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(2060) Chiron is a large centaur that has been reported active on multiple occasions including during aphelion passage. Studies of Chirons coma during active periods have resulted in the detection of C(triple)N and CO outgassing. Significant work remains to be undertaken to comprehend the activation mechanisms on Chiron and the parent molecules of the gas phases detected. This work reports the study of the ices on Chirons surface and coma and seeks spectral indicators of volatiles associated with the activity. Additionally, we discuss how these detections could be related to the activation mechanism for Chiron and, potentially, other centaurs. In July 2023, the James Webb Space Telescope (JWST) observed Chiron when it was active near its aphelion. We present JWST/NIRSpec spectra from 0.97 to 5.27 microns with a resolving power of 1000, and compare them with laboratory data for identification of the spectral bands. We report the first detections on Chiron of absorption bands of several volatile ices, including CO2, CO, C2H6, C3H8, and C2H2. We also confirm the presence of water ice in its amorphous state. A key discovery arising from these data is the detection of fluorescence emissions of CH4, revealing the presence of a gas coma rich in this hyper-volatile molecule, which we also identify to be in non-local thermal equilibrium (nonLTE). CO2 gas emission is also detected in the fundamental stretching band at 4.27 microns. We argue that the presence of CH4 emission is the first proof of the desorption of CH4 due to a density phase transition of amorphous water ice at low temperature in agreement with the estimated temperature of Chiron during the JWST observations (61 K). Detection of photolytic and proton irradiation products of CH4 and CO2 on the surface, in the coma ice grains, or in the ring material is also detected via a forest of absorption features from 3.5 to 5.3 microns., Comment: 4 figures in paper plus 2 more in the appendix. Accepted as A&A Letter

We observed Sedna, Gonggong, and Quaoar with the NIRSpec instrument on the James Webb Space Telescope (JWST). All three bodies were observed in the low-resolution prism mode at wavelengths spanning 0.7 to 5.2 $\mu$m. Quaoar was also observed at 10x higher spectral resolution from 0.97 to 3.16 $\mu$m using medium-resolution gratings. Sedna's spectrum shows a large number of absorption features due to ethane (C$_2$H$_6$), as well as acetylene (C$_2$H$_2$), ethylene (C$_2$H$_4$), H$_2$O, and possibly minor CO$_2$. Gonggong's spectrum also shows several, but fewer and weaker, ethane features, along with stronger and cleaner H$_2$O features and CO$_2$ complexed with other molecules. Quaoar's prism spectrum shows even fewer and weaker ethane features, the deepest and cleanest H$_2$O features, a feature at 3.2 $\mu$m possibly due to HCN, and CO$_2$ ice. The higher-resolution medium grating spectrum of Quaoar reveals several overtone and combination bands of ethane and methane (CH$_4$). Spectra of all three objects show steep red spectral slopes and strong, broad absorptions between 2.7 and 3.6 $\mu$m indicative of complex organic molecules. The suite of light hydrocarbons and complex organic molecules are interpreted as the products of irradiation of methane. We infer that the differences in apparent abundances of irradiation products are likely due to their distinctive orbits, which lead to different timescales of methane retention and to different charged particle irradiation environments. In all cases, however, the continued presence of light hydrocarbons implies a resupply of methane to the surface. We suggest that these three bodies have undergone internal melting and geochemical evolution similar to the larger dwarf planets and distinct from all smaller KBOs., Comment: 32 pages, 9 figures, 5 tables, accepted for publication in Icarus

James Webb Space Telescope's NIRSpec infrared imaging spectrometer observed the outer solar system dwarf planets Eris and Makemake in reflected sunlight at wavelengths spanning 1 through 5 microns. Both objects have high albedo surfaces that are rich in methane ice, with a texture that permits long optical path lengths through the ice for solar photons. There is evidence for N2 ice absorption around 4.2 um on Eris, though not on Makemake. No CO ice absorption is seen at 4.67 um on either body. For the first time, absorption bands of two heavy isotopologues of methane are observed at 2.615 um (13CH4), 4.33 um (12CH3D), and 4.57 um (12CH3D). These bands enable us to measure D/H ratios of (2.5 +/- 0.5) x 10-4 and (2.9 +/- 0.6) x 10-4, along with 13C/12C ratios of 0.012 +/- 0.002 and 0.010 +/- 0.003 in the surface methane ices of Eris and Makemake, respectively. The measured D/H ratios are much lower than that of presumably primordial methane in comet 67P/Churyumov-Gerasimenko, but they are similar to D/H ratios in water in many comets and larger outer solar system objects. This similarity suggests that the hydrogen atoms in methane on Eris and Makemake originated from water, indicative of geochemical processes in past or even ongoing hot environments in their deep interiors. The 13C/12C ratios are consistent with commonly observed solar system values, suggesting no substantial enrichment in 13C as could happen if the methane currently on their surfaces was the residue of a much larger inventory that had mostly been lost to space. Possible explanations include geologically recent outgassing from the interiors as well as processes that cycle the surface methane inventory to keep the uppermost surfaces refreshed.

Enceladus is a prime target in the search for life in our solar system, having an active plume likely connected to a large liquid water subsurface ocean. Using the sensitive NIRSpec instrument onboard JWST, we searched for organic compounds and characterized the plume's composition and structure. The observations directly sample the fluorescence emissions of H2O and reveal an extraordinarily extensive plume (up to 10,000 km or 40 Enceladus radii) at cryogenic temperatures (25 K) embedded in a large bath of emission originating from Enceladus' torus. Intriguingly, the observed outgassing rate (300 kg/s) is similar to that derived from close-up observations with Cassini 15 years ago, and the torus density is consistent with previous spatially unresolved measurements with Herschel 13 years ago, suggesting that the vigor of gas eruption from Enceladus has been relatively stable over decadal timescales. This level of activity is sufficient to maintain a derived column density of 4.5x1017 m-2 for the embedding equatorial torus, and establishes Enceladus as the prime source of water across the Saturnian system. We performed searches for several non-water gases (CO2, CO, CH4, C2H6, CH3OH), but none were identified in the spectra. On the surface of the trailing hemisphere, we observe strong H2O ice features, including its crystalline form, yet we do not recover CO2, CO nor NH3 ice signatures from these observations. As we prepare to send new spacecraft into the outer solar system, these observations demonstrate the unique ability of JWST in providing critical support to the exploration of distant icy bodies and cryovolcanic plumes., Comment: Accepted for publication in Nature Astronomy on May 17th 2023

We summarize the comet science provided by surveys. This includes surveys where the detections of comets are an advantageous benefit but were not part of the survey\'s original intent, as well as some pointed surveys where comet science was the goal. Many of the surveys are made using astrophysical and heliophysics assets. The surveys in our scope include those using ground-based as well as space-based telescope facilities. Emphasis is placed on current or recent surveys, and science that has resulted since the publication of Comets II, though key advancements made by earlier surveys (e.g. IRAS, COBE, NEAT, etc.) will be mentioned. The proportionally greater number of discoveries of comets by surveys have yielded in turn larger samples of comet populations and sub-populations for study, resulting in better defined evolutionary trends. While providing an array of remarkable discoveries, most of the survey data has been only cursorily investigated. It is clear that continuing to fund ground- and space-based surveys of large numbers of comets is vital if we are to address science goals that can give us a population-wide picture of comet properties., Comment: 5 figures, 21 pages, submitted for Comets III

A near surface thermal model for Arrokoth is developed based on the recently released $10^5$ facet model of the body. This thermal solution takes into account Arrokoth's surface re-radiation back onto itself. The solution method exploits Arrokoth's periodic orbital character to develop a thermal response using a time-asymptotic solution method, which involves a Fourier transform solution of the heat equation, an approach recently used by others. We display detailed thermal solutions assuming that Arrokoth's near surface material's thermal inertia ${\cal I} = $ 2.5 W/m$^{-2}$K$^{-1}$s$^{1/2}$. We predict that at New Horizons' encounter with Arrokoth its encounter hemisphere surface temperatures were $\sim$ 57-59 K in its polar regions, 30-40 K on its equatorial zones, and 11-13 K for its winter hemisphere. Arrokoth's orbitally averaged temperatures are around 30-35 K in its polar regions, and closer to 40 K near its equatorial zones. Thermal reradiation from the surrounding surface amounts to less than 5\% of the total energy budget, while the total energy ensconced into and exhumed out Arrokoth's interior via thermal conduction over one orbit is about 0.5\% of the total energy budget. As a generalized application of this thermal modeling together with other KBO origins considerations, we favor the interpretation that New Horizons' REX instrument's $29 \pm 5$K brightness temperature measurement is consistent with Arrokoth's near surface material's being made of sub-to-few mm sized tholin-coated amorphous \water ice grains with 1 W/m$^{-2}$K$^{-1}$s$^{1/2}$ $< {\cal I} < $10-20 W/m$^{-2}$K$^{-1}$s$^{1/2}$, and which are characterized by an X-band emissivity in the range 0.9 and 1., Comment: Accepted on Feb. 21, 2022 for publication in Planetary Science Journal (PSJ)

The Kuiper Belt is a distant region of the Solar System. On 1 January 2019, the New Horizons spacecraft flew close to (486958) 2014 MU69, a Cold Classical Kuiper Belt Object, a class of objects that have never been heated by the Sun and are therefore well preserved since their formation. Here we describe initial results from these encounter observations. MU69 is a bi-lobed contact binary with a flattened shape, discrete geological units, and noticeable albedo heterogeneity. However, there is little surface color and compositional heterogeneity. No evidence for satellites, ring or dust structures, gas coma, or solar wind interactions was detected. By origin MU69 appears consistent with pebble cloud collapse followed by a low velocity merger of its two lobes., Comment: 43 pages, 8 figure

The Cold Classical Kuiper Belt, a class of small bodies in undisturbed orbits beyond Neptune, are primitive objects preserving information about Solar System formation. The New Horizons spacecraft flew past one of these objects, the 36 km long contact binary (486958) Arrokoth (2014 MU69), in January 2019. Images from the flyby show that Arrokoth has no detectable rings, and no satellites (larger than 180 meters diameter) within a radius of 8000 km, and has a lightly-cratered smooth surface with complex geological features, unlike those on previously visited Solar System bodies. The density of impact craters indicates the surface dates from the formation of the Solar System. The two lobes of the contact binary have closely aligned poles and equators, constraining their accretion mechanism.

The outer Solar System object (486958) Arrokoth (provisional designation 2014 MU$_{69}$) has been largely undisturbed since its formation. We study its surface composition using data collected by the New Horizons spacecraft. Methanol ice is present along with organic material, which may have formed through radiation of simple molecules. Water ice was not detected. This composition indicates hydrogenation of carbon monoxide-rich ice and/ or energetic processing of methane condensed on water ice grains in the cold, outer edge of the early Solar System. There are only small regional variations in color and spectra across the surface, suggesting Arrokoth formed from a homogeneous or well-mixed reservoir of solids. Microwave thermal emission from the winter night side is consistent with a mean brightness temperature of 29$\pm$5 K., Comment: 31 pages, 8 figures

Pluto's atmospheric haze settles out rapidly compared with geological timescales. It needs to be accounted for as a surface material, distinct from Pluto's icy bedrock and from the volatile ices that migrate via sublimation and condensation on seasonal timescales. This paper explores how a steady supply of atmospheric haze might affect three distinct provinces on Pluto. We pose the question of why they each look so different from one another if the same haze material is settling out onto all of them. Cthulhu is a more ancient region with comparatively little present-day geological activity, where the haze appears to simply accumulate over time. Sputnik Planitia is a very active region where glacial convection, as well as sublimation and condensation rapidly refresh the surface, hiding recently deposited haze from view. Lowell Regio is a region of intermediate age featuring very distinct coloration from the rest of Pluto. Using a simple model haze particle as a colorant, we are not able to match the colors in both Lowell Regio and Cthulhu. To account for their distinct colors, we propose that after arrival at Pluto's surface, haze particles may be less inert than might be supposed from the low surface temperatures. They must either interact with local materials and environments to produce distinct products in different regions, or else the supply of haze must be non-uniform in time and/or location, such that different products are delivered to different places.

A unique feature of Pluto's large satellite Charon is its dark red northern polar cap. Similar colours on Pluto's surface have been attributed to organic macromolecules produced by energetic radiation processing of hydrocarbons. The polar location of this material on Charon implicates the temperature extremes that result from Charon's high obliquity and long seasons. The escape of Pluto's atmosphere provides a potential feed stock for production of complex chemistry. Gas from Pluto that is transiently cold-trapped and processed at Charon's winter pole was proposed as an explanation on the basis of an image of Charon's northern hemisphere, but not modelled quantitatively. Here we report images of the southern hemisphere illuminated by Pluto-shine and also images taken during the approach phase showing the northern polar cap over a range of longitudes. We model the surface thermal environment on Charon, the supply and temporary cold-trapping of material escaping from Pluto, and, while cold-trapped, its photolytic processing into more complex and less volatile molecules. The model results are consistent with the proposed mechanism producing the observed colour pattern on Charon.

New Horizons observations suggest that CH4 on Pluto has a complex history, involving reservoirs of different composition, thickness and stability controlled by volatile processes occurring on different timescales. In order to interpret these observations, we use a Pluto volatile transport model able to simulate the cycles of N2 and CH4 ices over millions of years. By assuming fixed solid mixing ratios, we explore how changes in surface albedos, emissivities and thermal inertias impact volatile transport. This work is therefore a direct and natural continuation of the work by Bertrand et al. (2018), which only explored the N2 cycles. Results show that bright CH4 deposits can create cold traps for N2 ice outside Sputnik Planitia, leading to a strong coupling between the N2 and CH4 cycles. Depending on the assumed albedo for CH4 ice, the model predicts CH4 ice accumulation (1) at the same equatorial latitudes where the Bladed Terrain Deposits are observed, supporting the idea that these CH4-rich deposits are massive and perennial, or (2) at mid-latitudes (25{\deg}N-70{\deg}N), forming a thick mantle which is consistent with New Horizons observations. In our simulations, both CH4 ice reservoirs are not in an equilibrium state and either one can dominate the other over long timescales, depending on the assumptions made for the CH4 albedo. This suggests that long-term volatile transport exists between the observed reservoirs. The model also reproduces the formation of N2 deposits at mid-latitudes and in the equatorial depressions surrounding the Bladed Terrain, as observed by New Horizons. At the poles, only seasonal CH4 and N2 deposits are obtained in Pluto's current orbital configuration. Finally, we show that Pluto's atmosphere always contained, over the last astronomical cycles, enough gaseous CH4 to absorb most of the incoming Lyman-flux., Comment: Accepted in Icarus

Pluto's landscape is shaped by the cycles of the volatile ices covering its surface. In particular, the Sputnik Planitia (SP) ice sheet displays a large diversity of terrains, with bright and dark plains, pits, topographic depressions and evidences of recent and past glacial flows. Outside SP, New Horizons also revealed numerous N2 ice deposits, in Tombaugh Regio and at mid-northern latitudes. These observations suggest a complex history involving volatile and glacial processes on different timescales. We present numerical simulations of volatile transport on Pluto performed with a model able to simulate the N2 cycle over millions of years (Myrs), taking into account the changes of obliquity and orbital parameters as experienced by Pluto. Results show that over one obliquity cycle, the latitudes of SP between 25{\deg}S-30{\deg}N are dominated by N2 condensation, while the latitudes between 30-50{\deg}N are dominated by N2 sublimation. We find that a net amount of 1 km of ice has sublimed at the northern edge of SP during the last 2 Myrs. By comparing these results with the observed geology of SP, we can relate the formation of the pits and the brightness of the ice to the ice flux occurring at the annual timescale, while the glacial flows at its eastern edge and the erosion of the water ice mountains all around the ice sheet are related to the astronomical timescale. We also perform simulations with a glacial flow scheme which shows that SP is currently at its minimum extent. We also explore the stability of N2 ice outside SP. Results show that it is not stable at the poles but rather in the equatorial regions, in particular in depressions, where thick deposits may persist over tens of Myrs, before being trapped in SP. Finally, another key result is that the minimum and maximum surface pressures obtained over the simulated Myrs remain in the range of mm-Pa and Pa, respectively., Comment: 49 pages, 16 figures

We present a community-led assessment of the solar system investigations achievable with NASA's next-generation space telescope, the Wide Field InfraRed Survey Telescope (WFIRST). WFIRST will provide imaging, spectroscopic, and coronagraphic capabilities from 0.43-2.0 $\mu$m and will be a potential contemporary and eventual successor to JWST. Surveys of irregular satellites and minor bodies are where WFIRST will excel with its 0.28 deg$^2$ field of view Wide Field Instrument (WFI). Potential ground-breaking discoveries from WFIRST could include detection of the first minor bodies orbiting in the Inner Oort Cloud, identification of additional Earth Trojan asteroids, and the discovery and characterization of asteroid binary systems similar to Ida/Dactyl. Additional investigations into asteroids, giant planet satellites, Trojan asteroids, Centaurs, Kuiper Belt Objects, and comets are presented. Previous use of astrophysics assets for solar system science and synergies between WFIRST, LSST, JWST, and the proposed NEOCam mission are discussed. We also present the case for implementation of moving target tracking, a feature that will benefit from the heritage of JWST and enable a broader range of solar system observations., Comment: 58 pages, 14 figures, 7 tables

We present a summary of the campaign of remote observations that supported the European Space Agency's Rosetta mission. Telescopes across the globe (and in space) followed comet 67P/Churyumov-Gerasimenko from before Rosetta's arrival until nearly the end of mission in September 2016. These provided essential data for mission planning, large-scale context information for the coma and tails beyond the spacecraft, and a way to directly compare 67P with other comets. The observations revealed 67P to be a relatively `well behaved' comet, typical of Jupiter family comets and with activity patterns that repeat from orbit-to-orbit. Comparison between this large collection of telescopic observations and the in situ results from Rosetta will allow us to better understand comet coma chemistry and structure. This work is just beginning as the mission ends -- in this paper we present a summary of the ground-based observations and early results, and point to many questions that will be addressed in future studies., Comment: Author prepared version; final published version available at journal. 22 pages

Aims. Polarimetric characteristics of comets at large heliocentric distances is a relatively unexplored area; we extend the idea by adding and analysing the data for three Jupiter family comets (JFCs). Methods. With the FORS2 instrument of the ESO VLT, we performed quasi-simultaneous photometry and polarimetry of three active JFCs 67P/Churyumov-Gerasimenko, 74P/Smirnova-Chernykh, and 152P/Helin-Lawrence. Results. We obtained in total 23 polarimetric measurements at different epochs, covering a phase-angle range ~1 -16 degrees and heliocentric distances from 3 to 4.6 au. From our observations we obtained both colour and polarimetric maps to look for structures in the comae and tails of the comets. Conclusions. 74P/Smirnova-Chernykh and 152P/Helin-Lawrence exhibit enough activity at large heliocentric distances to be detectable in polarimetric measurements. Polarimetric and colour maps indicate no evidence of dust particle

On July 14th 2015, NASA's New Horizons mission gave us an unprecedented detailed view of the Pluto system. The complex compositional diversity of Pluto's encounter hemisphere was revealed by the Ralph/LEISA infrared spectrometer on board of New Horizons. We present compositional maps of Pluto defining the spatial distribution of the abundance and textural properties of the volatiles methane and nitrogen ices and non-volatiles water ice and tholin. These results are obtained by applying a pixel-by-pixel Hapke radiative transfer model to the LEISA scans. Our analysis focuses mainly on the large scale latitudinal variations of methane and nitrogen ices and aims at setting observational constraints to volatile transport models. Specifically, we find three latitudinal bands: the first, enriched in methane, extends from the pole to 55deg N, the second dominated by nitrogen, continues south to 35deg N, and the third, composed again mainly of methane, reaches 20deg N. We demonstrate that the distribution of volatiles across these surface units can be explained by differences in insolation over the past few decades. The latitudinal pattern is broken by Sputnik Planitia, a large reservoir of volatiles, with nitrogen playing the most important role. The physical properties of methane and nitrogen in this region are suggestive of the presence of a cold trap or possible volatile stratification. Furthermore our modeling results point to a possible sublimation transport of nitrogen from the northwest edge of Sputnik Planitia toward the south., Comment: 43 pages, 7 figures; accepted for publication in Icarus

The New Horizons spacecraft mapped colors and infrared spectra across the encounter hemispheres of Pluto and Charon. The volatile ices CH$_4$, CO, and N$_2$, that dominate Pluto's surface, have complicated spatial distributions resulting from sublimation, condensation, and glacial flow acting over seasonal and geological timescales. Pluto's H$_2$O ice "bedrock" is also mapped, with isolated outcrops occurring in a variety of settings. Pluto's surface exhibits complex regional color diversity associated with its distinct provinces. Charon's color pattern is simpler, dominated by neutral low latitudes and a reddish northern polar region. Charon near infrared spectra reveal highly localized areas with strong NH$_3$ absorption tied to small craters with relatively fresh-appearing impact ejecta., Comment: in Science 351, aad9189 (2016)

The New Horizons mission has provided resolved measurements of Pluto's moons Styx, Nix, Kerberos, and Hydra. All four are small, with equivalent spherical diameters of $\approx$40 km for Nix and Hydra and ~10 km for Styx and Kerberos. They are also highly elongated, with maximum to minimum axis ratios of $\approx$2. All four moons have high albedos ( $\approx$50-90 %) suggestive of a water-ice surface composition. Crater densities on Nix and Hydra imply surface ages $\gtrsim$ 4 Ga. The small moons rotate much faster than synchronous, with rotational poles clustered nearly orthogonal to the common pole directions of Pluto and Charon. These results reinforce the hypothesis that the small moons formed in the aftermath of a collision that produced the Pluto-Charon binary., Comment: in Science 351, aae0030 (2016)

We discuss two semi-independent calibration techniques used to determine the in-flight radiometric calibration for the New Horizons' Multi-spectral Visible Imaging Camera (MVIC). The first calibration technique compares the observed stellar flux to modeled values. The difference between the two provides a calibration factor that allows the observed flux to be adjusted to the expected levels for all observations, for each detector. The second calibration technique is a channel-wise relative radiometric calibration for MVIC's blue, near-infrared and methane color channels using observations of Charon and scaling from the red channel stellar calibration. Both calibration techniques produce very similar results (better than 7% agreement), providing strong validation for the techniques used. Since the stellar calibration can be performed without a color target in the field of view and covers all of MVIC's detectors, this calibration was used to provide the radiometric keywords delivered by the New Horizons project to the Planetary Data System (PDS). These keywords allow each observation to be converted from counts to physical units; a description of how these keywords were generated is included. Finally, mitigation techniques adopted for the gain drift observed in the near-infrared detector and one of the panchromatic framing cameras is also discussed.

Thermal observations of the Pluto-Charon system acquired by the Herschel Space Observatory in February 2012 are presented. They consist of photometric measurements with the PACS and SPIRE instruments (nine visits to the Pluto system each), covering six wavelengths from 70 to 500 $\mu$m altogether. The thermal light curve of Pluto-Charon is observed in all filters, albeit more marginally at 160 and especially 500 $\mu$m. Putting these data into the context of older ISO, Spitzer and ground-based observations indicates that the brightness temperature (T$_B$) of the system (rescaled to a common heliocentric distance) drastically decreases with increasing wavelength, from $\sim$53 K at 20 $\mu$m to $\sim$35 K at 500 $\mu$m, and perhaps ever less at longer wavelengths. Considering a variety of diurnal and/or seasonal thermophysical models, we show that T$_B$ values of 35 K are lower than any expected temperature for the dayside surface or subsurface of Pluto and Charon, implying a low surface emissivity. Based on multiterrain modeling, we infer a spectral emissivity that decreases steadily from 1 at 20-25 $\mu$m to $\sim$0.7 at 500~$\mu$m. This kind of behavior is usually not observed in asteroids (when proper allowance is made for subsurface sounding), but is found in several icy surfaces of the solar system. We tentatively identify that a combination of a strong dielectric constant and a considerable surface material transparency (typical penetration depth $\sim$1 cm) is responsible for the effect. Our results have implications for the interpretation of the temperature measurements by REX/New Horizons at 4.2 cm wavelength., Comment: 15 pages, 9 figures, 2 tables

The Pluto system was recently explored by NASA's New Horizons spacecraft, making closest approach on 14 July 2015. Pluto's surface displays diverse landforms, terrain ages, albedos, colors, and composition gradients. Evidence is found for a water-ice crust, geologically young surface units, surface ice convection, wind streaks, volatile transport, and glacial flow. Pluto's atmosphere is highly extended, with trace hydrocarbons, a global haze layer, and a surface pressure near 10 microbars. Pluto's diverse surface geology and long-term activity raise fundamental questions about how small planets remain active many billions of years after formation. Pluto's large moon Charon displays tectonics and evidence for a heterogeneous crustal composition, its north pole displays puzzling dark terrain. Small satellites Hydra and Nix have higher albedos than expected., Comment: 8 pages - Initial Science paper from NASA's New Horizons Pluto Encounter

The methane-nitrogen phase diagram of Prokhvatilov and Yantsevich (1983) indicates that at temperatures relevant to the surfaces of icy dwarf planets like Pluto, two phases contribute to the methane absorptions: nitrogen saturated with methane $\bf{\bar{N_{2}}}$:CH$_{4}$ and methane saturated with nitrogen $\bf{\bar{CH_{4}}}$:N$_{2}$. No optical constants are available so far for the latter component limiting construction of a proper model, in compliance with thermodynamic equilibrium considerations. New optical constants for solid solutions of methane diluted in nitrogen (N$_{2}$:CH$_{4}$) and nitrogen diluted in methane (CH$_{4}$:N$_{2}$) are presented at temperatures between 40 and 90 K, in the wavelength range 1.1-2.7 $\mu$m at different mixing ratios. These optical constants are derived from transmission measurements of crystals grown from the liquid phase in closed cells. A systematic study of the changes of methane and nitrogen solid mixtures spectral behavior with mixing ratio and temperature is presented.

We present an update of the visible and near-infrared colour database of Minor Bodies in the Outer Solar System (MBOSSes), which now includes over 2000 measurement epochs of 555 objects, extracted from over 100 articles. The list is fairly complete as of December 2011. The database is now large enough to enable any dataset with a large dispersion to be safely identified and rejected from the analysis. The selection method used is quite insensitive to individual outliers. Most of the rejected datasets were observed during the early days of MBOSS photometry. The spectral gradient over the visible range is derived from the colours, as well as the R absolute magnitude M(1, 1). The average colours, absolute magnitude, and spectral gradient are listed for each object, as well as the physico-dynamical classes using a classification adapted from Gladman and collaborators. Colour-colour diagrams, histograms, and various other plots are presented to illustrate and investigate class characteristics and trends with other parameters, whose significances are evaluated using standard statistical tests. The colour tables and all plots are also available on the MBOSS colour web page http://www.eso.org/~ohainaut/MBOSS which will be updated when new measurements are published., Comment: 26 pages + 29 pages supplement. A&A in press

Trans-Neptunian objects (TNO) represent the leftovers of the formation of the Solar System. Their physical properties provide constraints to the models of formation and evolution of the various dynamical classes of objects in the outer Solar System. Based on a sample of 19 classical TNOs we determine radiometric sizes, geometric albedos and beaming parameters. Our sample is composed of both dynamically hot and cold classicals. We study the correlations of diameter and albedo of these two subsamples with each other and with orbital parameters, spectral slopes and colors. We have done three-band photometric observations with Herschel/PACS and we use a consistent method for data reduction and aperture photometry of this sample to obtain monochromatic flux densities at 70.0, 100.0 and 160.0 \mu m. Additionally, we use Spitzer/MIPS flux densities at 23.68 and 71.42 \mu m when available, and we present new Spitzer flux densities of eight targets. We derive diameters and albedos with the near-Earth asteroid thermal model (NEATM). As auxiliary data we use reexamined absolute visual magnitudes from the literature and data bases, part of which have been obtained by ground based programs in support of our Herschel key program. We have determined for the first time radiometric sizes and albedos of eight classical TNOs, and refined previous size and albedo estimates or limits of 11 other classicals. The new size estimates of 2002 MS4 and 120347 Salacia indicate that they are among the 10 largest TNOs known. Our new results confirm the recent findings that there are very diverse albedos among the classical TNOs and that cold classicals possess a high average albedo (0.17 +/- 0.04). Diameters of classical TNOs strongly correlate with orbital inclination in our sample. We also determine the bulk densities of six binary TNOs., Comment: 21 pages, 9 figures, accepted for publication in Astronomy and Astrophysics

We present Herschel PACS photometry of 18 Plutinos and determine sizes and albedos for these objects using thermal modeling. We analyze our results for correlations, draw conclusions on the Plutino size distribution, and compare to earlier results. Flux densities are derived from PACS mini scan-maps using specialized data reduction and photometry methods. In order to improve the quality of our results, we combine our PACS data with existing Spitzer MIPS data where possible, and refine existing absolute magnitudes for the targets. The physical characterization of our sample is done using a thermal model. Uncertainties of the physical parameters are derived using customized Monte Carlo methods. The correlation analysis is performed using a bootstrap Spearman rank analysis. We find the sizes of our Plutinos to range from 150 to 730 km and geometric albedos to vary between 0.04 and 0.28. The average albedo of the sample is 0.08 \pm 0.03, which is comparable to the mean albedo of Centaurs, Jupiter Family comets and other Trans-Neptunian Objects. We were able to calibrate the Plutino size scale for the first time and find the cumulative Plutino size distribution to be best fit using a cumulative power law with q = 2 at sizes ranging from 120-400 km and q = 3 at larger sizes. We revise the bulk density of 1999 TC36 and find a density of 0.64 (+0.15/-0.11) g cm-3. On the basis of a modified Spearman rank analysis technique our Plutino sample appears to be biased with respect to object size but unbiased with respect to albedo. Furthermore, we find biases based on geometrical aspects and color in our sample. There is qualitative evidence that icy Plutinos have higher albedos than the average of the sample., Comment: 18 pages, 8 figures, 8 tables, accepted for publication in A&A

Physical characterization of Trans-Neptunian objects, a primitive population of the outer solar system, may provide constraints on their formation and evolution. The goal of this work is to characterize a set of 15 scattered disk (SDOs) and detached objects, in terms of their size, albedo, and thermal properties. Thermal flux measurements obtained with the Herschel-PACS instrument at 70, 100 and 160 \mu m, and whenever applicable, with Spitzer-MIPS at 24 and 70 \mu m, are modeled with radiometric techniques, in order to derive the objects' individual size, albedo and when possible beaming factor. Error bars are obtained from a Monte-Carlo approach. We look for correlations between these and other physical and orbital parameters. Diameters obtained for our sample range from 100 to 2400 km, and the geometric albedos (in V band) vary from 3.8 % to 84.5 %. The unweighted mean V geometric albedo for the whole sample is 11.2 % (excluding Eris); 6.9 % for the SDOs, and 17.0 % for the detached objects (excluding Eris). We obtain new bulk densities for three binary systems: Ceto/Phorcys, Typhon/Echidna and Eris/Dysnomia. Apart from correlations clearly due to observational bias, we find significant correlations between albedo and diameter (more reflective objects being bigger), and between albedo, diameter and perihelion distance (brighter and bigger objects having larger perihelia). We discuss possible explanations for these correlations., Comment: Accepted for publication in Astronomy and Astrophysics (24/01/2012): 20 pages, 8 figures

Thermal emission from Kuiper Belt object (136108) Haumea was measured with Herschel-PACS at 100 and 160 micrometers for almost a full rotation period. Observations clearly indicate a 100-micrometer thermal lightcurve with an amplitude of a factor of ~ 2, which is positively correlated with the optical lightcurve. This confirms that both are primarily due to shape effects. A 160-micrometer lightcurve is marginally detected. Radiometric fits of the mean Herschel- and Spitzer- fluxes indicate an equivalent diameter D ~ 1300 km and a geometric albedo p_v ~ 0.70-0.75. These values agree with inferences from the optical lightcurve, supporting the hydrostatic equilibrium hypothesis. The large amplitude of the 100-micrometer lightcurve suggests that the object has a high projected a/b axis ratio (~ 1.3) and a low thermal inertia as well as possible variable infrared beaming. This may point to fine regolith on the surface, with a lunar-type photometric behavior. The quality of the thermal data is not sufficient to clearly detect the effects of a surface dark spot., Comment: Accepted for publication in Astronomy & Astrophysics (special issue on Herschel first results)

The goal of the Herschel Open Time Key programme "TNOs are Cool!" is to derive the physical and thermal properties for a large sample of Centaurs and trans-Neptunian objects (TNOs), including resonant, classical, detached and scattered disk objects. We present results for seven targets either observed in PACS point-source, or in mini scan-map mode. Spitzer-MIPS observations were included for three objects. The sizes of these targets range from 100 km to almost 1000 km, five have low geometric albedos below 10%, (145480) 2005 TB190 has a higher albedo above 15%. Classical thermal models driven by an intermediate beaming factor of $\eta$=1.2 or $\eta$-values adjusted to the observed colour temperature fit the multi-band observations well in most cases. More sophisticated thermophysical models give very similar diameter and albedo values for thermal inertias in the range 0-25 Jm-2s-0.5K-1, consistent with very low heat conductivities at temperatures far away from the Sun. The early experience with observing and model strategies will allow us to derive physical and thermal properties for our complete Herschel TNO sample of 140 targets as a benchmark for understanding the solar system debris disk, and extra-solar ones as well., Comment: 5 pages, 2 figures, accepted for publication in the A&A Herschel Special Issue

A unique feature of Plutos large satellite Charon is its dark red northern polar cap. Similar colours on Plutos surface have been attributed to tholin-like organic macromolecules produced by energetic radiation processing of hydrocarbons. The polar location on Charon implicates the temperature extremes that result from Charons high obliquity and long seasons in the production of this material. The escape of Pluto's atmosphere provides a potential feedstock for a complex chemistry. Gas from Pluto that is transiently cold-trapped and processed at Charon's winter pole was proposed as an explanation for the dark coloration on the basis of an image of Charon's northern hemisphere, but not modelled quantitatively. Here we report images of the southern hemisphere illuminated by Pluto-shine and also images taken during the approach phase that show the northern polar cap over a range of longitudes. We model the surface thermal environment on Charon and the supply and temporary cold-trapping of material escaping from Pluto, as well as the photolytic processing of this material into more complex and less volatile molecules while cold-trapped. The model results are consistent with the proposed mechanism for producing the observed colour pattern on Charon.