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Infrared spectroscopy, e.g., with JWST, provides a glimpse into the chemical inventory of the innermost region of protoplanetary discs, where terrestrial planets eventually form. The chemical make-up of regions inside snowlines is connected to the material drifting from the outer regions, which can be modeled with dust evolution models. However, infrared observations are limited by the high dust extinction in the inner disc, and only probes the abundances of gaseous species in the disc surface layers. As a result, the bulk mass of delivered volatiles is not directly relatable to what is measured through infrared spectra. In this paper, we investigate how the delivery of dust and ice after prolonged pebble drift affects the observable reservoir of water vapor in the inner disc. We develop a 1+1D approach based on dust evolution models to determine the delivery and distribution of vapor compared to the height of the $\tau = 1$ surface in the dust continuum. We find that the observable column density of water vapor at wavelengths probed by JWST spans many orders of magnitude over time, exhibiting different radial profiles depending on dust properties, drift rate, and local processing. In the presence of a traffic-jam effect inside the snowline, the observable vapor reservoir appears constant in time despite the ongoing delivery by pebble drift, such that water is effectively smuggled unnoticed. Differences in measured column densities then originate not only from variations in bulk vapor content, but also from differences in the properties and distribution of dust particles., Comment: 14 pages, 8 figures, accepted in MNRAS

We present a JWST MIRI/MRS spectrum of the inner disk of WISE J044634.16$-$262756.1B (hereafter J0446B), an old ($\sim$34 Myr) M4.5 star but with hints of ongoing accretion. The spectrum is molecule-rich and dominated by hydrocarbons. We detect 14 molecular species (H$_2$, CH$_3$, CH$_4$, C$_2$H$_2$, $^{13}$CCH$_2$, C$_2$H$_4$, C$_2$H$_6$, C$_3$H$_4$, C$_4$H$_2$, C$_6$H$_6$, HCN, HC$_3$N, CO$_2$ and $^{13}$CO$_2$) and 2 atomic lines ([Ne II] and [Ar II]), all observed for the first time in a disk at this age. The detection of spatially unresolved H$_2$ and Ne gas strongly supports that J0446B hosts a long-lived primordial disk, rather than a debris disk. The marginal H$_2$O detection and the high C$_2$H$_2$/CO$_2$ column density ratio indicate that the inner disk of J0446B has a very carbon-rich chemistry, with a gas-phase C/O ratio $\gtrsim$2, consistent with what have been found in most primordial disks around similarly low-mass stars. In the absence of significant outer disk dust substructures, inner disks are expected to first become water-rich due to the rapid inward drift of icy pebbles, and evolve into carbon-rich as outer disk gas flows inward on longer timescales. The faint millimeter emission in such low-mass star disks implies that they may have depleted their outer icy pebble reservoir early and already passed the water-rich phase. Models with pebble drift and volatile transport suggest that maintaining a carbon-rich chemistry for tens of Myr likely requires a slowly evolving disk with $\alpha-$viscosity $\lesssim10^{-4}$. This study represents the first detailed characterization of disk gas at $\sim$30 Myr, strongly motivating further studies into the final stages of disk evolution., Comment: Accepted by ApJL. 8 figures in the main text

This work aims at providing fundamental general tools for the analysis of water spectra as observed in protoplanetary disks with JWST-MIRI. We analyze 25 high-quality spectra from the JDISC Survey reduced with asteroid calibrators as presented in Pontoppidan et al. (2024). First, we present a spectral atlas to illustrate the clustering of H$_2$O transitions from different upper level energies ($E_u$) and identify single (un-blended) transitions that provide the most reliable measurements. With that, we demonstrate two important excitation effects: the opacity saturation of ortho-para line pairs that overlap, and the non-LTE excitation of $v=1-1$ lines scattered across the $v=0-0$ rotational band. Second, we define a shorter list of fundamental lines spanning $E_u=$ 1500-6000 K to develop simple line-ratio diagnostic diagrams for the radial temperature distribution of water in inner disks, which can be interpreted using discrete temperature components or a radial gradient. Third, we report the detection of disk-rotation Doppler broadening of molecular lines, which confirms the radial distribution of water emission including, for the first time, the radially-extended $\approx$ 170-220 K reservoir close to the snowline. The combination of measured line ratios and broadening suggests that drift-dominated disks have shallower temperature gradients with an extended cooler disk surface enriched by ice sublimation. We also report the first detection of a H$_2$O-rich inner disk wind from narrow blue-shifted absorption in the ro-vibrational lines. We summarize these findings and tools into a general recipe to make the study of water in planet-forming regions reliable, effective, and sustainable for samples of $> 100$ disks., Comment: Accepted for publication in The Astronomical Journal

The mid-infrared water vapor emission spectrum provides a novel way to characterize the delivery of icy pebbles towards the innermost ($<5$ au) regions of planet-forming disks. Recently, JWST MIRI-MRS showed that compact disks exhibit an excess of low-energy water vapor emission relative to extended multi-gapped disks, suggesting that icy pebble drift is more efficient in the former. We carry out detailed emission line modeling to retrieve the excitation conditions of rotational water vapor emission in a sample of four compact and three extended disks within the JDISC Survey. We present two-temperature H$_2$O slab model retrievals and, for the first time, constrain the spatial distribution of water vapor by fitting parametric radial temperature and column density profiles. Such models statistically outperform the two-temperature slab fits. We find a correlation between the observable hot water vapor mass and stellar mass accretion rate, as well as an anti-correlation between cold water vapor mass and sub-mm dust disk radius, confirming previously reported water line flux trends. We find that the mid-IR spectrum traces H$_2$O with temperatures down to 180-300 K, but the coldest 150-170 K gas remains undetected. Furthermore the H$_2$O temperature profiles are generally steeper and cooler than the expected `super-heated' dust temperature in passive irradiated disks. The column density profiles are used to estimate icy pebble mass fluxes, which suggest that compact and extended disks may produce markedly distinct inner-disk exoplanet populations if local feeding mechanisms dominate their assembly., Comment: Accepted for publication in ApJ

We present James Webb Space Telescope (JWST) Mid-InfraRed Instrument (MIRI) observations of warm CO and H$_2$O gas in emission toward the low-mass protostar IRAS 15398-3359, observed as part of the CORINOS program. The CO is detected via the rovibrational fundamental band and hot band near 5 $\mu$m, whereas the H$_2$O is detected in the rovibrational bending mode at 6-8 $\mu$m. Rotational analysis indicates that the CO originates in a hot reservoir of $1598\pm118$ K, while the water is much cooler at $204\pm 7$ K. Neither the CO nor the H$_2$O line images are significantly spatially extended, constraining the emission to within $\sim$40 au of the protostar. The compactness and high temperature of the CO are consistent with an origin in the embedded protostellar disk, or a compact disk wind. In contrast, the water must arise from a cooler region and requires a larger emitting area (compared to CO) to produce the observed fluxes. The water may arise from a more extended part of the disk, or from the inner portion of the outflow cavity. Thus, the origin of the molecular emission observed with JWST remains ambiguous. Better constraints on the overall extinction, comparison with realistic disk models, and future kinematically-resolved observations may all help to pinpoint the true emitting reservoirs., Comment: 15 pages, 13 figures. Accepted for publication in ApJ

We present deep 1.4-4.8 um JWST-NIRCam imaging of the Serpens Main star-forming region and identify 20 candidate protostellar outflows, most with bipolar structure and identified driving sources. The outflow position angles (PAs) are strongly correlated, and aligned within +/- 24 degrees of the major axis of the Serpens filament. These orientations are further aligned with the angular momentum vectors of the two disk shadows in this region. We estimate that the probability of this number of young stars being co-aligned if sampled from a uniform PA distribution is 10^-4. This in turn suggests that the aligned protostars, which seem to be at similar evolutionary stages based on their outflow dynamics, formed at similar times with a similar spin inherited from a local cloud filament. Further, there is tentative evidence for a systematic change in average position angle between the north-western and south-eastern cluster, as well as increased scatter in the PAs of the south-eastern protostars. SOFIA-HAWC+ archival dust polarization observations of Serpens Main at 154 and 214 um are perpendicular to the dominant jet orientation in NW region in particular. We measure and locate shock knots and edges for all of the outflows and provide an identifying catalog. We suggest that Serpens main is a cluster that formed from an isolated filament, and due to its youth retains its primordial outflow alignment., Comment: 18 pages, 7 figures

We present a JWST imaging survey with NIRCam and MIRI of NGC 346, the brightest star-forming region in the Small Magellanic Cloud (SMC). By combining aperture and point spread function (PSF) photometry of eleven wavelength bands across these two instruments, we have detected more than 200,000 unique sources. Using near-infrared (IR) color analysis, we observe various evolved and young populations, including 196 young stellar objects (YSOs) and pre-main sequence stars suitable for forthcoming spectroscopic studies. We expand upon this work, creating mid-IR color-magnitude diagrams and determining color cuts to identify 833 reddened sources which are YSO candidates. We observe that these candidate sources are spatially associated with regions of dusty, filamentary nebulosity. Furthermore, we fit model YSO spectral energy distributions (SEDs) to a selection of sources with detections across all of our MIRI bands. We classify with a high degree of confidence 23 YSOs in this sample and estimate their radii, bolometric temperatures, luminosities, and masses. We detect YSOs approaching 1 solar mass, the lowest-mass extragalactic YSOs confirmed to date.

GQ Lup B is a forming brown dwarf companion ($M\sim10-30~M_J$) showing evidence for an infrared excess associated with a disk surronding the companion itself. Here we present mid-infrared (MIR) observations of GQ Lup B with the Medium Resolution Spectrograph (MRS) on JWST, spanning $4.8-11.7~\mu$m. We remove the stellar contamination using reference differential imaging based on principal component analysis (PCA), demonstrating that the MRS can perform high-contrast science. Our observations provide a sensitive probe of the disk surrounding GQ Lup B. We find no sign of a silicate feature, similar to other disk surrounding very low mass objects, which likely implies significant grain growth ($a_{\mathrm{min}}\gtrsim5~\mu$m), and potentially dust settling. Additionally, we find that if the emission is dominated by an inner wall, the disk around the companion might have an inner cavity larger than the one set by sublimation. Conversely, if our data probe the emission from a thin flat disk, we find the disk to be very compact. More observations are required to confirm this finding and assess the vertical structure of the disk. This approach paves the path to the future study of circumplanetary disks and their physical properties. Our results demonstrate that MIR spectroscopic observations can reveal the physical characteristics of disks around forming companions, providing unique insights into the formation of giant planets, brown dwarfs and their satellites., Comment: 13 pages, 4 figures, accepted for publication in ApJL

We present MIRI MRS observations of the large, multi-gapped protoplanetary disk around the T-Tauri star AS 209. The observations reveal hundreds of water vapor lines from 4.9 to 25.5 $\mu$m towards the inner $\sim1$ au in the disk, including the first detection of ro-vibrational water emission in this disk. The spectrum is dominated by hot ($\sim800$ K) water vapor and OH gas, with only marginal detections of CO$_2$, HCN, and a possible colder water vapor component. Using slab models with a detailed treatment of opacities and line overlap, we retrieve the column density, emitting area, and excitation temperature of water vapor and OH, and provide upper limits for the observable mass of other molecules. Compared to MIRI spectra of other T-Tauri disks, the inner disk of AS 209 does not appear to be atypically depleted in CO$_2$ nor HCN. Based on \textit{Spitzer IRS} observations, we further find evidence for molecular emission variability over a 10-year baseline. Water, OH, and CO$_2$ line luminosities have decreased by factors 2-4 in the new MIRI epoch, yet there are minimal continuum emission variations. The origin of this variability is yet to be understood., Comment: Accepted for publication in ApJ

We discuss statistical relationships between the mass of protoplanetary disks and the hydrogen deuteride (HD) line emission and the dust spectral energy distribution (SED) determined using 3000 ProDiMo disk models. The models have 15 free parameters describing disk physical properties, the central star, and the local radiation field. The sampling of physical parameters is done using a Monte Carlo approach to evaluate the probability density functions of observables as a function of physical parameters. We find that the HD fractional abundance is almost constant even though the UV flux varies by several orders of magnitude. Probing the statistical relation between the physical quantities and the HD flux, we find that low-mass (optically thin) disks display a tight correlation between the average disk gas temperature and HD line flux, while massive disks show no such correlation. We demonstrate that the central star luminosity, disk size, dust size distribution, and HD flux may be used to determine the disk gas mass to within a factor of three. We also find that the far-IR and sub-mm/mm SEDs and the HD flux may serve as strong constraints for determining the disk gas mass to within a factor of two. If the HD lines are fully spectrally resolved ($R\gtrsim 1.5\times10^6, \Delta v=0.2~\rm km\,s^{-1}$), the 56 $\mu$m and 112 $\mu$m HD line profiles alone may constrain the disk gas mass to within a factor of two., Comment: 31 pages, 16 figures, ApJ accepted, preprint

We present an analysis of the JWST/MIRI-MRS spectrum of Sz114, an accreting M5 star surrounded by a large dust disk with a gap at ~39au. The spectrum is molecular-rich: we report the detection of water, CO, CO2, HCN, C2H2, and H2. The only identified atomic/ionic transition is from [NeII] at 12.81 micron. A distinct feature of this spectrum is the forest of water lines with the 17.22 micron emission surpassing that of most late M-star disks by an order of magnitude in flux and aligning instead with disks of earlier-type stars. Moreover, flux rations of C2H2/H2O and HCN/H2O in Sz114 also resemble those of earlier-type disks, with a slightly elevated CO2/H2O ratio. While accretion heating can boost all infrared lines, the unusual properties of Sz114 could be explained by the young age of the source, its formation under unusual initial conditions (a large massive disk), and/or the presence of dust substructures. The latter delay the inward drift of icy pebbles and thus preserve a lower C/O ratio over an extended period. In contrast, late M-star disks-which are typically faint, small in size, and likely lack significant substructures-may have more quickly depleted the outer icy reservoir and already evolved out of a water-rich inner disk phase. Our findings underscore the unexpected diversity within mid-infrared spectra of late M-star disks, highlighting the need to expand the observational sample for a comprehensive understanding of their variations and thoroughly test pebble drift and planet formation models., Comment: 15 pages, 7 figures, submitted to ApJL

Previous analyses of mid-infrared water spectra from young protoplanetary disks observed with the Spitzer-IRS found an anti-correlation between water luminosity and the millimeter dust disk radius observed with ALMA. This trend was suggested to be evidence for a fundamental process of inner disk water enrichment, used to explain properties of the Solar System 40 years ago, in which icy pebbles drift inward from the outer disk and sublimate after crossing the snowline. Previous analyses of IRS water spectra, however, were uncertain due to the low spectral resolution that blended lines together. We present new JWST-MIRI spectra of four disks, two compact and two large with multiple radial gaps, selected to test the scenario that water vapor inside the snowline is regulated by pebble drift. The higher spectral resolving power of MIRI-MRS now yields water spectra that separate individual lines, tracing upper level energies from 900 K to 10,000 K. These spectra clearly reveal excess emission in the low-energy lines in compact disks, compared to the large disks, demonstrating an enhanced cool component with $T \approx$ 170-400 K and equivalent emitting radius $R_{\rm{eq}}\approx$ 1-10 au. We interpret the cool water emission as ice sublimation and vapor diffusion near the snowline, suggesting that there is indeed a higher inwards mass flux of icy pebbles in compact disks. Observation of this process opens up multiple exciting prospects to study planet formation chemistry in inner disks with JWST., Comment: Accepted for publication in ApJ Letters

JWST observations of NGC 346, a star-forming region in the metal-poor Small Magellanic Cloud, reveal a substantial population of sub-solar mass young stellar objects (YSOs) with IR excess. We detected $\sim$500 YSOs and pre main sequence (PMS) stars from more than 45,000 unique sources utilizing all four NIRCam wide filters with deep, high-resolution imaging, where ongoing low-mass star formation is concentrated along dust filaments. From these observations, we construct detailed near-IR colour-magnitude diagrams with which preliminary categorizations of YSO classes are made. For the youngest, most deeply-embedded objects, JWST/NIRCam reaches over 10 magnitudes below Spitzer observations at comparable wavelengths, and two magnitudes fainter than HST for more-evolved PMS sources, corresponding to $\sim$0.1 M$_\odot$. For the first time in an extragalactic environment, we detect embedded low-mass star-formation. Furthermore, evidence of IR excess and accretion suggests that dust required for rocky planet formation is present at metallicities as low as 0.2 $Z_\odot$., Comment: 16 pages, 2 figures, Accepted Nature Astronomy

This work presents ground-based spectrally-resolved water emission at R = 30000-100000 over infrared wavelengths covered by JWST (2.9-12.8 $\mu$m). Two new surveys with iSHELL and VISIR are combined with previous spectra from CRIRES and TEXES to cover parts of multiple ro-vibrational and rotational bands observable within telluric transmission bands, for a total of $\approx160$ spectra and 85 disks (30 of which are JWST targets in Cycle 1). The general expectation of a range of regions and excitation conditions traced by infrared water spectra is for the first time supported by the combined kinematics and excitation as spectrally resolved at multiple wavelengths. The main findings from this analysis are: 1) water lines are progressively narrower from the ro-vibrational bands at 2-9 $\mu$m to the rotational lines at 12 $\mu$m, and partly match a broad (BC) and narrow (NC) emission components, respectively, as extracted from ro-vibrational CO spectra; 2) rotation diagrams of resolved water lines from upper level energies of 4000-9500 K show vertical spread and curvatures indicative of optically thick emission ($\approx 10^{18}$ cm$^{-2}$) from a range of excitation temperatures ($\approx 800$-1100 K); 3) the new 5 $\mu$m spectra demonstrate that slab model fits to the rotational lines at $> 10$ $\mu$m strongly over-predict the ro-vibrational emission bands at $< 9$ $\mu$m, implying non-LTE vibrational excitation. We discuss these findings in the context of emission from a disk surface and a molecular inner disk wind, and provide a list of guidelines to support the analysis of spectrally-unresolved JWST spectra., Comment: Accepted for publication on AJ

We present an analysis of an unusual pattern of water vapor emission from the $\sim$2 Myr-old low-mass binary system VV CrA, as observed in infrared spectra obtained with VLT-CRIRES, VLT-VISIR, and Spitzer-IRS. Each component of the binary shows emission from water vapor in both the L ($\sim3\,\mu$m) and N ($\sim 12\,\mu$m) bands. The N-band and Spitzer spectra are similar to those previously observed from young stars with disks, and are consistent with emission from an extended protoplanetary disk. Conversely, the CRIRES L-band data of VV CrA A show an unusual spectrum, which requires the presence of a water reservoir with high temperature ($T\gtrsim1500$ K), column density ($N_\mathrm{H2O}\sim 3\times10^{20}\ \mathrm{cm}^{-2}$), and turbulent broadening ($v\sim 10$ km s$^{-1}$), but very small emitting area ($A\lesssim0.005$ AU$^2$). Similarity with previously observed water emission from V1331 Cyg (Doppmann et al. 2011) and SVS 13 (Carr et al. 2004) suggests that the presence of such a reservoir may be linked to evolutionary state, perhaps related to the presence of high accretion rates or winds. While the inner disk may harbor such a reservoir, simple Keplerian models do not match well with emitting line shapes, and alternative velocity fields must be considered. We also present a new idea, that the unusual emission could arise in a circumplanetary disk, embedded within the larger VV CrA A protoplanetary disk. Additional data are likely required to determine the true physical origin of this unusual spectral pattern., Comment: 32 pages, 17 figures, 5 appendix figures, 2 tables. Accepted for publication in ApJ

The origin of complex organic molecules (COMs) in young Class 0 protostars has been one of the major questions in astrochemistry and star formation. While COMs are thought to form on icy dust grains via gas-grain chemistry, observational constraints on their formation pathways have been limited to gas-phase detection. Sensitive mid-infrared spectroscopy with JWST enables unprecedented investigation of COM formation by measuring their ice absorption features. We present an overview of JWST/MIRI MRS spectroscopy and imaging of a young Class 0 protostar, IRAS 15398-3359, and identify several major solid-state absorption features in the 4.9-28 $\mu$m wavelength range. These can be attributed to common ice species, such as H$_2$O, CH$_3$OH, NH$_3$, and CH$_4$, and may have contributions from more complex organic species, such as C$_2$H$_5$OH and CH$_3$CHO. The MRS spectra show many weaker emission lines at 6-8 $\mu$m, which are due to warm CO gas and water vapor, possibly from a young embedded disk previously unseen. Finally, we detect emission lines from [Fe II], [Ne II], [S I], and H$_2$, tracing a bipolar jet and outflow cavities. MIRI imaging serendipitously covers the south-western (blue-shifted) outflow lobe of IRAS 15398-3359, showing four shell-like structures similar to the outflows traced by molecular emission at sub-mm wavelengths. This overview analysis highlights the vast potential of JWST/MIRI observations and previews scientific discoveries in the coming years., Comment: Accepted to ApJL. The methods of data reduction and spectral extraction are updated

We present an overview and first results from a $M$-band spectroscopic survey of planet-forming disks performed with iSHELL on IRTF, using two slits that provide resolving power R $\approx$ 60,000-92,000 (5-3.3 km/s). iSHELL provides a nearly complete coverage at 4.52-5.24 $\mu$m in one shot, covering $>50$ lines from the R and P branches of $^{12}$CO and $^{13}$CO for each of multiple vibrational levels, and providing unprecedented information on the excitation of multiple emission and absorption components. Some of the most notable new findings of this survey are: 1) the detection of two CO Keplerian rings at $<2$ au (in HD 259431), 2) the detection of H${_2}$O ro-vibrational lines at 5 $\mu$m (in AS 205 N), and 3) the common kinematic variability of CO lines over timescales of 1-14 years. By homogeneously analyzing this survey together with a previous VLT-CRIRES survey of cooler stars, we discuss a unified view of CO spectra where emission and absorption components scan the disk surface across radii from a dust-free region within dust sublimation out to $\approx10$ au. We classify two fundamental types of CO line shapes interpreted as emission from Keplerian rings (double-peak lines) and a disk surface plus a low-velocity part of a wind (triangular lines), where CO excitation reflects different emitting regions (and their gas-to-dust ratio) rather than just the irradiation spectrum. A disk+wind interpretation for the triangular lines naturally explains several properties observed in CO spectra, including the line blue-shifts, line shapes that turn into narrow absorption at high inclinations, and the frequency of disk winds as a function of stellar type., Comment: Accepted for publication on The Astronomical Journal

We present a synergic study of protoplanetary disks to investigate links between inner disk gas molecules and the large-scale migration of solid pebbles. The sample includes 63 disks where two types of measurements are available: i) spatially-resolved disk images revealing the radial distribution of disk pebbles (mm-cm dust grains), from millimeter observations with ALMA or the SMA, and ii) infrared molecular emission spectra as observed with Spitzer. The line flux ratios of H2O with HCN, C2H2, and CO2 all anti-correlate with the dust disk radius R$_{dust}$, expanding previous results found by Najita et al. (2013) for HCN/H2O and the dust disk mass. By normalization with the dependence on accretion luminosity common to all molecules, only the H2O luminosity maintains a detectable anti-correlation with disk radius, suggesting that the strongest underlying relation is between H2O and R$_{dust}$. If R$_{dust}$ is set by large-scale pebble drift, and if molecular luminosities trace the elemental budgets of inner disk warm gas, these results can be naturally explained with scenarios where the inner disk chemistry is fed by sublimation of oxygen-rich icy pebbles migrating inward from the outer disk. Anti-correlations are also detected between all molecular luminosities and the infrared index n$_{13-30}$, which is sensitive to the presence and size of an inner disk dust cavity. Overall, these relations suggest a physical interconnection between dust and gas evolution both locally and across disk scales. We discuss fundamental predictions to test this interpretation and study the interplay between pebble drift, inner disk depletion, and the chemistry of planet-forming material., Comment: Accepted for publication on ApJ

We present multi-epoch Hubble Space Telescope imaging of the Great Disk Shadow in the Serpens star-forming region. The near-infrared images show strong variability of the disk shadow, revealing dynamics of the inner disk on time scales of months. The Great Shadow is projected onto the Serpens reflection nebula by an unresolved protoplanetary disk surrounding the young intermediate-mass star SVS2/CK3/EC82. Since the shadow extends out to a distance of at least 17,000 au, corresponding to a light travel time of 0.24 years, the images may reveal detailed changes in the disk scale height and position angle on time scales as short as a day, corresponding to the angular resolution of the images, and up to the 1.11 year span between two observing epochs. We present a basic retrieval of temporal changes in the disk density structure, based on the images. We find that the inner disk changes position angle on time scales of months, and that the change is not axisymmetric, suggesting the presence of a non-axisymmetric dynamical forcing on $\sim$1\,au size scales. We consider two different scenarios, one in which a quadrupolar disk warp orbits the central star, and one in which an unequal-mass binary orbiting out of the disk plane displaces the photo-center relative to the shadowing disk. Continued space-based monitoring of the Serpens Disk Shadow is required to distinguish between these scenarios, and could provide unique, and detailed, insight into the dynamics of inner protoplanetary disks not available through other means., Comment: Accepted for publication in the Astrophysical Journal

The gaseous mass of protoplanetary disks is a fundamental quantity in planet formation. The presence of gas is necessary to assemble planetesimals, it determines timescales of giant planet birth, and it is an unknown factor for a wide range of properties of planet formation, from chemical abundances (X/H) to the mass efficiency of planet formation. The gas mass obtained from traditional tracers, such as dust thermal continuum and CO isotopologues, are now known to have significant (1 - 2 orders of magnitude) discrepancies. Emission from the isotopologue of H2, hydrogen deuteride (HD), offers an alternative measurement of the disk gas mass. Of all of the regions of the spectrum, the far-infrared stands out in that orders of magnitude gains in sensitivity can be gleaned by cooling a large aperture telescope to 8 K. Such a facility can open up a vast new area of the spectrum to exploration. One of the primary benefits of this far-infrared revolution would be the ability to survey hundreds of planet-forming disks in HD emission to derive their gaseous masses. For the first time, we will have statistics on the gas mass as a function of evolution, tracing birth to dispersal as a function of stellar spectral type. These measurements have broad implications for our understanding of the time scale during which gas is available to form giant planets, the dynamical evolution of the seeds of terrestrial worlds, and the resulting chemical composition of pre-planetary embryos carrying the elements needed for life. Measurements of the ground-state line of HD requires a space-based observatory operating in the far-infrared at 112 microns., Comment: Science white paper submitted to the Astro2020 Decadal Survey

Water is fundamental to our understanding of the evolution of planetary systems and the delivery of volatiles to the surfaces of potentially habitable planets. Yet, we currently have essentially no facilities capable of observing this key species comprehensively. With this white paper, we argue that we need a relatively large, cold space-based observatory equipped with a high-resolution spectrometer, in the mid- through far-infrared wavelength range (25-600~$\mu$m) in order to answer basic questions about planet formation, such as where the Earth got its water, how giant planets and planetesimals grow, and whether water is generally available to planets forming in the habitable zone of their host stars., Comment: Science white paper submitted to the Astro2020 Decadal Survey

The dominant reservoirs of elemental nitrogen in protoplanetary disks have not yet been observationally identified. Likely candidates are HCN, NH$_3$ and N$_2$. The relative abundances of these carriers determine the composition of planetesimals as a function of disk radius due to strong differences in their volatility. A significant sequestration of nitrogen in carriers less volatile than N$_2$ is likely required to deliver even small amounts of nitrogen to the Earth and potentially habitable exo-planets. While HCN has been detected in small amounts in inner disks ($<10$ au), so far only relatively insensitive upper limits on inner disk NH$_3$ have been obtained. We present new Gemini-TEXES high resolution spectroscopy of the 10.75 $\mu$m band of warm NH$_3$, and use 2-dimensional radiative transfer modeling to improve previous upper limits by an order of magnitude to $\rm [NH_3/H_{nuc}]<10^{-7}$ at 1 au. These NH$_3$ abundances are significantly lower than those typical for ices in circumstellar envelopes ($[{\rm NH_3/H_{nuc}}]\sim 3\times 10^{-6}$). We also consistently retrieve the inner disk HCN gas abundances using archival Spitzer spectra, and derive upper limits on the HCN ice abundance in protostellar envelopes using archival ground-based 4.7 $\mu$m spectroscopy ([HCN$_{\rm ice}$]/[H$_2$O$_{\rm ice}$]$<1.5-9$\%). We identify the NH$_3$/HCN ratio as an indicator of chemical evolution in the disk, and use this ratio to suggest that inner disk nitrogen is efficiently converted from NH$_3$ to N$_2$, significantly increasing the volatility of nitrogen in planet-forming regions., Comment: Accepted for publication in the Astrophysical Journal

The HIgh-Resolution Mid-infrarEd Spectrometer (HIRMES) is the 3rd Generation Instrument for the Stratospheric Observatory For Infrared Astronomy (SOFIA), currently in development at the NASA Goddard Space Flight Center (GSFC), and due for commissioning in 2019. By combining direct-detection Transition Edge Sensor (TES) bolometer arrays, grating-dispersive spectroscopy, and a host of Fabry-Perot tunable filters, HIRMES will provide the ability for High Resolution (R~100,000), Mid-Resolution (R~10,000), and Low-Resolution (R~600) slit-spectroscopy, and 2D Spectral Imaging (R~2000 at selected wavelengths) over the 25 - 122 {\mu}m mid-far infrared waveband. The driving science application is the evolution of proto-planetary systems via measurements of water-vapor, water-ice, deuterated hydrogen (HD), and neutral oxygen lines. However, HIRMES has been designed to be as flexible as possible to cover a wide range of science cases that fall within its phase-space, all whilst reaching sensitivities and observing powers not yet seen thus far on SOFIA, providing unique observing capabilities which will remain unmatched for decades., Comment: Accepted to the Journal of Astronomical Instrumentation (SOFIA Special Edition) on 11th November 2018

At a time when ALMA produces spectacular high resolution images of gas and dust in circumstellar disks, the next observational frontier in our understanding of planet formation and the chemistry of planet-forming material may be found in the mid- to far-infrared wavelength range. A large, actively cooled far-infrared telescope in space will offer enormous spectroscopic sensitivity improvements of 3-4 orders of magnitude, making it possible to uniquely survey certain fundamental properties of planet formation. Specifically, the Origins Space Telescope (OST), a NASA flagship concept to be submitted to the 2020 decadal survey, will provide a platform that allows complete surveys of warm and cold water around young stars of all masses and across all evolutionary stages, and to measure their total planet-forming gas mass using the ground-state line of HD. While this white paper is formulated in the context of the NASA Origins Space Telescope concept, it can be applied in general to inform any future space-based, cold far-infrared observatory., Comment: White paper submitted to The National Academies of Science, Engineering, and Medicine Exoplanet Science Strategy Committee

Pandeia is the exposure time calculator (ETC) system developed for the James Webb Space Telescope (JWST) that will be used for creating JWST proposals. It includes a simulation-hybrid Python engine that calculates the two-dimensional pixel-by-pixel signal and noise properties of the JWST instruments. This allows for appropriate handling of realistic point spread functions, MULTIACCUM detector readouts, correlated detector readnoise, and multiple photometric and spectral extraction strategies. Pandeia includes support for all the JWST observing modes, including imaging, slitted/slitless spectroscopy, integral field spectroscopy, and coronagraphy. Its highly modular, data-driven design makes it easily adaptable to other observatories. An implementation for use with WFIRST is also available.

We present deep Herschel-PACS spectroscopy of far-infrared water lines from a sample of four protoplanetary disks around solar-mass stars, selected to have strong water emission at mid-infrared wavelengths. By combining the new Herschel spectra with archival Spitzer-IRS spectroscopy, we retrieve a parameterized radial surface water vapor distribution from 0.1-100 AU using two-dimensional dust and line radiative transfer modeling. The surface water distribution is modeled with a step model comprising of a constant inner and outer relative water abundance and a critical radius at which the surface water abundance is allowed to change. We find that the four disks have critical radii of $\sim 3-11$ AU, at which the surface water abundance decreases by at least 5 orders of magnitude. The measured values for the critical radius are consistently smaller than the location of the surface snow line, as predicted by the observed spectral energy distribution. This suggests that the sharp drop-off of the surface water abundance is not solely due to the local gas-solid balance, but may also be driven by the de-activation of gas-phase chemical pathways to water below 300 K. Assuming a canonical gas-to-dust ratio of 100, as well as coupled gas and dust temperatures $T_{\rm gas}=T_{\rm dust}$, the best-fit inner water abundances become implausibly high (0.01-1.0 ${\rm H_{2}}^{-1}$). Conversely, a model in which the gas and dust temperatures are decoupled leads to canonical inner disk water abundances of $\sim 10^{-4} \rm H_{2}^{-1}$, while retaining gas-to-dust ratios of 100. That is, the evidence for gas-dust decoupling in disk surfaces is stronger than for enhanced gas-to-dust ratios.

Transitional disks around young stars are promising candidates to look for recently formed, embedded planets. Planet-disk interaction models predict that planets clear a gap in the gas while trapping dust at larger radii. Other physical mechanisms could be responsible for cavities as well. Previous observations have revealed that gas is still present inside these cavities, but the spatial distribution of this gas remains uncertain. We present high spatial resolution observations with the Atacama Large Millimeter/submillimeter Array (ALMA) of 13CO and C18O lines of four well-studied transitional disks. The observations are used to set constraints on the gas surface density, specifically cavity size and density drop inside the cavity. The physical-chemical model DALI is used to analyze the gas images of SR21, HD135344B, DoAr44 and IRS48. The main parameters of interest are the size, depth and shape of the gas cavity. CO isotope-selective photodissociation is included to properly constrain the surface density in the outer disk from C18O emission. The gas cavities are up to 3 times smaller than those of the dust in all four disks. Model fits indicate that the surface density inside the gas cavities decreases by a factor of 100-10000 compared with the surface density profile derived from the outer disk. A comparison with an analytical model of gap depths by planet-disk interaction shows that the disk viscosities are likely low, with a<1E-3 for planet masses <10 MJup. The resolved measurements of the gas and dust in transition disk cavities support the predictions of models that describe how planet-disk interactions sculpt gas disk structures and influence the evolution of dust grains. These observed structures strongly suggest the presence of giant planetary companions in transition disk cavities, although at smaller orbital radii than is typically indicated from the dust cavity radii alone., Comment: Accepted by A&A; version after language-editing

Molecular snow lines in protoplanetary disks have been studied theoretically for decades because of their importance in shaping planetary architectures and compositions. The water snow line lies in the planet formation region at < 10 AU, and so far its location has been estimated only indirectly from spatially-unresolved spectroscopy. This work presents a proof-of-concept method to directly image the water snow line in protoplanetary disks through its physical and chemical imprint in the local dust properties. We adopt a physical disk model that includes dust coagulation, fragmentation, drift, and a change in fragmentation velocities of a factor 10 between dry silicates and icy grains as found by laboratory work. We find that the presence of a water snow line leads to a sharp discontinuity in the radial profile of the dust emission spectral index {\alpha}_mm, due to replenishment of small grains through fragmentation. We use the ALMA simulator to demonstrate that this effect can be observed in protoplanetary disks using spatially-resolved ALMA images in two continuum bands. We explore the model dependence on the disk viscosity and find that the spectral index reveals the water snow line for a wide range of conditions, with opposite trends when the emission is optically thin rather than thick. If the disk viscosity is low ({\alpha}_visc < 10^-3) the snow line produces a ring-like structure with a minimum at {\alpha}_mm ~ 2 in the optically thick regime, possibly similar to what has been measured with ALMA in the innermost region of the HL Tau disk., Comment: 6 pages, 4 figures, accepted for publication in ApJ Letters

This study reports an unusual heterogeneity in [$^{12}$C$^{16}$O]/[$^{13}$C$^{16}$O] abundance ratios of carbon monoxide observed in the gas phase toward seven ~ solar-mass YSOs and three dense foreground clouds in the nearby star-forming regions, Ophiuchus, Corona Australis, Orion, Vela and an isolated core, L43. Robust isotope ratios were derived using infrared absorption spectroscopy of the 4.7 $\mu$m fundamental and 2.3 $\mu$m overtone rovibrational bands of CO at very high resolution ($\lambda$/$\Delta$$\lambda\approx 95,000$), observed with the CRIRES spectrograph on the Very Large Telescope. We find [$^{12}$C$^{16}$O]/[$^{13}$C$^{16}$O] values ranging from ~ 85 to 165, significantly higher than those of the local interstellar medium (~ 65 to 69). These observations are evidence for isotopic heterogeneity in carbon reservoirs in solar-type YSO environments, and encourage the need for refined Galactic chemical evolution models to explain the $^{12}$C/$^{13}$C discrepancy between the solar system and local ISM. The oxygen isotope ratios are consistent with isotopologue-specific photodissociation by CO self-shielding toward the disks, VV CrA N and HL Tau, further substantiating models predicting CO self-shielding on disk surfaces. However, we find that CO self-shielding is an unlikely general explanation for the high [$^{12}$C$^{16}$O]/[$^{13}$C$^{16}$O] ratios observed in this study. Comparison of the solid CO against gas-phase [$^{12}$C$^{16}$O]/[$^{13}$C$^{16}$O] suggests that interactions between CO ice and gas reservoirs need to be further investigated as at least a partial explanation for the unusually high [$^{12}$C$^{16}$O]/[$^{13}$C$^{16}$O] observed., Comment: 16 pages, 14 figures, 7 tables. Accepted for publication in The Astrophysical Journal

We report a detection of water vapor in the protoplanetary disk around DoAr 44 with the Texas Echelon Cross Echelle Spectrograph --- a visitor instrument on the Gemini north telescope. The DoAr 44 disk consists of an optically thick inner ring and outer disk, separated by a dust-cleared 36 AU gap, and has therefore been termed "pre-transitional". To date, this is the only disk with a large inner gap known to harbor detectable quantities of warm (T=450 K) water vapor. In this work, we detect and spectrally resolve three mid-infrared pure rotational emission lines of water vapor from this source, and use the shapes of the emission lines to constrain the location of the water vapor. We find that the emission originates near 0.3 AU --- the inner disk region. This characteristic region coincides with that inferred for both optically thick and thin thermal infrared dust emission, as well as rovibrational CO emission. The presence of water in the dust-depleted region implies substantial columns of hydrogen (>10^{22} cm-2) as the water vapor would otherwise be destroyed by photodissociation. Combined with the dust modeling, this column implies a gas/small-dust ratio in the optically thin dusty region of >1000. These results demonstrate that DoAr 44 has maintained similar physical and chemical conditions to classical protoplanetary disks in its terrestrial-planet forming regions, in spite of having formed a large gap., Comment: Paper accepted to the Astrophysical Journal Letters

The Thirty Meter Telescope (TMT) International Observatory (TIO) will be a revolutionary leap forward in astronomical observing capabilities, enabling us to address some of the most profound questions about the universe. From unraveling the mysteries of dark matter and dark energy to exploring the origins of stars and planets, TMT will transform our understanding of the cosmos. The TIO Detailed Science Case (DSC) presents science goals that inform the top-level requirements for the observatory's design and operations, including the telescope, enclosure, instruments, and adaptive optics system., Comment: 275 pages. 2024 version. Updated from 2015 and 2022

Advances in infrared and submillimeter technology have allowed for detailed observations of the molecular content of the planet-forming regions of protoplanetary disks. In particular, disks around solar-type stars now have growing molecular inventories that can be directly compared with both prestellar chemistry and that inferred for the early solar nebula. The data directly address the old question whether the chemistry of planet-forming matter is similar or different and unique relative to the chemistry of dense clouds and protostellar envelopes. The answer to this question may have profound consequences for the structure and composition of planetary systems. The practical challenge is that observations of emission lines from disks do not easily translate into chemical concentrations. Here, we present a two-dimensional radiative transfer model of RNO 90, a classical protoplanetary disk around a solar-mass star, and retrieve the concentrations of dominant molecular carriers of carbon, oxygen and nitrogen in the terrestrial region around 1 AU. We compare our results to the chemical inventory of dense clouds and protostellar envelopes, and argue that inner disk chemistry is, as expected, fundamentally different from prestellar chemistry. We find that the clearest discriminant may be the concentration of CO$_2$, which is extremely low in disks, but one of the most abundant constituents of dense clouds and protostellar envelopes., Comment: 12 pages, 3 figures, accepted for publication in Faraday Discussions, volume 168

Volatiles are compounds with low sublimation temperatures, and they make up most of the condensible mass in typical planet-forming environments. They consist of relatively small, often hydrogenated, molecules based on the abundant elements carbon, nitrogen and oxygen. Volatiles are central to the process of planet formation, forming the backbone of a rich chemistry that sets the initial conditions for the formation of planetary atmospheres, and act as a solid mass reservoir catalyzing the formation of planets and planetesimals. This growth has been driven by rapid advances in observations and models of protoplanetary disks, and by a deepening understanding of the cosmochemistry of the solar system. Indeed, it is only in the past few years that representative samples of molecules have been discovered in great abundance throughout protoplanetary disks - enough to begin building a complete budget for the most abundant elements after hydrogen and helium. The spatial distributions of key volatiles are being mapped, snow lines are directly seen and quantified, and distinct chemical regions within protoplanetary disks are being identified, characterized and modeled. Theoretical processes invoked to explain the solar system record are now being observationally constrained in protoplanetary disks, including transport of icy bodies and concentration of bulk condensibles. The balance between chemical reset - processing of inner disk material strong enough to destroy its memory of past chemistry, and inheritance - the chemically gentle accretion of pristine material from the interstellar medium in the outer disk, ultimately determines the final composition of pre-planetary matter. This chapter focuses on making the first steps toward understanding whether the planet formation processes that led to our solar system are universal., Comment: Accepted for publication as a chapter in Protostars and Planets VI, University of Arizona Press (2014), eds. H. Beuther, R. Klessen, C. Dullemond, Th. Henning

Young stars are known to show variability due to non-steady mass accretion rate from their circumstellar disks. Accretion flares can produce strong energetic irradiation and heating that may affect the disk in the planet formation region, close to the central star. During an extreme accretion outburst in the young star EX Lupi, the prototype of EXor variables, remarkable changes in molecular gas emission from $\sim1$ AU in the disk have recently been observed (Banzatti et al. 2012). Here, we focus on water vapor and explore how it is affected by variable accretion luminosity in T Tauri stars. We monitored a young highly variable solar-mass star, DR Tau, using simultaneously two high/medium-resolution ESO-VLT spectrographs: VISIR at 12.4 $\mu$m to observe water lines from the disk, and X-shooter covering from 0.3 to 2.5 $\mu$m to constrain the stellar accretion. Three epochs spanning timescales from several days to several weeks were obtained. Accretion luminosity was estimated to change within a factor $\sim2$, and no change in water emission was detected at a significant level. In comparison to EX Lupi and EXor outbursts, DR Tau suggests that the less long-lived and weaker variability phenomena typical of T Tauri stars may leave water at planet-forming radii in the disk mostly unaffected. We propose that these systems may provide evidence for two processes that act over different timescales: UV photochemistry in the disk atmosphere (faster) and heating of the disk deeper layers (slower)., Comment: 8 pages, 7 figures, accepted for publication in The Astrophysical Journal

We present a large, comprehensive survey of rovibrational CO line emission at 4.7 micron from 69 protoplanetary disks, obtained with CRIRES on the ESO Very Large Telescope at the highest available spectral resolving power (R=95,000, v=3.2 km/s). The CO fundamental band (Delta v=1) is a well-known tracer of warm gas in the inner, planet-forming regions of gas-rich disks around young stars, with the lines formed in the super-heated surfaces of the disks at radii of 0.1-10 AU. Our high spectral resolution data provide new insight into the kinematics of the inner disk gas. Pure double-peaked Keplerian profiles are surprisingly uncommon, beyond the frequency expected based on disk inclination. The majority of the profiles are consistent with emission from a disk plus a slow (few km/s) molecular disk wind. This is evidenced by analysis of different categories as well as an overall tendency for line profiles to have excess blue emission. Weak emission lines from isotopologues and vibrationally excited levels are readily detected. In general, 13CO lines trace cooler gas than the bulk 12CO emission and may arise from further out in the disk, as indicated by narrower line profiles. A high fraction of the sources show vibrationally excited emission (~50%) which is correlated with accretion luminosity, consistent with ultra-violet (UV) fluorescent excitation. Disks around early-type Herbig AeBe stars have narrower lines, on average, than their lower-mass late-type counterparts, due to their increased luminosity. Evolutionary changes in CO are also seen. Removal of the protostellar envelope between class I and II results in the disappearance of the strong absorption lines and CO ice feature characteristic of class I spectra. However, CO emission from class I and II objects is similar in detection frequency, excitation and line shape, indicating that inner disk characteristics are established early., Comment: Accepted to ApJ

In this work, we introduce the use of H I Pfund-beta (4.6538 micron) as a tracer of mass accretion from protoplanetary disks onto young stars. Pf-beta was serendipitously observed in NIRSPEC and CRIRES surveys of CO fundamental emission, amounting to a sample size of 120 young stars with detected Pf-beta emission. Using a subsample of disks with previously measured accretion luminosities, we show that Pf-beta line luminosity is well correlated with accretion luminosity over a range of at least three orders of magnitude. We use this correlation to derive accretion luminosities for all 120 targets, 65 of which are previously unreported in the literature. We also report accretion rates for 67 targets, 16 previously unmeasured. Our large sample size and our ability to probe high extinction values allow for relatively unbiased comparisons between different types of disks. We find that the transitional disks in our sample have lower than average Pf-beta line luminosities, and thus accretion luminosities, at a marginally significant level. We also show that high Pf-beta equivalent width is a signature of transitional disks with high inner disk gas/dust ratios. In contrast, we find that disks with signatures of slow disk winds have Pf-beta luminosities comparable to those of other disks in our sample. Finally, we investigate accretion rates for stage I disks, including significantly embedded targets. We find that stage I and stage II disks have statistically indistinguishable Pf-beta line luminosities, implying similar accretion rates, and that the accretion rates of stage I disks are too low to be consistent with quiescent accretion. Our results are instead consistent with both observational and theoretical evidence that stage I objects experience episodic, rather than quiescent, accretion.

We find a trend between the mid-infrared HCN/H2O flux ratio and submillimeter disk mass among T Tauri stars in Taurus. While it may seem puzzling that the molecular emission properties of the inner disk (< few AU) are related to the properties of the outer disk (beyond ~20 AU) probed by the submillimeter continuum, an interesting possible interpretation is that the trend is a result of planetesimal and protoplanet formation. Because objects this large are decoupled from the accretion flow, when they form, they can lock up water (and oxygen) beyond the snow line, thereby enhancing the C/O ratio in the inner disk and altering the molecular abundances there. We discuss the assumptions that underlie this interpretation, a possible alternative explanation, and related open questions that motivate future work. Whatever its origin, understanding the meaning of the relation between the HCN/H2O ratio and disk mass is of interest as trends like this among T Tauri disk properties are relatively rare., Comment: 20 pages, 4 figures. To be published in the Astrophysical Journal

We report the detection of a unique CO2 ice band toward the deeply embedded, low-mass protostar HOPS-68. Our spectrum, obtained with the Infrared Spectrograph onboard the Spitzer Space Telescope, reveals a 15.2 micron CO2 ice bending mode profile that cannot modeled with the same ice structure typically found toward other protostars. We develop a modified CO2 ice profile decomposition, including the addition of new high-quality laboratory spectra of pure, crystalline CO2 ice. Using this model, we find that 87-92% of the CO2 is sequestered as spherical, CO2-rich mantles, while typical interstellar ices show evidence of irregularly-shaped, hydrogen-rich mantles. We propose that (1) the nearly complete absence of unprocessed ices along the line-of-sight is due to the flattened envelope structure of HOPS-68, which lacks cold absorbing material in its outer envelope, and possesses an extreme concentration of material within its inner (10 AU) envelope region and (2) an energetic event led to the evaporation of inner envelope ices, followed by cooling and re-condensation, explaining the sequestration of spherical, CO2 ice mantles in a hydrogen-poor mixture. The mechanism responsible for the sublimation could be either a transient accretion event or shocks in the interaction region between the protostellar outflow and envelope. The proposed scenario is consistent with the rarity of the observed CO2 ice profile, the formation of nearly pure CO2 ice, and the production of spherical ice mantles. HOPS-68 may therefore provide a unique window into the protostellar feedback process, as outflows and heating shape the physical and chemical structure of protostellar envelopes and molecular clouds., Comment: Accepted to the Astrophysical Journal, 2013 February 15: 14 pages, 9 figures, 3 tables

Spectral energy distributions are presented for 94 young stars surrounded by disks in the Serpens Molecular Cloud, based on photometry and Spitzer IRS spectra. Taking a distance to the cloud of 415 pc rather than 259 pc, the distribution of ages is shifted to lower values, in the 1-3 Myr range, with a tail up to 10 Myr. The mass distribution spans 0.2-1.2 Msun, with median mass of 0.7 Msun. The distribution of fractional disk luminosities in Serpens resembles that of the young Taurus Molecular Cloud, with most disks consistent with optically thick, passively irradiated disks in a variety of disk geometries (Ldisk/Lstar ~ 0.1). In contrast, the distributions for the older Upper Scorpius and Eta Chamaeleontis clusters are dominated by optically thin lower luminosity disks (Ldisk/Lstar ~ 0.02). This evolution in fractional disk luminosities is concurrent with that of disk fractions. The actively accreting and non-accreting stars (based on Ha data) in Serpens show very similar distributions in fractional disk luminosities, differing only in the brighter tail dominated by strongly accreting stars. In contrast with a sample of Herbig Ae/Be stars, the T Tauri stars in Serpens do not have a clear separation in fractional disk luminosities for different disk geometries: both flared and flat disks present wider, overlapping distributions. This result is consistent with previous suggestions of a faster evolution for disks around Herbig Ae/Be stars. Furthermore, the results for the mineralogy of the dust in the disk surface do not show any correlation to either stellar and disk characteristics or mean cluster age in the 1-10 Myr range probed here. A possible explanation for the lack of correlation is that the processes affecting the dust within disks have short timescales, happening repeatedly, making it difficult to distinguish long lasting evolutionary effects. [abridged], Comment: ApJ in press

We present Spitzer IRS spectroscopy of CO2 ice bending mode spectra at 15.2 micrometer toward 19 young stellar objects with luminosity lower than 1 Lsun (3 with luminosity lower than 0.1 Lsun). Ice on dust grain surfaces can encode the history of heating because pure CO2 ice forms only at elevated temperature, T > 20 K, and thus around protostars of higher luminosity. Current internal luminosities of YSOs with L < 1 Lsun do not provide the conditions needed to produce pure CO2 ice at radii where typical envelopes begin. The presence of detectable amounts of pure CO2 ice would signify a higher past luminosity. Many of the spectra require a contribution from a pure, crystalline CO2 component, traced by the presence of a characteristic band splitting in the 15.2 micrometer bending mode. About half of the sources (9 out of 19) in the low luminosity sample have evidence for pure CO2 ice, and six of these have significant double-peaked features, which are very strong evidence of pure CO2 ice. The presence of the pure CO2 ice component indicates that the dust temperature, and hence luminosity of the central star/accretion disk system, must have been higher in the past. An episodic accretion scenario, in which mixed CO-CO2 ice is converted to pure CO2 ice during each high luminosity phase, explains the presence of pure CO2 ice, the total amount of CO2 ice, and the observed residual C18O gas., Comment: Accepted for publication in ApJ, total 24 pages, 14 figures

During the embedded phase of pre-main sequence stellar evolution, a disk forms from the dense envelope while an accretion-driven outflow carves out a cavity within the envelope. Highly excited H2O emission in spatially unresolved Spitzer/IRS spectra of a low-mass Class 0 object, NGC 1333 IRAS 4B, has previously been attributed to the envelope-disk accretion shock but could instead be produced in an outflow. As part of the survey of low-mass sources in the Water in Star Forming Regions with Herschel (WISH-LM) program, we used Herschel/PACS to obtain a far-IR spectrum and several Nyquist-sampled spectral images with to determine the origin of excited H2O emission from NGC 1333 IRAS 4B. The spectrum has high signal-to-noise in a rich forest of H2O, CO, and OH lines, providing a near-complete census of far-IR molecular emission from a Class 0 protostar. The excitation diagrams for the three molecules all require fits with two excitation temperatures, indicating the presence of two physical components. The highly excited component of H2O emission is characterized by subthermal excitation of 1500 K gas with a density of 10^5 - 10^7 cm-3, conditions that also reproduce the mid-IR H2O emission detected by Spitzer. On the other hand, a high density, low temperature gas can reproduce the H2O spectrum observed by Spitzer but underpredicts the H2O lines seen by Herschel. Nyquist-sampled spectral maps of several lines show two spatial components of H2O emission, one centered at 1200 AU south of the central source at the position of the blueshifted outflow lobe and a second centered on-source. Both spatial components of the far-IR H2O emission are consistent with emission from the outflow. The gas cooling from the IRAS 4B envelope cavity walls is dominated by far-IR H2O emission, in contrast to stronger [O I] and CO cooling from more evolved protostars. [one sentence truncated], Comment: 24 total pages; accepted by A&A

The physical processes leading to the disappearance of disks around young stars are not well understood. A subclass of transitional disks, the so-called cold disks with large inner dust holes, provide a crucial laboratory for studying disk dissipation processes. IRS 48 has a 30 AU radius hole previously measured from dust continuum imaging at 18.7 micron. Using new optical spectra, we determine that IRS 48 is a pre-main sequence A0 star. In order to characterize this disk's gas distribution, we obtained AO-assisted VLT CRIRES high resolution (R ~100,000) spectra of the CO fundamental rovibrational band at 4.7 micron. All CO emission, including that from isotopologues and vibrationally excited molecules, is off-source and peaks at 30 AU. The gas is thermally excited to a rotational temperature of 260 K and is also strongly UV pumped, showing a vibrational excitation temperature of ~5000 K. We model the kinematics and excitation of the gas and posit that the CO emission arises from the dust hole wall. Prior imaging of UV-excited PAH molecules, usually a gas tracer, within the hole makes the large CO hole even more unexpected., Comment: 35 pages, 13 figures, accepted to ApJ

Icy grain mantles are commonly observed through infrared spectroscopy toward dense clouds, cloud cores, protostellar envelopes and protoplanetary disks. Up to 80% of the available oxygen, carbon and nitrogen are found in such ices; the most common ice constituents - H2O, CO2 and CO - are second in abundance only to H2 in many star forming regions. In addition to being a molecular reservoir, ice chemistry is responsible for much of the chemical evolution from H2O to complex, prebiotic molecules. Combining the existing ISO, Spitzer, VLT and Keck ice data results in a large sample of ice sources (\sime80) that span all stages of star formation and a large range of protostellar luminosities (<0.1-105 L\odot). Here we summarize the different techniques that have been applied to mine this ice data set on information on typical ice compositions in different environments and what this implies about how ices form and evolve during star and planet formation. The focus is on how to maximize the use of empirical constraints from ice observations, followed by the application of information from experiments and models. This strategy is used to identify ice bands and to constrain which ices form early during cloud formation, which form later in the prestellar core and which require protostellar heat and/or UV radiation to form. The utility of statistical tests, survival analysis and ice maps is highlighted; the latter directly reveals that the prestellar ice formation takes place in two phases, associated with H2O and CO ice formation, respectively, and that most protostellar ice variation can be explained by differences in the prestellar CO ice formation stage. Finally, special attention is paid to the difficulty of observing complex ices directly and how gas observations, experiments and models help in constraining this ice chemistry stage., Comment: 14 pages, including 13 figures. To appear in the proceedings of IAU Symposium 280: "The Molecular Universe"

Ices regulate much of the chemistry during star formation and account for up to 80% of the available oxygen and carbon. In this paper, we use the Spitzer c2d ice survey, complimented with data sets on ices in cloud cores and high-mass protostars, to determine standard ice abundances and to present a coherent picture of the evolution of ices during low- and high-mass star formation. The median ice composition H2O:CO:CO2:CH3OH:NH3:CH4:XCN is 100:29:29:3:5:5:0.3 and 100:13:13:4:5:2:0.6 toward low- and high-mass protostars, respectively, and 100:31:38:4:-:-:- in cloud cores. In the low-mass sample, the ice abundances with respect to H2O of CH4, NH3, and the component of CO2 mixed with H2O typically vary by <25%, indicative of co-formation with H2O. In contrast, some CO and CO2 ice components, XCN and CH3OH vary by factors 2-10 between the lower and upper quartile. The XCN band correlates with CO, consistent with its OCN- identification. The origin(s) of the different levels of ice abundance variations are constrained by comparing ice inventories toward different types of protostars and background stars, through ice mapping, analysis of cloud-to-cloud variations, and ice (anti-)correlations. Based on the analysis, the first ice formation phase is driven by hydrogenation of atoms, which results in a H2O-dominated ice. At later prestellar times, CO freezes out and variations in CO freeze-out levels and the subsequent CO-based chemistry can explain most of the observed ice abundance variations. The last important ice evolution stage is thermal and UV processing around protostars, resulting in CO desorption, ice segregation and formation of complex organic molecules. The distribution of cometary ice abundances are consistent with with the idea that most cometary ices have a protostellar origin., Comment: 48 pages, including 19 figures. Accepted for publication in ApJ