction industry. The anodic aluminum oxide (AAO) coating has a high ability to prevent the development of extensive pitting corrosion in aluminum substrates, particularly in marine sites, as was observed during a 10-year atmospheric corrosion study carried out in several marine and industrial sites. However, this study also evidenced that this coating can be highly affected by the deposition of particulate material in industrial polluted environments, sometimes in unexpected ways. This study presents information on the atmospheric corrosion of anodized aluminum exposed at two different chemical industrial complexes: a fertilizer production plant and a pulp and paper mill. Visual assessment of surface changes, pitting depth and mass variation with exposure were determined to quantify the degradation suffered. Additionally, SEM/EDS analyses were carried out on the exposed surfaces. Based on the results obtained, the role played by the deposition of airborne particles present in the two environments with respect to the type and level of damage observed is discussed. Deposits of roasted pyrite ash and phosphates or of wood chips and lime particles enhanced pitting corrosion or caused dissolution of the AAO coating. [ABSTRACT FROM AUTHOR]

Nuclear energy is a particularly regulated and politicised part of energy production. In this article, we analyse how private companies have promoted their interests in this challenging sector. We focus on the case of Finland, where manufacturing industries have regarded cheap and abundant power as a key component of their business strategies. From the 1950s onwards, nuclear energy seemed a particularly attractive option, as Finland had few alternative power sources. However, private companies faced opposition from a number of actors. They included the Soviets, who were eager to sell their reactors, while the Finns wanted to buy Western ones; centrist and left-wing politicians, who favoured state-controlled options; and finally, the environmental movement, which from the 1980s onwards opposed the construction of all new reactors. Politicians rejected proposals for a fifth nuclear reactor until the industrialists learned to present the reactor as a 'green' project, which would reduce carbon dioxide emissions. [ABSTRACT FROM AUTHOR]

High-colored wastewater generated during the cellulose bleaching process causes the inhibition of biological activity when released into the environment. This study aimed to evaluate the bacterium's capacity, identified as RGM2262, to degrade a complex phenolic structure such as lignin, which is found in high concentrations in the effluents generated during the production of cellulose, raw material for the manufacture of paper. To determine the values of the experimental variables that allow for a greater degradation of organic matter, an experimental model was carried out through experimental design. Thus, the experimental matrix was obtained with the variables pH 7 (−1) to 9 (+1) and a treatment time of 1 day (−1) to 5 days (+1). The results show that, at pH 8 and pH 9, both treatments—with bacteria in bio-films and without bio-films—were efficient. On the second day of treatment, 100% of the color and the phenolic structure were removed, with a similar rate constant, and at the same time, 80% COD and 70% of TOC, respectively. [ABSTRACT FROM AUTHOR]

Energy management is the most prominent means of improving energy efficiency, and improved energy efficiency constitutes the cornerstone in decarbonization. For successful industrial energy management, defining accurate energy performance indicators (EnPIs) is essential. Energy-intensive industries have previously been found to have an improvement potential regarding the current monitoring of EnPIs, especially at process level. While general models for developing and implementing EnPIs exist, manufacturing industries are diverse in terms of their production processes, which is why industry-tailored models for EnPI development are needed. One major outcome of this paper is a unique model specifically tailored for kraft pulp mills. The model derives from a practice-based approach for EnPI development, building on real-life experiences from a Swedish group of companies. This paper’s developed model, and the validation of the EnPIs, further increase the understanding of the kraft pulp industry’s processes and how to apply descriptive and explanatory indicators. The developed model can potentially be generalized to other sectors.

A shift from fossil fuels to renewable energy sources is essential to reduce global greenhouse gas emissions and climate change effects. Biofuels represent a promising low-carbon alternative for sectors that are hard to electrify, such as freight transport or aviation. This work investigates possible pathways for increasing the value of biomass at a Kraft pulp mill, focusing on black liquor and bark streams. Mathematical programming is coupled with superstructure optimization and systematic solution exploration to identify meaningful process configurations. The analysis of solutions under market variations allows for the identification of robust and competitive configurations for the co-production of pulp and fossil fuel alternatives. The results show that the integration of biorefineries in pulp mills results in better resource use and higher energy efficiency - diversifying the product portfolio and providing bio-based fuel products to the market while being economically viable. By incorporating fuel production in the conventional Kraft process, the carbon conversion efficiency of the mill can be increased from 48% to up to 67%. Extending the analysis, up to 2% of the European road freight transportation fuel could be provided with combined pulp and fuel production, and 5% of the worldwide fuel demand for passenger aviation.

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The energy-intensive pulp and paper industry is a major contributor to carbon dioxide emissions. The potential to reduce energy consumption and carbon dioxide emissions is generally assessed using energy conservation supply curves and marginal abatement cost curves; however, both of these methods have inherent faults. For a given negative cost, conventional marginal abatement cost curves tend to favor options that lead to small reductions in carbon dioxide emissions over options that produce larger reductions. In the current study, we employed extended versions of energy conservation supply curves and marginal abatement cost curves to analyze the various options to reduce energy consumption and carbon dioxide emissions. The technical potential energy savings and carbon dioxide abatement were respectively estimated at 5.05% of the final energy use in the sector and 6.32% of carbon dioxide emissions in 2019. We determined that 52.3% of the electricity savings and 82.8% of fuel savings could be achieved in a cost-effective manner. Additionally, the utilization of solid recovered fuels remains a largely untapped opportunity to reduce carbon dioxide emissions for the Taiwanese pulp and paper industry. Thus, efforts should be made to establish a comprehensive database pertaining to the direction and volume of waste flows and improve waste collection networks with corresponding standards pertaining to solid recovered fuels quality and air pollution.

Structural symmetries of linear dynamical systems can be exploited for decoupling the dynamics and reducing the computational complexity of the controller implementation. However, in practical applications, inexact structural symmetries undermine the ability to decouple the system, resulting in the loss of any potential complexity reduction. To address this, we propose substituting an approximation with exact structural symmetries for the original system model, thereby introducing an approximation error. We focus on internal model controllers for cross-directional systems encountered in large-scale and high-speed control problems of synchrotrons or the process industry and characterise the stability, performance, and robustness properties of the resulting closed loop. While existing approaches replace the original system model with one that minimises the Frobenius norm of the approximation error, we show that this can lead to instability or poor performance. Instead, we propose approximations that are obtained from semidefinite programming problems. We show that our proposed approximations can yield stable systems even when the Frobenius norm approximation does not. The paper concludes with numerical examples and a case study of a synchrotron light source with inexact structural symmetries. Exploiting structural symmetries in large-scale and high-speed systems enables faster sampling times and the use of more advanced control techniques, even when the symmetries are approximate. [ABSTRACT FROM AUTHOR]

The pulp and paper industry is recognized as a well-established sector, which throughout its process, generates a vast amount of waste streams with the capacity to be valorized. Typically, these residues are burned for energy purposes, but their use as substrates for biological processes could be a more efficient and sustainable alternative. With this aim, it is essential to identify and characterize each type of waste to determine its biotechnological potential. In this context, this research highlights possible alternatives with lower environmental impact and higher revenues. The bio-based pathway should be a promising alternative for the valorization of pulp and paper industry wastes, in particular for bioproduct production such as bioethanol, polyhydroxyalkanoates (PHA), and biogas. This article focuses on state of the art regarding the identification and characterization of these wastes, their main applied deconstruction technologies and the valorization pathways reported for the production of the abovementioned bioproducts. [ABSTRACT FROM AUTHOR]