1. Pressure field assisted non-hydrolytic sol-gel in-situ synthesis of novel seed-pulp-structured C@ZrSiO4 pigments.
- Author
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Jiang, Feng, Li, Wen, Wang, Tao, Yu, Junling, Zhang, Junxiong, Wu, Qian, Zhang, Quan, Zhang, Xiaojun, Hu, Qing, Feng, Guo, Liu, Jianmin, and Yu, Yun
- Subjects
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PIGMENTS , *TRANSFORMATION groups , *SOL-gel processes , *X-ray diffraction , *COLORIMETERS - Abstract
Novel pressure field assisted non-hydrolytic sol-gel method is developed for the in-situ synthesis of novel seed-pulp-structured C@ZrSiO 4 pigments. The obtained pigments, which are composed of in-situ carbon derived from leaving organic groups as core and zircon as shell, were characterized via DSC-TG, XRD, FT-IR, Raman, XPS, SEM, TEM, UV–Vis, and automatic colorimeters. It was found that the pressure field promotes the non-hydrolytic sol-gel heterogeneous polycondensation reaction and the direct transformation of reaction groups into in-situ spherical carbon. Meanwhile, the in-situ spherical carbon was enclosed by heterogeneous condensation bonds wrap and formed a dense structure. The as-prepared pigments exhibited excellent color rendering performance (L* = 21.07, a* = 0.48, b* = 0.75) and thermal stability. [ABSTRACT FROM AUTHOR]
- Published
- 2024
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